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A reverberatory furnace is a
metallurgical Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the ...
or process furnace that isolates the material being processed from contact with the
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work (physics), work. The concept was originally applied solely to those materials capable of releasing chem ...
, but not from contact with
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
gases Gas is a state of matter that has neither a fixed volume nor a fixed shape and is a compressible fluid. A ''pure gas'' is made up of individual atoms (e.g. a noble gas like neon) or molecules of either a single type of atom ( elements such ...
. The term ''reverberation'' is used here in a generic sense of ''rebounding'' or '' reflecting'', not in the acoustic sense of ''echoing''.


Operation

Chemistry determines the optimum relationship between the fuel and the material, among other variables. The reverberatory furnace can be contrasted on the one hand with the
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being supplied above atmospheric pressure. In a ...
, in which fuel and material are mixed in a single chamber, and, on the other hand, with
crucible A crucible is a container in which metals or other substances may be melted or subjected to very high temperatures. Although crucibles have historically tended to be made out of clay, they can be made from any material that withstands temperat ...
, muffling, or retort furnaces, in which the subject material is isolated from the fuel and all of the products of combustion including gases and flying ash. There are, however, a great many furnace designs, and the terminology of metallurgy has not been very consistently defined, so it is difficult to categorically contradict other views. The applications of these devices fall into two general categories, metallurgical melting furnaces, and lower temperature processing furnaces typically used for metallic ores and other minerals. A reverberatory furnace is at a disadvantage from the standpoint of efficiency compared to a blast furnace due to the separation of the burning fuel and the subject material, and it is necessary to effectively utilize both reflected
radiant heat Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electro ...
and direct contact with the
exhaust gas Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through ...
es (
convection Convection is single or Multiphase flow, multiphase fluid flow that occurs Spontaneous process, spontaneously through the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoy ...
) to maximize
heat transfer Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, ...
. Historically these furnaces have used solid fuel, and
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the coal seam, ...
has proven to be the best choice. The brightly visible flames, due to the substantial volatile component, give more radiant heat transfer than
anthracite coal Anthracite, also known as hard coal and black coal, is a hard, compact variety of coal that has a submetallic lustre. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the highe ...
or
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ca ...
. Contact with the products of combustion, which may add undesirable elements to the subject material, is used to advantage in some processes. Control of the fuel/air balance can alter the exhaust gas chemistry toward either an oxidizing or a reducing mixture, and thus alter the chemistry of the material being processed. For example,
cast iron Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its car ...
can be '' puddled'' in an oxidizing atmosphere to convert it to the lower-carbon
mild steel Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states: * no minimum content is specified or required for chromium, cobalt ...
or bar iron. The Siemens-Martin oven in open hearth steelmaking is also a reverberatory furnace. Reverberatory furnaces (in this context, usually called air furnaces) were formerly also used for melting brass,
bronze Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
, and
pig iron Pig iron, also known as crude iron, is an intermediate good used by the iron industry in the production of steel. It is developed by smelting iron ore in a blast furnace. Pig iron has a high carbon content, typically 3.8–4.7%, along with si ...
for
foundry A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals pr ...
work. They were also, for the first 75 years of the 20th century, the dominant smelting furnace used in copper production, treating either roasted calcine or raw copper sulfide concentrate.W G Davenport, "Copper extraction from the 60s into the 21st century," in: ''Proceedings of the Copper 99–Cobre 99 International Conference. Volume I—Plenary Lectures/Movement of Copper and Industry Outlook/Copper Applications and Fabrication,'' Eds G A Eltringham, N L Piret and M Sahoo (The Minerals, Metals and Materials Society: Warrendale, Pennsylvania, 1999), 55–79. While they have been supplanted in this role, first by flash furnaces and more recently also by the Ausmelt and ISASMELT furnaces, they are very effective at producing slags with low copper losses.


History

The first reverberatory furnaces were perhaps in the medieval period, and were used for melting
bronze Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
for casting bells. The earliest known detailed description was provided by Biringuccio. They were first applied to smelting metals in the late 17th century. Sir Clement Clerke and his son Talbot built cupolas or reverberatory furnaces in the Avon Gorge below
Bristol Bristol () is a City status in the United Kingdom, cathedral city, unitary authority area and ceremonial county in South West England, the most populous city in the region. Built around the River Avon, Bristol, River Avon, it is bordered by t ...
in about 1678. In 1687, while obstructed from smelting lead (by litigation), they moved on to copper. In the following decades, reverberatory furnaces were widely adopted for smelting these metals and also tin. They had the advantage over older methods that the fuel was mineral coal, not charcoal or 'white coal' (chopped dried wood). In the 1690s, they (or associates) applied the reverberatory furnace (in this case known as an air furnace) to melting pig iron for
foundry A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals pr ...
purposes. This was used at
Coalbrookdale Coalbrookdale is a town in the Ironbridge Gorge and the Telford and Wrekin borough of Shropshire, England, containing a settlement of great significance in the history of iron ore smelting. It lies within the civil parish called The Gorge, Shro ...
and various other places, but became obsolete at the end of the 18th century with the introduction of the foundry cupola furnace, which was a kind of small blast furnace, and a quite different species from the reverberatory furnace. The
puddling furnace Puddling is the process of converting pig iron to bar (wrought) iron in a coal fired reverberatory furnace. It was developed in England during the 1780s. The molten pig iron was stirred in a reverberatory furnace, in an Redox, oxidizing enviro ...
, introduced by
Henry Cort Henry Cort (c. 1740 – 23 May 1800) was an English ironware producer who was formerly a Navy pay agent. During the Industrial Revolution in England, Cort began refining iron from pig iron to wrought iron (or bar iron) using innovative productio ...
in the 1780s to replace the older finery process, was also a variety of reverberatory furnace. Reverberatory furnaces were introduced to
Chile Chile, officially the Republic of Chile, is a country in western South America. It is the southernmost country in the world and the closest to Antarctica, stretching along a narrow strip of land between the Andes, Andes Mountains and the Paci ...
around 1830 by Charles Saint Lambert. This revolutionized Chilean copper mining to such degree that the country came to supply 19% of the copper produced worldwide in the 19th century. The use of mineral coal instead
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ca ...
in reverberatory furnances introduced by Saint Lambert also meant there was not longer a dependency on the scarce firewood to be found on
Atacama Desert The Atacama Desert () is a desert plateau located on the Pacific Ocean, Pacific coast of South America, in the north of Chile. Stretching over a strip of land west of the Andes Mountains, it covers an area of , which increases to if the barre ...
and its surrounding
semi-arid A semi-arid climate, semi-desert climate, or steppe climate is a aridity, dry climate sub-type. It is located on regions that receive precipitation below Evapotranspiration#Potential evapotranspiration, potential evapotranspiration, but not as l ...
areas as was the case with earlier smelting technology. By 1872 there were one hundred "smelting works" in Chile. Competition stemming from new processing techniques pushed Chilean copper production in the late 19th century back to represent 6% of the worldwide production, reaching a low of 4.3% in 1914.


Aluminium melting

Reverberatory furnaces are widely used to melt secondary
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
scrap for eventual use by die-casting industries. D. Florez-Orrego et al, (2023) "A systemic study for enhanced waste heat recovery and renewable energy integration towards decarbonizing the aluminium industry." in: ''Proceedings of 36th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems - ECOS 2023, June 25th – 30th.'' Las Palmas de Gran Canaria, Spain. The simplest reverberatory furnace is nothing more than a steel box lined with
alumina Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
refractory brick with a
flue A flue is a duct, pipe, or opening in a chimney for conveying exhaust gases from a fireplace, furnace, water heater, boiler, or generator to the outdoors. Historically the term flue meant the chimney itself. In the United States, they a ...
at one end and a vertically lifting door at the other. Conventional oil or
gas burner A gas burner is a device that produces a non-controlled flame by mixing a fuel gas such as acetylene, natural gas, or propane with an oxidizer such as the ambient air or supplied oxygen, and allowing for wikt:ignition, ignition and combustion. ...
s are placed usually on either side of the furnace to heat the brick and the eventual bath of molten metal is then poured into a
casting Casting is a manufacturing process in which a liquid material is usually poured into a mold, which contains a hollow cavity of the desired shape, and then allowed to solidify. The solidified part is also known as a casting, which is ejected or ...
machine to produce
ingots An ingot is a piece of relatively pure material, usually metal, that is cast into a shape suitable for further processing. In steelmaking, it is the first step among semi-finished casting products. Ingots usually require a second procedure of sh ...
. D. Florez-Orrego et al, (2023) "A systemic study for enhanced waste heat recovery and renewable energy integration towards decarbonizing the aluminium industry." in: ''Proceedings of 36th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems - ECOS 2023, June 25th – 30th.'' Las Palmas de Gran Canaria, Spain.


See also

* Open-hearth furnace *
Puddling furnace Puddling is the process of converting pig iron to bar (wrought) iron in a coal fired reverberatory furnace. It was developed in England during the 1780s. The molten pig iron was stirred in a reverberatory furnace, in an Redox, oxidizing enviro ...


References


Bibliography

* ''
Encyclopædia Britannica The is a general knowledge, general-knowledge English-language encyclopaedia. It has been published by Encyclopædia Britannica, Inc. since 1768, although the company has changed ownership seven times. The 2010 version of the 15th edition, ...
'', 14th ed. * * J. Day & R. F. Tylecote (eds.), ''The Industrial Revolution in Metals'' (1991) * P. W. King, "The Cupola at Bristol", ''Somerset Araeology and Natural History'' 140 (for 1997), 37–52 * P. W. King, "Sir Clement Clerke and the Adoption of coal in metallurgy", ''Transactions of the Newcomen Society'' 73(1) (2001–2), 33–53 *


External links

* {{DEFAULTSORT:Reverberatory Furnace Metallurgical furnaces