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Absorption Band
In spectroscopy, an absorption band is a range of wavelengths, frequency, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance. According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific Quantum state, states. When such quantum, quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the radiation changes the state of the atom or molecule from an Ground state, initial state to a Excited state, final state. Overview When electromagnetic radiation is absorbed by an atom or molecule, the energy of the radiation changes the state of the atom or molecule from an Ground state, initial state to a Excited state, final state. The number of states in a specific energy range is discrete for gaseous or diluted systems, with discrete energy levels. Condensed matter physics, Condensed systems, lik ...
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Atmospheric Transmission-en
An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosphere is the outer region of a star, which includes the layers above the opaque photosphere; stars of low temperature might have outer atmospheres containing compound molecules. The atmosphere of Earth is composed of nitrogen (78%), oxygen (21%), argon (0.9%), carbon dioxide (0.04%) and trace gases. Most organisms use oxygen for respiration; lightning and bacteria perform nitrogen fixation which produces ammonia that is used to make nucleotides and amino acids; plants, algae, and cyanobacteria use carbon dioxide for photosynthesis. The layered composition of the atmosphere minimises the harmful effects of sunlight, ultraviolet radiation, solar wind, and cosmic rays and thus protects the organisms from genetic damage. The current composition o ...
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Electronic Band Structure
In solid-state physics, the electronic band structure (or simply band structure) of a solid describes the range of energy levels that electrons may have within it, as well as the ranges of energy that they may not have (called ''band gaps'' or ''forbidden bands''). Band theory derives these bands and band gaps by examining the allowed quantum mechanical wave functions for an electron in a large, periodic lattice of atoms or molecules. Band theory has been successfully used to explain many physical properties of solids, such as electrical resistivity and optical absorption, and forms the foundation of the understanding of all solid-state devices (transistors, solar cells, etc.). Why bands and band gaps occur The formation of electronic bands and band gaps can be illustrated with two complementary models for electrons in solids. The first one is the nearly free electron model, in which the electrons are assumed to move almost freely within the material. In this model, the ...
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Dipole
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways: * An electric dipole moment, electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system is a pair of charges of equal magnitude but opposite sign separated by some typically small distance. (A permanent electric dipole is called an electret.) * A magnetic dipole is the closed circulation of an electric current system. A simple example is a single loop of wire with constant current through it. A bar magnet is an example of a magnet with a permanent magnetic dipole moment. Dipoles, whether electric or magnetic, can be characterized by their dipole moment, a vector quantity. For the simple electric dipole, the electric dipole moment points from the negative charge towards the positive charge, and has a magnitude equal to the strength of each charge times the separation between the charges. (To be precis ...
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Absorption Cross Section
In physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ..., absorption cross-section is a measure of the probability of an absorption process. More generally, the term cross section (physics), cross-section is used in physics to quantify the probability of a certain particle-particle interaction, e.g., scattering, absorption (electromagnetic radiation), electromagnetic absorption, etc. (Note that light in this context is described as consisting of elementary particle, particles, i.e., photons.) A typical absorption cross-section has units of cm2⋅molecule−1. In honor of the fundamental contribution of Maria Goeppert Mayer to this area, the unit for the two-photon absorption cross section is named the "GM". One GM is 10−50 cm4⋅s⋅photon−1. In the context of ozone ...
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Selection Rules
In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in atomic nuclei, and so on. The selection rules may differ according to the technique used to observe the transition. The selection rule also plays a role in chemical reactions, where some are formally spin-forbidden reactions, that is, reactions where the spin state changes at least once from reactants to products. In the following, mainly atomic and molecular transitions are considered. Overview In quantum mechanics the basis for a spectroscopic selection rule is the value of the ''transition moment integral'' :m_ = \int \psi_1^* \, \mu \, \psi_2 \, \mathrm\tau, where \psi_1 and \psi_2 are the wave functions of the two states, "state 1" and "state 2", involved in the transition, and is the transition moment operator. Thi ...
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Conservation Law (physics)
In physics, a conservation law states that a particular measurable property of an isolated physical system does not change as the system evolves over time. Exact conservation laws include conservation of mass-energy, conservation of linear momentum, conservation of angular momentum, and conservation of electric charge. There are also many approximate conservation laws, which apply to such quantities as mass, parity, lepton number, baryon number, strangeness, hypercharge, etc. These quantities are conserved in certain classes of physics processes, but not in all. A local conservation law is usually expressed mathematically as a continuity equation, a partial differential equation which gives a relation between the amount of the quantity and the "transport" of that quantity. It states that the amount of the conserved quantity at a point or within a volume can only change by the amount of the quantity which flows in or out of the volume. From Noether's theorem, every dif ...
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Magnetic Dipole
In electromagnetism, a magnetic dipole is the limit of either a closed loop of electric current or a pair of poles as the size of the source is reduced to zero while keeping the magnetic moment constant. It is a magnetic analogue of the Electric dipole moment, electric dipole, but the analogy is not perfect. In particular, a true magnetic monopole, the magnetic analogue of an electric charge, has never been observed in nature. However, magnetic monopole quasiparticles have been observed as emergent properties of certain condensed matter systems. Moreover, one form of magnetic dipole moment is associated with a fundamental quantum property—the Spin (physics), spin of elementary particles. Because magnetic monopoles do not exist, the magnetic field at a large distance from any static magnetic source looks like the field of a dipole with the same dipole moment. For higher-order sources (e.g. Quadrupole magnet, quadrupoles) with no dipole moment, their field decays towards zero wi ...
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Angular Momentum
Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total angular momentum of a closed system remains constant. Angular momentum has both a direction (geometry), direction and a magnitude, and both are conserved. Bicycle and motorcycle dynamics, Bicycles and motorcycles, flying discs, Rifling, rifled bullets, and gyroscopes owe their useful properties to conservation of angular momentum. Conservation of angular momentum is also why hurricanes form spirals and neutron stars have high rotational rates. In general, conservation limits the possible motion of a system, but it does not uniquely determine it. The three-dimensional angular momentum for a point particle is classically represented as a pseudovector , the cross product of the particle's position vector (relative to some origin) and its mo ...
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Momentum
In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If is an object's mass and is its velocity (also a vector quantity), then the object's momentum (from Latin '' pellere'' "push, drive") is: \mathbf = m \mathbf. In the International System of Units (SI), the unit of measurement of momentum is the kilogram metre per second (kg⋅m/s), which is dimensionally equivalent to the newton-second. Newton's second law of motion states that the rate of change of a body's momentum is equal to the net force acting on it. Momentum depends on the frame of reference, but in any inertial frame of reference, it is a ''conserved'' quantity, meaning that if a closed system is not affected by external forces, its total momentum does not change. Momentum is also conserved in special relativity (with a mo ...
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Energy
Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and light. Energy is a Conservation law, conserved quantity—the law of conservation of energy states that energy can be Energy transformation, converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a Classical field theory, field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, the internal energy contained within a thermodynamic system, and rest energy associated with an object's rest mass. These are not mutual ...
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Plasmon
In physics, a plasmon is a quantum of plasma oscillation. Just as light (an optical oscillation) consists of photons, the plasma oscillation consists of plasmons. The plasmon can be considered as a quasiparticle since it arises from the quantization of plasma oscillations, just like phonons are quantizations of mechanical vibrations. Thus, plasmons are collective (a discrete number) oscillations of the free electron gas density. For example, at optical frequencies, plasmons can couple with a photon to create another quasiparticle called a plasmon polariton. The field of study and manipulation of plasmons is called plasmonics. Derivation The plasmon was initially proposed in 1952 by David Pines and David Bohm and was shown to arise from a Hamiltonian for the long-range electron-electron correlations. Since plasmons are the quantization of classical plasma oscillations, most of their properties can be derived directly from Maxwell's equations. Explanation Plasmons ...
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