
In
physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, Hooke's law is an
empirical law
Scientific laws or laws of science are statements, based on repeated experiments or observations, that describe or predict a range of natural phenomena. The term ''law'' has diverse usage in many cases (approximate, accurate, broad, or narrow) ...
which states that the
force
In physics, a force is an influence that can cause an Physical object, object to change its velocity unless counterbalanced by other forces. In mechanics, force makes ideas like 'pushing' or 'pulling' mathematically precise. Because the Magnitu ...
() needed to extend or compress a
spring by some distance ()
scales linearly with respect to that distance—that is, where is a constant factor characteristic of the spring (i.e., its
stiffness
Stiffness is the extent to which an object resists deformation in response to an applied force.
The complementary concept is flexibility or pliability: the more flexible an object is, the less stiff it is.
Calculations
The stiffness, k, of a ...
), and is small compared to the total possible deformation of the spring. The law is named after 17th-century British physicist
Robert Hooke
Robert Hooke (; 18 July 16353 March 1703) was an English polymath who was active as a physicist ("natural philosopher"), astronomer, geologist, meteorologist, and architect. He is credited as one of the first scientists to investigate living ...
. He first stated the law in 1676 as a Latin
anagram
An anagram is a word or phrase formed by rearranging the letters of a different word or phrase, typically using all the original letters exactly once. For example, the word ''anagram'' itself can be rearranged into the phrase "nag a ram"; which ...
. He published the solution of his anagram in 1678 as: ("as the extension, so the force" or "the extension is proportional to the force"). Hooke states in the 1678 work that he was aware of the law since 1660.
Hooke's equation holds (to some extent) in many other situations where an
elastic
Elastic is a word often used to describe or identify certain types of elastomer, Elastic (notion), elastic used in garments or stretch fabric, stretchable fabrics.
Elastic may also refer to:
Alternative name
* Rubber band, ring-shaped band of rub ...
body is
deformed, such as wind blowing on a tall building, and a musician plucking a
string
String or strings may refer to:
*String (structure), a long flexible structure made from threads twisted together, which is used to tie, bind, or hang other objects
Arts, entertainment, and media Films
* ''Strings'' (1991 film), a Canadian anim ...
of a guitar. An elastic body or material for which this equation can be assumed is said to be
linear-elastic or Hookean.
Hooke's law is only a
first-order linear approximation to the real response of springs and other elastic bodies to applied forces. It must eventually fail once the forces exceed some limit, since no material can be compressed beyond a certain minimum size, or stretched beyond a maximum size, without some permanent deformation or change of state. Many materials will noticeably deviate from Hooke's law well before those
elastic limit
In materials science and engineering, the yield point is the point on a stress–strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and w ...
s are reached.
On the other hand, Hooke's law is an accurate approximation for most solid bodies, as long as the forces and deformations are small enough. For this reason, Hooke's law is extensively used in all branches of science and engineering, and is the foundation of many disciplines such as
seismology
Seismology (; from Ancient Greek σεισμός (''seismós'') meaning "earthquake" and -λογία (''-logía'') meaning "study of") is the scientific study of earthquakes (or generally, quakes) and the generation and propagation of elastic ...
,
molecular mechanics
Molecular mechanics uses classical mechanics to model molecular systems. The Born–Oppenheimer approximation is assumed valid and the potential energy of all systems is calculated as a function of the nuclear coordinates using Force field (chemi ...
and
acoustics
Acoustics is a branch of physics that deals with the study of mechanical waves in gases, liquids, and solids including topics such as vibration, sound, ultrasound and infrasound. A scientist who works in the field of acoustics is an acoustician ...
. It is also the fundamental principle behind the
spring scale
A spring scale, spring balance or newton meter is a type of mechanical force gauge or weighing scale. It consists of a Spring (device), spring fixed at one end with a hook to attach an object at the other. It works in accordance with Hooke's law ...
, the
manometer
Pressure measurement is the measurement of an applied force by a fluid (liquid or gas) on a surface. Pressure is typically measured in units of force per unit of surface area. Many techniques have been developed for the measurement of pressu ...
, the
galvanometer
A galvanometer is an electromechanical measuring instrument for electric current. Early galvanometers were uncalibrated, but improved versions, called ammeters, were calibrated and could measure the flow of current more precisely. Galvanomet ...
, and the
balance wheel
A balance wheel, or balance, is the timekeeping device used in mechanical watches and small clocks, analogous to the pendulum in a pendulum clock. It is a weighted wheel that rotates back and forth, being returned toward its center position b ...
of the
mechanical clock
A clock or chronometer is a device that measures and displays time. The clock is one of the oldest human inventions, meeting the need to measure intervals of time shorter than the natural units such as the day, the lunar month, and the ye ...
.
The modern
theory of elasticity
Solid mechanics (also known as mechanics of solids) is the branch of continuum mechanics that studies the behavior of solid materials, especially their motion and deformation under the action of forces, temperature changes, phase changes, and ...
generalizes Hooke's law to say that the
strain (deformation) of an elastic object or material is proportional to the
stress applied to it. However, since general stresses and strains may have multiple independent components, the "proportionality factor" may no longer be just a single real number, but rather a
linear map
In mathematics, and more specifically in linear algebra, a linear map (also called a linear mapping, linear transformation, vector space homomorphism, or in some contexts linear function) is a mapping V \to W between two vector spaces that p ...
(a
tensor
In mathematics, a tensor is an algebraic object that describes a multilinear relationship between sets of algebraic objects associated with a vector space. Tensors may map between different objects such as vectors, scalars, and even other ...
) that can be represented by a
matrix
Matrix (: matrices or matrixes) or MATRIX may refer to:
Science and mathematics
* Matrix (mathematics), a rectangular array of numbers, symbols or expressions
* Matrix (logic), part of a formula in prenex normal form
* Matrix (biology), the m ...
of real numbers.
In this general form, Hooke's law makes it possible to deduce the relation between strain and stress for complex objects in terms of intrinsic properties of the materials they are made of. For example, one can deduce that a
homogeneous
Homogeneity and heterogeneity are concepts relating to the uniformity of a substance, process or image. A homogeneous feature is uniform in composition or character (i.e., color, shape, size, weight, height, distribution, texture, language, i ...
rod with uniform
cross section
Cross section may refer to:
* Cross section (geometry)
** Cross-sectional views in architecture and engineering 3D
*Cross section (geology)
* Cross section (electronics)
* Radar cross section, measure of detectability
* Cross section (physics)
**A ...
will behave like a simple spring when stretched, with a stiffness directly proportional to its cross-section area and inversely proportional to its length.
Formal definition
Linear springs

Consider a simple
helical spring that has one end attached to some fixed object, while the free end is being pulled by a force whose magnitude is . Suppose that the spring has reached a state of
equilibrium
Equilibrium may refer to:
Film and television
* ''Equilibrium'' (film), a 2002 science fiction film
* '' The Story of Three Loves'', also known as ''Equilibrium'', a 1953 romantic anthology film
* "Equilibrium" (''seaQuest 2032'')
* ''Equilibr ...
, where its length is not changing anymore. Let be the amount by which the free end of the spring was displaced from its "relaxed" position (when it is not being stretched). Hooke's law states that
or, equivalently,
where is a positive real number, characteristic of the spring. A spring with spaces between the coils can be compressed, and the same formula holds for compression, with and both negative in that case.
According to this formula, the
graph
Graph may refer to:
Mathematics
*Graph (discrete mathematics), a structure made of vertices and edges
**Graph theory, the study of such graphs and their properties
*Graph (topology), a topological space resembling a graph in the sense of discret ...
of the applied force as a function of the displacement will be a straight line passing through the
origin
Origin(s) or The Origin may refer to:
Arts, entertainment, and media
Comics and manga
* ''Origin'' (comics), a Wolverine comic book mini-series published by Marvel Comics in 2002
* ''The Origin'' (Buffy comic), a 1999 ''Buffy the Vampire Sl ...
, whose
slope
In mathematics, the slope or gradient of a Line (mathematics), line is a number that describes the direction (geometry), direction of the line on a plane (geometry), plane. Often denoted by the letter ''m'', slope is calculated as the ratio of t ...
is .
Hooke's law for a spring is also stated under the convention that is the
restoring force
In physics, the restoring force is a force that acts to bring a body to its equilibrium position. The restoring force is a function only of position of the mass or particle, and it is always directed back toward the equilibrium position of the s ...
exerted by the spring on whatever is pulling its free end. In that case, the equation becomes
since the direction of the restoring force is opposite to that of the displacement.
Torsional springs
The
torsional
In the field of solid mechanics, torsion is the twisting of an object due to an applied torque. Torsion could be defined as strain or angular deformation, and is measured by the angle a chosen section is rotated from its equilibrium position. Th ...
analog of Hooke's law applies to
torsional springs. It states that the torque (τ) required to rotate an object is directly proportional to the angular displacement (θ) from the equilibrium position. It describes the relationship between the torque applied to an object and the resulting angular
deformation due to torsion. Mathematically, it can be expressed as:
:
Where:
* τ is the
torque
In physics and mechanics, torque is the rotational analogue of linear force. It is also referred to as the moment of force (also abbreviated to moment). The symbol for torque is typically \boldsymbol\tau, the lowercase Greek letter ''tau''. Wh ...
measured in Newton-meters or N·m.
* k is the
torsional constant (measured in N·m/radian), which characterizes the stiffness of the torsional spring or the resistance to angular displacement.
* θ is the
angular displacement
The angular displacement (symbol θ, , or φ) – also called angle of rotation, rotational displacement, or rotary displacement – of a physical body is the angle (in units of radians, degrees, turns, etc.) through which the body rotates ( ...
(measured in radians) from the equilibrium position.
Just as in the linear case, this law shows that the torque is proportional to the angular displacement, and the negative sign indicates that the torque acts in a direction opposite to the angular displacement, providing a restoring force to bring the system back to equilibrium.
General "scalar" springs
Hooke's spring law usually applies to any elastic object, of arbitrary complexity, as long as both the deformation and the stress can be expressed by a single number that can be both positive and negative.
For example, when a block of rubber attached to two parallel plates is deformed by
shearing, rather than stretching or compression, the shearing force and the sideways displacement of the plates obey Hooke's law (for small enough deformations).
Hooke's law also applies when a straight steel bar or concrete beam (like the one used in buildings), supported at both ends, is bent by a weight placed at some intermediate point. The displacement in this case is the deviation of the beam, measured in the transversal direction, relative to its unloaded shape.
Vector formulation
In the case of a helical spring that is stretched or compressed along its
axis
An axis (: axes) may refer to:
Mathematics
*A specific line (often a directed line) that plays an important role in some contexts. In particular:
** Coordinate axis of a coordinate system
*** ''x''-axis, ''y''-axis, ''z''-axis, common names ...
, the applied (or restoring) force and the resulting elongation or compression have the same direction (which is the direction of said axis). Therefore, if and are defined as
vector
Vector most often refers to:
* Euclidean vector, a quantity with a magnitude and a direction
* Disease vector, an agent that carries and transmits an infectious pathogen into another living organism
Vector may also refer to:
Mathematics a ...
s, Hooke's
equation
In mathematics, an equation is a mathematical formula that expresses the equality of two expressions, by connecting them with the equals sign . The word ''equation'' and its cognates in other languages may have subtly different meanings; for ...
still holds and says that the force vector is the
elongation vector multiplied by a fixed
scalar
Scalar may refer to:
*Scalar (mathematics), an element of a field, which is used to define a vector space, usually the field of real numbers
*Scalar (physics), a physical quantity that can be described by a single element of a number field such a ...
.
General tensor form
Some elastic bodies will deform in one direction when subjected to a force with a different direction. One example is a horizontal wood beam with non-square rectangular cross section that is bent by a transverse load that is neither vertical nor horizontal. In such cases, the ''magnitude'' of the displacement will be proportional to the magnitude of the force , as long as the direction of the latter remains the same (and its value is not too large); so the scalar version of Hooke's law will hold. However, the force and displacement ''vectors'' will not be scalar multiples of each other, since they have different directions. Moreover, the ratio between their magnitudes will depend on the direction of the vector .
Yet, in such cases there is often a fixed
linear relation
In linear algebra, a linear relation, or simply relation, between elements of a vector space or a module is a linear equation that has these elements as a solution.
More precisely, if e_1,\dots,e_n are elements of a (left) module over a ring ( ...
between the force and deformation vectors, as long as they are small enough. Namely, there is a
function
Function or functionality may refer to:
Computing
* Function key, a type of key on computer keyboards
* Function model, a structured representation of processes in a system
* Function object or functor or functionoid, a concept of object-orie ...
from vectors to vectors, such that , and for any real numbers , and any displacement vectors , . Such a function is called a (second-order)
tensor
In mathematics, a tensor is an algebraic object that describes a multilinear relationship between sets of algebraic objects associated with a vector space. Tensors may map between different objects such as vectors, scalars, and even other ...
.
With respect to an arbitrary
Cartesian coordinate system
In geometry, a Cartesian coordinate system (, ) in a plane (geometry), plane is a coordinate system that specifies each point (geometry), point uniquely by a pair of real numbers called ''coordinates'', which are the positive and negative number ...
, the force and displacement vectors can be represented by 3 × 1
matrices
Matrix (: matrices or matrixes) or MATRIX may refer to:
Science and mathematics
* Matrix (mathematics), a rectangular array of numbers, symbols or expressions
* Matrix (logic), part of a formula in prenex normal form
* Matrix (biology), the ...
of real numbers. Then the tensor connecting them can be represented by a 3 × 3 matrix of real coefficients, that, when
multiplied by the displacement vector, gives the force vector:
That is,
for . Therefore, Hooke's law can be said to hold also when and are vectors with variable directions, except that the stiffness of the object is a tensor , rather than a single real number .
Hooke's law for continuous media

The stresses and strains of the material inside a
continuous
Continuity or continuous may refer to:
Mathematics
* Continuity (mathematics), the opposing concept to discreteness; common examples include
** Continuous probability distribution or random variable in probability and statistics
** Continuous ...
elastic material (such as a block of rubber, the wall of a
boiler
A boiler is a closed vessel in which fluid (generally water) is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, centra ...
, or a steel bar) are connected by a linear relationship that is mathematically similar to Hooke's spring law, and is often referred to by that name.
However, the strain state in a solid medium around some point cannot be described by a single vector. The same parcel of material, no matter how small, can be compressed, stretched, and sheared at the same time, along different directions. Likewise, the stresses in that parcel can be at once pushing, pulling, and shearing.
In order to capture this complexity, the relevant state of the medium around a point must be represented by two-second-order tensors, the
strain tensor
In mechanics, strain is defined as relative deformation, compared to a position configuration. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the ...
(in lieu of the displacement ) and the
stress tensor (replacing the restoring force ). The analogue of Hooke's spring law for continuous media is then
where is a fourth-order tensor (that is, a linear map between second-order tensors) usually called the
stiffness tensor
Stiffness is the extent to which an object resists deformation in response to an applied force.
The complementary concept is flexibility or pliability: the more flexible an object is, the less stiff it is.
Calculations
The stiffness, k, of a ...
or
elasticity tensor
The elasticity tensor is a fourth-rank tensor describing the stress-strain relation in
a linear elastic material. Other names are elastic modulus tensor and stiffness tensor. Common symbols include \mathbf and \mathbf.
The defining equation can ...
. One may also write it as
where the tensor , called the
compliance tensor, represents the inverse of said linear map.
In a Cartesian coordinate system, the stress and strain tensors can be represented by 3 × 3 matrices
Being a linear mapping between the nine numbers and the nine numbers , the stiffness tensor is represented by a matrix of real numbers . Hooke's law then says that
where .
All three tensors generally vary from point to point inside the medium, and may vary with time as well. The strain tensor merely specifies the displacement of the medium particles in the neighborhood of the point, while the stress tensor specifies the forces that neighboring parcels of the medium are exerting on each other. Therefore, they are independent of the composition and physical state of the material. The stiffness tensor , on the other hand, is a property of the material, and often depends on physical state variables such as temperature,
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
, and
microstructure
Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material (such as metals, polymer ...
.
Due to the inherent symmetries of , , and , only 21 elastic coefficients of the latter are independent. This number can be further reduced by the symmetry of the material: 9 for an
orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...
crystal, 5 for an
hexagonal
In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°.
Regular hexagon
A regular hexagon is d ...
structure, and 3 for a
cubic
Cubic may refer to:
Science and mathematics
* Cube (algebra), "cubic" measurement
* Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex
** Cubic crystal system, a crystal system w ...
symmetry. For
isotropic
In physics and geometry, isotropy () is uniformity in all orientations. Precise definitions depend on the subject area. Exceptions, or inequalities, are frequently indicated by the prefix ' or ', hence '' anisotropy''. ''Anisotropy'' is also ...
media (which have the same physical properties in any direction), can be reduced to only two independent numbers, the
bulk modulus
The bulk modulus (K or B or k) of a substance is a measure of the resistance of a substance to bulk compression. It is defined as the ratio of the infinitesimal pressure increase to the resulting ''relative'' decrease of the volume.
Other mo ...
and the
shear modulus
In materials science, shear modulus or modulus of rigidity, denoted by ''G'', or sometimes ''S'' or ''μ'', is a measure of the Elasticity (physics), elastic shear stiffness of a material and is defined as the ratio of shear stress to the shear s ...
, that quantify the material's resistance to changes in volume and to shearing deformations, respectively.
Analogous laws
Since Hooke's law is a simple proportionality between two quantities, its formulas and consequences are mathematically similar to those of many other physical laws, such as those describing the motion of
fluid
In physics, a fluid is a liquid, gas, or other material that may continuously motion, move and Deformation (physics), deform (''flow'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are M ...
s, or the
polarization
Polarization or polarisation may refer to:
Mathematics
*Polarization of an Abelian variety, in the mathematics of complex manifolds
*Polarization of an algebraic form, a technique for expressing a homogeneous polynomial in a simpler fashion by ...
of a
dielectric
In electromagnetism, a dielectric (or dielectric medium) is an Insulator (electricity), electrical insulator that can be Polarisability, polarised by an applied electric field. When a dielectric material is placed in an electric field, electric ...
by an
electric field
An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
.
In particular, the tensor equation relating elastic stresses to strains is entirely similar to the equation relating the
viscous stress tensor
The viscous stress tensor is a tensor used in continuum mechanics to model the part of the stress at a point within some material that can be attributed to the strain rate, the rate at which it is deforming around that point.
The viscous stres ...
and the
strain rate tensor
In continuum mechanics, the strain-rate tensor or rate-of-strain tensor is a physical quantity that describes the rate of change of the strain (i.e., the relative deformation) of a material in the neighborhood of a certain point, at a certain ...
in flows of
viscous
Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for example, syrup h ...
fluids; although the former pertains to
static stresses (related to ''amount'' of deformation) while the latter pertains to
dynamical stresses (related to the ''rate'' of deformation).
Units of measurement
In
SI units
The International System of Units, internationally known by the abbreviation SI (from French ), is the modern form of the metric system and the world's most widely used system of measurement. It is the only system of measurement with official st ...
, displacements are measured in meters (m), and forces in
newtons (N or kg·m/s
2). Therefore, the spring constant , and each element of the tensor , is measured in newtons per meter (N/m), or kilograms per second squared (kg/s
2).
For continuous media, each element of the stress tensor is a force divided by an area; it is therefore measured in units of pressure, namely
pascals (Pa, or N/m
2, or kg/(m·s
2). The elements of the strain tensor are
dimensionless
Dimensionless quantities, or quantities of dimension one, are quantities implicitly defined in a manner that prevents their aggregation into units of measurement. ISBN 978-92-822-2272-0. Typically expressed as ratios that align with another sy ...
(displacements divided by distances). Therefore, the entries of are also expressed in units of pressure.
General application to elastic materials
Objects that quickly regain their original shape after being deformed by a force, with the molecules or atoms of their material returning to the initial state of stable equilibrium, often obey Hooke's law.
Hooke's law only holds for some materials under certain loading conditions. Steel exhibits linear-elastic behavior in most engineering applications; Hooke's law is valid for it throughout its elastic range (i.e., for stresses below the
yield strength
In materials science and engineering, the yield point is the point on a stress–strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and w ...
). For some other materials, such as aluminium, Hooke's law is only valid for a portion of the elastic range. For these materials a
proportional limit
In materials science and engineering, the yield point is the point on a stress–strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and wi ...
stress is defined, below which the errors associated with the linear approximation are negligible.
Rubber is generally regarded as a "non-Hookean" material because its elasticity is stress dependent and sensitive to temperature and loading rate.
Generalizations of Hooke's law for the case of
large deformations is provided by models of
neo-Hookean solid
A neo-Hookean solid is a hyperelastic material model, similar to Hooke's law, that can be used for predicting the nonlinear stress–strain behavior of materials undergoing large deformations. The model was proposed by Ronald Rivlin in 1948 us ...
s and
Mooney–Rivlin solid
In continuum mechanics, a Mooney–Rivlin solidMooney, M., 1940, ''A theory of large elastic deformation'', Journal of Applied Physics, 11(9), pp. 582–592.Rivlin, R. S., 1948, ''Large elastic deformations of isotropic materials. IV. Further deve ...
s.
Derived formulae
Tensional stress of a uniform bar
A rod of any
elastic
Elastic is a word often used to describe or identify certain types of elastomer, Elastic (notion), elastic used in garments or stretch fabric, stretchable fabrics.
Elastic may also refer to:
Alternative name
* Rubber band, ring-shaped band of rub ...
material may be viewed as a linear
spring. The rod has length and cross-sectional area . Its
tensile stress
In continuum mechanics, stress is a physical quantity that describes forces present during deformation. For example, an object being pulled apart, such as a stretched elastic band, is subject to ''tensile'' stress and may undergo elongati ...
is linearly proportional to its fractional extension or strain by the
modulus of elasticity
An elastic modulus (also known as modulus of elasticity (MOE)) is a quantity that describes an object's or substance's resistance to being deformed elastically (i.e., non-permanently) when a stress is applied to it.
Definition
The elastic modu ...
:
The modulus of elasticity may often be considered constant. In turn,
(that is, the fractional change in length), and since
it follows that:
The change in length may be expressed as
Spring energy
The potential energy stored in a spring is given by
which comes from adding up the energy it takes to incrementally compress the spring. That is, the integral of force over displacement. Since the external force has the same general direction as the displacement, the potential energy of a spring is always non-negative. Substituting
gives
This potential can be visualized as a
parabola
In mathematics, a parabola is a plane curve which is Reflection symmetry, mirror-symmetrical and is approximately U-shaped. It fits several superficially different Mathematics, mathematical descriptions, which can all be proved to define exactl ...
on the -plane such that . As the spring is stretched in the positive -direction, the potential energy increases parabolically (the same thing happens as the spring is compressed). Since the change in potential energy changes at a constant rate:
Note that the change in the change in is constant even when the displacement and acceleration are zero.
Relaxed force constants (generalized compliance constants)
Relaxed force constants (the inverse of generalized
compliance constants) are uniquely defined for molecular systems, in contradistinction to the usual "rigid" force constants, and thus their use allows meaningful correlations to be made between force fields calculated for
reactants,
transition state
In chemistry, the transition state of a chemical reaction is a particular configuration along the reaction coordinate. It is defined as the state corresponding to the highest potential energy along this reaction coordinate. It is often marked w ...
s, and products of a
chemical reaction
A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
. Just as the
potential energy
In physics, potential energy is the energy of an object or system due to the body's position relative to other objects, or the configuration of its particles. The energy is equal to the work done against any restoring forces, such as gravity ...
can be written as a quadratic form in the internal coordinates, so it can also be written in terms of generalized forces. The resulting coefficients are termed
compliance constants. A direct method exists for calculating the compliance constant for any internal coordinate of a molecule, without the need to do the normal mode analysis. The suitability of relaxed force constants (inverse compliance constants) as
covalent bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atom ...
strength descriptors was demonstrated as early as 1980. Recently, the suitability as non-covalent bond strength descriptors was demonstrated too.
Harmonic oscillator

A mass attached to the end of a spring is a classic example of a
harmonic oscillator
In classical mechanics, a harmonic oscillator is a system that, when displaced from its equilibrium position, experiences a restoring force ''F'' proportional to the displacement ''x'':
\vec F = -k \vec x,
where ''k'' is a positive const ...
. By pulling slightly on the mass and then releasing it, the system will be set in
sinusoidal
A sine wave, sinusoidal wave, or sinusoid (symbol: ∿) is a periodic wave whose waveform (shape) is the trigonometric sine function. In mechanics, as a linear motion over time, this is '' simple harmonic motion''; as rotation, it correspond ...
oscillating motion about the equilibrium position. To the extent that the spring obeys Hooke's law, and that one can neglect
friction
Friction is the force resisting the relative motion of solid surfaces, fluid layers, and material elements sliding against each other. Types of friction include dry, fluid, lubricated, skin, and internal -- an incomplete list. The study of t ...
and the mass of the spring, the amplitude of the oscillation will remain constant; and its
frequency
Frequency is the number of occurrences of a repeating event per unit of time. Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio ...
will be independent of its amplitude, determined only by the mass and the stiffness of the spring:
This phenomenon made possible the construction of accurate
mechanical clock
A clock or chronometer is a device that measures and displays time. The clock is one of the oldest human inventions, meeting the need to measure intervals of time shorter than the natural units such as the day, the lunar month, and the ye ...
s and watches that could be carried on ships and people's pockets.
Rotation in gravity-free space
If the mass were attached to a spring with force constant and rotating in free space, the spring tension () would supply the required
centripetal force
Centripetal force (from Latin ''centrum'', "center" and ''petere'', "to seek") is the force that makes a body follow a curved trajectory, path. The direction of the centripetal force is always orthogonality, orthogonal to the motion of the bod ...
():
Since and , then:
Given that , this leads to the same frequency equation as above:
Linear elasticity theory for continuous media
Isotropic materials
Isotropic materials are characterized by properties which are independent of direction in space. Physical equations involving isotropic materials must therefore be independent of the coordinate system chosen to represent them. The strain tensor is a symmetric tensor. Since the
trace
Trace may refer to:
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* ''Trace'' (Son Volt album), 1995
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* Trace (band), a Dutch progressive rock band
* ''The Trace'' (album), by Nell
Other uses in arts and entertainment
* ...
of any tensor is independent of any coordinate system, the most complete coordinate-free decomposition of a symmetric tensor is to represent it as the sum of a constant tensor and a traceless symmetric tensor. Thus in
index notation
In mathematics and computer programming, index notation is used to specify the elements of an array of numbers. The formalism of how indices are used varies according to the subject. In particular, there are different methods for referring to th ...
:
where is the
Kronecker delta
In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise:
\delta_ = \begin
0 &\text i \neq j, \\
1 &\ ...
. In direct tensor notation:
where is the second-order identity tensor.
The first term on the right is the constant tensor, also known as the
volumetric strain tensor, and the second term is the traceless symmetric tensor, also known as the
deviatoric strain tensor or shear tensor.
The most general form of Hooke's law for isotropic materials may now be written as a linear combination of these two tensors:
where is the
bulk modulus
The bulk modulus (K or B or k) of a substance is a measure of the resistance of a substance to bulk compression. It is defined as the ratio of the infinitesimal pressure increase to the resulting ''relative'' decrease of the volume.
Other mo ...
and is the
shear modulus
In materials science, shear modulus or modulus of rigidity, denoted by ''G'', or sometimes ''S'' or ''μ'', is a measure of the Elasticity (physics), elastic shear stiffness of a material and is defined as the ratio of shear stress to the shear s ...
.
Using the relationships between the
elastic moduli
An elastic modulus (also known as modulus of elasticity (MOE)) is a quantity that describes an object's or substance's resistance to being deformed elastically (i.e., non-permanently) when a stress is applied to it.
Definition
The elastic modu ...
, these equations may also be expressed in various other ways. A common form of Hooke's law for isotropic materials, expressed in direct tensor notation, is
where and are the
Lamé constants
Lamé may refer to:
*Lamé (fabric)
Lamé ( ; ) is a type of fabric Woven fabric, woven or Knitted fabric, knit with threads made of metallic fiber wrapped around natural or synthetic fibers like silk, nylon, or spandex for added strength an ...
, is the second-rank identity tensor, and I is the symmetric part of the fourth-rank identity tensor. In index notation:
The inverse relationship is
Therefore, the compliance tensor in the relation is
In terms of
Young's modulus
Young's modulus (or the Young modulus) is a mechanical property of solid materials that measures the tensile or compressive stiffness when the force is applied lengthwise. It is the modulus of elasticity for tension or axial compression. Youn ...
and
Poisson's ratio
In materials science and solid mechanics, Poisson's ratio (symbol: ( nu)) is a measure of the Poisson effect, the deformation (expansion or contraction) of a material in directions perpendicular to the specific direction of loading. The value ...
, Hooke's law for isotropic materials can then be expressed as
This is the form in which the strain is expressed in terms of the stress tensor in engineering. The expression in expanded form is
where is
Young's modulus
Young's modulus (or the Young modulus) is a mechanical property of solid materials that measures the tensile or compressive stiffness when the force is applied lengthwise. It is the modulus of elasticity for tension or axial compression. Youn ...
and is
Poisson's ratio
In materials science and solid mechanics, Poisson's ratio (symbol: ( nu)) is a measure of the Poisson effect, the deformation (expansion or contraction) of a material in directions perpendicular to the specific direction of loading. The value ...
. (See
3-D elasticity
Linear elasticity is a mathematical model of how solid objects deform and become internally stressed by prescribed loading conditions. It is a simplification of the more general nonlinear theory of elasticity and a branch of continuum mechani ...
).
In matrix form, Hooke's law for isotropic materials can be written as
where is the engineering shear strain. The inverse relation may be written as
which can be simplified thanks to the Lamé constants:
In vector notation this becomes
where is the identity tensor.
Plane stress
Under
plane stress conditions, . In that case Hooke's law takes the form
In vector notation this becomes
The inverse relation is usually written in the reduced form
Plane strain
Under
plane strain
Plane most often refers to:
* Aero- or airplane, a powered, fixed-wing aircraft
* Plane (geometry), a flat, 2-dimensional surface
* Plane (mathematics), generalizations of a geometrical plane
Plane or planes may also refer to:
Biology
* Pl ...
conditions, . In this case Hooke's law takes the form
Anisotropic materials
The symmetry of the
Cauchy stress tensor
In continuum mechanics, the Cauchy stress tensor (symbol \boldsymbol\sigma, named after Augustin-Louis Cauchy), also called true stress tensor or simply stress tensor, completely defines the state of stress at a point inside a material in the d ...
() and the generalized Hooke's laws () implies that . Similarly, the symmetry of the
infinitesimal strain tensor
In continuum mechanics, the infinitesimal strain theory is a mathematical approach to the description of the deformation of a solid body in which the displacements of the material particles are assumed to be much smaller (indeed, infinitesimall ...
implies that . These symmetries are called the minor symmetries of the stiffness tensor c. This reduces the number of elastic constants from 81 to 36.
If in addition, since the displacement gradient and the Cauchy stress are work conjugate, the stress–strain relation can be derived from a strain energy density functional (), then
The arbitrariness of the order of differentiation implies that . These are called the major symmetries of the stiffness tensor. This reduces the number of elastic constants from 36 to 21. The major and minor symmetries indicate that the stiffness tensor has only 21 independent components.
Matrix representation (stiffness tensor)
It is often useful to express the anisotropic form of Hooke's law in matrix notation, also called
Voigt notation. To do this we take advantage of the symmetry of the stress and strain tensors and express them as six-dimensional vectors in an orthonormal coordinate system () as
Then the stiffness tensor (c) can be expressed as
and Hooke's law is written as
Similarly the compliance tensor (s) can be written as
Change of coordinate system
If a linear elastic material is rotated from a reference configuration to another, then the material is symmetric with respect to the rotation if the components of the stiffness tensor in the rotated configuration are related to the components in the reference configuration by the relation
where are the components of an
orthogonal rotation matrix . The same relation also holds for inversions.
In matrix notation, if the transformed basis (rotated or inverted) is related to the reference basis by
then
In addition, if the material is symmetric with respect to the transformation then
Orthotropic materials
Orthotropic material
In material science and solid mechanics, orthotropic materials have material properties at a particular point which differ along three orthogonal axes, where each axis has twofold rotational symmetry. These directional differences in strength can ...
s have three
orthogonal
In mathematics, orthogonality (mathematics), orthogonality is the generalization of the geometric notion of ''perpendicularity''. Although many authors use the two terms ''perpendicular'' and ''orthogonal'' interchangeably, the term ''perpendic ...
planes of symmetry. If the basis vectors () are normals to the planes of symmetry then the coordinate transformation relations imply that
The inverse of this relation is commonly written as
where
* is the
Young's modulus
Young's modulus (or the Young modulus) is a mechanical property of solid materials that measures the tensile or compressive stiffness when the force is applied lengthwise. It is the modulus of elasticity for tension or axial compression. Youn ...
along axis
* is the
shear modulus
In materials science, shear modulus or modulus of rigidity, denoted by ''G'', or sometimes ''S'' or ''μ'', is a measure of the Elasticity (physics), elastic shear stiffness of a material and is defined as the ratio of shear stress to the shear s ...
in direction on the plane whose normal is in direction
* is the
Poisson's ratio
In materials science and solid mechanics, Poisson's ratio (symbol: ( nu)) is a measure of the Poisson effect, the deformation (expansion or contraction) of a material in directions perpendicular to the specific direction of loading. The value ...
that corresponds to a contraction in direction when an extension is applied in direction .
Under ''plane stress'' conditions, , Hooke's law for an orthotropic material takes the form
The inverse relation is
The transposed form of the above stiffness matrix is also often used.
Transversely isotropic materials
A
transversely isotropic material is symmetric with respect to a rotation about an
axis of symmetry
An axis (: axes) may refer to:
Mathematics
*A specific line (often a directed line) that plays an important role in some contexts. In particular:
** Coordinate axis of a coordinate system
*** ''x''-axis, ''y''-axis, ''z''-axis, common names f ...
. For such a material, if is the axis of symmetry, Hooke's law can be expressed as
More frequently, the axis is taken to be the axis of symmetry and the inverse Hooke's law is written as
:
Universal elastic anisotropy index
To grasp the degree of anisotropy of any class, a universal elastic anisotropy index (AU)
was formulated. It replaces the
Zener ratio, which is suited for
cubic crystals.
Thermodynamic basis
Linear deformations of elastic materials can be approximated as
adiabatic. Under these conditions and for quasistatic processes the
first law of thermodynamics
The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. For a thermodynamic process affecting a thermodynamic system without transfer of matter, the law distinguishes two ...
for a deformed body can be expressed as
where is the increase in
internal energy
The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accoun ...
and is the
work
Work may refer to:
* Work (human activity), intentional activity people perform to support themselves, others, or the community
** Manual labour, physical work done by humans
** House work, housework, or homemaking
** Working animal, an ani ...
done by external forces. The work can be split into two terms
where is the work done by
surface force
Surface force denoted ''fs'' is the force that acts across an internal or external surface element in a material body.
Normal forces and shear forces between objects are types of surface force. All cohesive forces and contact forces between obj ...
s while is the work done by
body force
In physics, a body force is a force that acts throughout the volume of a body.Springer site - Book 'Solid mechanics'preview paragraph 'Body forces'./ref> Forces due to gravity, electric fields and magnetic fields are examples of body forces. Bod ...
s. If is a
variation of the displacement field in the body, then the two external work terms can be expressed as
where is the surface
traction vector, is the body force vector, represents the body and represents its surface. Using the relation between the
Cauchy stress and the surface traction, (where is the unit outward normal to ), we have
Converting the
surface integral
In mathematics, particularly multivariable calculus, a surface integral is a generalization of multiple integrals to integration over surfaces. It can be thought of as the double integral analogue of the line integral. Given a surface, o ...
into a
volume integral
In mathematics (particularly multivariable calculus), a volume integral (∭) is an integral over a 3-dimensional domain; that is, it is a special case of multiple integrals. Volume integrals are especially important in physics for many applica ...
via the
divergence theorem
In vector calculus, the divergence theorem, also known as Gauss's theorem or Ostrogradsky's theorem, reprinted in is a theorem relating the '' flux'' of a vector field through a closed surface to the ''divergence'' of the field in the volume ...
gives
Using the symmetry of the Cauchy stress and the identity
we have the following
From the definition of
strain and from the equations of
equilibrium
Equilibrium may refer to:
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* '' The Story of Three Loves'', also known as ''Equilibrium'', a 1953 romantic anthology film
* "Equilibrium" (''seaQuest 2032'')
* ''Equilibr ...
we have
Hence we can write
and therefore the variation in the
internal energy
The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accoun ...
density is given by
An
elastic
Elastic is a word often used to describe or identify certain types of elastomer, Elastic (notion), elastic used in garments or stretch fabric, stretchable fabrics.
Elastic may also refer to:
Alternative name
* Rubber band, ring-shaped band of rub ...
material is defined as one in which the total internal energy is equal to the
potential energy
In physics, potential energy is the energy of an object or system due to the body's position relative to other objects, or the configuration of its particles. The energy is equal to the work done against any restoring forces, such as gravity ...
of the internal forces (also called the elastic strain energy). Therefore, the internal energy density is a function of the strains, and the variation of the internal energy can be expressed as
Since the variation of strain is arbitrary, the stress–strain relation of an elastic material is given by
For a linear elastic material, the quantity is a linear function of , and can therefore be expressed as
where c is a fourth-rank tensor of material constants, also called the stiffness tensor. We can see why c must be a fourth-rank tensor by noting that, for a linear elastic material,
In index notation
The right-hand side constant requires four indices and is a fourth-rank quantity. We can also see that this quantity must be a tensor because it is a linear transformation that takes the strain tensor to the stress tensor. We can also show that the constant obeys the tensor transformation rules for fourth-rank tensors.
See also
*
Acoustoelastic effect The acoustoelastic effect is how the sound velocities (both longitudinal and shear wave velocities) of an elastic material change if subjected to an initial static stress field. This is a non-linear effect of the constitutive relation between ...
*
Elastic potential energy
Elastic energy is the mechanical potential energy stored in the configuration of a material or physical system as it is subjected to elastic deformation by work performed upon it. Elastic energy occurs when objects are impermanently compressed, s ...
*
Laws of science
Scientific laws or laws of science are statements, based on repeated experiments or observations, that describe or predict a range of natural phenomena. The term ''law'' has diverse usage in many cases (approximate, accurate, broad, or narrow) ...
*
List of scientific laws named after people
This is a list of scientific laws named after people ( eponymous laws). For other lists of eponyms, see eponym.
See also
* Eponym
An eponym is a noun after which or for which someone or something is, or is believed to be, named. Adjectives ...
*
Quadratic form
In mathematics, a quadratic form is a polynomial with terms all of degree two (" form" is another name for a homogeneous polynomial). For example,
4x^2 + 2xy - 3y^2
is a quadratic form in the variables and . The coefficients usually belong t ...
*
Series and parallel springs
*
Spring system
In engineering and physics, a spring system or spring network is a model of physics described as a graph with a position at each vertex and a spring of given stiffness and length along each edge. This generalizes Hooke's law to higher dimensions ...
*
Simple harmonic motion of a mass on a spring
*
Sine wave
A sine wave, sinusoidal wave, or sinusoid (symbol: ∿) is a periodic function, periodic wave whose waveform (shape) is the trigonometric function, trigonometric sine, sine function. In mechanics, as a linear motion over time, this is ''simple ...
*
Solid mechanics
Solid mechanics (also known as mechanics of solids) is the branch of continuum mechanics that studies the behavior of solid materials, especially their motion and deformation (mechanics), deformation under the action of forces, temperature chang ...
*
Spring pendulum
Notes
References
Hooke's law - The Feynman Lectures on PhysicsHooke's Law - Classical Mechanics - Physics - MIT OpenCourseWare
External links
JavaScript Applet demonstrating Springs and Hooke's lawJavaScript Applet demonstrating Spring Force
{{Elastic moduli
Robert Hooke
1676 in science
Elasticity (physics)
Solid mechanics
Springs (mechanical)
Structural analysis