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Anatase
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Thin films of TiO2-coated glass show antifogging and self-cleaning properties under ultraviolet radiation. Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a tetragonal system. Anatase is metastable at all temperatures and pressures, with rutile being the equilibrium polymorph. Nevertheless, anatase is often the first titanium dioxide phase to form in many processes due to its lower surface energy, with a trans ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anatase Crystal Structure
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Thin films of TiO2-coated glass show antifogging and self-cleaning properties under ultraviolet radiation. Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a tetragonal system. Anatase is metastable at all temperatures and pressures, with rutile being the equilibrium polymorph. Nevertheless, anatase is often the first titanium dioxide phase to form in many processes due to its lower surface energy, with a transform ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titanium Dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insoluble to water, although mineral forms can appear black. As a pigment, it has a wide range of applications, including paint, sunscreen, and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million tonnes. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide have been valued at a price of $13.2 billion. Structure In all three of its main dioxides, titanium exhibits octahedral geometry, being bonded to six oxide anions. The oxides in turn are bonded to three Ti centers. The overall crystal structure of rutile is tetragonal in symmetry whereas anatase and brookite are orthorhombic. The oxygen substructures are all slight dist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Brookite
Brookite is the orthorhombic variant of titanium dioxide (TiO2), which occurs in four known natural polymorphic forms (minerals with the same composition but different structure). The other three of these forms are akaogiite (monoclinic), anatase (tetragonal) and rutile (tetragonal). Brookite is rare compared to anatase and rutile and, like these forms, it exhibits photocatalytic activity. Brookite also has a larger cell volume than either anatase or rutile, with 8 TiO2 groups per unit cell, compared with 4 for anatase and 2 for rutile.Anatase and Brookite . Wikis.lib.ncsu.edu (2007-05-08). Retrieved on 2011-10-14. (Fe), |
Rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visible wavelengths of any known crystal and also exhibits a particularly large birefringence and high dispersion. Owing to these properties, it is useful for the manufacture of certain optical elements, especially polarization optics, for longer visible and infrared wavelengths up to about 4.5 micrometres. Natural rutile may contain up to 10% iron and significant amounts of niobium and tantalum. Rutile derives its name from the Latin ('red'), in reference to the deep red color observed in some specimens when viewed by transmitted light. Rutile was first described in 1803 by Abraham Gottlob Werner. Occurrence Rutile is a common accessory mineral in high-temperature and high-pressure metamorphic rocks and in igneous rocks. Thermodynamically, ru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metastable
In chemistry and physics, metastability denotes an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is only slightly pushed, it will settle back into its hollow, but a stronger push may start the ball rolling down the slope. Bowling pins show similar metastability by either merely wobbling for a moment or tipping over completely. A common example of metastability in science is isomerisation. Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by (possibly large) barriers in the potential energy. During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values. In isolation: *the state of least energy is the only one the system will inhabit for an indefinite length of time, until more external energy is added to the system (unique "ab ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Akaogiite
Akaogiite ( IMA symbol Aka) is an exceedingly rare mineral, one of the natural forms of titanium dioxide (TiO2). It is a high-pressure polymorph Polymorphism, polymorphic, polymorph, polymorphous, or polymorphy may refer to: Computing * Polymorphism (computer science), the ability in programming to present the same programming interface for differing underlying forms * Ad hoc polymorphi ... of TiO2, along with anatase, brookite and another high-pressure phase called "TiO2 II". Rutile is the stable polymorph of TiO2, most commonly found at standard temperatures and pressures. Akaogiite can be found at the Nördlinger Ries Crater, a meteor crater in Germany, where the extreme pressure during the impact allowed its formation. References Oxide minerals Titanium minerals Monoclinic minerals {{oxide-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Self-cleaning Surfaces
Self-cleaning surfaces are a class of materials with the inherent ability to remove any debris or bacteria from their surfaces in a variety of ways. The self-cleaning functionality of these surfaces are commonly inspired by natural phenomena observed in lotus leaves, gecko feet, and water striders to name a few. The majority of self-cleaning surfaces can be placed into three categories: # superhydrophobic # superhydrophilic # photocatalytic. History The first instance of a self-cleaning surface was created in 1995. Paz et al. created a transparent titanium dioxide (TiO2) film that was used to coat glass and provide the ability for the glass to self-clean. The first commercial application of this self-cleaning surface, Pilkington Activ, was developed by Pilkington glass in 2001. This product implements a two-stage cleaning process. The first stage consists of photocatalysis of any fouling matter on the glass. This stage is followed by the glass becoming superhydrophilic and allowi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Birefringence
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress. Birefringence is responsible for the phenomenon of double refraction whereby a ray of light, when incident upon a birefringent material, is split by polarization into two rays taking slightly different paths. This effect was first described by Danish scientist Rasmus Bartholin in 1669, who observed it in calcite, a crystal having one of the strongest birefringences. In the 19th century Augustin-Jean Fresnel described the phenomenon in terms of polarization, understanding light as a wave with field components in transverse pola ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Greek Language
Greek ( el, label= Modern Greek, Ελληνικά, Elliniká, ; grc, Ἑλληνική, Hellēnikḗ) is an independent branch of the Indo-European family of languages, native to Greece, Cyprus, southern Italy (Calabria and Salento), southern Albania, and other regions of the Balkans, the Black Sea coast, Asia Minor, and the Eastern Mediterranean. It has the longest documented history of any Indo-European language, spanning at least 3,400 years of written records. Its writing system is the Greek alphabet, which has been used for approximately 2,800 years; previously, Greek was recorded in writing systems such as Linear B and the Cypriot syllabary. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic, and many other writing systems. The Greek language holds a very important place in the history of the Western world. Beginning with the epics of Homer, ancient Greek literature includes many works of l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mohs Scale Of Mineral Hardness
The Mohs scale of mineral hardness () is a Qualitative property, qualitative ordinal scale, from 1 to 10, characterizing scratch hardness, scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the German geologist and Mineralogy, mineralogist Friedrich Mohs, in his book ''"Versuch einer Elementar-Methode zur naturhistorischen Bestimmung und Erkennung der Fossilien"''; it is one of several definitions of Hardness comparison, hardness in materials science, some of which are more quantitative. The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by Theophrastus in his treatise ''On Stones'', , followed by Pliny the Elder in his ''Natural History (Pliny), Naturalis Historia'', . The Mohs scale is useful for identification of minerals in the field, but is not an accurate predictor of how well materials endure in an industrial s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Specific Gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), water at its densest (at ); for gases, the reference is air at room temperature (). The term "relative density" (often abbreviated r.d. or RD) is often preferred in scientific usage, whereas the term "specific gravity" is deprecation, deprecated. If a substance's relative density is less than 1 then it is less dense than the reference; if greater than 1 then it is denser than the reference. If the relative density is exactly 1 then the densities are equal; that is, equal volumes of the two substances have the same mass. If the reference material is water, then a substance with a relative density (or specific gravity) less than 1 will float in water. For example, an ice cube, with a relative density of about 0.91, will float. A substance wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group *** Periclase *** Manganosite **Zincite group *** Zincite *** Bromellite *** Tenorite *** Litharge * ** Cuprite ** Ice * **Hematite group ***Corundum ***Hematite *** Ilmenite * **Rutile group *** Rutile *** Pyrolusite *** Cassiterite ** Baddeleyite ** Uraninite ** Thorianite * **Spinel group *** Spinel *** Gahnite ***Magnetite ***Franklinite *** Chromite ** Chrysoberyl ** Columbite *Hydroxide subgroup: ** Brucite ** Manganite **Romanèchite **Goethite group: *** Diaspore *** Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
