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Abnormal Grain Growth
In materials science, abnormal or discontinuous grain growth, also referred to as exaggerated or secondary recrystallisation grain growth, is a grain growth phenomenon in which certain energetically favorable grains (crystallites) grow rapidly in a matrix of finer grains, resulting in a bimodal distribution of grain size. In ceramic materials, this phenomenon can result in the formation of elongated prismatic, acicular (needle-like) grains in a densified matrix. This microstructure has the potential to improve fracture toughness by impeding the propagation of cracks. Mechanisms Abnormal grain growth (AGG) is encountered in metallic or ceramic systems exhibiting one or more of several characteristics: # Systems with secondary phase inclusions, precipitates or impurities above a certain threshold concentration. # Systems with a highly anisotropic surface energy. # Systems far from chemical equilibrium. Abnormal grain growth occurs due to very high local rates of interface ...
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Toughening
In materials science, toughening refers to the process of making a material more resistant to the propagation of cracks. When a crack propagates, the associated irreversible work in different materials classes is different. Thus, the most effective toughening mechanisms differ among different materials classes. The crack tip plasticity is important in toughening of metals and long-chain polymers. Ceramics have limited crack tip plasticity and primarily rely on different toughening mechanisms. Toughening in metals For the case of a ductile material such as a metal, this toughness is typically proportional to the fracture stress and strain as well as the gauge length of the crack. The plane strain toughness in a metal is given by:Courtney, T. H. (2005). Mechanical Behavior of Materials. United States: Waveland Press, Inc. :G_ = B\sigma_\epsilon_\rho where G_ is the plane strain toughness, B is a constant that incorporates the stress state, \sigma_ is the tensile flow stress at fra ...
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Metall
Since the release of ''Mega Man'', numerous characters have appeared across the series. Overview Key: = Does Not Appear List indicator(s) * A dark grey cell indicates that the character was not in the property or that the character's presence in the property has yet to be announced. * A Main indicates a character had a starring role in the property. * A Recurring indicates the character appeared in two or more times within the property. * A Guest indicates the character appeared once in the property. ''Classic Mega Man'' characters Main characters Mega Man DLN-001 Mega Man, known in Japan as is the main protagonist of the original ''Mega Man'' series. Dr. Light originally created him to be a lab assistant named Rock, but he was modified for combat after Dr. Wily reprogrammed the original Robot Masters to take over the world. His Variable Weapons System allows him to copy the weapons of other Robot Masters and use them as his own. Dr. Light Doctor Thomas Light, k ...
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Tungsten Carbide
Tungsten carbide (chemical formula: ) is a carbide containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into shapes through sintering for use in industrial machinery, engineering facilities, molding blocks, cutting tools, chisels, abrasives, armor-piercing bullets and jewelry. Tungsten carbide is approximately three times as stiff as steel, with a Young's modulus of approximately 530–700 GPa, and is twice as dense as steel. It is comparable with corundum (α- ) in hardness, approaching that of a diamond, and can be polished and finished only with abrasives of superior hardness such as cubic boron nitride and diamond. Tungsten carbide tools can be operated at cutting speeds much higher than high-speed steel (a special steel blend for cutting tools). Tungsten carbide powder was first synthesized by H. Moissan in 1893, and the industrial production of the cemented form starte ...
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Barium Titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. It is the barium salt of metatitanic acid. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and Piezoelectricity, piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics. Structure The solid exists in one of four polymorphs depending on temperature. From high to low temperature, these crystal symmetries of the four polymorphs are Cubic crystal system, cubic, Tetragonal crystal system, tetragonal, Orthorhombic crystal system, orthorhombic and Trigonal crystal system, rhombohedral crystal structure. All of these phases exhibit the ferroelectric effect apart from the cubic phase. The high temperature cubic phase is easiest to describe, as it consists of regular corner-sharing octahedral TiO6 units ...
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Yttria
Yttrium oxide, also known as yttria, is Y2 O3. It is an air-stable, white solid substance. The thermal conductivity of yttrium oxide is 27 W/(m·K). Applications Phosphors Yttrium oxide is widely used to make Eu:YVO4 and Eu:Y2O3 phosphors that give the red color in color TV picture tubes. Yttria lasers Y2O3 is a prospective solid-state laser material. In particular, lasers with ytterbium as dopant allow the efficient operation both in continuous operation and in pulsed regimes. At high concentration of excitations (of order of 1%) and poor cooling, the quenching of emission at laser frequency and avalanche broadband emission takes place. (Yttria-based lasers are not to be confused with YAG lasers using yttrium aluminium garnet, a widely used crystal host for rare earth laser dopants). Gas lighting The original use of the mineral yttria and the purpose of its extraction from mineral sources was as part of the process of making gas mantles and other products for turning the fla ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a synthetic product. Examples include fused quartz, fumed silica, opal, and aerogels. It is used in structural materials, microelectronics, and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored. Silicon dioxide is a common fundamental constituent of glass. Structure In the majority of silicon dioxides, the silicon atom shows Tetrahedral molecular geometry, tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. ...
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Alumina
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, ALOX or alundum in various forms and applications and alumina is refined from bauxite. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire,which have an alumina content approaching 100%. Al2O3 is used as feedstock to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point. Natural occurrence Corundum is the most common naturally occurring crystalline form of aluminium oxide. Rubies and sapphires are gem-quality forms of corundum, which owe their characteristic colours to trace impurities. Rubies are given their ...
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Anatase
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a Tetragonal crystal system, tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other Polymorphism (materials science), polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most Chemical stability, stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in Igneous rock, igneous and Metamorphic rock, metamorphic rocks. Glass coated with a thin film of TiO2 shows Anti-fog, antifogging and Self-cleaning surfaces, self-cleaning properties under ultraviolet radiation. Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a Tetragonal crystal system, tetragonal system. Anatase is metastable at all temperatures and pressures, with ru ...
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Zircon
Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green. The name derives from the Persian ''zargun'', meaning "gold-hued". This word is changed into " jargoon", a term applied to light-colored zircons. The English word "zircon" is derived from ''Zirkon'', which is the German adaptation of this word. Yellow, orange, and red zircon is also known as " hyacint ...
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Crystal Habit
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or aggregate of crystals. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities due to limited space in the Crystallization, crystallizing medium (commonly in Rock (geology), rocks).Klein, Cornelis, 2007, ''Minerals and Rocks: Exercises in Crystal and Mineral Chemistry, Crystallography, X-ray Powder Diffraction, Mineral and Rock Identification, and Ore Mineralogy,'' Wiley, third edition, Wenk, Hans-Rudolph and Andrei Bulakh, 2004, ''Minerals: Their Constitution and Origin,'' Cambridge, first edition, Crystal forms Recognizing the habit can aid in mineral identification and description, as the crystal habit is an external representation of the Crystal structure, internal ordered atomic arrangement. Most natural crystals, however, do not display ideal habits and are commonly malformed. Hence, it is also important to des ...
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Rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visible wavelengths of any known crystal and also exhibits a particularly large birefringence and high dispersion. Owing to these properties, it is useful for the manufacture of certain optical elements, especially polarization optics, for longer visible and infrared wavelengths up to about 4.5 micrometres. Natural rutile may contain up to 10% iron and significant amounts of niobium and tantalum. Rutile derives its name from the Latin ('red'), in reference to the deep red color observed in some specimens when viewed by transmitted light. Rutile was first described in 1803 by Abraham Gottlob Werner using specimens obtained in Horcajuelo de la Sierra, Madrid (Spain), which is consequently the type locality. Occurrence Rutile is a comm ...
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