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Llullaillaco () is a dormant
stratovolcano A stratovolcano, also known as a composite volcano, is a typically conical volcano built up by many alternating layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with ...
on the border between
Argentina Argentina, officially the Argentine Republic, is a country in the southern half of South America. It covers an area of , making it the List of South American countries by area, second-largest country in South America after Brazil, the fourt ...
(
Salta Province Salta () is a Provinces of Argentina, province of Argentina, located in the northwest of the country. Neighboring provinces are from the east clockwise Formosa Province, Formosa, Chaco Province, Chaco, Santiago del Estero Province, Santiago del Es ...
) and
Chile Chile, officially the Republic of Chile, is a country in western South America. It is the southernmost country in the world and the closest to Antarctica, stretching along a narrow strip of land between the Andes, Andes Mountains and the Paci ...
(
Antofagasta Region The Antofagasta Region (, ) is one of Chile's Administrative divisions of Chile, sixteen first-order administrative divisions. Being the second-largest region of Chile in area, it comprises three provinces, Antofagasta Province, Antofagasta, El ...
). It lies in the
Puna de Atacama The Puna de Atacama or Atacama Plateau''Atacama Plateau''
article at the ''Encyclopædia Bri ...
, a region of tall volcanic peaks on a high
plateau In geology and physical geography, a plateau (; ; : plateaus or plateaux), also called a high plain or a tableland, is an area of a highland consisting of flat terrain that is raised sharply above the surrounding area on at least one side. ...
close to the
Atacama Desert The Atacama Desert () is a desert plateau located on the Pacific Ocean, Pacific coast of South America, in the north of Chile. Stretching over a strip of land west of the Andes Mountains, it covers an area of , which increases to if the barre ...
, one of the driest places in the world. Its maximum elevation is most commonly given as , making it the second- or third-highest volcano in the world. Despite its height, it is not clear whether the volcano has any
glacier A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier forms where the accumulation of snow exceeds its ablation over many years, often centuries. It acquires ...
s or merely patches of perennial snow and ice. Between and elevation there is a sparse plant cover, while at lower altitudes the climate is too dry for plants to grow. A species of mouse on Llullaillaco is the highest-living known vertebrate species. The volcano formed during the
Pleistocene The Pleistocene ( ; referred to colloquially as the ''ice age, Ice Age'') is the geological epoch (geology), epoch that lasted from to 11,700 years ago, spanning the Earth's most recent period of repeated glaciations. Before a change was fin ...
in two stages, named Llullaillaco I and Llullaillaco II. The oldest rocks are about 1.5 million years old. About 150,000 years ago, the volcano's southeastern flank collapsed, generating a debris avalanche that reached as far as from the summit. During the last stage, three conspicuous
lava flow Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a Natural satellite, moon onto its surface. Lava may be erupted at a volcano or through a Fissure vent, fractu ...
s were emplaced on the summit. The youngest dated rocks are 930 ± 140 years old, but there are reports of activity from the 19th century. There are a number of archaeological sites on the mountain and at its foot; Llullaillaco marks the highest archaeological site in the world. The first recorded ascent was in 1950. In 1999, the mummified remains of three children, known as the Children of Llullaillaco, were found at its summit. They are presumed to have been
human sacrifice Human sacrifice is the act of killing one or more humans as part of a ritual, which is usually intended to please or appease deity, gods, a human ruler, public or jurisdictional demands for justice by capital punishment, an authoritative/prie ...
s.


Name

The name ''Llullaillaco'' is usually associated to the Quechua word meaning "false", "lie" or "deceitful" and or meaning "water". This name probably refers to
meltwater Meltwater (or melt water) is water released by the melting of snow or ice, including glaciers, glacial ice, tabular icebergs and ice shelf, ice shelves over oceans. Meltwater is often found during early spring (season), spring when snow packs a ...
from snow, which flows down the slopes but then is absorbed into the soil; normally mountains are sources for water. Another possibility is that it refers to the danger from
flood A flood is an overflow of water (list of non-water floods, or rarely other fluids) that submerges land that is usually dry. In the sense of "flowing water", the word may also be applied to the inflow of the tide. Floods are of significant con ...
s in the local valleys. Other translations are ( Aymara) "hot water" after "warm" and "water", and (Quechua) "thinking", "memory"+"water" or "thing that hardens after forming tender" , which may refer to volcanic activity.


Geography and geomorphology

Llullaillaco is located in the northwestern Argentine
Andes The Andes ( ), Andes Mountains or Andean Mountain Range (; ) are the List of longest mountain chains on Earth, longest continental mountain range in the world, forming a continuous highland along the western edge of South America. The range ...
, towards the southern end of the Puna. The frontier between Argentina and Chile passes over the mountain. The Argentine portion is in the Los Andes Department of
Salta Province Salta () is a Provinces of Argentina, province of Argentina, located in the northwest of the country. Neighboring provinces are from the east clockwise Formosa Province, Formosa, Chaco Province, Chaco, Santiago del Estero Province, Santiago del Es ...
and the Chilean in Chile's
Antofagasta Region The Antofagasta Region (, ) is one of Chile's Administrative divisions of Chile, sixteen first-order administrative divisions. Being the second-largest region of Chile in area, it comprises three provinces, Antofagasta Province, Antofagasta, El ...
. About northeast of Llullaillaco, a
railway Rail transport (also known as train transport) is a means of transport using wheeled vehicles running in railway track, tracks, which usually consist of two parallel steel railway track, rails. Rail transport is one of the two primary means of ...
(the Salta-Antofagasta railway) crosses the Andes at Socompa. Humans first moved into the area about 8,000 BCE. The region was inhabited by hunters and shepherds in pre-Hispanic times. At some point between 1470 and 1532 CE, the
Inca empire The Inca Empire, officially known as the Realm of the Four Parts (, ), was the largest empire in pre-Columbian America. The administrative, political, and military center of the empire was in the city of Cusco. The History of the Incas, Inca ...
occupied the region. There are numerous abandoned mines in the region, and the active
lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...
production plant "Proyecto Mariana" at Salar de Llullaillaco. Azufrera Esperanto is an abandoned sulfur mine north of Llullaillaco and is associated with an area of hydrothermal alteration. The mine can be reached through a road or path from the northwest. Another abandoned mine lies south of the volcano. Mina Amalia is an abandoned
borate A borate is any of a range of boron oxyanions, anions containing boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt of such anions, such as sodium metaborate, and borax . The name also refers to esters of su ...
mine and Mina Luisa and Mina Maria abandoned
salt mine Salt mining extracts natural salt deposits from underground. The mined salt is usually in the form of halite (commonly known as rock salt), and extracted from evaporite formations. History Before the advent of the modern internal combustio ...
s at Salar de Llullaillaco. A
weather station A weather station is a facility, either on land or sea, with instruments and equipment for measuring atmosphere of Earth, atmospheric conditions to provide information for weather forecasting, weather forecasts and to study the weather and clima ...
installed on Llullaillaco in 2004 was for some time the highest in the world. The region is dry and located at high altitudes, making work in the area difficult. The extreme environmental conditions have been compared to conditions on
Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...
.


Geomorphology

The volcano is an imposing mountain, rising by and above the Salar de Punta Negra and Sala de Llullaillaco away, respectively. With a summit height of , (or ) it is one of the highest mountains in the Andes (third highest in Chile and seventh-highest in the Andes, according to John Biggar) and the second- or third-highest volcano in the world (
Ojos del Salado Nevado Ojos del Salado is a Dormant volcano, dormant complex volcano in the Andes on the Argentina–Chile border. It is the highest volcano on Earth and the highest peak in Chile. The upper reaches of Ojos del Salado consist of several overlapp ...
is the highest). In the early 20th century, Llullaillaco was thought to be the highest volcano in the world. The elevation is to a large degree consequence of the underlying terrain, which rises about above sea level. The height of the mountain and the clear air in the region make Llullaillaco visible from
Cerro Paranal Cerro Paranal is a mountain in the Atacama Desert of northern Chile and is the home of the Paranal Observatory. Prior to the construction of the observatory, the summit was a horizontal control point with an elevation of ; now it is above sea ...
, away as measured through
Google Earth Google Earth is a web mapping, web and computer program created by Google that renders a 3D computer graphics, 3D representation of Earth based primarily on satellite imagery. The program maps the Earth by superimposition, superimposing satelli ...
. The view from the mountain extends from
Licancabur Licancabur () is a prominent, stratovolcano on the Bolivia–Chile border in the Central Volcanic Zone of the Andes. It is capped by a wide summit crater which contains Licancabur Lake, a Volcanic crater lake, crater lake that is among the hig ...
north over the Nevados de Cachi mountains east to Ojos del Salado south; mountains in between are visible as well. Llullaillaco is a
composite volcano A stratovolcano, also known as a composite volcano, is a typically conical volcano built up by many alternating layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with a ...
formed mostly by
lava flow Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a Natural satellite, moon onto its surface. Lava may be erupted at a volcano or through a Fissure vent, fractu ...
s. It rises about above the surrounding terrain and hundreds of metres above surrounding mountains. The summit of Llullaillaco is formed by a small cone with about four associated
lava dome In volcanology, a lava dome is a circular, mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruptions ...
s, which reach lengths of and have abrupt walls. Three hollows, probably
volcanic crater A volcanic crater is an approximately circular depression in the ground caused by volcanic activity. It is typically a bowl-shaped feature containing one or more vents. During volcanic eruptions, molten magma and volcanic gases rise from an ...
s, lie east of a long crest at the summit. The slopes of the volcano are fairly steep, with an altitude drop of over only horizontal distance. The slopes high up are steeper than those at lower altitudes. A plateau at elevation is the remnant of an eroded
crater A crater is a landform consisting of a hole or depression (geology), depression on a planetary surface, usually caused either by an object hitting the surface, or by geological activity on the planet. A crater has classically been described ...
from an early stage in Llullaillaco's development. Three young-looking, long lava flows emanate from the summit cone to the north and south. Morphologically, these flows are reddish-black aa lava flows and feature black and reddish glassy blocks with sizes of . The fronts of the stubby, lobe-shaped flows are up to thick. The northern flow has prominent
levee A levee ( or ), dike (American English), dyke (British English; see American and British English spelling differences#Miscellaneous spelling differences, spelling differences), embankment, floodbank, or stop bank is an elevated ridge, natural ...
-like structures and splits into a northwestern and northeastern branch upon reaching an obstacle. The southwestern lava flow is long and was fairly viscous when it was erupted. It almost reaches a road southwest of the volcano. The third flow is just east from the southwestern and descends an altitude of . The flows have levee-like structures and ridges. On the northern flank is Azufrera Esperanto, an high eroded volcano with
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
deposits and traces of
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
alteration. The existence of a cave on Llullaillaco is doubtful. The edifice covers an elliptical area of with about - of volcanic rock. The ground at Llullaillaco is formed mostly by lavic rocks and block debris, which are frequently buried by
tephra Tephra is fragmental material produced by a Volcano, volcanic eruption regardless of composition, fragment size, or emplacement mechanism. Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, ...
. The rocks are grey, except where
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
has coloured them black, brown, red or yellow, and their appearance is vitrophyric or
porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning ...
. Several dry valleys originate on Llullaillaco, including Quebrada de las Zorritas on the north-northeastern slope, Quebrada El Salado and Quebrada Llullaillaco on the northwestern slope, and Quebrada La Barda on the southwestern slope. Most of the dry valleys drain into Salar de Punta Negra. There is little erosion by water, and the valley network is poorly developed. There is water only episodically, during
snowmelt In hydrology, snowmelt is surface runoff produced from melting snow. It can also be used to describe the period or season during which such runoff is produced. Water produced by snowmelt is an important part of the annual water cycle in many part ...
. Only Quebrada de las Zorritas carries permanent water. There is a permanent spring there, possibly in Quebrada de Llullaillaco and Quebrada de Tocomar as well, while there are no known springs on the Argentine side of Llullaillaco. Darapsky in 1900 reported the existence of warm springs at Ojo del Llullaillaco and Ojo de Zorritas Several small lakes are found at elevation. At elevation on the northwestern flank is Lago Llullaillaco lake, a frozen waterbody. It is one of the highest lakes in the world. File:Llullaillaco Sunset.jpg, alt=A mountain glows red above a shaded valley, Llullaillaco during sunset File:Parque Nacional Llullaillaco, Chile.jpg, alt=A dirt road across yellow rocky desert heads to a brown-grey mountain, Llullailaco with a road leading to the mountain. File:Llullaillaco from Base Camp on western slopes. See bobvillarreal.com for more..jpg, alt=A white-grey mountain with snow patches rises above a rock-covered terrain, Llullaillaco from the base camp. File:Llullaillaco 2.jpg, alt=A dark tongue of lava descends from a low mountain with snowy patches, Lava flow from Llullaillaco File:Llullaillaco 1.jpg, alt=A low cone with a black tongue rises above white, sparsely vegetated terrain, Llullaillaco in Salta


Debris avalanche

A major
landslide Landslides, also known as landslips, rockslips or rockslides, are several forms of mass wasting that may include a wide range of ground movements, such as rockfalls, mudflows, shallow or deep-seated slope failures and debris flows. Landslides ...
occurred in the volcano's history during the late Pleistocene, probably triggered by volcanic activity. This landslide descended the eastern-southeastern flanks of the volcano into Argentina, first over a steep slope of 20° on the volcano, split around Cerro Rosado and entered the Salina de Llullaillaco east of the summit, extending up to into the salar. The toe of the avalanche reaches a thickness of above the salar in the avalanche's southern lobe. Part of the avalanche was channelled in a valley between Cerro Rosado and an unnamed volcano farther south. When it reached Cerro Rosado, the avalanche climbed about and mostly continued to flow southeast into the main avalanche path, with only a small flow continuing northeastwards. Part of the run-up avalanche later collapsed backward over the main avalanche deposit. Unlike Socompa farther north, a landslide scar is only poorly developed at Llullaillaco despite the large size of the collapse; it was largely filled in later by lava flows and volcaniclastic debris. This landslide has been subdivided into four
facies In geology, a facies ( , ; same pronunciation and spelling in the plural) is a body of rock with distinctive characteristics. The characteristics can be any observable attribute of rocks (such as their overall appearance, composition, or con ...
and features landforms like levees up to high, longitudinal ridges and a run-up mark on Cerro Rosado. Such ridges may be associated with uneven underlying terrain. The surface of the slide is covered by lava bombs less than long, blocks exceeding width, cobbles, and
gravel Gravel () is a loose aggregation of rock fragments. Gravel occurs naturally on Earth as a result of sedimentation, sedimentary and erosion, erosive geological processes; it is also produced in large quantities commercially as crushed stone. Gr ...
-like rocks. The largest blocks with sizes of up to are found close to the collapse scarp. Overall, the margins of the landslide are very crisp and the surface covered by hummocks. The landslide deposit covers a surface of about . Its volume has been estimated at and the speed at . This speed range is comparable to that of the
Colima Colima, officially the Free and Sovereign State of Colima, is among the 31 states that make up the 32 Federal Entities of Mexico. It shares its name with its capital and main city, Colima. Colima is a small state of western Mexico on the cen ...
,
Lastarria Lastarria is a high stratovolcano that lies on the border between Chile and Argentina. It is remote, and the surroundings are uninhabited but can be reached through an unpaved road. The volcano is part of the Central Volcanic Zone, one of the ...
, and Mount St. Helens debris avalanches. The landslide occurred no earlier than 156,000 – 148,000 ± 5,000 years ago, it might coincide with the 48,000-year-old lava flow. Another possibility is that the collapse took place in multiple failures. Some volcanic rocks were still hot at the time of the collapse, indicating that volcanic activity occurred immediately before the collapse. A smaller undated avalanche occurred on the northeastern flank. Such landslides are common at volcanoes, where they are favoured by the steep edifices that form from lava flows being stacked on top of each other. It is not usually known what triggers the collapse, although eruption-associated earthquakes are suspected to play a role. Other volcanoes in the region with sector collapses are: Lastarria, Ollague, San Pedro, Socompa, and Tata Sabaya. The Mellado and Cerro Rosado volcanoes close to Llullaillaco also display evidence of sector collapses.


Geology


Regional setting

Volcanism in the Andes is caused by the
subduction Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at the convergent boundaries between tectonic plates. Where one tectonic plate converges with a second p ...
of the
Nazca Plate The Nazca plate or Nasca plate, named after the Nazca region of southern Peru, is an oceanic list of tectonic plates, tectonic plate in the eastern Pacific Ocean basin off the west coast of South America. The ongoing subduction, along the Peru– ...
and the Antarctic Plate beneath the South America Plate. The Nazca Plate subducts at a speed of and the Antarctic Plate at a speed of . Volcanism is not continuous along the Andes; rather it occurs in four distinct volcanic zones: Northern Volcanic Zone (NVZ), Central Volcanic Zone (CVZ), Southern Volcanic Zone (SVZ) and Austral Volcanic Zone (AVZ). The formation of
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...
results from the release of
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
and other volatile material from the subducting plate, which is then injected into the above-lying mantle wedge. The volcanic zones are separated by gaps, where subduction occurs at a flatter angle due to the presence of ridges on the downgoing plate: The Nazca Ridge in the gap between the NVZ and CVZ, the Juan Fernandez Ridge in the one between the CVZ and SVZ, and the gap between the SVZ and AVZ is associated with the Chile Triple Junction. Minor ridges are associated with decreased volcanism rather than its cessation; the Taltal Ridge projects under Llullaillaco, an area where magma output was less than to the north and south. About 178
Holocene The Holocene () is the current geologic time scale, geological epoch, beginning approximately 11,700 years ago. It follows the Last Glacial Period, which concluded with the Holocene glacial retreat. The Holocene and the preceding Pleistocene to ...
volcanoes are found in the
Andes The Andes ( ), Andes Mountains or Andean Mountain Range (; ) are the List of longest mountain chains on Earth, longest continental mountain range in the world, forming a continuous highland along the western edge of South America. The range ...
, 60 of which have been active in historical times. In addition, there are large
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcanic eruption. An eruption that ejects large volumes of magma over a short period of time can cause significant detriment to the str ...
s and monogenetic volcanoes. Llullaillaco is one of more than 1,000 volcanoes in the CVZ. At least 44 volcanic centres with historical activity and 18 large caldera-forming volcanoes have been identified in the Central Volcanic Zone; the most active is
Lascar A lascar was a sailor or militiaman from the Indian subcontinent, Southeast Asia, the Arab world, British Somaliland or other lands east of the Cape of Good Hope who was employed on European ships from the 16th century until the mid-20th centur ...
, and Guallatiri and San Pedro have had historical eruptions as well. Volcanism in the Central Volcanic Zone takes place mostly on the
Altiplano The Altiplano (Spanish language, Spanish for "high plain"), Collao (Quechuan languages, Quechua and Aymara language, Aymara: Qullaw, meaning "place of the Qulla people, Qulla") or Andean Plateau, in west-central South America, is the most extens ...
and the Cordillera Occidental, where high
stratovolcano A stratovolcano, also known as a composite volcano, is a typically conical volcano built up by many alternating layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with ...
es with heights of over occur. One of the largest vertical drops on Eart, almost , exists between the summit of Llullaillaco and the Peru-Chile Trench farther west. The Wadati-Benioff zone lies at depth.


Local setting

The region is dominated by large volcanic cones (often more than high) in the Altiplano and Western Cordillera, and extensive salt flats in low-altitude areas. Southeast of the mountain is Salina de Llullaillaco, Salar de Llullaillaco in Argentina, and Salar de Punta Negra northwest of Llullaillaco in Chile. Neighbouring mountains are high Cerro Mitral southwest and high Volcan Chuculay north of Llullaillaco. Cerro Rosado is east of Llullaillaco; it is a high volcano which erupted dacitic lava flows on its northeastern and southern flanks during the
Pliocene The Pliocene ( ; also Pleiocene) is the epoch (geology), epoch in the geologic time scale that extends from 5.33 to 2.58Quaternary The Quaternary ( ) is the current and most recent of the three periods of the Cenozoic Era in the geologic time scale of the International Commission on Stratigraphy (ICS), as well as the current and most recent of the twelve periods of the ...
. Mitral mountain () lies southwest of Llullaillaco and is of Miocene age. It features an eroded crater that opens to the northwest. Iris mountain () north of Llullaillaco is constructed of Pliocene rocks. Other volcanoes in the neighbourhood are Dos Naciones, Cerro Silla, and Cerro 5074. Llullaillaco is associated with a local crustal upwarp. Salar de Llullaillaco is a salt pan east of the volcano, behind Cerro Rosado. It lies at elevation, and features warm springs at its western and southwestern shores. Due east of Salar de Llullaillaco is Salar de Arizaro. The terrain around Llullaillaco consists of
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomina ...
and dacite
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a Natural satellite, moon onto its surface. Lava may be erupted at a volcano or through a Fissure vent, fractu ...
s and pyroclastics of Miocene to Pliocene age. The
basement A basement is any Storey, floor of a building that is not above the grade plane. Especially in residential buildings, it often is used as a utility space for a building, where such items as the Furnace (house heating), furnace, water heating, ...
in the thick crust is formed by
Paleozoic The Paleozoic ( , , ; or Palaeozoic) Era is the first of three Era (geology), geological eras of the Phanerozoic Eon. Beginning 538.8 million years ago (Ma), it succeeds the Neoproterozoic (the last era of the Proterozoic Eon) and ends 251.9 Ma a ...
sedimentary and volcanic rocks, including marine and volcanic sediments and
intrusive rock Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form ''Igneous intrusion, intrusions'', such as batholiths, dike (geology), dikes, Sill (geology), sills, laccoliths, and volcanic necks.I ...
s. It is mostly buried by
Cenozoic The Cenozoic Era ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterized by the dominance of mammals, insects, birds and angiosperms (flowering plants). It is the latest of three g ...
volcanic rocks, except in isolated outcrops both west and east of Llullaillaco: The 282 ± 7 million years old Llullaillaco
pluton In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
ic complex, the
Devonian The Devonian ( ) is a period (geology), geologic period and system (stratigraphy), system of the Paleozoic era (geology), era during the Phanerozoic eon (geology), eon, spanning 60.3 million years from the end of the preceding Silurian per ...
-
Carboniferous The Carboniferous ( ) is a Geologic time scale, geologic period and System (stratigraphy), system of the Paleozoic era (geology), era that spans 60 million years, from the end of the Devonian Period Ma (million years ago) to the beginning of the ...
Zorritas Formation and
Oligocene The Oligocene ( ) is a geologic epoch (geology), epoch of the Paleogene Geologic time scale, Period that extends from about 33.9 million to 23 million years before the present ( to ). As with other older geologic periods, the rock beds that defin ...
-Miocene layers in the Quebrada de las Zorritas. The rocks of Llullaillaco overlie both this basement and
Tertiary Tertiary (from Latin, meaning 'third' or 'of the third degree/order..') may refer to: * Tertiary period, an obsolete geologic period spanning from 66 to 2.6 million years ago * Tertiary (chemistry), a term describing bonding patterns in organic ch ...
ignimbrites. The terrain around the mountain is partially covered by
alluvial Alluvium (, ) is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. Alluvium is also sometimes called alluvial deposit. Alluvium is ...
sediments, debris and
pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of extremely vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicula ...
. Volcanism in the Central Andes began during the
Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately 143.1 Mya. ...
. A pause in volcanism occurred between 38 and 27 million years ago; about 26 million years ago, the Farallon Plate broke up into the Cocos and Nazca Plates, volcanism resumed in the Central Andes and increased subduction of the Nazca Plate during the late Oligocene caused the
volcanic arc A volcanic arc (also known as a magmatic arc) is a belt of volcanoes formed above a subducting oceanic tectonic plate, with the belt arranged in an arc shape as seen from above. Volcanic arcs typically parallel an oceanic trench, with the arc ...
to broaden to about . 25 million years ago, the "Quechua event" triggered the uplift of the Puna-Altiplano, a highland covering a surface area of and reaching an altitude of . In the late Miocene-Pliocene a phase of strong ignimbrite volcanism occurred. About 2 million years ago, the "Diaguita deformation" was characterized by a change in the deformation regimen from crustal shortening to
strike-slip fault In geology, a fault is a planar fracture or discontinuity in a volume of rock across which there has been significant displacement as a result of rock-mass movements. Large faults within Earth's crust result from the action of plate tectonic ...
ing and of volcanism from voluminous felsic eruptions to isolated stratovolcanoes and
back-arc The back-arc region is the area behind a volcanic arc. In island arc, island volcanic arcs, it consists of back-arc basins of oceanic crust with abyssal zone, abyssal depths, which may be separated by remnant arcs, similar to island arcs. In conti ...
mafic volcanism. A slowdown in the subduction may have caused this change. Nowadays most volcanism occurs at the western edge of the Puna, where volcanoes such as Lascar and Llullaillaco formed. Volcanism in the Central Volcanic Zone may be affected by deep-seated lineaments, such as the Olacapato-El Toro and Archibarca lineaments, which control where
volcano A volcano is commonly defined as a vent or fissure in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most oft ...
es and geothermal systems form. They extend diagonally across the volcanic arc and are accompanied by volcanic manifestations at substantial distances from the arc. The Archibarca lineament runs from the Escondida
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
deposit, over Llullaillaco (where it crosses the volcanic arc), Corrida de Cori, Archibarca, Antofalla to the Galán caldera; it influenced the development of Llullaillaco. Other faults are the northeast-southwest trending Guanaqueros and the northwest-southeast trending Imilac-Salina del Fraile; Llullaillaco formed on the trace of the latter fault.


Composition

Llullaillaco has produced dacites, which define a potassium- and aluminium-rich
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic ...
suite. Some rocks display shoshonitic characteristics typical for lavas erupted at large distance from the trenches. Others have medium contents of potassium.
Phenocryst image:montblanc granite phenocrysts.JPG, 300px, Granites often have large feldspar, feldspathic phenocrysts. This granite, from the Switzerland, Swiss side of the Mont Blanc massif, has large white phenocrysts of plagioclase (that have trapezoid sh ...
s are mostly
hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
or
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
with lesser quantities of
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
;
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...
, iron-titanium oxides, opaque minerals,
sphene Titanite, or sphene (), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly rep ...
,
sulfide Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families o ...
s and
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...
are rare. Some phenocrysts show evidence of a complex history. Older rocks contain
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
. Elemental
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
is found at Llullaillaco, specifically at Azufrera Esperanto; sulfur reserves are estimated to amount to . Trace element data are typical for Central Volcanic Zone rocks. Rocks become more
felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...
the younger they are: Older rocks contain more quartz and biotite than recent ones, and display higher iron and lower
alkali metal The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...
contents. The composition may reflect magma differentiation in a solitary
magma chamber A magma chamber is a large pool of liquid rock beneath the surface of the Earth. The molten rock, or magma, in such a chamber is less dense than the surrounding country rock, which produces buoyant forces on the magma that tend to drive it u ...
, but with occasional replenishment with more primitive/ differentiated melts. Processes in the chamber such as magma mixing and crystallization of
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
yielded melts with homogeneous composition and low volatile concentrations that upon eruption formed viscous lava flows. A lithospheric structure probably directed magma flows over long time periods along the same pathway, and magma interacted with the crust as it ascended. The depth of the magma source probably varied over the history of the volcano. The total magma output at Llullaillaco is between and .


Climate

The climate in the region is cold, dry and sunny. There are only limited climate data from Llullaillaco. Temperatures at the summit are about -, with temperature maximums ranging from in summer to in winter. The temperature of the ground fluctuates strongly between day and night, and can reach in summer. The climate is extremely sunny, perhaps one of the sunniest places on Earth, and
UV radiation Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of t ...
is intense. The high insolation is due to the lack of
cloud cover Cloud cover (also known as cloudiness, cloudage, or cloud amount) refers to the fraction of the sky obscured by clouds on average when observed from a particular location. Okta is the usual unit for measurement of the cloud cover. The cloud c ...
, the high altitude, and the close coincidence between
summer solstice The summer solstice or estival solstice occurs when one of Earth's poles has its maximum tilt toward the Sun. It happens twice yearly, once in each hemisphere ( Northern and Southern). The summer solstice is the day with the longest peri ...
with the day where Earth is closest to the Sun which boosts the maximum possible daily insolation. Mean annual precipitation reaches , decreasing from west to east, and is episodic to the point that it is difficult to give average values. It is most often associated with either
convective Convection is single or multiphase fluid flow that occurs spontaneously through the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the convec ...
activity during summer or
cyclone In meteorology, a cyclone () is a large air mass that rotates around a strong center of low atmospheric pressure, counterclockwise in the Northern Hemisphere and clockwise in the Southern Hemisphere as viewed from above (opposite to an ant ...
s during winter.
Snowfall Snow consists of individual ice crystals that grow while suspended in the atmosphere—usually within clouds—and then fall, accumulating on the ground where they undergo further changes. It consists of frozen crystalline water througho ...
can occur down to altitudes of . The Andean Dry Diagonal, where half of the precipitation falls in summer and the other half in winter, crosses the Andes at Llullaillaco. It and the
Atacama Desert The Atacama Desert () is a desert plateau located on the Pacific Ocean, Pacific coast of South America, in the north of Chile. Stretching over a strip of land west of the Andes Mountains, it covers an area of , which increases to if the barre ...
owe its existence to the rainshadow effect of the Andes, air subsidence within
South Pacific High The South Pacific High is a semi-permanent subtropical anticyclone located in the southeast Pacific Ocean. The area of high atmospheric pressure and the presence of the Humboldt Current in the underlying ocean make the west coast of Peru and nort ...
, and the cold
Humboldt Current The Humboldt Current, also called the Peru Current, is a cold, low-salinity ocean current that flows north along the western coast of South America.Montecino, Vivian, and Carina B. Lange. "The Humboldt Current System: Ecosystem components and pro ...
off the Pacific coast. Owing to the high evaporation rates and low precipitation, the soils at Llullaillaco are among the driest on Earth. The climate has not always been uniformly dry. Between 14,000 and 9,500 years ago during the late glacial, a wet period gave rise to lakes in the Altiplano ( Lake Tauca pluvial). Water discharge from Llullaillaco and neighbouring mountains into Salar de Punta Negra increased, leading to the formation of standing water bodies. As glaciers retreated between 15,000 and 10,000 years ago, lakes shrank. Climate was extremely dry between 9,000 and 4,000 years ago and temperatures warmer than today during the early
Holocene The Holocene () is the current geologic time scale, geological epoch, beginning approximately 11,700 years ago. It follows the Last Glacial Period, which concluded with the Holocene glacial retreat. The Holocene and the preceding Pleistocene to ...
(
Holocene Climatic Optimum The Holocene Climate Optimum (HCO) was a warm period in the first half of the Holocene epoch, that occurred in the interval roughly 9,500 to 5,500 years BP, with a thermal maximum around 8000 years BP. It has also been known by many other names ...
). Deposits in Quebrada de las Zorritas valley indicate that between 2,500 and 1,600 years
before present Before Present (BP) or "years before present (YBP)" is a time scale used mainly in archaeology, geology, and other scientific disciplines to specify when events occurred relative to the origin of practical radiocarbon dating in the 1950s. Because ...
runoff was more intense.


Snow and glaciers

It is not clear whether there are
glacier A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier forms where the accumulation of snow exceeds its ablation over many years, often centuries. It acquires ...
s on Llullaillaco – some sources contend that there are no glaciers on Llullaillaco, which would make it the highest mountain in the world without one, while others state that there are small glaciers above altitude, four permanent snowpatches of glaciers on the northeastern and southern flanks, or a single () glacier above elevation. In 2006 the General Water Directorate of Chile stated that there were seven separate ice bodies on the mountain, all on the northwestern side. An ice slab was reported in 1958 on the western slope between elevation, but it is not a glacier. The lack of glaciers is a consequence of the dry climate, as the high
insolation Solar irradiance is the power per unit area ( surface power density) received from the Sun in the form of electromagnetic radiation in the wavelength range of the measuring instrument. Solar irradiance is measured in watts per square metre ...
and dry air cause all snow to evaporate before it can form glaciers. However, Llullaillaco has permanent snow fields in protected niches, which are not large enough to give rise to glaciers. high penitentes occur above altitude, especially in more sheltered areas and around the old crater. The snowline lies at elevation. Temporary snow cover also occurs. The snow and icefields on Llullaillaco reach thicknesses of and supply water to the Salar de Punta Negra. The occurrence of past glaciation at Llullaillaco and its neighbours during the Pleistocene is also uncertain. Some traces of past glacier activity are found in the summit area;
cirque A (; from the Latin word ) is an amphitheatre-like valley formed by Glacier#Erosion, glacial erosion. Alternative names for this landform are corrie (from , meaning a pot or cauldron) and ; ). A cirque may also be a similarly shaped landform a ...
s may have existed on the northwestern slope, where glaciers may have descended to elevation, and a
moraine A moraine is any accumulation of unconsolidated debris (regolith and Rock (geology), rock), sometimes referred to as glacial till, that occurs in both currently and formerly glaciated regions, and that has been previously carried along by a gla ...
girdle may have formed at elevation. There is evidence of glacial landforms destroyed by lava and volcanic
mudflow A mudflow, also known as mudslide or mud flow, is a form of mass wasting involving fast-moving flow of debris and dirt that has become liquified by the addition of water. Such flows can move at speeds ranging from 3 meters/minute to 5 meters/se ...
s. It was once believed that Llullaillaco had experienced three large glaciations, but the "
moraine A moraine is any accumulation of unconsolidated debris (regolith and Rock (geology), rock), sometimes referred to as glacial till, that occurs in both currently and formerly glaciated regions, and that has been previously carried along by a gla ...
s" are actually mudflow/volcanic deposits. Some landforms indicate that any glaciation occurred before the
last glacial maximum The Last Glacial Maximum (LGM), also referred to as the Last Glacial Coldest Period, was the most recent time during the Last Glacial Period where ice sheets were at their greatest extent between 26,000 and 20,000 years ago. Ice sheets covered m ...
. Even when temperatures decreased during the
last glacial maximum The Last Glacial Maximum (LGM), also referred to as the Last Glacial Coldest Period, was the most recent time during the Last Glacial Period where ice sheets were at their greatest extent between 26,000 and 20,000 years ago. Ice sheets covered m ...
, the climate at Llullaillaco may have been too dry to permit glacier development. If any glacier expansion took place, it was during the late glacial when the climate was moister.
Periglacial Periglaciation (adjective: "periglacial", referring to places at the edges of glacial areas) describes geomorphic processes that result from seasonal thawing and freezing, very often in areas of permafrost. The meltwater may refreeze in ice wedg ...
phenomena are observed on Llullaillaco, commencing at altitude and reaching their maximum around on the Chilean and on the Argentine side. They are
solifluction Solifluction is a collective name for gradual processes in which a mass moves down a slope ("mass wasting") related to freeze-thaw activity. This is the standard modern meaning of solifluction, which differs from the original meaning given to i ...
surfaces, cryoplanation surfaces, block ramparts, and
patterned ground Patterned ground is the distinct and often symmetrical natural pattern of geometric shapes formed by the deformation of ground material in periglacial regions. It is typically found in remote regions of the Arctic, Antarctica, and the Outback ...
.
Permafrost Permafrost () is soil or underwater sediment which continuously remains below for two years or more; the oldest permafrost has been continuously frozen for around 700,000 years. Whilst the shallowest permafrost has a vertical extent of below ...
is found at higher altitudes and is connected to the snowfields. Cryoplanation and solifluction landforms are also observed on Iris and Mitral. The landforms probably developed during past periods where the climate was more humid.


Flora and fauna

Vegetation is scarce in the
arid Aridity is the condition of geographical regions which make up approximately 43% of total global available land area, characterized by low annual precipitation, increased temperatures, and limited water availability.Perez-Aguilar, L. Y., Plata ...
climate, especially below altitude where precipitation is too low to permit vegetation development. It takes the form of a
steppe In physical geography, a steppe () is an ecoregion characterized by grassland plains without closed forests except near rivers and lakes. Steppe biomes may include: * the montane grasslands and shrublands biome * the tropical and subtropica ...
, with sparse
cushion plant A cushion plant is a compact, low-growing, mat-forming plant that is found in alpine, subalpine, arctic, or subarctic environments around the world. The term "cushion" is usually applied to woody plants that grow as spreading mats, are limited i ...
s and
shrub A shrub or bush is a small to medium-sized perennial woody plant. Unlike herbaceous plants, shrubs have persistent woody stems above the ground. Shrubs can be either deciduous or evergreen. They are distinguished from trees by their multiple ...
s. '' Acantholippia punensis'', '' Atriplex imbricata'', and '' Cristaria andicola'' are the first plants that grow above this elevation. They are joined at altitude by '' Stipa frigida'' which can be found up to of altitude. The maximum vegetation density is found around with 12% of the surface. At this altitude, '' Adesmia spinosissima'', '' Fabiana bryoides'', '' Mulinum crassifolium'', and '' Parastrephia quadrangularis'' are found in addition to the previously mentioned plants. Above this altitude, plant cover decreases again, probably due to low temperatures, and disappears above elevation; most of the volcano lies above this line. '' Deyeuxia curvula'', '' Distichia muscoides'' and '' Oxychloe andina'' form
wetlands A wetland is a distinct semi-aquatic ecosystem whose groundcovers are flooded or saturated in water, either permanently, for years or decades, or only seasonally. Flooding results in oxygen-poor ( anoxic) processes taking place, especially ...
('' bofedales'') in valleys. The fauna is represented by
deer A deer (: deer) or true deer is a hoofed ruminant ungulate of the family Cervidae (informally the deer family). Cervidae is divided into subfamilies Cervinae (which includes, among others, muntjac, elk (wapiti), red deer, and fallow deer) ...
,
guanaco The guanaco ( ; ''Lama guanicoe'') is a camelid native to South America, closely related to the llama. Guanacos are one of two wild South American camelids; the other species is the vicuña, which lives at higher elevations. Etymology The gua ...
s,
vicuña The vicuña (''Lama vicugna'') or vicuna (both , very rarely spelled ''vicugna'', Vicugna, its former genus name) is one of the two wild South American camelids, which live in the high alpine tundra, alpine areas of the Andes; the other cameli ...
s and vizcachas. Especially around waterbodies are birds like ducks,
flamingo Flamingos or flamingoes () are a type of wading bird in the family Phoenicopteridae, which is the only extant family in the order Phoenicopteriformes. There are four flamingo species distributed throughout the Americas (including the Caribbe ...
s and rheas. Most animals do not reach altitudes above . A
scorpion Scorpions are predatory arachnids of the Order (biology), order Scorpiones. They have eight legs and are easily recognized by a pair of Chela (organ), grasping pincers and a narrow, segmented tail, often carried in a characteristic forward cur ...
species ('' Brachistosternus llullaillaco'') is named after the volcano. There seems to be a population of the Punta de Vacas leaf-eared mouse on Llullaillaco; it likely is the highest-elevation permanent population of any known
vertebrate Vertebrates () are animals with a vertebral column (backbone or spine), and a cranium, or skull. The vertebral column surrounds and protects the spinal cord, while the cranium protects the brain. The vertebrates make up the subphylum Vertebra ...
species.
Lichen A lichen ( , ) is a hybrid colony (biology), colony of algae or cyanobacteria living symbiotically among hypha, filaments of multiple fungus species, along with yeasts and bacteria embedded in the cortex or "skin", in a mutualism (biology), m ...
s grow on rocks.
Algae Algae ( , ; : alga ) is an informal term for any organisms of a large and diverse group of photosynthesis, photosynthetic organisms that are not plants, and includes species from multiple distinct clades. Such organisms range from unicellular ...
including snow algae and
cyanobacteria Cyanobacteria ( ) are a group of autotrophic gram-negative bacteria that can obtain biological energy via oxygenic photosynthesis. The name "cyanobacteria" () refers to their bluish green (cyan) color, which forms the basis of cyanobacteri ...
live on the penitentes, sometimes forming coloured patches, and
alga Algae ( , ; : alga ) is an informal term for any organisms of a large and diverse group of photosynthetic organisms that are not plants, and includes species from multiple distinct clades. Such organisms range from unicellular microalgae, suc ...
e and
microbial mat A microbial mat is a multi-layered sheet or biofilm of microbial colonies, composed of mainly bacteria and/or archaea. Microbial mats grow at interfaces between different types of material, mostly on submerged or moist surfaces, but a few surviv ...
s grow in Lago Llullaillaco. A species of bacterium ('' Subtercola vilae'') was discovered in the lake. The microorganisms in the lake resemble these of other Central Andean lakes, such as Aguas Calientes and Lake Licancabur, in some ways and differ in others. Species-poor
fungal A fungus (: fungi , , , or ; or funguses) is any member of the group of eukaryotic organisms that includes microorganisms such as yeasts and molds, as well as the more familiar mushrooms. These organisms are classified as one of the tradit ...
and
bacterial Bacteria (; : bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were among the ...
communities have been found in the soils (more precisely: tephra) of Llullaillaco, with the fungus '' Naganishia friedmanii'' being the most common species. The soils are extremely poor in
organic matter Organic matter, organic material or natural organic matter is the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have come fro ...
and have simple ecological communities. They have to survive environmental conditions among the most extreme on the planet, with aridity, strong UV radiation, daily freeze-thaw cycles and a lack of nutrients. Life may depend on unusual food sources like gaseous
carbon monoxide Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
or organic material (e.g remains of plants) transported to the mountain by winds, while
photosynthetic Photosynthesis ( ) is a Biological system, system of biological processes by which Photoautotrophism, photosynthetic organisms, such as most plants, algae, and cyanobacteria, convert light energy, typically from sunlight, into the chemical ener ...
organisms are limited to sites with higher water availability. The area of Llullaillaco is part of the Llullaillaco National Park, a
protected area Protected areas or conservation areas are locations which receive protection because of their recognized natural or cultural values. Protected areas are those areas in which human presence or the exploitation of natural resources (e.g. firewood ...
created in 1995 and named after the mountain.
Air pollution Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
from the Escondida copper mine may reach Llullaillaco and threaten ecosystems there.


Archaeology

Archaeological sites on mountains are widespread in the Andes, with forty mountains featuring sites in Salta Province alone. In the 1950s a number of
archaeological site An archaeological site is a place (or group of physical sites) in which evidence of past activity is preserved (either prehistoric or recorded history, historic or contemporary), and which has been, or may be, investigated using the discipline ...
s were discovered on Llullaillaco. The initial discovery was in 1952; further expeditions took place during the second half of the 20th century. Some sites were looted after their discovery. Three Inca roads come to Llullaillaco from Salar de Llullaillaco, Salar de Punta Negra and Socompa, and meet at a '' tambo'' (inn) at an altitude of on the northeastern flank. The ''tambo'' consists of numerous buildings; it was probably a
base camp Mountaineering, mountain climbing, or alpinism is a set of outdoor activities that involves ascending mountains. Mountaineering-related activities include traditional outdoor climbing, skiing, and traversing via ferratas that have become sp ...
for ascents. On the road from Salar de Llullaillaco is a
cemetery A cemetery, burial ground, gravesite, graveyard, or a green space called a memorial park or memorial garden, is a place where the remains of many death, dead people are burial, buried or otherwise entombed. The word ''cemetery'' (from Greek ...
, where 16 bodies were found in 1972. The cemetery may host the bodies of people killed in the construction of the Llullaillaco archaeological sites. Half-destroyed walls form a building complex, which was built on terraces and partly buried by loose debris from the mountain above. Two water sites lie between the cemetery and the ''tambo''. An Inca ceremonial path begins at the ''tambo'' and leads up the volcano. It is wide (narrower in steeper reaches) and marked by wooden posts and
cairn A cairn is a human-made pile (or stack) of stones raised for a purpose, usually as a marker or as a burial mound. The word ''cairn'' comes from the (plural ). Cairns have been and are used for a broad variety of purposes. In prehistory, t ...
s, probably for the case that the path is covered in snow. It continues past two waystations at and elevation, which consist of small buildings and protecting walls. At altitude, the path splits at the so-called "Portezuelo del Inca". One continues to the summit, the other to a plateau at elevation. Another set of protecting walls and small buildings form another waystation at elevation. Two enclosures and a platform are on the plateau, forming the highest archaeological site on Earth. The Inca roads connect with the major north–south Inca road that runs between
San Pedro de Atacama San Pedro de Atacama is a Chilean town and commune in El Loa Province, Antofagasta Region. It is located east of Antofagasta, some 106 km (60 mi) southeast of Calama and the Chuquicamata copper mine, overlooking the Licancabur volcan ...
and Copiapo. Infrastructure such as road markers, shelters and ''tambos'' are found along the road close to Llullaillaco. The paths on Llullaillaco are not simple footpaths but equipped with retaining walls, delimited edges and staircases (above "Portezuelo del Inca"). They were built by the Inca, their construction methods perhaps reflecting Inca mythology. They were discovered by Mathias Rebitsch in 1958. Llullaillaco appears to have been the most important Inca
sacred mountain Sacred mountains are central to certain religions, and are usually the subjects of many legends. For many, the most symbolic aspect of a mountain is the peak because it is believed that it is closest to heaven or other religious realms. Many reli ...
in the region and possibly all of the Central Andes, and the complex of archaeological sites is one of the most significant in the Andes. In the case of Llullaillaco, they may have been sites of
pilgrimage A pilgrimage is a travel, journey to a holy place, which can lead to a personal transformation, after which the pilgrim returns to their daily life. A pilgrim (from the Latin ''peregrinus'') is a traveler (literally one who has come from afar) w ...
used by the local
Atacama people The Atacama people, also called Atacameño, are an Indigenous people from the Atacama Desert and altiplano region in the north of Chile and Argentina and southern Bolivia, mainly the Antofagasta Region. According to the Argentinean Census in 2010 ...
during Inca rule, no evidence of pre-Inca activity has been found. About forty-five structures have been identified at Llullaillaco, distributed across several sites and with clear architectonic differences, implying not all of them were built by the state. Among the structures are
stone circle A stone circle is a ring of megalithic standing stones. Most are found in Northwestern Europe – especially Stone circles in the British Isles and Brittany – and typically date from the Late Neolithic and Early Bronze Age, with most being ...
s and roofed buildings. Archeological sites are also found in the valleys that drain Llullaillaco towards the Salar de Punta Negra, including the Quebrada Llullaillaco and the Quebrada de las Zorritas where the Inca paths ascend the mountain. The complex of archaeological sites has become subject of scientific research. Because of the findings, the summit area of the volcano in 2001 was classified as a ''Lugar Histórico Nacional'' by the government of Argentina, and on 24 June 2014 the entire Llullaillaco complex was declared a
World Heritage Site World Heritage Sites are landmarks and areas with legal protection under an treaty, international treaty administered by UNESCO for having cultural, historical, or scientific significance. The sites are judged to contain "cultural and natural ...
by
UNESCO The United Nations Educational, Scientific and Cultural Organization (UNESCO ) is a List of specialized agencies of the United Nations, specialized agency of the United Nations (UN) with the aim of promoting world peace and International secur ...
. A number of myths are associated with Llullaillaco, and the mountain is still important to the inhabitants of Socaire east of the
Salar de Atacama Salar de Atacama, located south of San Pedro de Atacama, is the largest Salt pan (geology), salt flat in Chile. It is surrounded by mountains and lacks drainage outlets. To the east, it is enclosed by the main chain of the Andes, while to the wes ...
, from where it is visible. Some ascents are done for ritual reasons.


Children of Llullaillaco

In March 1999, excavations of the platform by a team of archaeologists led by Johan Reinhard, found three
mummies A mummy is a dead human or an animal whose soft tissues and Organ (biology), organs have been preserved by either intentional or accidental exposure to Chemical substance, chemicals, extreme cold, very low humidity, or lack of air, so that the ...
of children buried at depth in partially natural, partially excavated pits. They were a 7-year-old boy, a 6-year-old girl and a 15-year-old girl (later research has suggested lower ages for all three), which are known as "El Niño", "La Niña del Rayo" and "La Doncella" respectively. They were found clothed and in a seated position and were ostensibly human sacrifices offered to the gods of the
Incan The Inca Empire, officially known as the Realm of the Four Parts (, ), was the largest empire in pre-Columbian America. The administrative, political, and military center of the empire was in the city of Cusco. The Inca civilisation rose fr ...
pantheon on mountaintops. It is not clear how they were killed; most likely, they were suffocated or buried alive but unconscious, and the boy may have been dead before reaching the summit. The younger children bore traces of cranial deformation. The Llullaillaco bodies are among the best preserved known
pre-Columbian In the history of the Americas, the pre-Columbian era, also known as the pre-contact era, or as the pre-Cabraline era specifically in Brazil, spans from the initial peopling of the Americas in the Upper Paleolithic to the onset of European col ...
mummies owing to the cold, dry and oxygen-poor conditions of the summit which prevent microbial decay of the bodies – except for the youngest mummy, which had been damaged by
lightning Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
. Inca human sacrifices were initiated for various reasons, either to mark particular events such as the death of an Inca Emperor, to appease nature during
natural disaster A natural disaster is the very harmful impact on a society or community brought by natural phenomenon or Hazard#Natural hazard, hazard. Some examples of natural hazards include avalanches, droughts, earthquakes, floods, heat waves, landslides ...
s or to secure resources from the mountain gods. The chosen sacrifices were children, as the gods were thought to prefer pure offerings, preferably children with unblemished bodies and virgin girls. According to historical sources and analyses of the mummies, the children came from families with high social standing and were well nourished. They were brought to mountains thousands of kilometres away and killed at the top. Other archaeological objects found along with the mummies included: Bags made out of
leather Leather is a strong, flexible and durable material obtained from the tanning (leather), tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffal ...
, headdresses with
feather Feathers are epidermal growths that form a distinctive outer covering, or plumage, on both avian (bird) and some non-avian dinosaurs and other archosaurs. They are the most complex integumentary structures found in vertebrates and an exa ...
s,
pottery Pottery is the process and the products of forming vessels and other objects with clay and other raw materials, which are fired at high temperatures to give them a hard and durable form. The place where such wares are made by a ''potter'' is al ...
(cooking instruments like jars, plates, pots and vases),
statues A statue is a free-standing sculpture in which the realistic, full-length figures of persons or animals are carved or cast in a durable material such as wood, metal or stone. Typical statues are life-sized or close to life-size. A sculpture ...
representing both people (male and female) and animals made out of
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
,
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
or ''
Spondylus ''Spondylus'' is a genus of bivalve molluscs, the only genus in the family Spondylidae and subfamily Spondylinae. They are known in English as spiny oysters or thorny oysters (although they are not, in fact, true oysters, but are related to sc ...
'' (
oyster Oyster is the common name for a number of different families of salt-water bivalve molluscs that live in marine or brackish habitats. In some species, the valves are highly calcified, and many are somewhat irregular in shape. Many, but no ...
) shells, shoes and
textile Textile is an Hyponymy and hypernymy, umbrella term that includes various Fiber, fiber-based materials, including fibers, yarns, Staple (textiles)#Filament fiber, filaments, Thread (yarn), threads, and different types of #Fabric, fabric. ...
s, wooden and woolen vessels. The vessels and bags contained
coca Coca is any of the four cultivated plants in the family Erythroxylaceae, native to western South America. Coca is known worldwide for its psychoactive alkaloid, cocaine. Coca leaves contain cocaine which acts as a mild stimulant when chewed or ...
leaves, hairs and human nails. A total of 145 objects were found together with the mummies.
Radiocarbon dating Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for Chronological dating, determining the age of an object containing organic material by using the properties of carbon-14, radiocarbon, a radioactive Isotop ...
has yielded an age of death of 1430–1520 AD for one of the mummies. Their discovery drew interest among specialists and the public, and has been cited as a cause for increased
tourism Tourism is travel for pleasure, and the Commerce, commercial activity of providing and supporting such travel. World Tourism Organization, UN Tourism defines tourism more generally, in terms which go "beyond the common perception of tourism as ...
to the mountain and increased attention dedicated to native people issues in the region. In 2003 the mummies were at the Catholic University of Salta, before being transferred to the Museum of High Altitude Archaeology of Argentina in 2007, which had been built explicitly to host these mummies. They are kept under special storage conditions to prevent damage. The bodies found at Llullaillaco – both the mummies on the summit and these in the cemetery – have been subject to various scientific analyses. The placement of the mummies in museums led to lengthy disputes with organizations advocating the rights of indigenous people.


Eruption history

The volcano developed in two stages, Llullaillaco I and Llullaillaco II. The first stage originated from two centres (Llullaillaco and Azufrera Esperanto) developed in a north–south line, producing up to long lava flows and lava domes in their summit regions. The cones and associated lava flows are heavily eroded by
glaciation A glacial period (alternatively glacial or glaciation) is an interval of time (thousands of years) within an ice age that is marked by colder temperatures and glacier advances. Interglacials, on the other hand, are periods of warmer climate be ...
and
hydrothermal alteration Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a Rock (geology), rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in t ...
and buried by more recent volcanic rocks, but still make up about 70% of the surface of the volcano especially in its western sector. The former crater of Llullaillaco forms a plateau at elevation. At the high Azufrera Esperanto mountain north of Llullaillaco little original volcanic substance is preserved. Erosion has exposed deeply altered whiteish rock there. Llullaillaco II on the southern and northeastern flank is better preserved; the toes of the lava flows reach thicknesses of . Its lava flows are less extensive than the ones of Llullaillaco I. Pyroclastic flow deposits with a composition similar to Llullaillaco II are found on the southern slope of the volcano and may have formed before the lava eruptions began. An older unit is formed by ignimbrites and
pyroclastic flow A pyroclastic flow (also known as a pyroclastic density current or a pyroclastic cloud) is a fast-moving current of hot gas and volcanic matter (collectively known as tephra) that flows along the ground away from a volcano at average speeds of b ...
s. Older lava flows extend west from the volcano and are partly buried by sediments closer to the edifice. The landslide probably took place during an eruption. An
explosive eruption In volcanology, an explosive eruption is a volcanic eruption of the most violent type. A notable example is the 1980 eruption of Mount St. Helens. Such eruptions result when sufficient gas has dissolved under pressure within a Viscosity, viscous ...
of Llullaillaco II produced a long deposit of lava blocks and pyroclastic pumice, with fallout reaching Cerro Rosado. It is possible that some lava flows interacted with glaciers, causing them to melt, and volcanic rocks overran glacial and periglacial landforms. The oldest dated rocks at Llullaillaco were erupted 1.5 ± 0.4 million years ago, forming a lava flow northwest of Llullaillaco's main edifice. Llullaillaco I is of early Pleistocene age, but the time of the transition between Llullaillaco I and Llullaillaco II is unclear: Either it took place 450,000 years ago, or less than 41,000 ± 1,000 years ago. Ages of 5,600 ± 250 years have been obtained for Llullaillaco II rocks recovered at an altitude of over . The young-looking lava flows were at first thought to be of Holocene age, but dating methods yielded ages of less than one million years ( potassium-argon dating) for the northern flow, 48,000 ± 12,000 years ( argon-argon dating) on the southwestern flow and 930 ± 140 years (
surface exposure dating Surface exposure dating is a collection of geochronological techniques for estimating the length of time that a rock has been exposed at or near Earth's surface. Surface exposure dating is used to date glacial advances and retreats, erosion hist ...
) on a different flow.


Historical activity and hazards

Llullaillaco has been active in historical time, making it the highest historically active volcano on Earth. Three eruptions were recorded during the 19th century, which were however not directly observed and are unconfirmed: * A small explosive eruption took place in February 1854. * In September 1868, (according to a 1899 report) large fissures opened on its slopes and lava flowed out of the volcano. * The May 1877 explosive eruption may have been a flank eruption triggered by the 1877 Iquique earthquake. Activity was probably limited to the emission of steam and ash, given the presence of the archaeological sites. Other reports mention eruptions in 1920, 1931, 1936 and 1960. According to anecdotes recorded in the 19th century, the mountain occasionally smoked, including during the mapping of the Chile-Argentina border on 5 May 1879. Allegedly palaeontologist and zoologist
Rodolfo Amando Philippi Rodolfo Amando (or Rudolph Amandus) Philippi (14 September 1808 – 23 July 1904) was a German–Chilean paleontologist and zoologist. Philippi contributed primarily to malacology and paleontology, but also published a major work on Diptera of C ...
saw the mountain smoke in 1854, but Philippi's own report makes no mention of smoke. The volcano is currently considered dormant and there are no known
fumarole A fumarole (or fumerole) is a vent in the surface of the Earth or another rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...
s, but Lago Llullaillaco and some ice on the volcano bear traces of geothermal heating. There are warm springs around Salar de Llullaillaco. Llullaillaco is classified as being mid-range in terms of dangerousness to Argentina, being its 16th most dangerous volcano in a list of 38. Future eruptive activity may result in the emission of pyroclastic flows and lava flows and may cause sector collapses, although they would be a small danger to life or property, given that the area is sparsely inhabited and largely devoid of economic activity.


Climbing and access

The easiest ascent is along the former Inca route on the northeastern flank of the mountain, which can be reached from Chile. The intense UV radiation, lack of oxygen,
blizzard A blizzard is a severe Winter storm, snowstorm characterized by strong sustained winds and low visibility, lasting for a prolonged period of time—typically at least three or four hours. A ground blizzard is a weather condition where snow th ...
s,
hypothermia Hypothermia is defined as a body core temperature below in humans. Symptoms depend on the temperature. In mild hypothermia, there is shivering and mental confusion. In moderate hypothermia, shivering stops and confusion increases. In severe ...
and lightning are common hazards at Llullaillaco. There are reports of
landmine A land mine, or landmine, is an explosive weapon often concealed under or camouflaged on the ground, and designed to destroy or disable enemy targets as they pass over or near it. Land mines are divided into two types: anti-tank mines, whi ...
s in the area; the mines were removed in 2006 thanks to a multinational effort.A new base camp was inaugurated in 2020. The volcano can be reached from Argentina via Tolar Grande. Access from Chile is through roads which from
Chile Route 5 Chile Highway 5 or Route 5 known locally as ''Ruta 5'' is Chile's longest route, . It is part of the Pan-American Highway. Stretch It runs from the Peruvian border connecting with Peru Highway 1 north of Arica to Puerto Montt where it conn ...
, Socompa Pass,
Taltal Taltal is a Chilean commune and city in Antofagasta Province, Antofagasta Region. According to the 2012 census, the commune has a population of 11,132 and has an area of . The commune is home to Paranal Observatory and includes the northern po ...
or Toconao lead to Salar de Punta Negra. From there, a road leads to Llullaillaco. It splits at Aguada de las Zorritas in three: One road ends close to a mountain pass north of Llullaillaco, a second ends at Azufrera Esperanto and the third rounds the volcano from southwest, crossing into Argentina south of Llullaillaco. According to John Biggar, some roads are dead ends. Two ascent routes with camps lead from Chile and Argentina to the summit. The first known ascent by Westerners was by the Chileans Bion González and Juan Harsheim in 1952 but the indigenous people had ascended it long before. The volcano is the highest mountain with proven prehistoric ascents and demonstrates that high altitudes were no obstacle to indigenous people in the Americas, who also built on mountains with primitive technology.


See also

*
List of volcanoes in Chile The Smithsonian Institution's Global Volcanism Program lists 105 volcanoes in Chile that have been active during the Holocene.List of volcanoes in Argentina This is a list of active and extinct volcanoes in Argentina. Volcanoes References

{{Andean volcanoes, state=collapsed Volcanoes of Argentina, Lists of landforms of Argentina, Volcanoes Lists of volcanoes, Argentina Andean Vol ...
* List of Andean peaks with known pre-Columbian ascents *
List of volcanoes by elevation A list (incomplete) of volcanoes on Earth arranged by elevation in metres. Above 6,000 metres Above 5,000 metres Above 4,000 metres Above 3,000 metres Above 2,000 metres Above 1,000 metres Below 1,000 metres Measured ...


References


Sources

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External links


Complete description, history, place name and routes of Llullaillaco in Andeshandbook

Museum of High Mountain Archaeology
* * {{authority control Stratovolcanoes of Argentina Stratovolcanoes of Chile Atacama Desert Volcanoes of Antofagasta Region Volcanoes of Salta Province Andean Volcanic Belt Polygenetic volcanoes Subduction volcanoes Argentina–Chile border International mountains of South America Holocene stratovolcanoes Pleistocene stratovolcanoes Pleistocene South America Quaternary South America Six-thousanders of the Andes Mountains of Antofagasta Region Mountains of Salta Province Puna de Atacama