Boron Group
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The boron group are the
chemical element A chemical element is a chemical substance whose atoms all have the same number of protons. The number of protons is called the atomic number of that element. For example, oxygen has an atomic number of 8: each oxygen atom has 8 protons in its ...
s in group 13 of the
periodic table The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows (" periods") and columns (" groups"). It is an icon of chemistry and is widely used in physics and other s ...
, consisting of
boron Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...
(B),
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
(Al),
gallium Gallium is a chemical element; it has Chemical symbol, symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in 1875, elemental gallium is a soft, silvery metal at standard temperature and pressure. ...
(Ga),
indium Indium is a chemical element; it has Symbol (chemistry), symbol In and atomic number 49. It is a silvery-white post-transition metal and one of the softest elements. Chemically, indium is similar to gallium and thallium, and its properties are la ...
(In),
thallium Thallium is a chemical element; it has Symbol (chemistry), symbol Tl and atomic number 81. It is a silvery-white post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Che ...
(Tl) and nihonium (Nh). This group lies in the
p-block A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term seems to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-bl ...
of the periodic table. The elements in the boron group are characterized by having three
valence electron In chemistry and physics, valence electrons are electrons in the outermost shell of an atom, and that can participate in the formation of a chemical bond if the outermost shell is not closed. In a single covalent bond, a shared pair forms with b ...
s. These elements have also been referred to as the triels. Several group 13 elements have biological roles in the
ecosystem An ecosystem (or ecological system) is a system formed by Organism, organisms in interaction with their Biophysical environment, environment. The Biotic material, biotic and abiotic components are linked together through nutrient cycles and en ...
. Boron is a trace element in humans and is essential for some plants. Lack of boron can lead to stunted plant growth, while an excess can also cause harm by inhibiting growth. Aluminium has neither a biological role nor significant toxicity and is considered safe. Indium and gallium can stimulate metabolism; gallium is credited with the ability to bind itself to iron proteins. Thallium is highly toxic, interfering with the function of numerous vital enzymes, and has seen use as a
pesticide Pesticides are substances that are used to control pests. They include herbicides, insecticides, nematicides, fungicides, and many others (see table). The most common of these are herbicides, which account for approximately 50% of all p ...
.


Characteristics

Like other groups, the members of this family show patterns in
electron configuration In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon ato ...
, especially in the outermost shells, resulting in trends in chemical behavior: The boron group is notable for trends in the electron configuration, as shown above, and in some of its elements' characteristics. Boron differs from the other group members in its
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...
, refractivity and reluctance to participate in metallic bonding. An example of a trend in reactivity is boron's tendency to form reactive compounds with hydrogen. Although situated in
p-block A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term seems to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-bl ...
, the group is notorious for violation of the
octet rule The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The ru ...
by its members boron and (to a lesser extent) aluminium. All members of the group are characterized as ''
trivalent In chemistry, the valence (US spelling) or valency (British spelling) of an atom is a measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Valence is generally understood to be the number of chemica ...
''.


Chemical reactivity


Hydrides

Most of the elements in the boron group show increasing reactivity as the elements get heavier in atomic mass and higher in atomic number.
Boron Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...
, the first element in the group, is generally unreactive with many elements except at high temperatures, although it is capable of forming many compounds with
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
, sometimes called '' boranes''. The simplest borane is diborane, or B2H6. Another example is B10H14. The next group-13 elements,
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
and
gallium Gallium is a chemical element; it has Chemical symbol, symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in 1875, elemental gallium is a soft, silvery metal at standard temperature and pressure. ...
, form fewer stable hydrides, although both AlH3 and GaH3 exist. Indium, the next element in the group, is not known to form many hydrides, except in complex compounds such as the
phosphine Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula , classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting ...
complex (Cy= cyclohexyl). No stable compound of thallium and hydrogen has been synthesized in any laboratory.


Oxides

All of the boron-group elements are known to form a trivalent oxide, with two atoms of the element bonded covalently with three atoms of
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
. These elements show a trend of increasing pH (from
acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
ic to
basic Basic or BASIC may refer to: Science and technology * BASIC, a computer programming language * Basic (chemistry), having the properties of a base * Basic access authentication, in HTTP Entertainment * Basic (film), ''Basic'' (film), a 2003 film ...
).
Boron oxide Boron oxide may refer to one of several oxides of boron: *Boron trioxide (B2O3, diboron trioxide), the most common form *Boron monoxide (BO) *Boron suboxide Boron suboxide (chemical formula B6O) is a solid compound with a structure built of eight ...
(B2O3) is slightly acidic,
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
and gallium oxide (Al2O3 and Ga2O3 respectively) are amphoteric, indium(III) oxide (In2O3) is nearly amphoteric, and
thallium(III) oxide Thallium(III) oxide, also known as thallic oxide, is a chemical compound of thallium and oxygen. It occurs in nature as the rare mineral avicennite. Its structure is related to that of Mn2O3 which has a bixbyite like structure. Tl2O3 is metallic ...
(Tl2O3) is a Lewis base because it dissolves in acids to form salts. Each of these compounds are stable, but thallium oxide decomposes at temperatures higher than 875 °C.


Halides

The elements in group 13 are also capable of forming stable compounds with the
halogens The halogens () are a group (periodic table), group in the periodic table consisting of six chemically related chemical element, elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and ten ...
, usually with the formula MX3 (where M is a boron-group element and X is a halogen.)
Fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
, the first halogen, is able to form stable compounds with every element that has been tested (except
neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...
and
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
), and the boron group is no exception. It is even hypothesized that nihonium could form a compound with fluorine, NhF3, before spontaneously decaying due to nihonium's radioactivity.
Chlorine Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
also forms stable compounds with all of the elements in the boron group, including thallium, and is hypothesized to react with nihonium. All of the elements will react with
bromine Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between th ...
under the right conditions, as with the other halogens but less vigorously than either chlorine or fluorine.
Iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
will react with all natural elements in the periodic table except for the noble gases, and is notable for its explosive reaction with aluminium to form AlI3.
Astatine Astatine is a chemical element; it has Symbol (chemistry), symbol At and atomic number 85. It is the abundance of elements in Earth's crust, rarest naturally occurring element in the Earth's crust, occurring only as the Decay chain, decay product ...
, the fifth halogen, has only formed a few compounds, due to its radioactivity and short half-life, and no reports of a compound with an At–Al, –Ga, –In, –Tl, or –Nh bond have been seen, although scientists think that it should form salts with metals.
Tennessine Tennessine is a synthetic element; it has Chemical symbol, symbol Ts and atomic number 117. It has the second-highest atomic number and joint-highest atomic mass of all known elements and is the penultimate element of the Period 7 element, 7th ...
, the sixth and final member of group 17, may also form compounds with the elements in the boron group; however, because Tennessine is purely synthetic and thus must be created artificially, its chemistry has not been investigated, and any compounds would likely decay nearly instantly after formation due to its extreme radioactivity.


Physical properties

It has been noticed that the elements in the boron group have similar
physical properties A physical property is any property of a physical system that is measurable. The changes in the physical properties of a system can be used to describe its changes between momentary states. A quantifiable physical property is called ''physical ...
, although most of boron's are exceptional. For example, all of the elements in the boron group, except for boron itself, are soft. Moreover, all of the other elements in group 13 are relatively reactive at moderate
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
s, while boron's reactivity only becomes comparable at very high temperatures. One characteristic that all do have in common is having three electrons in their
valence shell In chemistry and physics, valence electrons are electrons in the outermost shell of an atom, and that can participate in the formation of a chemical bond if the outermost shell is not closed. In a single covalent bond, a shared pair forms with b ...
s. Boron, being a metalloid, is a thermal and electrical insulator at room temperature, but a good conductor of heat and electricity at high temperatures. Unlike boron, the metals in the group are good conductors under normal conditions. This is in accordance with the long-standing
generalization A generalization is a form of abstraction whereby common properties of specific instances are formulated as general concepts or claims. Generalizations posit the existence of a domain or set of elements, as well as one or more common characteri ...
that all metals conduct heat and electricity better than most non-metals.


Oxidation states

The inert s-pair effect is significant in the group-13 elements, especially the heavier ones like thallium. This results in a variety of oxidation states. In the lighter elements, the +3 state is the most stable, but the +1 state becomes more prevalent with increasing atomic number, and is the most stable for thallium. Boron is capable of forming compounds with lower oxidization states, of +1 or +2, and aluminium can do the same. Gallium can form compounds with the oxidation states +1, +2 and +3. Indium is like gallium, but its +1 compounds are more stable than those of the lighter elements. The strength of the inert-pair effect is maximal in thallium, which is generally only stable in the oxidation state of +1, although the +3 state is seen in some compounds. Stable and monomeric gallium, indium and thallium radicals with a formal oxidation state of +2 have since been reported. Nihonium may have +5 oxidation state.


Periodic trends

There are several trends that can be observed in the properties of the boron group members. The boiling points of these elements drop from period to period, while densities tend to rise.


Nuclear

With the exception of the synthetic nihonium, all of the elements of the boron group have stable
isotopes Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), but ...
. Because all their
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
s are odd, boron, gallium and thallium have only two stable isotopes, while aluminium and indium are monoisotopic, having only one, although most indium found in nature is the weakly radioactive 115In. 10B and 11B are both stable, as are 27Al, 69Ga and 71Ga, 113In, and 203Tl and 205Tl. All of these isotopes are readily found in macroscopic quantities in nature. In theory, though, all isotopes with an
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
greater than 66 are supposed to be unstable to
alpha decay Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
. Conversely, all elements with atomic numbers are less than or equal to 66 (except Tc, Pm, Sm and Eu) have at least one isotope that is theoretically energetically stable to all forms of decay (with the exception of
proton decay In particle physics, proton decay is a hypothetical form of particle decay in which the proton decays into lighter subatomic particles, such as a neutral pion and a positron. The proton decay hypothesis was first formulated by Andrei Sakharov ...
, which has never been observed, and
spontaneous fission Spontaneous fission (SF) is a form of radioactive decay in which a heavy atomic nucleus splits into two or more lighter nuclei. In contrast to induced fission, there is no inciting particle to trigger the decay; it is a purely probabilistic proc ...
, which is theoretically possible for elements with atomic numbers greater than 40). Like all other elements, the elements of the boron group have radioactive isotopes, either found in trace quantities in nature or produced synthetically. The longest-lived of these unstable isotopes is the indium isotope 115In, with its extremely long
half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...
of . This isotope makes up the vast majority of all naturally occurring indium despite its slight radioactivity. The shortest-lived is 7B, with a half-life of a mere , being the boron isotope with the fewest neutrons and a enough to measure. Some radioisotopes have important roles in scientific research; a few are used in the production of goods for commercial use or, more rarely, as a component of finished products.


History

The boron group has had many names over the years. According to former conventions it was Group IIIB in the European naming system and Group IIIA in the American. The group has also gained two collective names, "earth metals" and "triels". The latter name is derived from the Latin prefix ''tri-'' ("three") and refers to the three valence electrons that all of these elements, without exception, have in their
valence shell In chemistry and physics, valence electrons are electrons in the outermost shell of an atom, and that can participate in the formation of a chemical bond if the outermost shell is not closed. In a single covalent bond, a shared pair forms with b ...
s. The name "triels" was first suggested by International Union of Pure and Applied Chemistry (IUPAC) in 1970. Boron was known to the ancient Egyptians, but only in the mineral
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
. The metalloid element was not known in its pure form until 1808, when
Humphry Davy Sir Humphry Davy, 1st Baronet (17 December 177829 May 1829) was a British chemist and inventor who invented the Davy lamp and a very early form of arc lamp. He is also remembered for isolating, by using electricity, several Chemical element, e ...
was able to extract it by the method of
electrolysis In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of c ...
. Davy devised an experiment in which he dissolved a boron-containing compound in water and sent an electric current through it, causing the elements of the compound to separate into their pure states. To produce larger quantities he shifted from electrolysis to reduction with sodium. Davy named the element ''boracium''. At the same time two French chemists,
Joseph Louis Gay-Lussac Joseph Louis Gay-Lussac ( , ; ; 6 December 1778 – 9 May 1850) was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen by volume (with Alexander von Humboldt), f ...
and Louis Jacques Thénard, used iron to reduce boric acid. The boron they produced was
oxidize Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
d to boron oxide. Aluminium, like boron, was first known in minerals before it was finally extracted from
alum An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , such that is a valence (chemistry), monovalent cation such as potassium ...
, a common mineral in some areas of the world.
Antoine Lavoisier Antoine-Laurent de Lavoisier ( ; ; 26 August 17438 May 1794), When reduced without charcoal, it gave off an air which supported respiration and combustion in an enhanced way. He concluded that this was just a pure form of common air and that i ...
and Humphry Davy had each separately tried to extract it. Although neither succeeded, Davy had given the metal its current name. It was only in 1825 that the Danish scientist
Hans Christian Ørsted Hans Christian Ørsted (; 14 August 1777 – 9 March 1851), sometimes Transliteration, transliterated as Oersted ( ), was a Danish chemist and physicist who discovered that electric currents create magnetic fields. This phenomenon is known as ...
successfully prepared a rather impure form of the element. Many improvements followed, a significant advance being made just two years later by
Friedrich Wöhler Friedrich Wöhler Royal Society of London, FRS(For) HonFRSE (; 31 July 180023 September 1882) was a German chemist known for his work in both organic chemistry, organic and inorganic chemistry, being the first to isolate the chemical elements be ...
, whose slightly modified procedure still yielded an impure product. The first pure sample of aluminium is credited to Henri Etienne Sainte-Claire Deville, who substituted sodium for potassium in the procedure. At that time aluminium was considered precious, and it was displayed next to such metals as gold and silver. The method used today,
electrolysis In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of c ...
of aluminium oxide dissolved in cryolite, was developed by Charles Martin Hall and
Paul Héroult Paul (Louis-Toussaint) Héroult (10 April 1863 – 9 May 1914) was a French scientist. He was one of the inventors of the Hall-Héroult process for smelting aluminium, and developed the first successful commercial electric arc furnace. He li ...
in the late 1880s. Thallium, the heaviest stable element in the boron group, was discovered by
William Crookes Sir William Crookes (; 17 June 1832 – 4 April 1919) was an English chemist and physicist who attended the Royal College of Chemistry, now part of Imperial College London, and worked on spectroscopy. He was a pioneer of vacuum tubes, inventing ...
and
Claude-Auguste Lamy Claude Auguste Lamy (; 15 June 1820 – 20 March 1878) was a French physicist and chemist chemist who discovered the element thallium independently from William Crookes in 1862; as a result, they are considered co-discoverers, although th ...
in 1861. Unlike gallium and indium, thallium had not been predicted by
Dmitri Mendeleev Dmitri Ivanovich Mendeleev ( ; ) was a Russian chemist known for formulating the periodic law and creating a version of the periodic table of elements. He used the periodic law not only to correct the then-accepted properties of some known ele ...
, having been discovered before Mendeleev invented the periodic table. As a result, no one was really looking for it until the 1850s when Crookes and Lamy were examining residues from sulfuric acid production. In the spectra they saw a completely new line, a streak of deep green, which Crookes named after the Greek word θαλλός (), referring to a green shoot or twig. Lamy was able to produce larger amounts of the new metal and determined most of its chemical and physical properties. Indium is the fourth element of the boron group but was discovered before the third, gallium, and after the fifth, thallium. In 1863
Ferdinand Reich Ferdinand Reich (19 February 1799 – 27 April 1882) was a German chemist who co-discovered indium in 1863 with Hieronymous Theodor Richter. Reich was born in Bernburg, Anhalt-Bernburg, Holy Roman Empire and died in Freiberg, Saxony, Freibe ...
and his assistant, Hieronymous Theodor Richter, were looking in a sample of the mineral zinc blende, also known as
sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...
(ZnS), for the spectroscopic lines of the newly discovered element thallium. Reich heated the ore in a coil of
platinum Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...
metal and observed the lines that appeared in a
spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify mate ...
. Instead of the green thallium lines that he expected, he saw a new line of deep indigo-blue. Concluding that it must come from a new element, they named it after the characteristic indigo color it had produced. Emsley, p. 192 Gallium minerals were not known before August 1875, when the element itself was discovered. It was one of the elements that the inventor of the periodic table,
Dmitri Mendeleev Dmitri Ivanovich Mendeleev ( ; ) was a Russian chemist known for formulating the periodic law and creating a version of the periodic table of elements. He used the periodic law not only to correct the then-accepted properties of some known ele ...
, had predicted to exist six years earlier. While examining the spectroscopic lines in zinc blende the French chemist Paul Emile Lecoq de Boisbaudran found indications of a new element in the ore. In just three months he was able to produce a sample, which he purified by dissolving it in a
potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utili ...
(KOH) solution and sending an electric current through it. The next month he presented his findings to the French Academy of Sciences, naming the new element after the Greek name for Gaul, modern France. The last confirmed element in the boron group, nihonium, was not discovered but rather created or synthesized. The element's synthesis was first reported by the Dubna Joint Institute for Nuclear Research team in Russia and the
Lawrence Livermore National Laboratory Lawrence Livermore National Laboratory (LLNL) is a Federally funded research and development centers, federally funded research and development center in Livermore, California, United States. Originally established in 1952, the laboratory now i ...
in the United States, though it was the Dubna team who successfully conducted the experiment in August 2003. Nihonium was discovered in the
decay chain In nuclear science a decay chain refers to the predictable series of radioactive disintegrations undergone by the nuclei of certain unstable chemical elements. Radioactive isotopes do not usually decay directly to stable isotopes, but rather ...
of
moscovium Moscovium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Mc and atomic number 115. It was first synthesized in 2003 by a joint team of Russian and American scientists at the Joint Institute for Nuclear Resea ...
, which produced a few precious atoms of nihonium. The results were published in January of the following year. Since then around 13 atoms have been synthesized and various isotopes characterized. However, their results did not meet the stringent criteria for being counted as a discovery, and it was the later
RIKEN is a national scientific research institute in Japan. Founded in 1917, it now has about 3,000 scientists on seven campuses across Japan, including the main site at Wakō, Saitama, Wakō, Saitama Prefecture, on the outskirts of Tokyo. Riken is a ...
experiments of 2004 aimed at directly synthesizing nihonium that were acknowledged by
IUPAC The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is ...
as the discovery.


Etymology

The name "boron" comes from the Arabic word for the mineral borax, (بورق, ''boraq'') which was known before boron was ever extracted. The "-on" suffix is thought to have been taken from "carbon". Aluminium was named by Humphry Davy in the early 1800s. It is derived from the Greek word ''alumen'', meaning bitter salt, or the Latin ''
alum An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , such that is a valence (chemistry), monovalent cation such as potassium ...
'', the mineral. Gallium is derived from the Latin ''Gallia'', referring to France, the place of its discovery. Indium comes from the Latin word ''indicum'', meaning
indigo dye Indigo dye is an organic compound with a distinctive indigo, blue color. Indigo is a natural dye obtained from the leaves of some plants of the Indigofera#Uses, ''Indigofera'' genus, in particular ''Indigofera tinctoria''. Dye-bearing ''Indigofer ...
, and refers to the element's prominent indigo spectroscopic line. Thallium, like indium, is named after the Greek word for the color of its spectroscopic line: , meaning a green twig or shoot. "Nihonium" is named after
Japan Japan is an island country in East Asia. Located in the Pacific Ocean off the northeast coast of the Asia, Asian mainland, it is bordered on the west by the Sea of Japan and extends from the Sea of Okhotsk in the north to the East China Sea ...
(''Nihon'' in Japanese), where it was discovered.


Occurrence and abundance


Boron

Boron, with its atomic number of 5, is a very light element. Almost never found free in nature, it is very low in abundance, composing only 0.001% (10 ppm) of the Earth's crust. It is known to occur in over a hundred different minerals and
ores Ore is natural Rock (geology), rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the ...
, however: the main source is
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
, but it is also found in colemanite,
boracite Boracite is a magnesium borate mineral with formula: Mg3 B7 O13 Cl. It occurs as blue green, colorless, gray, yellow to white crystals in the orthorhombic - pyramidal crystal system. Boracite also shows pseudo-isometric cubical and octahedral fo ...
,
kernite Kernite, also known as rasorite, is a hydrated sodium borate hydroxide mineral with formula . It is a colorless to white mineral crystallizing in the monoclinic crystal system typically occurring as prismatic to acicular (crystal habit), acicular ...
, tusionite, berborite and fluoborite. Major world miners and extractors of boron include
Turkey Turkey, officially the Republic of Türkiye, is a country mainly located in Anatolia in West Asia, with a relatively small part called East Thrace in Southeast Europe. It borders the Black Sea to the north; Georgia (country), Georgia, Armen ...
, the
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,
Argentina Argentina, officially the Argentine Republic, is a country in the southern half of South America. It covers an area of , making it the List of South American countries by area, second-largest country in South America after Brazil, the fourt ...
,
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
,
Bolivia Bolivia, officially the Plurinational State of Bolivia, is a landlocked country located in central South America. The country features diverse geography, including vast Amazonian plains, tropical lowlands, mountains, the Gran Chaco Province, w ...
and
Peru Peru, officially the Republic of Peru, is a country in western South America. It is bordered in the north by Ecuador and Colombia, in the east by Brazil, in the southeast by Bolivia, in the south by Chile, and in the south and west by the Pac ...
. Turkey is by far the most prominent of these, accounting for around 70% of all boron extraction in the world. The United States is second, most of its yield coming from the state of
California California () is a U.S. state, state in the Western United States that lies on the West Coast of the United States, Pacific Coast. It borders Oregon to the north, Nevada and Arizona to the east, and shares Mexico–United States border, an ...
.


Aluminium

Aluminium, in contrast to boron, is the most abundant metal in the Earth's crust, and the third most abundant element. It composes about 8.2% (82,000 ppm) of the Earth's crust, surpassed only by
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
. It is like boron, however, in that it is uncommon in nature as a free element. This is due to aluminium's tendency to attract oxygen atoms, forming several
aluminium oxide Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several Aluminium oxide (compounds), aluminium oxides, and specifically identified as alum ...
s. Aluminium is now known to occur in nearly as many minerals as boron, including
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
s,
turquoise Turquoise is an opaque, blue-to-green mineral that is a hydrous phosphate of copper and aluminium, with the chemical formula . It is rare and valuable in finer grades and has been prized as a gemstone for millennia due to its hue. The robi ...
s and
beryl Beryl ( ) is a mineral composed of beryllium aluminium Silicate minerals#Cyclosilicates, silicate with the chemical formula Be3Al2(SiO3)6. Well-known varieties of beryl include emerald and Aquamarine (gem), aquamarine. Naturally occurring Hex ...
s, but the main source is the ore
bauxite Bauxite () is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (), boehmite (γ-AlO(OH)), and diaspore (α-AlO(OH) ...
. The world's leading countries in the extraction of aluminium are
Ghana Ghana, officially the Republic of Ghana, is a country in West Africa. It is situated along the Gulf of Guinea and the Atlantic Ocean to the south, and shares borders with Côte d’Ivoire to the west, Burkina Faso to the north, and Togo to t ...
,
Suriname Suriname, officially the Republic of Suriname, is a country in northern South America, also considered as part of the Caribbean and the West Indies. It is a developing country with a Human Development Index, high level of human development; i ...
,
Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
and
Indonesia Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania, between the Indian Ocean, Indian and Pacific Ocean, Pacific oceans. Comprising over List of islands of Indonesia, 17,000 islands, including Sumatra, ...
, followed by
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
,
Guinea Guinea, officially the Republic of Guinea, is a coastal country in West Africa. It borders the Atlantic Ocean to the west, Guinea-Bissau to the northwest, Senegal to the north, Mali to the northeast, Côte d'Ivoire to the southeast, and Sier ...
and
Brazil Brazil, officially the Federative Republic of Brazil, is the largest country in South America. It is the world's List of countries and dependencies by area, fifth-largest country by area and the List of countries and dependencies by population ...
.


Gallium

Gallium is a relatively rare element in the Earth's crust and is not found in as many minerals as its lighter homologues. Its abundance on the Earth is a mere 0.0018% (18 ppm). Its production is very low compared to other elements, but has increased greatly over the years as extraction methods have improved. Gallium can be found as a trace in a variety of ores, including bauxite and
sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...
, and in such minerals as
diaspore Diaspore ()also called diasporite, empholite, kayserite, or tanatariteis an aluminium hydroxide oxide mineral, α-AlO(OH), crystallizing in the orthorhombic system and isomorphous with goethite. It occurs sometimes as flattened crystals, but ...
and germanite. Trace amounts have been found in
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
as well. The gallium content is greater in a few minerals, including gallite (CuGaS2), but these are too rare to be counted as major sources and make negligible contributions to the world's supply.


Indium

Indium is another rare element in the boron group at only 0.000005% (0.05 ppm),. Very few indium-containing minerals are known, all of them scarce: an example is indite. Indium is found in several zinc ores, but only in minute quantities; likewise some copper and lead ores contain traces. As is the case for most other elements found in ores and minerals, the indium extraction process has become more efficient in recent years, ultimately leading to larger yields.
Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...
is the world's leader in indium reserves, but both the
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
and
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
have comparable amounts.


Thallium

Thallium is of intermediate abundance in the Earth's crust, estimated to be 0.00006% (0.6 ppm). It is found on the ground in some rocks, in the soil and in clay. Many sulfide ores of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
and
cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...
contain thallium. In minerals it is found in moderate quantities: some examples are crookesite (in which it was first discovered), lorandite, routhierite, bukovite, hutchinsonite and sabatierite. There are other minerals that contain small amounts of thallium, but they are very rare and do not serve as primary sources.


Nihonium

Nihonium is an element that is never found in nature but has been created in a laboratory. It is therefore classified as a
synthetic element A synthetic element is a known chemical element that does not occur naturally on Earth: it has been created by human manipulation of fundamental particles in a nuclear reactor, a particle accelerator, or the explosion of an atomic bomb; thus, it i ...
with no stable isotopes.


Applications

With the exception of synthetic nihonium, all the elements in the boron group have numerous uses and applications in the production and content of many items.


Boron

Boron has found many industrial applications in recent decades, and new ones are still being found. A common application is in
fiberglass Fiberglass (American English) or fibreglass (English in the Commonwealth of Nations, Commonwealth English) is a common type of fibre-reinforced plastic, fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened i ...
. There has been rapid expansion in the market for
borosilicate glass Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), ma ...
; most notable among its special qualities is a much greater resistance to
thermal expansion Thermal expansion is the tendency of matter to increase in length, area, or volume, changing its size and density, in response to an increase in temperature (usually excluding phase transitions). Substances usually contract with decreasing temp ...
than regular glass. Another commercially expanding use of boron and its derivatives is in
ceramics A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porce ...
. Several boron compounds, especially the oxides, have unique and valuable properties that have led to their substitution for other materials that are less useful. Boron may be found in pots, vases, plates, and ceramic pan-handles for its insulating properties. The compound
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
is used in bleaches, for both clothes and teeth. The hardness of boron and some of its compounds give it a wide array of additional uses. A small part (5%) of the boron produced finds use in agriculture.


Aluminium

Aluminium is a metal with numerous familiar uses in everyday life. It is most often encountered in
construction Construction are processes involved in delivering buildings, infrastructure, industrial facilities, and associated activities through to the end of their life. It typically starts with planning, financing, and design that continues until the a ...
materials, in
electrical Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
devices, especially as the conductor in cables, and in tools and vessels for cooking and preserving food. Aluminium's lack of reactivity with food products makes it particularly useful for canning. Its high affinity for oxygen makes it a powerful
reducing agent In chemistry, a reducing agent (also known as a reductant, reducer, or electron donor) is a chemical species that "donates" an electron to an (called the , , , or ). Examples of substances that are common reducing agents include hydrogen, carbon ...
. Finely powdered pure aluminium oxidizes rapidly in air, generating a huge amount of heat in the process (burning at about or ), leading to applications in
welding Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, primarily by using high temperature to melting, melt the parts together and allow them to cool, causing Fusion welding, fusion. Co ...
and elsewhere that a large amount of heat is needed. Aluminium is a component of
alloys An alloy is a mixture of chemical elements of which in most cases at least one is a metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have properties ...
used for making lightweight bodies for aircraft. Cars also sometimes incorporate aluminium in their framework and body, and there are similar applications in military equipment. Less common uses include components of decorations and some guitars. The element is also sees use in a diverse range of electronics.


Gallium

Gallium and its derivatives have only found applications in recent decades.
Gallium arsenide Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a Zincblende (crystal structure), zinc blende crystal structure. Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monoli ...
has been used in
semiconductors A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels ...
, in
amplifiers An amplifier, electronic amplifier or (informally) amp is an electronic device that can increase the magnitude of a signal (a time-varying voltage or current). It is a two-port electronic circuit that uses electric power from a power suppl ...
, in solar cells (for example in
satellites A satellite or an artificial satellite is an object, typically a spacecraft, placed into orbit around a celestial body. They have a variety of uses, including communication relay, weather forecasting, navigation ( GPS), broadcasting, scientif ...
) and in tunnel
diode A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...
s for FM transmitter circuits. Gallium alloys are used mostly for dental purposes. Gallium ammonium chloride is used for the leads in
transistors A transistor is a semiconductor device used to Electronic amplifier, amplify or electronic switch, switch electrical signals and electric power, power. It is one of the basic building blocks of modern electronics. It is composed of semicondu ...
. A major application of gallium is in
LED A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corresp ...
lighting. The pure element has been used as a
dopant A dopant (also called a doping agent) is a small amount of a substance added to a material to alter its physical properties, such as electrical or optics, optical properties. The amount of dopant is typically very low compared to the material b ...
in semiconductors, and has additional uses in electronic devices with other elements. Gallium has the property of being able to 'wet' glass and porcelain, and thus can be used to make mirrors and other highly reflective objects. Gallium can be added to alloys of other metals to lower their melting points.


Indium

Indium's uses can be divided into four categories: the largest part (70%) of the production is used for coatings, usually combined as
indium tin oxide Indium tin oxide (ITO) is a ternary composition of indium, tin and oxygen in varying proportions. Depending on the oxygen content, it can be described as either a ceramic or an alloy. Indium tin oxide is typically encountered as an oxygen-saturate ...
(ITO); a smaller portion (12%) goes into alloys and
solder Solder (; North American English, NA: ) is a fusible alloy, fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces aft ...
s; a similar amount is used in electrical components and in semiconductors; and the final 6% goes to minor applications. Among the items in which indium may be found are platings, bearings, display devices, heat reflectors, phosphors, and nuclear control rods. Indium tin oxide has found a wide range of applications, including glass coatings,
solar panel A solar panel is a device that converts sunlight into electricity by using photovoltaic (PV) cells. PV cells are made of materials that produce excited electrons when exposed to light. These electrons flow through a circuit and produce direct ...
s, streetlights, electrophosetic displays (EPDs), electroluminescent displays (ELDs), plasma display panels (PDPs), electrochemic displays (ECs), field emission displays (FEDs), sodium lamps, windshield glass and
cathode-ray tube A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a ...
s, making it the single most important indium compound.


Thallium

Thallium is used in its elemental form more often than the other boron-group elements. Uncompounded thallium is used in low-melting glasses, photoelectric cells, switches, mercury alloys for low-range glass thermometers, and thallium salts. It can be found in lamps and electronics, and is also used in myocardial imaging. The possibility of using thallium in semiconductors has been researched, and it is a known
catalyst Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quick ...
in organic synthesis. Thallium hydroxide (TlOH) is used mainly in the production of other thallium compounds. Thallium sulfate (Tl2SO4) is an outstanding
vermin Vermin (colloquially varmint(s) or varmit(s)) are pests or nuisance animals that spread diseases and destroy crops, livestock, and property. Since the term is defined in relation to human activities, which species are included vary by regi ...
-killer, and it is a principal component in some rat and mouse poisons. However, the United States and some European countries have banned the substance because of its high toxicity to humans. In other countries, though, the market for the substance is growing. Tl2SO4 is also used in optical systems.


Biological role

None of the group-13 elements has a major biological role in complex animals, but some are at least associated with a living being. As in other groups, the lighter elements usually have more biological roles than the heavier. The heaviest ones are toxic, as are the other elements in the same periods. Boron is essential in most plants, whose cells use it for such purposes as strengthening
cell wall A cell wall is a structural layer that surrounds some Cell type, cell types, found immediately outside the cell membrane. It can be tough, flexible, and sometimes rigid. Primarily, it provides the cell with structural support, shape, protection, ...
s. It is found in humans, certainly as a essential trace element, but there is ongoing debate over its significance in human nutrition. Boron's chemistry does allow it to form complexes with such important molecules as
carbohydrates A carbohydrate () is a biomolecule composed of carbon (C), hydrogen (H), and oxygen (O) atoms. The typical hydrogen-to-oxygen atomic ratio is 2:1, analogous to that of water, and is represented by the empirical formula (where ''m'' and ''n'' ma ...
, so it is plausible that it could be of greater use in the human body than previously thought. Boron has also been shown to be able to replace
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
in some of its functions, particularly in the healing of wounds. Aluminium has no known biological role in plants or animals, despite its widespread occurrence in nature. Gallium is not essential for the human body, but its relation to iron(III) allows it to become bound to proteins that transport and store iron. Gallium can also stimulate metabolism. Indium and its heavier homologues have no biological role, although indium salts in small doses, like gallium, can stimulate metabolism.


Toxicity

Each element of the boron group has a unique toxicity profile to plants and animals. As an example of boron toxicity, it has been observed to harm
barley Barley (), a member of the grass family, is a major cereal grain grown in temperate climates globally. It was one of the first cultivated grains; it was domesticated in the Fertile Crescent around 9000 BC, giving it nonshattering spikele ...
in concentrations exceeding 20 mM. The symptoms of boron toxicity are numerous in plants, complicating research: they include reduced cell division, decreased shoot and root growth, decreased production of leaf chlorophyll, inhibition of photosynthesis, lowering of stomata conductance, reduced proton extrusion from roots, and deposition of
lignin Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidit ...
and
suberin Suberin is a lipophilic, complex polyester biopolymer found in plants. It is composed of long-chain fatty acids (called suberin acids) and glycerol. Suberin is interconnected with cutin and lignin and forms a protective barrier in the epidermal ...
. Aluminium does not present a prominent toxicity hazard in small quantities, but very large doses are slightly toxic. Gallium is not considered toxic, although it may have some minor effects. Indium is not toxic and can be handled with nearly the same precautions as gallium, but some of its compounds are slightly to moderately toxic. Thallium, unlike gallium and indium, is extremely toxic, and has caused many poisoning deaths. Its most noticeable effect, apparent even from tiny doses, is
hair loss Hair loss, also known as alopecia or baldness, refers to a loss of hair from part of the head or body. Typically at least the head is involved. The severity of hair loss can vary from a small area to the entire body. Inflammation or scarring ...
all over the body, but it causes a wide range of other symptoms, disrupting and eventually halting the functions of many organs. The nearly colorless, odorless and tasteless nature of thallium compounds has led to their use by murderers. The incidence of thallium poisoning, intentional and accidental, increased when thallium (with its similarly toxic compound, thallium sulfate) was introduced to control rats and other pests. The use of thallium pesticides has therefore been prohibited since 1975 in many countries, including the USA. Nihonium is a highly unstable element and decays by emitting alpha particles. Due to its strong
radioactivity Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
, it would definitely be extremely toxic, although significant quantities of nihonium (larger than a few atoms) have not yet been assembled.


Notes


References


Bibliography

* * *


External links


oxide (chemical compound) – Britannica Online Encyclopedia
Britannica.com. Retrieved on 2011-05-16.

Rsc.org. Retrieved on 2011-05-16.
Trends In Chemical Reactivity Of Group 13 Elements
Tutorvista.com. Retrieved on 2011-05-16.

etymonline.com Retrieved on 2011-07-27 {{DEFAULTSORT:Boron Group Periodic table Groups (periodic table)