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In
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies th ...
, the island of stability is a predicted set of
isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s of
superheavy element Superheavy elements, also known as transactinide elements, transactinides, or super-heavy elements, or superheavies for short, are the chemical elements with atomic number greater than 104. The superheavy elements are those beyond the actinides in ...
s that may have considerably longer
half-lives Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * '' Half Life: A Parable for t ...
than known isotopes of these elements. It is predicted to appear as an "island" in the chart of nuclides, separated from known
stable A stable is a building in which working animals are kept, especially horses or oxen. The building is usually divided into stalls, and may include storage for equipment and feed. Styles There are many different types of stables in use tod ...
and long-lived
primordial radionuclide In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
s. Its theoretical existence is attributed to stabilizing effects of predicted " magic numbers" of
proton A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an e ...
s and
neutron The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
s in the superheavy mass region. Several predictions have been made regarding the exact location of the island of stability, though it is generally thought to center near
copernicium Copernicium is a synthetic chemical element; it has symbol Cn and atomic number 112. Its known isotopes are extremely radioactive, and have only been created in a laboratory. The most stable known isotope, copernicium-285, has a half-life of ap ...
and flerovium isotopes in the vicinity of the predicted closed neutron
shell Shell may refer to: Architecture and design * Shell (structure), a thin structure ** Concrete shell, a thin shell of concrete, usually with no interior columns or exterior buttresses Science Biology * Seashell, a hard outer layer of a marine ani ...
at ''N'' = 184. These models strongly suggest that the closed shell will confer further stability towards fission and
alpha decay Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
. While these effects are expected to be greatest near
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
''Z'' = 114 ( flerovium) and ''N'' = 184, the region of increased stability is expected to encompass several neighboring elements, and there may also be additional islands of stability around heavier nuclei that are doubly magic (having magic numbers of both protons and neutrons). Estimates of the stability of the nuclides within the island are usually around a half-life of minutes or days; some optimists propose half-lives on the order of millions of years. Although the nuclear shell model predicting magic numbers has existed since the 1940s, the existence of long-lived superheavy nuclides has not been definitively demonstrated. Like the rest of the superheavy elements, the nuclides within the island of stability have never been found in nature; thus, they must be created artificially in a
nuclear reaction In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two atomic nucleus, nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a t ...
to be studied. Scientists have not found a way to carry out such a reaction, for it is likely that new types of reactions will be needed to populate nuclei near the center of the island. Nevertheless, the successful synthesis of superheavy elements up to ''Z'' = 118 (
oganesson Oganesson is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint ...
) with up to 177 neutrons demonstrates a slight stabilizing effect around elements 110 to
114 114 may refer to: *114 (number) *AD 114 *114 BC *114 (1st London) Army Engineer Regiment, Royal Engineers, an English military unit *114 (Antrim Artillery) Field Squadron, Royal Engineers, a Northern Irish military unit *114 (MBTA bus) *114 (New Je ...
that may continue in heavier isotopes, consistent with the existence of the island of stability.


Introduction


Nuclide stability

The composition of a
nuclide Nuclides (or nucleides, from nucleus, also known as nuclear species) are a class of atoms characterized by their number of protons, ''Z'', their number of neutrons, ''N'', and their nuclear energy state. The word ''nuclide'' was coined by the A ...
(
atomic nucleus The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford at the Department_of_Physics_and_Astronomy,_University_of_Manchester , University of Manchester ...
) is defined by the number of protons ''Z'' and the number of neutrons ''N'', which sum to
mass number The mass number (symbol ''A'', from the German word: ''Atomgewicht'', "atomic weight"), also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is appro ...
''A''. Proton number ''Z'', also named the atomic number, determines the position of an element in the
periodic table The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows (" periods") and columns (" groups"). It is an icon of chemistry and is widely used in physics and other s ...
. The approximately 3300 known nuclides are commonly represented in a
chart A chart (sometimes known as a graph) is a graphics, graphical representation for data visualization, in which "the data is represented by symbols, such as bars in a bar chart, lines in a line chart, or slices in a pie chart". A chart can repres ...
with ''Z'' and ''N'' for its axes and the
half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...
for
radioactive decay Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
indicated for each unstable nuclide (see figure). , 251 nuclides are observed to be
stable A stable is a building in which working animals are kept, especially horses or oxen. The building is usually divided into stalls, and may include storage for equipment and feed. Styles There are many different types of stables in use tod ...
(having never been observed to decay); generally, as the number of protons increases, stable nuclei have a higher
neutron–proton ratio The neutron–proton ratio (N/Z ratio or nuclear ratio) of an atomic nucleus is the ratio of its number of neutrons to its number of protons. Among stable nuclei and naturally occurring nuclei, this ratio generally increases with increasing atomi ...
(more neutrons per proton). The last element in the periodic table that has a stable
isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
is
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
(''Z'' = 82), with stability (i.e., half-lives of the longest-lived isotopes) generally decreasing in heavier elements, especially beyond curium (''Z'' = 96). The half-lives of nuclei also decrease when there is a lopsided neutron–proton ratio, such that the resulting nuclei have too few or too many neutrons to be stable. The stability of a nucleus is determined by its
binding energy In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
, higher binding energy conferring greater stability. The binding energy per nucleon increases with atomic number to a broad plateau around ''A'' = 60, then declines. If a nucleus can be split into two parts that have a lower total energy (a consequence of the mass defect resulting from greater binding energy), it is unstable. The nucleus can hold together for a finite time because there is a potential barrier opposing the split, but this barrier can be crossed by
quantum tunneling In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This me ...
. The lower the barrier and the masses of the fragments, the greater the probability per unit time of a split. Protons in a nucleus are bound together by the
strong force In nuclear physics and particle physics, the strong interaction, also called the strong force or strong nuclear force, is one of the four known fundamental interactions. It confines quarks into protons, neutrons, and other hadron particles, an ...
, which counterbalances the Coulomb repulsion between positively charged protons. In heavier nuclei, larger numbers of uncharged neutrons are needed to reduce repulsion and confer additional stability. Even so, as physicists started to synthesize elements that are not found in nature, they found the stability decreased as the nuclei became heavier. Thus, they speculated that the periodic table might come to an end. The discoverers of
plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
(element 94) considered naming it "ultimium", thinking it was the last. Following the discoveries of heavier elements, of which some decayed in microseconds, it then seemed that instability with respect to
spontaneous fission Spontaneous fission (SF) is a form of radioactive decay in which a heavy atomic nucleus splits into two or more lighter nuclei. In contrast to induced fission, there is no inciting particle to trigger the decay; it is a purely probabilistic proc ...
would limit the existence of heavier elements. In 1939, an upper limit of potential element synthesis was estimated around element 104, and following the first discoveries of
transactinide element Superheavy elements, also known as transactinide elements, transactinides, or super-heavy elements, or superheavies for short, are the chemical elements with atomic number greater than 104. The superheavy elements are those beyond the actinides in ...
s in the early 1960s, this upper limit prediction was extended to element 108.


Magic numbers

As early as 1914, the possible existence of
superheavy element Superheavy elements, also known as transactinide elements, transactinides, or super-heavy elements, or superheavies for short, are the chemical elements with atomic number greater than 104. The superheavy elements are those beyond the actinides in ...
s with atomic numbers well beyond that of uranium—then the heaviest known element—was suggested, when German physicist Richard Swinne proposed that superheavy elements around ''Z'' = 108 were a source of radiation in
cosmic rays Cosmic rays or astroparticles are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar ...
. Although he did not make any definitive observations, he hypothesized in 1931 that
transuranium element The transuranium (or transuranic) elements are the chemical elements with atomic number greater than 92, which is the atomic number of uranium. All of them are radioactively unstable and decay into other elements. Except for neptunium and pluton ...
s around ''Z'' = 100 or ''Z'' = 108 may be relatively long-lived and possibly exist in nature. In 1955, American physicist
John Archibald Wheeler John Archibald Wheeler (July 9, 1911April 13, 2008) was an American theoretical physicist. He was largely responsible for reviving interest in general relativity in the United States after World War II. Wheeler also worked with Niels Bohr to e ...
also proposed the existence of these elements; he is credited with the first usage of the term "superheavy element" in a 1958 paper published with Frederick Werner. This idea did not attract wide interest until a decade later, after improvements in the
nuclear shell model In nuclear physics, atomic physics, and nuclear chemistry, the nuclear shell model utilizes the Pauli exclusion principle to model the structure of atomic nuclei in terms of energy levels. The first shell model was proposed by Dmitri Ivanenk ...
. In this model, the atomic nucleus is built up in "shells", analogous to
electron shell In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (o ...
s in atoms. Independently of each other, neutrons and protons have
energy level A quantum mechanics, quantum mechanical system or particle that is bound state, bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical mechanics, classical pa ...
s that are normally close together, but after a given shell is filled, it takes substantially more energy to start filling the next. Thus, the binding energy per nucleon reaches a local maximum and nuclei with filled shells are more stable than those without. This theory of a nuclear shell model originates in the 1930s, but it was not until 1949 that German physicists Maria Goeppert Mayer and Johannes Hans Daniel Jensen et al. independently devised the correct formulation. The numbers of nucleons for which shells are filled are called magic numbers. Magic numbers of 2, 8, 20, 28, 50, 82 and 126 have been observed for neutrons, and the next number is predicted to be 184. Protons share the first six of these magic numbers, and 126 has been predicted as a magic proton number since the 1940s. Nuclides with a magic number of each—such as 16O (''Z'' = 8, ''N'' = 8), 132Sn (''Z'' = 50, ''N'' = 82), and 208Pb (''Z'' = 82, ''N'' = 126)—are referred to as "doubly magic" and are more stable than nearby nuclides as a result of greater binding energies. In the late 1960s, more sophisticated shell models were formulated by American physicist William Myers and Polish physicist Władysław Świątecki, and independently by German physicist Heiner Meldner (1939–2019). With these models, taking into account Coulomb repulsion, Meldner predicted that the next proton magic number may be 114 instead of 126. Myers and Świątecki appear to have coined the term "island of stability", and American chemist Glenn Seaborg, later a discoverer of many of the superheavy elements, quickly adopted the term and promoted it. Myers and Świątecki also proposed that some superheavy nuclei would be longer-lived as a consequence of higher fission barriers. Further improvements in the nuclear shell model by Soviet physicist Vilen Strutinsky led to the emergence of the macroscopic–microscopic method, a nuclear mass model that takes into consideration both smooth trends characteristic of the liquid drop model and local fluctuations such as shell effects. This approach enabled Swedish physicist Sven Nilsson et al., as well as other groups, to make the first detailed calculations of the stability of nuclei within the island. With the emergence of this model, Strutinsky, Nilsson, and other groups argued for the existence of the doubly magic nuclide 298Fl (''Z'' = 114, ''N'' = 184), rather than 310 Ubh (''Z'' = 126, ''N'' = 184) which was predicted to be doubly magic as early as 1957. Subsequently, estimates of the proton magic number have ranged from 114 to 126, and there is still no consensus.


Discoveries

Interest in a possible island of stability grew throughout the 1960s, as some calculations suggested that it might contain nuclides with half-lives of billions of years. They were also predicted to be especially stable against spontaneous fission in spite of their high atomic mass. It was thought that if such elements exist and are sufficiently long-lived, there may be several novel applications as a consequence of their nuclear and chemical properties. These include use in
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel electric charge, charged particles to very high speeds and energies to contain them in well-defined particle beam, beams. Small accelerators are used for fundamental ...
s as
neutron source A neutron source is any device that emits neutrons, irrespective of the mechanism used to produce the neutrons. Neutron sources are used in physics, engineering, medicine, nuclear weapons, petroleum exploration, biology, chemistry, and nuclear p ...
s, in
nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission or atomic bomb) or a combination of fission and fusion reactions (thermonuclear weapon), producing a nuclear exp ...
s as a consequence of their predicted low
critical mass In nuclear engineering, critical mass is the minimum mass of the fissile material needed for a sustained nuclear chain reaction in a particular setup. The critical mass of a fissionable material depends upon its nuclear properties (specific ...
es and high number of neutrons emitted per fission, and as
nuclear fuel Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other atomic nucleus, nuclear devices to generate energy. Oxide fuel For fission reactors, the fuel (typically based on uranium) is ...
to power space missions. These speculations led many researchers to conduct searches for superheavy elements in the 1960s and 1970s, both in nature and through
nucleosynthesis Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons (protons and neutrons) and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in ...
in particle accelerators. During the 1970s, many searches for long-lived superheavy nuclei were conducted. Experiments aimed at synthesizing elements ranging in atomic number from 110 to 127 were conducted at laboratories around the world. These elements were sought in fusion-evaporation reactions, in which a heavy target made of one nuclide is
irradiated Irradiation is the process by which an object is exposed to radiation. An irradiator is a device used to expose an object to radiation, most often gamma radiation, for a variety of purposes. Irradiators may be used for sterilizing medical and p ...
by accelerated ions of another in a
cyclotron A cyclotron is a type of particle accelerator invented by Ernest Lawrence in 1929–1930 at the University of California, Berkeley, and patented in 1932. Lawrence, Ernest O. ''Method and apparatus for the acceleration of ions'', filed: Januar ...
, and new nuclides are produced after these nuclei fuse and the resulting excited system releases energy by evaporating several particles (usually protons, neutrons, or alpha particles). These reactions are divided into "cold" and "hot" fusion, which respectively create systems with lower and higher excitation energies; this affects the yield of the reaction. For example, the reaction between 248Cm and 40Ar was expected to yield isotopes of element 114, and that between 232Th and 84Kr was expected to yield isotopes of element 126. None of these attempts were successful, indicating that such experiments may have been insufficiently sensitive if reaction cross sections were low—resulting in lower yields—or that any nuclei reachable via such fusion-evaporation reactions might be too short-lived for detection. Subsequent successful experiments reveal that half-lives and cross sections indeed decrease with increasing atomic number, resulting in the synthesis of only a few short-lived atoms of the heaviest elements in each experiment; , the highest reported cross section for a superheavy nuclide near the island of stability is for 288Mc in the reaction between 243Am and 48Ca. Similar searches in nature were also unsuccessful, suggesting that if superheavy elements do exist in nature, their abundance is less than 10−14 moles of superheavy elements per mole of ore. Despite these unsuccessful attempts to observe long-lived superheavy nuclei, new superheavy elements were synthesized every few years in laboratories through light-ion bombardment and cold fusion reactions; rutherfordium, the first transactinide, was discovered in 1969, and copernicium, eight protons closer to the island of stability predicted at ''Z'' = 114, was reached by 1996. Even though the half-lives of these nuclei are very short (on the order of
second The second (symbol: s) is a unit of time derived from the division of the day first into 24 hours, then to 60 minutes, and finally to 60 seconds each (24 × 60 × 60 = 86400). The current and formal definition in the International System of U ...
s), the very existence of elements heavier than rutherfordium is indicative of stabilizing effects thought to be caused by closed shells; a model not considering such effects would forbid the existence of these elements due to rapid spontaneous fission. Flerovium, with the expected magic 114 protons, was first synthesized in 1998 at the Joint Institute for Nuclear Research in
Dubna Dubna ( rus, Дубна́, p=dʊbˈna) is a town in Moscow Oblast, Russia. It has a status of '' naukograd'' (i.e. town of science), being home to the Joint Institute for Nuclear Research, an international nuclear physics research center and o ...
, Russia, by a group of physicists led by
Yuri Oganessian Yuri Tsolakovich Oganessian (born 14 April 1933) is an Armenian and Russian nuclear physicist who is best known as a researcher of superheavy elements. He has led the discovery of multiple chemical elements. He succeeded Georgy Flyorov as dir ...
. A single atom of element 114 was detected, with a lifetime of 30.4 seconds, and its
decay product In nuclear physics, a decay product (also known as a daughter product, daughter isotope, radio-daughter, or daughter nuclide) is the remaining nuclide left over from radioactive decay. Radioactive decay often proceeds via a sequence of steps ( d ...
s had half-lives measurable in minutes. Because the produced nuclei underwent alpha decay rather than fission, and the half-lives were several
orders of magnitude In a ratio scale based on powers of ten, the order of magnitude is a measure of the nearness of two figures. Two numbers are "within an order of magnitude" of each other if their ratio is between 1/10 and 10. In other words, the two numbers are wi ...
longer than those previously predicted or observed for superheavy elements, this event was seen as a "textbook example" of a decay chain characteristic of the island of stability, providing strong evidence for the existence of the island of stability in this region. Even though the original 1998 chain was not observed again, and its assignment remains uncertain, further successful experiments in the next two decades led to the discovery of all elements up to
oganesson Oganesson is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint ...
, whose half-lives were found to exceed initially predicted values; these decay properties further support the presence of the island of stability. However, a 2021 study on the decay chains of flerovium isotopes suggests that there is no strong stabilizing effect from ''Z'' = 114 in the region of known nuclei (''N'' = 174), and that extra stability would be predominantly a consequence of the neutron shell closure. Although known nuclei still fall several neutrons short of ''N'' = 184 where maximum stability is expected (the most neutron-rich confirmed nuclei, 293Lv and 294Ts, only reach ''N'' = 177), and the exact location of the center of the island remains unknown, the trend of increasing stability closer to ''N'' = 184 has been demonstrated. For example, the isotope 285Cn, with eight more neutrons than 277Cn, has a half-life almost five orders of magnitude longer. This trend is expected to continue into unknown heavier isotopes in the vicinity of the shell closure.


Deformed nuclei

Though nuclei within the island of stability around ''N'' = 184 are predicted to be spherical, studies from the early 1990s—beginning with Polish physicists Zygmunt Patyk and Adam Sobiczewski in 1991—suggest that some superheavy elements do not have perfectly spherical nuclei. A change in the shape of the nucleus changes the position of neutrons and protons in the shell. Research indicates that large nuclei farther from spherical magic numbers are deformed, causing magic numbers to shift or new magic numbers to appear. Current theoretical investigation indicates that in the region ''Z'' = 106–108 and ''N'' ≈ 160–164, nuclei may be more resistant to fission as a consequence of shell effects for deformed nuclei; thus, such superheavy nuclei would only undergo alpha decay. Hassium-270 is now believed to be a doubly magic deformed nucleus, with deformed magic numbers ''Z'' = 108 and ''N'' = 162. It has a half-life of 9 seconds. This is consistent with models that take into account the deformed nature of nuclei intermediate between the actinides and island of stability near ''N'' = 184, in which a stability "peninsula" emerges at deformed magic numbers ''Z'' = 108 and ''N'' = 162. Determination of the decay properties of neighboring hassium and seaborgium isotopes near ''N'' = 162 provides further strong evidence for this region of relative stability in deformed nuclei. This also strongly suggests that the island of stability (for spherical nuclei) is not completely isolated from the region of stable nuclei, but rather that both regions are instead linked through an isthmus of relatively stable deformed nuclei.


Predicted decay properties

The
half-lives Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * '' Half Life: A Parable for t ...
of nuclei in the island of stability itself are unknown since none of the nuclides that would be "on the island" have been observed. Many physicists believe that the half-lives of these nuclei are relatively short, on the order of minutes or days. Some theoretical calculations indicate that their half-lives may be long, on the order of 100 years, or possibly as long as 109 years. The shell closure at ''N'' = 184 is predicted to result in longer partial half-lives for alpha decay and spontaneous fission. It is believed that the shell closure will result in higher fission barriers for nuclei around 298Fl, strongly hindering fission and perhaps resulting in fission half-lives 30 orders of magnitude greater than those of nuclei unaffected by the shell closure. For example, the neutron-deficient isotope 284Fl (with ''N'' = 170) undergoes fission with a half-life of 2.5 milliseconds, and is thought to be one of the most neutron-deficient nuclides with increased stability in the vicinity of the ''N'' = 184 shell closure. Beyond this point, some undiscovered isotopes are predicted to undergo fission with still shorter half-lives, limiting the existence and possible observation of superheavy nuclei far from the island of stability (namely for ''N'' < 170 as well as for ''Z'' > 120 and ''N'' > 184). These nuclei may undergo alpha decay or spontaneous fission in microseconds or less, with some fission half-lives estimated on the order of 10−20 seconds in the absence of fission barriers. In contrast, 298Fl (predicted to lie within the region of maximum shell effects) may have a much longer spontaneous fission half-life, possibly on the order of 1019 years. In the center of the island, there may be competition between alpha decay and spontaneous fission, though the exact ratio is model-dependent. The alpha decay half-lives of 1700 nuclei with 100 ≤ ''Z'' ≤ 130 have been calculated in a quantum tunneling model with both experimental and theoretical alpha decay Q-values, and are in agreement with observed half-lives for some of the heaviest isotopes. The longest-lived nuclides are also predicted to lie on the
beta-stability line Beta-decay stable isobars are the set of nuclides which cannot undergo beta decay, that is, the transformation of a neutron to a proton or a proton to a neutron within the nucleus. A subset of these nuclides are also stable with regards to dou ...
, for
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
is predicted to compete with the other decay modes near the predicted center of the island, especially for isotopes of elements 111–115. Unlike other decay modes predicted for these nuclides, beta decay does not change the mass number. Instead, a neutron is converted into a proton or vice versa, producing an adjacent isobar closer to the center of stability (the isobar with the lowest mass excess). For example, significant beta decay branches may exist in nuclides such as 291Fl and 291Nh; these nuclides have only a few more neutrons than known nuclides, and might decay via a "narrow pathway" towards the center of the island of stability. The possible role of beta decay is highly uncertain, as some isotopes of these elements (such as 290Fl and 293Mc) are predicted to have shorter partial half-lives for alpha decay. Beta decay would reduce competition and would result in alpha decay remaining the dominant decay channel, unless additional stability towards alpha decay exists in superdeformed isomers of these nuclides. Considering all decay modes, various models indicate a shift of the center of the island (i.e., the longest-living nuclide) from 298Fl to a lower atomic number, and competition between alpha decay and spontaneous fission in these nuclides; these include 100-year half-lives for 291Cn and 293Cn, a 1000-year half-life for 296Cn, a 300-year half-life for 294Ds, and a 3500-year half-life for 293Ds, with 294Ds and 296Cn exactly at the ''N'' = 184 shell closure. It has also been posited that this region of enhanced stability for elements with 112 ≤ ''Z'' ≤ 118 may instead be a consequence of nuclear deformation, and that the true center of the island of stability for spherical superheavy nuclei lies around 306 Ubb (''Z'' = 122, ''N'' = 184). This model defines the island of stability as the region with the greatest resistance to fission rather than the longest total half-lives; the nuclide 306Ubb is still predicted to have a short half-life with respect to alpha decay. The island of stability for spherical nuclei may also be a "coral reef" (i.e., a broad region of increased stability without a clear "peak") around ''N'' = 184 and 114 ≤ ''Z'' ≤ 120, with half-lives rapidly decreasing at higher atomic number, due to combined effects from proton and neutron shell closures. Another potentially significant decay mode for the heaviest superheavy elements was proposed to be
cluster decay Cluster decay, also named heavy particle radioactivity, heavy ion radioactivity or heavy cluster decay," is a rare type of nuclear decay in which an atomic nucleus emits a small "cluster" of neutrons and protons, more than in an alpha particle, ...
by Romanian physicists Dorin N. Poenaru and Radu A. Gherghescu and German physicist
Walter Greiner Walter Greiner (29 October 1935 – 6 October 2016) was a German theoretical physicist and professor of the Goethe University Frankfurt. His research interests lay in atomic physics, heavy ion physics, nuclear physics, elementary particle physic ...
. Its branching ratio relative to alpha decay is expected to increase with atomic number such that it may compete with alpha decay around ''Z'' = 120, and perhaps become the dominant decay mode for heavier nuclides around ''Z'' = 124. As such, it is expected to play a larger role beyond the center of the island of stability (though still influenced by shell effects), unless the center of the island lies at a higher atomic number than predicted.


Possible natural occurrence

Even though half-lives of hundreds or thousands of years would be relatively long for superheavy elements, they are far too short for any such nuclides to exist primordially on Earth. Additionally, instability of nuclei intermediate between primordial actinides ( 232Th, 235U, and 238U) and the island of stability may inhibit production of nuclei within the island in ''r''-process nucleosynthesis. Various models suggest that spontaneous fission will be the dominant decay mode of nuclei with ''A'' > 280, and that neutron-induced or beta-delayed fission—respectively neutron capture and beta decay immediately followed by fission—will become the primary reaction channels. As a result, beta decay towards the island of stability may only occur within a very narrow path or may be entirely blocked by fission, thus precluding the synthesis of nuclides within the island. The non-observation of superheavy nuclides such as 292Hs and 298Fl in nature is thought to be a consequence of a low yield in the ''r''-process resulting from this mechanism, as well as half-lives too short to allow measurable quantities to persist in nature. Various studies utilizing accelerator mass spectroscopy and crystal scintillators have reported upper limits of the natural abundance of such long-lived superheavy nuclei on the order of relative to their stable homologs. Despite these obstacles to their synthesis, a 2013 study published by a group of Russian physicists led by Valeriy Zagrebaev proposes that the longest-lived copernicium isotopes may occur at an abundance of 10−12 relative to lead, whereby they may be detectable in
cosmic ray Cosmic rays or astroparticles are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the ...
s. Similarly, in a 2013 experiment, a group of Russian physicists led by Aleksandr Bagulya reported the possible observation of three cosmogenic superheavy nuclei in
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
crystals in meteorites. The atomic number of these nuclei was estimated to be between 105 and 130, with one nucleus likely constrained between 113 and 129, and their lifetimes were estimated to be at least 3,000 years. Although this observation has yet to be confirmed in independent studies, it strongly suggests the existence of the island of stability, and is consistent with theoretical calculations of half-lives of these nuclides. The decay of heavy, long-lived elements in the island of stability is a proposed explanation for the unusual presence of the short-lived radioactive isotopes observed in Przybylski's Star.


Synthesis and difficulties

The manufacture of nuclei on the island of stability proves to be very difficult because the nuclei available as starting materials do not deliver the necessary sum of neutrons. Radioactive ion beams (such as 44S) in combination with actinide targets (such as 248 Cm) may allow the production of more neutron rich nuclei nearer to the center of the island of stability, though such beams are not currently available in the required intensities to conduct such experiments. Several heavier isotopes such as 250Cm and 254 Es may still be usable as targets, allowing the production of isotopes with one or two more neutrons than known isotopes, though the production of several milligrams of these rare isotopes to create a target is difficult. It may also be possible to probe alternative reaction channels in the same 48Ca-induced fusion-evaporation reactions that populate the most neutron-rich known isotopes, namely those at a lower excitation energy (resulting in fewer neutrons being emitted during de-excitation), or those involving evaporation of charged particles (''pxn'', evaporating a proton and several neutrons, or ''αxn'', evaporating an
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
and several neutrons). This may allow the synthesis of neutron-enriched isotopes of elements 111–117. Although the predicted cross sections are on the order of 1–900  fb, smaller than when only neutrons are evaporated (''xn'' channels), it may still be possible to generate otherwise unreachable isotopes of superheavy elements in these reactions. Some of these heavier isotopes (such as 291Mc, 291Fl, and 291Nh) may also undergo
electron capture Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Th ...
(converting a proton into a neutron) in addition to alpha decay with relatively long half-lives, decaying to nuclei such as 291Cn that are predicted to lie near the center of the island of stability. However, this remains largely hypothetical as no superheavy nuclei near the beta-stability line have yet been synthesized and predictions of their properties vary considerably across different models. In 2024, a team of researchers at the JINR observed one decay chain of the known isotope 289Mc as a product in the ''p2n'' channel of the reaction between 242Pu and 50Ti, an experiment targeting neutron-deficient livermorium isotopes. This was the first successful report of a charged-particle exit channel in a hot fusion reaction between an actinide target and a projectile with ''Z'' ≥ 20. The process of slow
neutron capture Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, wh ...
used to produce nuclides as heavy as 257 Fm is blocked by short-lived
isotopes of fermium Fermium (100Fm) is a synthetic element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be discovered (in fallout from nuclear testing) was 255Fm in 1952. 250Fm w ...
that undergo spontaneous fission (for example, 258Fm has a half-life of 370 μs); this is known as the "fermium gap" and prevents the synthesis of heavier elements in such a reaction. It might be possible to bypass this gap, as well as another predicted region of instability around ''A'' = 275 and ''Z'' = 104–108, in a series of controlled nuclear explosions with a higher neutron flux (about a thousand times greater than fluxes in existing reactors) that mimics the astrophysical ''r''-process. First proposed in 1972 by Meldner, such a reaction might enable the production of macroscopic quantities of superheavy elements within the island of stability; the role of fission in intermediate superheavy nuclides is highly uncertain, and may strongly influence the yield of such a reaction. It may also be possible to generate isotopes in the island of stability such as 298Fl in multi-nucleon transfer reactions in low-energy collisions of
actinide The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
nuclei (such as 238U and 248Cm). This inverse quasifission (partial fusion followed by fission, with a shift away from mass equilibrium that results in more asymmetric products) mechanism may provide a path to the island of stability if shell effects around ''Z'' = 114 are sufficiently strong, though lighter elements such as
nobelium Nobelium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol No and atomic number 102. It is named after Alfred Nobel, the inventor of dynamite and benefactor of science. A radioactive metal, it is the tenth transura ...
and seaborgium (''Z'' = 102–106) are predicted to have higher yields. Preliminary studies of the 238U + 238U and 238U + 248Cm transfer reactions have failed to produce elements heavier than
mendelevium Mendelevium is a synthetic chemical element; it has symbol Md ( formerly Mv) and atomic number 101. A metallic radioactive transuranium element in the actinide series, it is the first element by atomic number that currently cannot be produced ...
(''Z'' = 101), though the increased yield in the latter reaction suggests that the use of even heavier targets such as 254Es (if available) may enable production of superheavy elements. This result is supported by a later calculation suggesting that the yield of superheavy nuclides (with ''Z'' ≤ 109) will likely be higher in transfer reactions using heavier targets. A 2018 study of the 238U + 232Th reaction at the
Texas A&M Texas A&M University (Texas A&M, A&M, TA&M, or TAMU) is a public university, public, Land-grant university, land-grant, research university in College Station, Texas, United States. It was founded in 1876 and became the flagship institution of ...
Cyclotron Institute by Sara Wuenschel et al. found several unknown alpha decays that may possibly be attributed to new, neutron-rich isotopes of superheavy elements with 104 < ''Z'' < 116, though further research is required to unambiguously determine the atomic number of the products. This result strongly suggests that shell effects have a significant influence on cross sections, and that the island of stability could possibly be reached in future experiments with transfer reactions.


Other islands of stability

Further shell closures beyond the main island of stability in the vicinity of ''Z'' = 112–114 may give rise to additional islands of stability. Although predictions for the location of the next magic numbers vary considerably, two significant islands are thought to exist around heavier doubly magic nuclei; the first near 354126 (with 228 neutrons) and the second near 472164 or 482164 (with 308 or 318 neutrons). Nuclides within these two islands of stability might be especially resistant to spontaneous fission and have alpha decay half-lives measurable in years, thus having comparable stability to elements in the vicinity of flerovium. Other regions of relative stability may also appear with weaker proton shell closures in beta-stable nuclides; such possibilities include regions near 342126 and 462154. Substantially greater
electromagnetic repulsion In physics, electromagnetism is an interaction that occurs between particles with electric charge via electromagnetic fields. The electromagnetic force is one of the four fundamental forces of nature. It is the dominant force in the interacti ...
between protons in such heavy nuclei may greatly reduce their stability, and possibly restrict their existence to localized islands in the vicinity of shell effects. This may have the consequence of isolating these islands from the main chart of nuclides, as intermediate nuclides and perhaps elements in a "sea of instability" would rapidly undergo fission and essentially be nonexistent. It is also possible that beyond a region of relative stability around element 126, heavier nuclei would lie beyond a fission threshold given by the liquid drop model and thus undergo fission with very short lifetimes, rendering them essentially nonexistent even in the vicinity of greater magic numbers. It has also been posited that in the region beyond ''A'' > 300, an entire " continent of stability" consisting of a hypothetical phase of stable quark matter, comprising freely flowing up and down quarks rather than
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nucleus, atomic nuclei ...
s bound into protons and neutrons, may exist. Such a form of matter is theorized to be a ground state of
baryonic matter In particle physics, a baryon is a type of composite subatomic particle that contains an odd number of valence quarks, conventionally three. Protons and neutrons are examples of baryons; because baryons are composed of quarks, they belong to ...
with a greater binding energy per
baryon In particle physics, a baryon is a type of composite particle, composite subatomic particle that contains an odd number of valence quarks, conventionally three. proton, Protons and neutron, neutrons are examples of baryons; because baryons are ...
than
nuclear matter Nuclear matter is an idealized system of interacting nucleons (protons and neutrons) that exists in several phase (matter), phases of exotic matter that, as of yet, are not fully established. It is ''not'' matter in an atomic nucleus, but a ...
, favoring the decay of nuclear matter beyond this mass threshold into quark matter. If this state of matter exists, it could possibly be synthesized in the same fusion reactions leading to normal superheavy nuclei, and would be stabilized against fission as a consequence of its stronger binding that is enough to overcome Coulomb repulsion.


See also

* Island of inversion * Table of nuclides


Notes


References


Bibliography

* * * * *


External links


Island ahoy!
(''Nature'', 2006, with JINR diagram of heavy nuclides and predicted island of stability)
Can superheavy elements (such as ''Z'' = 116 or 118) be formed in a supernova? Can we observe them?
(''Cornell'', 2004 – "maybe")
Second postcard from the island of stability
(''CERN'', 2001; nuclides with 116 protons and mass 292)
First postcard from the island of nuclear stability
(''CERN'', 1999; first few ''Z'' = 114 atoms) {{featured article Isotopes Periodic table Hypothetical chemical elements Radioactivity Nuclear physics