
Solid is a
state of matter
In physics, a state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid, liquid, gas, and Plasma (physics), plasma.
Different states are distinguished by the ways the ...
where
molecules
A molecule is a group of two or more atoms that are held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemistry ...
are closely packed and can not slide past each other. Solids resist compression, expansion, or external forces that would alter its shape, with the degree to which they are resisted dependent upon the specific material under consideration. Solids also always possess the least amount of kinetic energy per atom/molecule relative to other phases
or, equivalently stated, solids are formed when matter in the liquid / gas phase is cooled below a certain temperature. This temperature is called the
melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state of matter, state from solid to liquid. At the melting point the solid and liquid phase (matter), phase exist in Thermodynamic equilib ...
of that substance and is an
intrinsic property, i.e. independent of how much of the matter there is. All matter in solids can be arranged on a microscopic scale under certain conditions.
Solids are characterized by
structural rigidity and resistance to applied external forces and pressure.
Unlike liquids, solids do not flow to take on the shape of their container, nor do they expand to fill the entire available volume like a gas. Much like the other three fundamental phases, solids also
expand when heated, the thermal energy put into increasing the distance and reducing the
potential energy
In physics, potential energy is the energy of an object or system due to the body's position relative to other objects, or the configuration of its particles. The energy is equal to the work done against any restoring forces, such as gravity ...
between atoms. However, solids do this to a much lesser extent. When heated to their melting point or
sublimation point, solids melt into a liquid or
sublimate directly into a gas, respectively. For solids that directly
sublimate into a gas, the melting point is replaced by the sublimation point. As a rule of thumb, melting will occur if the subjected pressure is higher than the substance's
triple point
In thermodynamics, the triple point of a substance is the temperature and pressure at which the three Phase (matter), phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium.. It is that temperature and pressure at ...
pressure,
and sublimation will occur otherwise. Melting and melting points refer exclusively to transitions between solids and liquids. Melting occurs across a great extent of temperatures, ranging from 0.10 K for
helium-3
Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron. (In contrast, the most common isotope, helium-4, has two protons and two neutrons.) Helium-3 and hydrogen-1 are the only stable nuclides with ...
under 30 bars (3 MPa) of pressure, to around 4,200 K at 1 atm for the composite
refractory
In materials science, a refractory (or refractory material) is a material that is resistant to decomposition by heat or chemical attack and that retains its strength and rigidity at high temperatures. They are inorganic, non-metallic compound ...
material
hafnium carbonitride.
The atoms in a solid are tightly bound to each other in one of two ways: regular
geometric lattices called
crystalline solids (e.g. metals,
water ice), or irregular arrangements called
amorphous solids
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymo ...
(e.g. glass, plastic).
Molecules and atoms forming crystalline lattices usually organize themselves in a few well-characterized packing structures,
such as body-centered cubic. The adopted structure can and will vary between various pressures and temperatures, as can be seen in
phase diagrams of the material (e.g.
that of water, see left and upper). When the material is composed of a single species of atom/molecule, the phases are designated as
allotropes
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: th ...
for atoms (e.g.
diamond
Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
/
graphite
Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...
for
carbon
Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
), and as
polymorphs (e.g. calcite / aragonite for
calcium carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
) for molecules.
Non-
porous solids invariably strongly resist any amount of
compression that would otherwise result in a decrease of total
volume
Volume is a measure of regions in three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch) ...
regardless of temperature,
[DEGENERACY PRESSURE IN A SOLID](_blank)
/ref> owing to the mutual-repulsion of neighboring electron clouds among its constituent atoms. In contrast to solids, gases are very easily compressed as the molecules in a gas are far apart with few intermolecular interactions. Some solids, especially metallic alloys, can be deformed or pulled apart with enough force. The degree to which this solid resists deformation in differing directions and axes are quantified by the elastic modulus
An elastic modulus (also known as modulus of elasticity (MOE)) is a quantity that describes an object's or substance's resistance to being deformed elastically (i.e., non-permanently) when a stress is applied to it.
Definition
The elastic modu ...
, tensile strength
Ultimate tensile strength (also called UTS, tensile strength, TS, ultimate strength or F_\text in notation) is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials, the ultimate ...
, specific strength, as well as other measurable quantities.
For the vast majority of substances, the solid phases have the highest density
Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
, moderately higher than that of the liquid phase (if there exists one), and solid blocks of these materials will sink below their liquids. Exceptions include water ( icebergs), gallium
Gallium is a chemical element; it has Chemical symbol, symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in 1875,
elemental gallium is a soft, silvery metal at standard temperature and pressure. ...
, and plutonium
Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
. All naturally occurring elements on the periodic table has a melting point at standard atmospheric pressure, with three exceptions: the noble gas
The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of Group (periodic table), group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some ...
helium
Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
, which remains a liquid even at absolute zero owing to zero-point energy
Zero-point energy (ZPE) is the lowest possible energy that a quantum mechanical system may have. Unlike in classical mechanics, quantum systems constantly Quantum fluctuation, fluctuate in their lowest energy state as described by the Heisen ...
; the metalloid
A metalloid is a chemical element which has a preponderance of material property, properties in between, or that are a mixture of, those of metals and Nonmetal (chemistry), nonmetals. The word metalloid comes from the Latin language, Latin ''meta ...
arsenic
Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...
, sublimating around 900 K; and the life-forming element carbon, which sublimates around 3,950 K.
When applied pressure is released, solids will (very) rapidly re-expand and release the stored energy in the process in a manner somewhat similar to those of gases. An example of this is the (oft-attempted) confinement of freezing water in an inflexible container (of steel, for example). The gradual freezing results in an increase in volume, as ice is less dense than water. With no additional volume to expand into, water ice subjects the interior to intense pressures, causing the container to explode with great force.
Solids' properties on a macroscopic scale can also depend on whether it is contiguous or not. Contiguous (non-aggregate) solids are characterized by structural rigidity (as in rigid bodies) and strong resistance to applied forces. For solids aggregates (e.g. gravel, sand, dust on lunar surface), solid particles can easily slip past one another, though changes of individual particles (quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
particles for sand) will still be greatly hindered. This leads to a perceived softness and ease of compression by operators. An illustrating example is the non-firmness of coastal sandand of the lunar regolith.
The branch of physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
that deals with solids is called solid-state physics
Solid-state physics is the study of rigid matter, or solids, through methods such as solid-state chemistry, quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state phy ...
, and is a major branch of condensed matter physics
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid State of matter, phases, that arise from electromagnetic forces between atoms and elec ...
(which includes liquids). Materials science
Materials science is an interdisciplinary field of researching and discovering materials. Materials engineering is an engineering field of finding uses for materials in other fields and industries.
The intellectual origins of materials sci ...
, also one of its numerous branches, is primarily concerned with the way in which a solid's composition and its properties are intertwined.
Microscopic description
The atoms, molecules or ions that make up solids may be arranged in an orderly repeating pattern, or irregularly. Materials whose constituents are arranged in a regular pattern are known as crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s. In some cases, the regular ordering can continue unbroken over a large scale, for example diamonds, where each diamond is a single crystal
In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no Grain boundary, grain bound ...
. Solid objects that are large enough to see and handle are rarely composed of a single crystal, but instead are made of a large number of single crystals, known as crystallite
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
Bacillite is a type of crystallite. It is rodlike with parallel Wikt:longulite ...
s, whose size can vary from a few nanometers to several meters. Such materials are called polycrystal
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
Bacillite is a type of crystallite. It is rodlike with parallel longulites.
S ...
line. Almost all common metals, and many ceramic
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...
s, are polycrystalline.
In other materials, there is no long-range order in the position of the atoms. These solids are known as amorphous solid
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...
s; examples include polystyrene
Polystyrene (PS) is a synthetic polymer made from monomers of the aromatic hydrocarbon styrene. Polystyrene can be solid or foamed. General-purpose polystyrene is clear, hard, and brittle. It is an inexpensive resin per unit weight. It i ...
and glass.
Whether a solid is crystalline or amorphous depends on the material involved, and the conditions in which it was formed. Solids that are formed by slow cooling will tend to be crystalline, while solids that are frozen rapidly are more likely to be amorphous. Likewise, the specific crystal structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ...
adopted by a crystalline solid depends on the material involved and on how it was formed.
While many common objects, such as an ice cube or a coin, are chemically identical throughout, many other common materials comprise a number of different substances packed together. For example, a typical rock is an aggregate of several different minerals and mineraloid
A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
s, with no specific chemical composition. Wood is a natural organic material consisting primarily of cellulose
Cellulose is an organic compound with the chemical formula, formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of glycosidic bond, β(1→4) linked glucose, D-glucose units. Cellulose is an important s ...
fibers embedded in a matrix of organic lignin
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidit ...
. In materials science, composites of more than one constituent material can be designed to have desired properties.
Classes of solids
The forces between the atoms in a solid can take a variety of forms. For example, a crystal of sodium chloride
Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs a ...
(common salt) is made up of ionic sodium
Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
and chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
, which are held together by ionic bond
Ionic bonding is a type of chemical bond
A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic ...
s. In diamond or silicon, the atoms share electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s and form covalent bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atom ...
s. In metals, electrons are shared in metallic bond
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be descr ...
ing. Some solids, particularly most organic compounds, are held together with van der Waals force
In molecular physics and chemistry, the van der Waals force (sometimes van der Waals' force) is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical elec ...
s resulting from the polarization of the electronic charge cloud on each molecule. The dissimilarities between the types of solid result from the differences between their bonding.
Metals
Metals typically are strong, dense, and good conductors of both electricity
Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
and heat
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-atomic, ato ...
.
The bulk of the elements in the periodic table
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows (" periods") and columns (" groups"). It is an icon of chemistry and is widely used in physics and other s ...
, those to the left of a diagonal line drawn from boron
Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...
to polonium, are metals.
Mixtures of two or more elements in which the major component is a metal are known as alloy
An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
s.
People have been using metals for a variety of purposes since prehistoric times.
The strength and reliability of metals has led to their widespread use in construction of buildings and other structures, as well as in most vehicles, many appliances and tools, pipes, road signs and railroad tracks. Iron and aluminium are the two most commonly used structural metals. They are also the most abundant metals in the Earth's crust
Earth's crust is its thick outer shell of rock, referring to less than one percent of the planet's radius and volume. It is the top component of the lithosphere, a solidified division of Earth's layers that includes the crust and the upper ...
. Iron is most commonly used in the form of an alloy, steel, which contains up to 2.1% carbon
Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
, making it much harder than pure iron.
Because metals are good conductors of electricity, they are valuable in electrical appliances and for carrying an electric current
An electric current is a flow of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is defined as the net rate of flow of electric charge through a surface. The moving particles are called charge c ...
over long distances with little energy loss or dissipation. Thus, electrical power grids rely on metal cables to distribute electricity. Home electrical systems, for example, are wired with copper for its good conducting properties and easy machinability. The high thermal conductivity
The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1.
Heat transfer occurs at a lower rate in materials of low ...
of most metals also makes them useful for stovetop cooking utensils.
The study of metallic elements and their alloy
An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
s makes up a significant portion of the fields of solid-state chemistry, physics, materials science and engineering.
Metallic solids are held together by a high density of shared, delocalized electrons, known as "metallic bond
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be descr ...
ing". In a metal, atoms readily lose their outermost ("valence") electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s, forming positive ions. The free electrons are spread over the entire solid, which is held together firmly by electrostatic interactions between the ions and the electron cloud. The large number of free electrons gives metals their high values of electrical and thermal conductivity. The free electrons also prevent transmission of visible light, making metals opaque, shiny and lustrous.
More advanced models of metal properties consider the effect of the positive ions cores on the delocalised electrons. As most metals have crystalline structure, those ions are usually arranged into a periodic lattice. Mathematically, the potential of the ion cores can be treated by various models, the simplest being the nearly free electron model.
Minerals
Minerals are naturally occurring solids formed through various geological processes under high pressures. To be classified as a true mineral, a substance must have a crystal structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ...
with uniform physical properties throughout. Minerals range in composition from pure elements and simple salt
In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
s to very complex silicate
A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used ...
s with thousands of known forms. In contrast, a rock sample is a random aggregate of minerals and/or mineraloid
A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
s, and has no specific chemical composition. The vast majority of the rocks of the Earth's crust
Earth's crust is its thick outer shell of rock, referring to less than one percent of the planet's radius and volume. It is the top component of the lithosphere, a solidified division of Earth's layers that includes the crust and the upper ...
consist of quartz (crystalline SiO2), feldspar, mica, chlorite
The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
, kaolin
Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina (). ...
, calcite, epidote, olivine
The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
, augite, hornblende
Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
, magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
, hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as , although this is not entirely accurate as the ratio of oxide to hydroxide can vary qu ...
and a few other minerals. Some minerals, like quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
, mica
Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
or feldspar
Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
are common, while others have been found in only a few locations worldwide. The largest group of minerals by far is the silicates
A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used for an ...
(most rocks are ≥95% silicates), which are composed largely of silicon
Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
and oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, with the addition of ions of aluminium, magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
, iron, calcium
Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
and other metals.
Ceramics
Ceramic solids are composed of inorganic compounds, usually oxide
An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
s of chemical elements. They are chemically inert, and often are capable of withstanding chemical erosion that occurs in an acidic or caustic environment. Ceramics generally can withstand high temperatures ranging from . Exceptions include non-oxide inorganic materials, such as nitride
In chemistry, a nitride is a chemical compound of nitrogen. Nitrides can be inorganic or organic, ionic or covalent. The nitride anion, N3−, is very elusive but compounds of nitride are numerous, although rarely naturally occurring. Some nitr ...
s, borides and carbide
In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece.
Interstitial / Metallic carbides
The carbides of th ...
s.
Traditional ceramic raw materials include clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
minerals such as kaolinite
Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () ...
, more recent materials include aluminium oxide (alumina
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
). The modern ceramic materials, which are classified as advanced ceramics, include silicon carbide
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A wide bandgap semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder a ...
and tungsten carbide. Both are valued for their abrasion resistance, and hence find use in such applications as the wear plates of crushing equipment in mining operations.
Most ceramic materials, such as alumina and its compounds, are formed from fine powders, yielding a fine grained polycrystalline microstructure that is filled with light-scattering centers comparable to the wavelength
In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats.
In other words, it is the distance between consecutive corresponding points of the same ''phase (waves ...
of visible light
Light, visible light, or visible radiation is electromagnetic radiation that can be perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400–700 nanometres (nm ...
. Thus, they are generally opaque materials, as opposed to transparent materials
In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable light scattering by particles, scattering of light. On a macroscopic scale ...
. Recent nanoscale (e.g. sol-gel) technology has, however, made possible the production of polycrystalline transparent ceramics such as transparent alumina and alumina compounds for such applications as high-power lasers. Advanced ceramics are also used in the medicine, electrical and electronics industries.
Ceramic engineering is the science and technology of creating solid-state ceramic materials, parts and devices. This is done either by the action of heat, or, at lower temperatures, using precipitation reactions from chemical solutions. The term includes the purification of raw materials, the study and production of the chemical compounds concerned, their formation into components, and the study of their structure, composition and properties.
Mechanically speaking, ceramic materials are brittle, hard, strong in compression and weak in shearing and tension. Brittle
A material is brittle if, when subjected to stress, it fractures with little elastic deformation and without significant plastic deformation. Brittle materials absorb relatively little energy prior to fracture, even those of high strength. ...
materials may exhibit significant tensile strength
Ultimate tensile strength (also called UTS, tensile strength, TS, ultimate strength or F_\text in notation) is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials, the ultimate ...
by supporting a static load. Toughness
In materials science and metallurgy, toughness is the ability of a material to absorb energy and plastically deform without fracturing.[fracture toughness
In materials science, fracture toughness is the critical stress intensity factor of a sharp Fracture, crack where propagation of the crack suddenly becomes rapid and unlimited. It is a material property that quantifies its ability to resist crac ...]
(denoted KIc) describes the ability of a material with inherent microstructural flaws to resist fracture via crack growth and propagation. If a material has a large value of fracture toughness
In materials science, fracture toughness is the critical stress intensity factor of a sharp Fracture, crack where propagation of the crack suddenly becomes rapid and unlimited. It is a material property that quantifies its ability to resist crac ...
, the basic principles of fracture mechanics
Fracture mechanics is the field of mechanics concerned with the study of the propagation of cracks in materials. It uses methods of analytical solid mechanics to calculate the driving force on a crack and those of experimental solid mechanics t ...
suggest that it will most likely undergo ductile fracture. Brittle fracture is very characteristic of most ceramic
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...
and glass-ceramic
Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses t ...
materials that typically exhibit low (and inconsistent) values of KIc.
For an example of applications of ceramics, the extreme hardness of zirconia
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zirconium silicate or zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral ba ...
is utilized in the manufacture of knife blades, as well as other industrial cutting tools. Ceramics such as alumina
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
, boron carbide and silicon carbide
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A wide bandgap semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder a ...
have been used in bulletproof vest
A bulletproof vest, also known as a ballistic vest or bullet-resistant vest, is a type of body armor designed to absorb impact and prevent the penetration of firearm projectiles and explosion fragments to the torso. The vest can be either soft ...
s to repel large-caliber rifle fire. Silicon nitride parts are used in ceramic ball bearings, where their high hardness makes them wear resistant. In general, ceramics are also chemically resistant and can be used in wet environments where steel bearings would be susceptible to oxidation (or rust).
As another example of ceramic applications, in the early 1980s, Toyota
is a Japanese Multinational corporation, multinational Automotive industry, automotive manufacturer headquartered in Toyota City, Aichi, Japan. It was founded by Kiichiro Toyoda and incorporated on August 28, 1937. Toyota is the List of manuf ...
researched production of an adiabatic ceramic engine with an operating temperature
An operating temperature is the allowable temperature range of the local ambient environment at which an electrical or mechanical device operates. The device will operate effectively within a specified temperature range which varies based on the de ...
of over . Ceramic engines do not require a cooling system and hence allow a major weight reduction and therefore greater fuel efficiency. In a conventional metallic engine, much of the energy released from the fuel must be dissipated as waste heat
Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utility ...
in order to prevent a meltdown of the metallic parts. Work is also being done in developing ceramic parts for gas turbine
A gas turbine or gas turbine engine is a type of Internal combustion engine#Continuous combustion, continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas gene ...
engines
An engine or motor is a machine designed to convert one or more forms of energy into mechanical energy.
Available energy sources include potential energy (e.g. energy of the Earth's gravitational field as exploited in hydroelectric power gen ...
. Turbine engines made with ceramics could operate more efficiently, giving aircraft greater range and payload for a set amount of fuel. Such engines are not in production, however, because the manufacturing of ceramic parts in the sufficient precision and durability is difficult and costly. Processing methods often result in a wide distribution of microscopic flaws that frequently play a detrimental role in the sintering process, resulting in the proliferation of cracks, and ultimate mechanical failure.
Glass ceramics
Glass-ceramic materials share many properties with both non-crystalline glasses and crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
ceramics
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porce ...
. They are formed as a glass, and then partially crystallized by heat treatment, producing both amorphous
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...
and crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
phases so that crystalline grains are embedded within a non-crystalline intergranular phase.
Glass-ceramics are used to make cookware (originally known by the brand name CorningWare) and stovetops that have high resistance to thermal shock
Thermal shock is a phenomenon characterized by a rapid change in temperature that results in a transient mechanical load on an object. The load is caused by the differential expansion of different parts of the object due to the temperature chang ...
and extremely low permeability to liquids. The negative coefficient of thermal expansion of the crystalline ceramic phase can be balanced with the positive coefficient of the glassy phase. At a certain point (~70% crystalline) the glass-ceramic has a net coefficient of thermal expansion close to zero. This type of glass-ceramic exhibits excellent mechanical properties and can sustain repeated and quick temperature changes up to 1000 °C.
Glass ceramics may also occur naturally when lightning
Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
strikes the crystalline (e.g. quartz) grains found in most beach sand
Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is usually defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural ...
. In this case, the extreme and immediate heat of the lightning (~2500 °C) creates hollow, branching rootlike structures called fulgurite via fusion.
Organic solids
Organic chemistry studies the structure, properties, composition, reactions, and preparation by synthesis (or other means) of chemical compounds of carbon
Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
and hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
, which may contain any number of other elements such as nitrogen
Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and the halogens: fluorine
Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
, chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
, bromine
Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between th ...
and iodine
Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
. Some organic compounds may also contain the elements phosphorus
Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...
or sulfur
Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
. Examples of organic solids include wood, paraffin wax
Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and melting poi ...
, naphthalene
Naphthalene is an organic compound with formula . It is the simplest polycyclic aromatic hydrocarbon, and is a white Crystal, crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 Parts-per notation ...
and a wide variety of polymer
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their br ...
s and plastic
Plastics are a wide range of synthetic polymers, synthetic or Semisynthesis, semisynthetic materials composed primarily of Polymer, polymers. Their defining characteristic, Plasticity (physics), plasticity, allows them to be Injection moulding ...
s.
Wood
Wood is a natural organic material consisting primarily of cellulose
Cellulose is an organic compound with the chemical formula, formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of glycosidic bond, β(1→4) linked glucose, D-glucose units. Cellulose is an important s ...
fibers embedded in a matrix of lignin
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidit ...
. Regarding mechanical properties, the fibers are strong in tension, and the lignin matrix resists compression. Thus wood has been an important construction material since humans began building shelters and using boats. Wood to be used for construction work is commonly known as ''lumber
Lumber is wood that has been processed into uniform and useful sizes (dimensional lumber), including beams and planks or boards. Lumber is mainly used for construction framing, as well as finishing (floors, wall panels, window frames). ...
'' or ''timber''. In construction, wood is not only a structural material, but is also used to form the mould for concrete.
Wood-based materials are also extensively used for packaging (e.g. cardboard) and paper, which are both created from the refined pulp. The chemical pulping processes use a combination of high temperature and alkaline (kraft) or acidic (sulfite) chemicals to break the chemical bonds of the lignin before burning it out.
Polymers
One important property of carbon in organic chemistry is that it can form certain compounds, the individual molecules of which are capable of attaching themselves to one another, thereby forming a chain or a network. The process is called polymerization and the chains or networks polymers, while the source compound is a monomer. Two main groups of polymers exist: those artificially manufactured are referred to as industrial polymers or synthetic polymers (plastics) and those naturally occurring as biopolymers.
Monomers can have various chemical substituents, or functional groups, which can affect the chemical properties of organic compounds, such as solubility and chemical reactivity, as well as the physical properties, such as hardness, density, mechanical or tensile strength, abrasion resistance, heat resistance, transparency, color, etc.. In proteins, these differences give the polymer the ability to adopt a biologically active conformation in preference to others (see self-assembly).
People have been using natural organic polymers for centuries in the form of waxes and shellac
Shellac () is a resin secreted by the female Kerria lacca, lac bug on trees in the forests of India and Thailand. Chemically, it is mainly composed of aleuritic acid, jalaric acid, shellolic acid, and other natural waxes. It is processed and s ...
, which is classified as a thermoplastic polymer. A plant polymer named cellulose
Cellulose is an organic compound with the chemical formula, formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of glycosidic bond, β(1→4) linked glucose, D-glucose units. Cellulose is an important s ...
provided the tensile strength for natural fibers and ropes, and by the early 19th century natural rubber was in widespread use. Polymers are the raw materials (the resins) used to make what are commonly called plastics. Plastics are the final product, created after one or more polymers or additives have been added to a resin during processing, which is then shaped into a final form. Polymers that have been around, and that are in current widespread use, include carbon-based polyethylene
Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bott ...
, polypropylene
Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer Propene, propylene.
Polypropylene belongs to the group of polyolefin ...
, polyvinyl chloride
Polyvinyl chloride (alternatively: poly(vinyl chloride), colloquial: vinyl or polyvinyl; abbreviated: PVC) is the world's third-most widely produced synthetic polymer of plastic (after polyethylene and polypropylene). About 40 million tons of ...
, polystyrene
Polystyrene (PS) is a synthetic polymer made from monomers of the aromatic hydrocarbon styrene. Polystyrene can be solid or foamed. General-purpose polystyrene is clear, hard, and brittle. It is an inexpensive resin per unit weight. It i ...
, nylons, polyester
Polyester is a category of polymers that contain one or two ester linkages in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include some natura ...
s, acrylics, polyurethane
Polyurethane (; often abbreviated PUR and PU) is a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane term ...
, and polycarbonate
Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate ester, carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, toughness, tough materials, and some grades are optically transp ...
s, and silicon-based silicone
In Organosilicon chemistry, organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (, where R = Organyl group, organic group). They are typically colorless oils or elastomer, rubber ...
s. Plastics are generally classified as "commodity", "specialty" and "engineering" plastics.
Composite materials
Composite material
A composite or composite material (also composition material) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a ...
s contain two or more macroscopic phases, one of which is often ceramic. For example, a continuous matrix, and a dispersed phase of ceramic particles or fibers.
Applications of composite materials range from structural elements such as steel-reinforced concrete, to the thermally insulative tiles that play a key and integral role in NASA's Space Shuttle thermal protection system, which is used to protect the surface of the shuttle from the heat of re-entry into the Earth's atmosphere. One example is Reinforced Carbon-Carbon (RCC), the light gray material that withstands reentry temperatures up to and protects the nose cap and leading edges of Space Shuttle's wings. RCC is a laminated composite material made from graphite
Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...
rayon
Rayon, also called viscose and commercialised in some countries as sabra silk or cactus silk, is a semi-synthetic fiber made from natural sources of regenerated cellulose fiber, cellulose, such as wood and related agricultural products. It has t ...
cloth and impregnated with a phenolic resin. After curing at high temperature in an autoclave, the laminate is pyrolized to convert the resin to carbon, impregnated with furfural alcohol in a vacuum chamber, and cured/pyrolized to convert the furfural alcohol to carbon. In order to provide oxidation resistance for reuse capability, the outer layers of the RCC are converted to silicon carbide.
Domestic examples of composites can be seen in the "plastic" casings of television sets, cell-phones and so on. These plastic casings are usually a composite made up of a thermoplastic matrix such as acrylonitrile butadiene styrene (ABS) in which calcium carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
chalk, talc
Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...
, glass fibers or carbon fibers have been added for strength, bulk, or electro-static dispersion. These additions may be referred to as reinforcing fibers, or dispersants, depending on their purpose.
Thus, the matrix material surrounds and supports the reinforcement materials by maintaining their relative positions. The reinforcements impart their special mechanical and physical properties to enhance the matrix properties. A synergism produces material properties unavailable from the individual constituent materials, while the wide variety of matrix and strengthening materials provides the designer with the choice of an optimum combination.
Semiconductors
Semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
s are materials that have an electrical resistivity (and conductivity) between that of metallic conductors and non-metallic insulators. They can be found in the periodic table
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows (" periods") and columns (" groups"). It is an icon of chemistry and is widely used in physics and other s ...
moving diagonally downward right from boron
Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...
. They separate the electrical conductors (or metals, to the left) from the insulators (to the right).
Devices made from semiconductor materials are the foundation of modern electronics, including radio, computers, telephones, etc. Semiconductor devices include the transistor
A transistor is a semiconductor device used to Electronic amplifier, amplify or electronic switch, switch electrical signals and electric power, power. It is one of the basic building blocks of modern electronics. It is composed of semicondu ...
, solar cell
A solar cell, also known as a photovoltaic cell (PV cell), is an electronic device that converts the energy of light directly into electricity by means of the photovoltaic effect. s, diode
A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...
s and integrated circuit
An integrated circuit (IC), also known as a microchip or simply chip, is a set of electronic circuits, consisting of various electronic components (such as transistors, resistors, and capacitors) and their interconnections. These components a ...
s. Solar photovoltaic panels are large semiconductor devices that directly convert light into electrical energy.
In a metallic conductor, current is carried by the flow of electrons, but in semiconductors, current can be carried either by electrons or by the positively charged " holes" in the electronic band structure
In solid-state physics, the electronic band structure (or simply band structure) of a solid describes the range of energy levels that electrons may have within it, as well as the ranges of energy that they may not have (called ''band gaps'' or '' ...
of the material. Common semiconductor materials include silicon, germanium
Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
and gallium arsenide
Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a Zincblende (crystal structure), zinc blende crystal structure.
Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monoli ...
.
Nanomaterials
Many traditional solids exhibit different properties when they shrink to nanometer sizes. For example, nanoparticle
A nanoparticle or ultrafine particle is a particle of matter 1 to 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At ...
s of usually yellow gold and gray silicon are red in color; gold nanoparticles melt at much lower temperatures (~300 °C for 2.5 nm size) than the gold slabs (1064 °C); and metallic nanowires are much stronger than the corresponding bulk metals. The high surface area of nanoparticles makes them extremely attractive for certain applications in the field of energy. For example, platinum metals may provide improvements as automotive fuel catalysts
Catalysis () is the increase in reaction rate, rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst ...
, as well as proton exchange membrane (PEM) fuel cells. Also, ceramic oxides (or cermets) of lanthanum, cerium
Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
, manganese and nickel are now being developed as solid oxide fuel cells (SOFC). Lithium, lithium-titanate and tantalum nanoparticles are being applied in lithium-ion batteries. Silicon nanoparticles have been shown to dramatically expand the storage capacity of lithium-ion batteries during the expansion/contraction cycle. Silicon nanowires cycle without significant degradation and present the potential for use in batteries with greatly expanded storage times. Silicon nanoparticles are also being used in new forms of solar energy cells. Thin film deposition of silicon
Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
quantum dots on the polycrystalline silicon substrate of a photovoltaic (solar) cell increases voltage output as much as 60% by fluorescing the incoming light prior to capture. Here again, surface area of the nanoparticles (and thin films) plays a critical role in maximizing the amount of absorbed radiation.
Biomaterials
Many natural (or biological) materials are complex composites with remarkable mechanical properties. These complex structures, which have risen from hundreds of million years of evolution, are inspiring materials scientists in the design of novel materials. Their defining characteristics include structural hierarchy, multifunctionality and self-healing capability. Self-organization is also a fundamental feature of many biological materials and the manner by which the structures are assembled from the molecular level up. Thus, self-assembly is emerging as a new strategy in the chemical synthesis of high performance biomaterials.
Physical properties
Physical properties of elements and compounds that provide conclusive evidence of chemical composition include odor, color, volume, density (mass per unit volume), melting point, boiling point, heat capacity, physical form and shape at room temperature (solid, liquid or gas; cubic, trigonal crystals, etc.), hardness, porosity, index of refraction and many others. This section discusses some physical properties of materials in the solid state.
Mechanical
The mechanical properties of materials describe characteristics such as their strength and resistance to deformation. For example, steel beams are used in construction because of their high strength, meaning that they neither break nor bend significantly under the applied load.
Mechanical properties include elasticity, plasticity, tensile strength
Ultimate tensile strength (also called UTS, tensile strength, TS, ultimate strength or F_\text in notation) is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials, the ultimate ...
, compressive strength
In mechanics, compressive strength (or compression strength) is the capacity of a material or Structural system, structure to withstand Structural load, loads tending to reduce size (Compression (physics), compression). It is opposed to ''tensil ...
, shear strength, fracture toughness
In materials science, fracture toughness is the critical stress intensity factor of a sharp Fracture, crack where propagation of the crack suddenly becomes rapid and unlimited. It is a material property that quantifies its ability to resist crac ...
, ductility
Ductility refers to the ability of a material to sustain significant plastic Deformation (engineering), deformation before fracture. Plastic deformation is the permanent distortion of a material under applied stress, as opposed to elastic def ...
(low in brittle materials) and indentation hardness. Solid mechanics
Solid mechanics (also known as mechanics of solids) is the branch of continuum mechanics that studies the behavior of solid materials, especially their motion and deformation (mechanics), deformation under the action of forces, temperature chang ...
is the study of the behavior of solid matter under external actions such as external forces and temperature changes.
A solid does not exhibit macroscopic flow, as fluids do. Any degree of departure from its original shape is called deformation. The proportion of deformation to original size is called strain. If the applied stress is sufficiently low, almost all solid materials behave in such a way that the strain is directly proportional to the stress (Hooke's law
In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring by some distance () scales linearly with respect to that distance—that is, where is a constant factor characteristic of ...
). The coefficient of the proportion is called the modulus of elasticity or Young's modulus
Young's modulus (or the Young modulus) is a mechanical property of solid materials that measures the tensile or compressive stiffness when the force is applied lengthwise. It is the modulus of elasticity for tension or axial compression. Youn ...
. This region of deformation is known as the linearly elastic region. Three models can describe how a solid responds to an applied stress:
* Elasticity – When an applied stress is removed, the material returns to its undeformed state.
* Viscoelasticity
In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist both shear flow and strain lin ...
– These are materials that behave elastically, but also have damping. When the applied stress is removed, work has to be done against the damping effects and is converted to heat within the material. This results in a hysteresis loop in the stress–strain curve. This implies that the mechanical response has a time-dependence.
* Plasticity – Materials that behave elastically generally do so when the applied stress is less than a yield value. When the stress is greater than the yield stress, the material behaves plastically and does not return to its previous state. That is, irreversible plastic deformation (or viscous flow) occurs after yield that is permanent.
Many materials become weaker at high temperatures. Materials that retain their strength at high temperatures, called refractory materials
In materials science, a refractory (or refractory material) is a material that is resistant to Thermal decomposition, decomposition by heat or chemical attack and that retains its strength and rigidity at high temperatures. They are Inorganic c ...
, are useful for many purposes. For example, glass-ceramic
Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses t ...
s have become extremely useful for countertop cooking, as they exhibit excellent mechanical properties and can sustain repeated and quick temperature changes up to 1000 °C.
In the aerospace industry, high performance materials used in the design of aircraft and/or spacecraft exteriors must have a high resistance to thermal shock. Thus, synthetic fibers spun out of organic polymers and polymer/ceramic/metal composite materials and fiber-reinforced polymers are now being designed with this purpose in mind.
Thermal
Because solids have thermal energy
The term "thermal energy" is often used ambiguously in physics and engineering. It can denote several different physical concepts, including:
* Internal energy: The energy contained within a body of matter or radiation, excluding the potential en ...
, their atoms vibrate about fixed mean positions within the ordered (or disordered) lattice. The spectrum of lattice vibrations in a crystalline or glassy network provides the foundation for the kinetic theory of solids. This motion occurs at the atomic level, and thus cannot be observed or detected without highly specialized equipment, such as that used in spectroscopy
Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.
Spectro ...
.
Thermal properties of solids include thermal conductivity
The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1.
Heat transfer occurs at a lower rate in materials of low ...
, which is the property of a material that indicates its ability to conduct heat. Solids also have a specific heat capacity
In thermodynamics, the specific heat capacity (symbol ) of a substance is the amount of heat that must be added to one unit of mass of the substance in order to cause an increase of one unit in temperature. It is also referred to as massic heat ...
, which is the capacity of a material to store energy in the form of heat (or thermal lattice vibrations).
Electrical
Electrical properties include both electrical resistivity and conductivity
Electrical resistivity (also called volume resistivity or specific electrical resistance) is a fundamental specific property of a material that measures its electrical resistance or how strongly it resists electric current. A low resistivity in ...
, dielectric strength, electromagnetic permeability, and permittivity
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter (epsilon), is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more ...
. Electrical conductors such as metals and alloys are contrasted with electrical insulators such as glasses and ceramics. Semiconductors behave somewhere in between. Whereas conductivity in metals is caused by electrons, both electrons and holes contribute to current in semiconductors. Alternatively, ions support electric current in ionic conductors.
Many materials also exhibit superconductivity
Superconductivity is a set of physical properties observed in superconductors: materials where Electrical resistance and conductance, electrical resistance vanishes and Magnetic field, magnetic fields are expelled from the material. Unlike an ord ...
at low temperatures; they include metallic elements such as tin and aluminium, various metallic alloys, some heavily doped semiconductors, and certain ceramics. The electrical resistivity of most electrical (metallic) conductors generally decreases gradually as the temperature is lowered, but remains finite. In a superconductor, however, the resistance drops abruptly to zero when the material is cooled below its critical temperature. An electric current flowing in a loop of superconducting wire can persist indefinitely with no power source.
A dielectric
In electromagnetism, a dielectric (or dielectric medium) is an Insulator (electricity), electrical insulator that can be Polarisability, polarised by an applied electric field. When a dielectric material is placed in an electric field, electric ...
, or electrical insulator, is a substance that is highly resistant to the flow of electric current. A dielectric, such as plastic, tends to concentrate an applied electric field within itself, which property is used in capacitors. A capacitor
In electrical engineering, a capacitor is a device that stores electrical energy by accumulating electric charges on two closely spaced surfaces that are insulated from each other. The capacitor was originally known as the condenser, a term st ...
is an electrical device that can store energy in the electric field between a pair of closely spaced conductors (called 'plates'). When voltage is applied to the capacitor, electric charges of equal magnitude, but opposite polarity, build up on each plate. Capacitors are used in electrical circuits as energy-storage devices, as well as in electronic filters to differentiate between high-frequency and low-frequency signals.
Electro-mechanical
Piezoelectricity
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress.
The piezoel ...
is the ability of crystals to generate a voltage in response to an applied mechanical stress. The piezoelectric effect is reversible in that piezoelectric crystals, when subjected to an externally applied voltage, can change shape by a small amount. Polymer materials like rubber, wool, hair, wood fiber, and silk often behave as electrets. For example, the polymer polyvinylidene fluoride (PVDF) exhibits a piezoelectric response several times larger than the traditional piezoelectric material quartz (crystalline SiO2). The deformation (~0.1%) lends itself to useful technical applications such as high-voltage sources, loudspeakers, lasers, as well as chemical, biological, and acousto-optic sensors and/or transducers.
Optical
Materials can transmit (e.g. glass) or reflect (e.g. metals) visible light.
Many materials will transmit some wavelengths while blocking others. For example, window glass is transparent to visible light
Light, visible light, or visible radiation is electromagnetic radiation that can be perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400–700 nanometres (nm ...
, but much less so to most of the frequencies of ultraviolet
Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
light that cause sunburn
Sunburn is a form of radiation burn that affects living tissue, such as skin, that results from an overexposure to ultraviolet (UV) radiation, usually from the Sun. Common symptoms in humans and other animals include red or reddish skin tha ...
. This property is used for frequency-selective optical filters, which can alter the color of incident light.
For some purposes, both the optical and mechanical properties of a material can be of interest. For example, the sensors on an infrared homing
Infrared homing is a Missile guidance#Passive homing, passive weapon guidance system which uses the infrared (IR) light emission from a target to track and follow it seamlessly. Missiles which use infrared seeking are often referred to as "he ...
("heat-seeking") missile must be protected by a cover that is transparent to infrared radiation
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those ...
. The current material of choice for high-speed infrared-guided missile domes is single-crystal sapphire
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name ''sapphire ...
. The optical transmission of sapphire does not actually extend to cover the entire mid-infrared range (3–5 μm), but starts to drop off at wavelengths greater than approximately 4.5 μm at room temperature. While the strength of sapphire is better than that of other available mid-range infrared dome materials at room temperature, it weakens above 600 °C. A long-standing trade-off exists between optical bandpass and mechanical durability; new materials such as transparent ceramics or optical nanocomposites may provide improved performance.
Guided lightwave transmission involves the field of fiber optics and the ability of certain glasses to transmit, simultaneously and with low loss of intensity, a range of frequencies (multi-mode optical waveguides) with little interference between them. Optical waveguides are used as components in integrated optical circuits or as the transmission medium in optical communication systems.
Opto-electronic
A solar cell or photovoltaic cell is a device that converts light energy into electrical energy. Fundamentally, the device needs to fulfill only two functions: photo-generation of charge carriers (electrons and holes) in a light-absorbing material, and separation of the charge carriers to a conductive contact that will transmit the electricity (simply put, carrying electrons off through a metal contact into an external circuit). This conversion is called the photoelectric effect
The photoelectric effect is the emission of electrons from a material caused by electromagnetic radiation such as ultraviolet light. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physi ...
, and the field of research related to solar cells is known as photovoltaics.
Solar cells have many applications. They have long been used in situations where electrical power from the grid is unavailable, such as in remote area power systems, Earth-orbiting satellites and space probes, handheld calculators, wrist watches, remote radiotelephones and water pumping applications. More recently, they are starting to be used in assemblies of solar modules (photovoltaic arrays) connected to the electricity grid through an inverter, that is not to act as a sole supply but as an additional electricity source.
All solar cells require a light absorbing material contained within the cell structure to absorb photons and generate electrons via the photovoltaic effect. The materials used in solar cells tend to have the property of preferentially absorbing the wavelengths of solar light that reach the earth surface. Some solar cells are optimized for light absorption beyond Earth's atmosphere, as well.
Fields of study
Solid-state physics
Solid-state chemistry
Materials science
References
External links
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