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Terbium(III) Oxalate
Terbium(III) oxalate is the oxalate of terbium with the chemical formula Tb2(C2O4)3. Its decahydrate can be obtained by reacting terbium(III) chloride and oxalic acid in an aqueous solution. Its decahydrate gradually loses water when heated and becomes anhydrous. Continued heating obtains terbium(III,IV) oxide. It decomposes in isolation from air to form terbium(III) oxide. The decomposed gas products are carbon monoxide and carbon dioxide. It reacts with hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ... to obtain H b(C2O4)26H2O.Moebius, R.; Matthes, F. The exchange of oxalate ions for chloride ions of the oxalate hydrates of the rare earths and yttrium. ''Zeitschrift fuer Chemie'', 1964. 4 (6): 234-235. ISSN: 0044-2402. References {{Oxalates Terbium comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III) Oxalate
Cerium(III) oxalate (cerous oxalate) is the Inorganic compound, inorganic cerium Salt (chemistry), salt of oxalic acid. It is a white crystalline solid with the chemical formula of Ce2(C2O4)3. It can be obtained by the reaction of oxalic acid with cerium(III) chloride. Uses Cerium(III) oxalate is used as an antiemetic. It has been identified as part of the invisible ink that was used by Stasi operatives during the Cold War. Toxicity Cerium(III) oxalate irritation, irritates human skin, skin and mucous membranes, and is a strong irritant to human eye, eyes. If it gets into the eyes, there is a danger of severe eye injury. Cerium salts increase the blood coagulation rate, and exposure to cerium salts can cause sensitivity to heat. Oxalates are corrosive to tissue and are powerful irritants. They have a caustic effect on the linings of the digestive tracts and can cause kidney damage. References {{Oxalates Cerium(III) compounds Oxalates Antiemetics ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terbium
Terbium is a chemical element; it has Symbol (chemistry), symbol Tb and atomic number 65. It is a silvery-white, rare earth element, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite. Swedish chemist Carl Gustaf Mosander discovered terbium as a chemical element in 1843. He detected it as an impurity in Yttrium(III) oxide, yttrium oxide (). Yttrium and terbium, as well as erbium and ytterbium, are named after the village of Ytterby in Sweden. Terbium was not isolated in pure form until the advent of ion exchange techniques. Terbium is used to dopant, dope calcium fluoride, calcium tungstate and strontium molybdate in solid-state devices, and as a crystal stabilizer of fuel cells that operate at elevated t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. Etymology Because it was produced from halite, rock salt according to the methods of Johann Rudolph Glauber, hydrochloric acid was historically called by European alchemists ''spirits of salt'' or ''acidum salis'' (salt acid). Both names are still used, especially in other languages, such as , , , , , , , , , , (''ensan''), zh, 盐酸 (''yánsuān''), and (''yeomsan''). Gaseous HCl was called ''marine acid air''. The name ''muriatic acid'' has the same origin (''muriatic'' means "pertaining to brine or salt", hence ''muriate'' means hydrochloride), and this ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Monoxide
Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest oxocarbon, carbon oxide. In coordination complexes, the carbon monoxide ligand is called ''metal carbonyl, carbonyl''. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds. Numerous environmental and biological sources generate carbon monoxide. In industry, carbon monoxide is important in the production of many compounds, including drugs, fragrances, and fuels. Indoors CO is one of the most acutely toxic contaminants affecting indoor air quality. CO may be emitted from tobacco smoke and generated from malfunctioning fuel-burning stoves (wood, kerosene, natural gas, propane) and fuel-burning heating systems (wood, oil, n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terbium(III) Oxide
Terbium(III) oxide, also known as terbium sesquioxide, is a sesquioxide of the rare earth metal terbium, having chemical formula . It is a p-type semiconductor, which conducts protons, which is enhanced when doped with calcium. It may be prepared by the reduction of in hydrogen at 1300 °C for 24 hours. : It is a basic oxide and easily dissolved to dilute acids, and then almost colourless terbium salt is formed. : Tb2O3 + 6 H+ → 2 Tb3+ + 3 H2O The crystal structure is cubic and the lattice constant is ''a'' = 1057 pm.N. C. Baenzinger, H. A. Eick, H. S. Schuldt, L. Eyring: ''Terbium Oxides. III. X-Ray Diffraction Studies of Several Stable Phases''. In: ''Journal of the American Chemical Society The ''Journal of the American Chemical Society'' (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ...'', 1961, 83, 10, S. 2219-23 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terbium(III,IV) Oxide
Terbium(III,IV) oxide, occasionally called tetraterbium heptaoxide, has the formula Tb4O7, though some texts refer to it as TbO1.75. There is some debate as to whether it is a discrete compound, or simply one phase in an interstitial oxide system. Tb4O7 is one of the main commercial terbium compounds, and the only such product containing at least some Tb(IV) (terbium in the +4 oxidation state), along with the more stable Tb(III). It is produced by heating the metal oxalate, and it is used in the preparation of other terbium compounds. It is also used in electronics and data storage, green energy technologies, medical imaging and diagnosis, and chemical processes. Terbium forms three other major oxides: Tb2O3, TbO2, and Tb6O11. Synthesis Tb4O7 is most often produced by ignition of the oxalate or the sulfate in air. The oxalate (at 1000 °C) is generally preferred, since the sulfate requires a higher temperature, and it produces an almost black product contaminated with Tb6O11 or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxalic Acid
Oxalic acid is an organic acid with the systematic name ethanedioic acid and chemical formula , also written as or or . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name is derived from early investigators who isolated oxalic acid from flowering plants of the genus '' Oxalis'', commonly known as wood-sorrels. It occurs naturally in many foods. Excessive ingestion of oxalic acid or prolonged skin contact can be dangerous. Oxalic acid is a much stronger acid than acetic acid. It is a reducing agent and its conjugate bases hydrogen oxalate () and oxalate () are chelating agents for metal cations. It is used as a cleaning agent, especially for the removal of rust, because it forms a water-soluble ferric iron complex, the ferrioxalate ion. Oxalic acid typically occurs as the dihydrate with the formula . History The preparation of salts of oxalic acid from plants had been known since at least 1745, when ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terbium(III) Chloride
Terbium(III) chloride ( Tb Cl3) is a chemical compound. In the solid state TbCl3 has the YCl3 layer structure. Terbium(III) chloride frequently forms a hexahydrate. Preparation The hexahydrate of terbium(III) chloride can be obtained by the reaction of terbium(III) oxide and hydrochloric acid: :Tb2O3 + 6 HCl → 2 TbCl3 + 3 H2O It can also be obtained by direct reaction of the elements: :2 Tb + 3 Cl2 → 2 TbCl3 Properties Terbium(III) chloride is a white, hygroscopic powder. It crystallizes in an orthorhombic plutonium(III) bromide crystal structure with space group Cmcm (No. 63). It can form a complex Tb(gly)3Cl3·3H2O with glycine. Applications The hexahydrate plays an important role as an activator of green phosphors in color TV tubes and is also used in specialty lasers and as a dopant in solid-state devices. Hazards Terbium(III) chloride causes hyperemia of the iris. Conditions/substances to avoid are: heat, acid An acid is a molecule or ion capable ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ytterbium(III) Oxalate
Ytterbium(III) oxalate is the oxalate of ytterbium, with the chemical formula Yb2(C2O4)3. Preparation Ytterbium(III) oxalate hydrate can be prepared by reacting an aqueous solution of ytterbium(III) chloride and a benzene solution of dimethyl oxalate Dimethyl oxalate is an organic compound with the formula or . It is the dimethyl ester of oxalic acid. Dimethyl oxalate is a colorless or white solid that is soluble in water. Production Dimethyl oxalate can be obtained by esterification of oxa .... Properties Ytterbium(III) oxalate pentahydrate is decomposed by heat to obtain the dihydrate, which is further heated to obtain ytterbium(III) oxide. It reacts with acids to obtain H b(C2O4)26H2O.Moebius, R.; Matthes, F. The exchange of oxalate ions for chloride ions of the oxalate hydrates of the rare earths and yttrium. ''Zeitschrift fuer Chemie'', 1964. 4 (6): 234-235. ISSN: 0044-2402. References {{Oxalates Ytterbium(III) compounds Oxalates ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Oxalate
Europium(III) oxalate (Eu2(C2O4)3) is a chemical compound of europium and oxalic acid. There are different hydrates including the decahydrate, hexahydrate and tetrahydrate. Europium(II) oxalate is also known. Preparation An excess of oxalate is added to a hot solution of Eu3+ cations. The resulting precipitate of Eu2(C2O4)3 ⋅ 10H2O is dried in a desiccator. Properties Europium(III) oxide (Eu2O3) can be prepared by calcining europium(III) oxalate. The dehydration of Eu2(C2O4)3 · 10H2O occurs below 200 °C: : The decomposition of this compound takes place in two stages, the first at 350 °C and the second at about 620 °C. : In the Mössbauer spectrum, Eu2(C2O4)3 · 10H2O shows an isomer shift of +0,26 mm/s with a line width of 2,38 mm/s, in reference to EuF3. The Debye temperature of Eu2(C2O4)3 is 166±15 K. Eu2(C2O4)3 · 10H2O crystallizes monoclinically in the space group of ''P21/c'' (space g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thulium(III) Oxalate
Thulium(III) oxalate is the oxalate of thulium with the chemical formula Tm2(C2O4)3. Its hydrate can be prepared by reacting an aqueous solution of thulium(III) chloride and a benzene solution of dimethyl oxalate. Its pentahydrate is decomposed by heat to obtain the dihydrate, which is further heated to obtain thulium(III) oxide. It reacts with hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ... to obtain H m(C2O4)26H2O.Moebius, R.; Matthes, F. The exchange of oxalate ions for chloride ions of the oxalate hydrates of the rare earths and yttrium. ''Zeitschrift fuer Chemie'', 1964. 4 (6): 234-235. ISSN: 0044-2402. References {{Oxalates Thulium compounds Oxalates ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
