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Europium(III) Oxalate
Europium(III) oxalate (Eu2(C2O4)3) is a chemical compound of europium and oxalic acid. There are different hydrates including the decahydrate, hexahydrate and tetrahydrate. Europium(II) oxalate is also known. Preparation An excess of oxalate is added to a hot solution of Eu3+ cations. The resulting precipitate of Eu2(C2O4)3 ⋅ 10H2O is dried in a desiccator. Properties Europium(III) oxide (Eu2O3) can be prepared by calcining europium(III) oxalate. The dehydration of Eu2(C2O4)3 · 10H2O occurs below 200 °C: : The decomposition of this compound takes place in two stages, the first at 350 °C and the second at about 620 °C. : In the Mössbauer spectrum, Eu2(C2O4)3 · 10H2O shows an isomer shift of +0,26 mm/s with a line width of 2,38 mm/s, in reference to EuF3. The Debye temperature of Eu2(C2O4)3 is 166±15 K. Eu2(C2O4)3 · 10H2O crystallizes monoclinically in the space group of ''P21/c'' (space g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III) Oxalate
Cerium(III) oxalate (cerous oxalate) is the Inorganic compound, inorganic cerium Salt (chemistry), salt of oxalic acid. It is a white crystalline solid with the chemical formula of Ce2(C2O4)3. It can be obtained by the reaction of oxalic acid with cerium(III) chloride. Uses Cerium(III) oxalate is used as an antiemetic. It has been identified as part of the invisible ink that was used by Stasi operatives during the Cold War. Toxicity Cerium(III) oxalate irritation, irritates human skin, skin and mucous membranes, and is a strong irritant to human eye, eyes. If it gets into the eyes, there is a danger of severe eye injury. Cerium salts increase the blood coagulation rate, and exposure to cerium salts can cause sensitivity to heat. Oxalates are corrosive to tissue and are powerful irritants. They have a caustic effect on the linings of the digestive tracts and can cause kidney damage. References {{Oxalates Cerium(III) compounds Oxalates Antiemetics ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zeitschrift Für Anorganische Und Allgemeine Chemie
The ''Zeitschrift für anorganische und allgemeine Chemie'' (''Journal of Inorganic and General Chemistry'') is a semimonthly peer-reviewed scientific journal covering inorganic chemistry, published by Wiley-VCH. The editors-in-chief are Thomas F. Fässler, Christian Limberg, Guodong Qian, and David Scheschkewitz. Originally the journal was published in German, but nowadays it is completely in English. Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2022 impact factor of 1.4. History In 1892, Gerhard Krüss (Ludwig Maximilian University of Munich), established the journal under the name ''Zeitschrift für Anorganische Chemie''. Krüss died three years later, and was succeeded by Richard Lorenz and Walther Nernst Walther Hermann Nernst (; 25 June 1864 – 18 November 1941) was a German physical chemist known for his work in thermodynamics, physical chemistry, electrochemistry, and solid-sta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acta Crystallographica Section C
''Acta Crystallographica Section C: Structural Chemistry'' is a journal for the rapid publication of research with structural content relating to the chemical sciences. Abstracting and indexing The journal is abstracted and indexed in: References {{Reflist External links IUCr journals official site Chemistry journals Academic journals established in 1948 English-language journals Wiley-Blackwell academic journals Monthly journals Bimonthly journals Online-only journals Academic journals associated with learned and professional societies ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoclinic Crystal System
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organizes the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hyperfine Interactions
"Hyperfine" is a song by Australian indie pop singer G Flip Georgia Claire Flipo (born 22 September 1993), known professionally as G Flip, is an Australian singer, songwriter, multi-instrumentalist and producer from Melbourne, Victoria. Their debut studio album, '' About Us'', was released on 30 August .... It was released on 8 May 2020. The song was voted number 7 in the Triple J Hottest 100, 2020 and peaked at number 88 on the ARIA charts in February 2021. It was certified platinum in February 2024. G Flip said "I wrote this song after having silly little bickering fights with my partner. In relationships it's so common to say 'it's fine' when it’s really not fine. If you care about someone, talk to them. In the context of what's going on, I thought it would be a good chance to drop a bit of a bop to sing along to and feel alive again in this time." Track listings Charts Certifications References {{G Flip 2020 songs 2020 singles G Flip songs [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Debye Temperature
In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat (heat capacity) in a solid. It treats the oscillation, vibrations of the Crystal structure#Classification, atomic lattice (heat) as phonons in a box in contrast to the Einstein solid, Einstein photoelectron model, which treats the solid as many individual, non-interacting quantum harmonic oscillators. The Debye model correctly predicts the low-temperature dependence of the heat capacity of solids, which is proportional to the cube of temperature – the Debye ''T'' 3 law. Similarly to the Einstein photoelectron model, it recovers the Dulong–Petit law at high temperatures. Due to simplifying assumptions, its accuracy suffers at intermediate temperatures. Derivation The Debye model treats atomic vibrations as phonons confined in the solid's volume. It is analogous to Planck's law of black body radiation, which treats elect ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Fluoride
Europium(III) fluoride is an inorganic compound with a chemical formula EuF3. Production Europium(III) fluoride can be produced by reacting europium(III) nitrate and ammonium fluoride: : Eu(NO3)3 + 3 NH4F → EuF3 + 3 NH4NO3 Europium(III) fluoride nanoparticles can be synthesized by microwave irradiation of europium(III) acetate in an ionic liquid that has tetrafluoroborate Tetrafluoroborate is the anion . This tetrahedral species is isoelectronic with tetrafluoroberyllate (), tetrafluoromethane (CF4), and tetrafluoroammonium () and is valence isoelectronic with many stable and important species including the perc ... as the anion. References {{Lanthanide halides Europium(III) compounds Fluorides Lanthanide halides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mössbauer Spectroscopy
Mössbauer spectroscopy is a spectroscopic technique based on the Mössbauer effect. This effect, discovered by Rudolf Mössbauer (sometimes written "Moessbauer", German: "Mößbauer") in 1958, consists of the nearly recoil-free emission and absorption of nuclear gamma rays in solids. The consequent nuclear spectroscopy method is exquisitely sensitive to small changes in the chemical environment of certain nuclei. Typically, three types of nuclear interactions may be observed: the isomer shift due to differences in nearby electron densities (also called the chemical shift in older literature), quadrupole splitting due to atomic-scale electric field gradients; and magnetic splitting due to non-nuclear magnetic fields. Due to the high energy and extremely narrow line widths of nuclear gamma rays, Mössbauer spectroscopy is a highly sensitive technique in terms of energy (and hence frequency) resolution, capable of detecting changes of just a few parts in 1011. It is a metho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemisches Zentralblatt
''Chemisches Zentralblatt'' is the first and oldest abstracts journal published in the field of chemistry. It covers the chemical literature from 1830 to 1969 and describes therefore the "birth" of chemistry as science, in contrast to alchemy. The information contained in this German journal is comparable with the content of the leading source of chemical information Chemical Abstracts Service (CAS), which started publishing abstracts in English in 1907. ''Chemisches Zentralblatt'' was founded as ''Pharmaceutisches Centralblatt'' by Gustav Theodor FechnerM. Pflücke: ''Das Chemische Zentralblatt 125 Jahre alt'', Angewandte Chemie ''66'' (1954) 537-541, DOI: :10.1002/ange.19540661708. and published by Leopold Voß in LeipzigR. Willstätter: ''Zur Hundertjahrfeier des Chemischen Zentralblattes'', Angewandte Chemie ''42'' (1925) 1049-1052, DOI: :10.1002/ange.19290424502. in 1830. In the first year, 544 pages containing 400 abstracts were published, reporting all relevant research res ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Decomposition (chemistry)
Chemical decomposition, or chemical breakdown, is the process or effect of simplifying a single chemical entity (normal molecule, reaction intermediate, etc.) into two or more fragments. Chemical decomposition is usually regarded and defined as the exact opposite of chemical synthesis. In short, the chemical reaction in which two or more products are formed from a single reactant is called a decomposition reaction. The details of a decomposition process are not always well defined. Nevertheless, some activation energy is generally needed to break the involved bonds and as such, higher temperatures generally accelerates decomposition. The net reaction can be an endothermic process, or in the case of spontaneous decompositions, an exothermic process. The stability of a chemical compound is eventually limited when exposed to extreme environmental conditions such as heat, radiation, humidity, or the acidity of a solvent. Because of this chemical decomposition is often an undesired che ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcination
Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition. The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO3(s) → CaO(s) + CO2(g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting. Industrial calcination generally emits carbon dioxide (). A calciner is a steel cylinder that rotates inside a heated furnace and performs indirect high-temperature processing (550–1150 °C, or 1000–2100 °F) within a controlled atmosphere. Etymology The process of calcination ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Oxide
Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and softest of the lanthanides. It is soft enough to be cut with a knife. Europium was discovered in 1896, provisionally designated as Σ; in 1901, it was named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, 1996, p. 156. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
