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Pyrosilicic Acid
Pyrosilicic acid is the chemical compound with formula or . It is one of the silicic acids and has pyrosilicate as its conjugate base. It was synthesized, using nonaqueous solutions, in 2017. :H6Si2O7(aq) -> 2 SiO2(s) + 3 H2O Pyrosilicic acid may be present in sea water and other natural waters at very low concentration.Katsumi Goto (1956): "Effect of pH on Polymerization of Silicic Acid". ''Journal of Physical Chemistry'', volume 60, issue 7, pages 1007–1008. M. F. Bechtold (1955): "Polymerization and Properties of Dilute Aqueous Silicic Acid from Cation Exchange". ''Journal of Physical Chemistry'', volume 59, issue 6, pages 532–541. Compounds formally derived from it, such as sodium pyrosilicate, are found in the sorosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid . ...
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Pyrosilicate
A pyrosilicate is a type of chemical compound; either an ionic compound that contains the pyrosilicate anion , or an organic compound with the hexavalent ≡-O-≡ group. The anion is also called disilicateViktor Renman (2017): "Structural and Electrochemical Relations in Electrode Materials for Rechargeable Batteries", Doctoral Thesis, Uppsala University, Department of Chemistry. ORCID: 0000-0001-8739-4054 Structure The pyrosilicate anion can be described as two tetrahedra that share a vertex (an oxygen atom). The vertices that are not shared carry a negative charge each. The structure of solid sodium pyrosilicate was described by Volker Kahlenberg and others in 2010.Volker Kahlenberg, Thomas Langreiter, and Erik Arroyabe (2010): " – The Missing Structural Link among Alkali Pyrosilicates". ''Zeitschrift für anorganishe und allgemeine Chemie'' (''Journal for Inorganic and General Chemistry''), volume 636, issue 11, pages 1974-1979. Yuri Smolin and Yuri Shepelev determin ...
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Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, usi ...
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Silicic Acid
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear molecule. The starkly different structures of the di ...
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Pyrosilicate
A pyrosilicate is a type of chemical compound; either an ionic compound that contains the pyrosilicate anion , or an organic compound with the hexavalent ≡-O-≡ group. The anion is also called disilicateViktor Renman (2017): "Structural and Electrochemical Relations in Electrode Materials for Rechargeable Batteries", Doctoral Thesis, Uppsala University, Department of Chemistry. ORCID: 0000-0001-8739-4054 Structure The pyrosilicate anion can be described as two tetrahedra that share a vertex (an oxygen atom). The vertices that are not shared carry a negative charge each. The structure of solid sodium pyrosilicate was described by Volker Kahlenberg and others in 2010.Volker Kahlenberg, Thomas Langreiter, and Erik Arroyabe (2010): " – The Missing Structural Link among Alkali Pyrosilicates". ''Zeitschrift für anorganishe und allgemeine Chemie'' (''Journal for Inorganic and General Chemistry''), volume 636, issue 11, pages 1974-1979. Yuri Smolin and Yuri Shepelev determin ...
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Conjugate Base
A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid donates a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a hydrogen ion. On the other hand, a conjugate base is what is left over after an acid has donated a proton during a chemical reaction. Hence, a conjugate base is a species formed by the removal of a proton from an acid, as in the reverse reaction it is able to gain a hydrogen ion. Because some acids are capable of releasing multiple protons, the conjugate base of an acid may itself be acidic. In summary, this can be represented as the following chemical reaction: :acid + base conjugate\ base + conjugate\ acid Johannes Nicolaus Brønsted and Martin Lowry introduced the Brønsted–Lowry theory, which proposed that any compound that can transfer a proton to any other compound is an acid, and the compound that accepts the proton is a ...
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Sea Water
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately of dissolved salts (predominantly sodium () and chloride () ions). The average density at the surface is 1.025 kg/L. Seawater is denser than both fresh water and pure water (density 1.0 kg/L at ) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases. At typical salinity, it freezes at about . The coldest seawater still in the liquid state ever recorded was found in 2010, in a stream under an Antarctic glacier: the measured temperature was . Seawater pH is typically limited to a range between 7.5 and 8.4. However, there is no universally accepted reference pH-scale for seawater and the difference between measuremen ...
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Sodium Pyrosilicate
Sodium pyrosilicate is the chemical compound . It is one of the sodium silicates, specifically a pyrosilicate, formally a salt of the unstable pyrosilicic acid .Myron C Waddell (1932): "Process of purifying technical sodium pyrosilicate hydrates". US patent US1931364A.J. F. Schairer and N. L. Bowen (1956): "The system ——". ''American Journal of Science'', volume 254, issue 3, pages 129-195 Structure The anhydrous solid has the triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ... crystal structure, with space group P (a = 5.8007(8) Å, b = 11.5811(15) Å, c = 23.157(3) Å, α = 89.709(10)°, β = 88.915(11)°, γ = 89.004(11)°, V = 1555.1(4) Å3, Z = 8, Dx = 2.615 g·cm−3, μ(Mo‐Kα) = 7.94 cm−1). The anions are arranged in layers parallel to the (100) ...
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Sorosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphism (materials science), polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this carbonate–silicate cycle, geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous e ...
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Oxoacids
An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H+ cation and the anion of the acid. Description Under Lavoisier's original theory, all acids contained oxygen, which was named from the Greek ὀξύς (''oxys'': acid, sharp) and the root -γενής (''-genes'': creator). It was later discovered that some acids, notably hydrochloric acid, did not contain oxygen and so acids were divided into oxo-acids and these new hydroacids. All oxyacids have the acidic hydrogen bound to an oxygen atom, so bond strength (length) is not a factor, as it is with binary nonmetal hydrides. Rather, the electronegativity of the central atom and the number of oxygen atoms determine oxyacid acidity. For oxyacids with the same central atom, acid strength increases with the number of oxygen atoms attach ...
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