In
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
, a Fock state or number state is a
quantum state
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in ...
that is an element of a
Fock space with a well-defined number of
particle
In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass.
They vary greatly in size or quantity, fro ...
s (or
quanta
Quanta is the plural of quantum.
Quanta may also refer to:
Organisations
* Quanta Computer, a Taiwan-based manufacturer of electronic and computer equipment
* Quanta Display Inc., a Taiwanese TFT-LCD panel manufacturer acquired by AU Optronic ...
). These states are named after the
Soviet
The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen national ...
physicist
Vladimir Fock. Fock states play an important role in the
second quantization formulation of quantum mechanics.
The particle representation was first treated in detail by
Paul Dirac
Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Unive ...
for
boson
In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer s ...
s and by
Pascual Jordan and
Eugene Wigner
Eugene Paul "E. P." Wigner ( hu, Wigner Jenő Pál, ; November 17, 1902 – January 1, 1995) was a Hungarian-American theoretical physicist who also contributed to mathematical physics. He received the Nobel Prize in Physics in 1963 "for his con ...
for
fermion
In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
s.
The Fock states of bosons and fermions obey useful relations with respect to the Fock space
creation and annihilation operators.
Definition
One specifies a multiparticle state of N non-interacting identical particles by writing the state as a sum of
tensor products of N one-particle states. Additionally, depending on the integrality of the particles'
spin, the tensor products must be
alternating
Alternating may refer to:
Mathematics
* Alternating algebra, an algebra in which odd-grade elements square to zero
* Alternating form, a function formula in algebra
* Alternating group, the group of even permutations of a finite set
* Alter ...
(anti-symmetric) or
symmetric products of the underlying one-particle
Hilbert space
In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natu ...
. Specifically:
*
Fermion
In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
s, having half-integer spin and obeying the
Pauli exclusion principle, correspond to antisymmetric tensor products.
*
Boson
In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer s ...
s, possessing integer spin (and not governed by the exclusion principle) correspond to symmetric tensor products.
If the number of particles is variable, one constructs the
Fock space as the
direct sum of the tensor product Hilbert spaces for each
particle number
The particle number (or number of particles) of a thermodynamic system, conventionally indicated with the letter ''N'', is the number of constituent particles in that system. The particle number is a fundamental parameter in thermodynamics which i ...
. In the Fock space, it is possible to specify the same state in a new notation, the occupancy number notation, by specifying the number of particles in each possible one-particle state.
Let
be an
orthonormal basis
In mathematics, particularly linear algebra, an orthonormal basis for an inner product space ''V'' with finite dimension is a basis for V whose vectors are orthonormal, that is, they are all unit vectors and orthogonal to each other. For ex ...
of states in the underlying one-particle Hilbert space. This induces a corresponding basis of the Fock space called the "occupancy number basis". A quantum state in the Fock space is called a Fock state if it is an element of the occupancy number basis.
A Fock state satisfies an important criterion: for each ''i'', the state is an eigenstate of the
particle number operator corresponding to the ''i''-th elementary state k
i. The corresponding eigenvalue gives the number of particles in the state. This criterion nearly defines the Fock states (one must in addition select a phase factor).
A given Fock state is denoted by
. In this expression,
denotes the number of particles in the i-th state k
i, and the particle number operator for the i-th state,
, acts on the Fock state in the following way:
:
Hence the Fock state is an eigenstate of the number operator with eigenvalue
.
Fock states often form the most convenient
basis of a Fock space. Elements of a Fock space that are
superpositions of states of differing
particle number
The particle number (or number of particles) of a thermodynamic system, conventionally indicated with the letter ''N'', is the number of constituent particles in that system. The particle number is a fundamental parameter in thermodynamics which i ...
(and thus not eigenstates of the number operator) are not Fock states. For this reason, not all elements of a Fock space are referred to as "Fock states".
If we define the aggregate particle number operator
as
:
the definition of Fock state ensures that the
variance
In probability theory and statistics, variance is the expectation of the squared deviation of a random variable from its population mean or sample mean. Variance is a measure of dispersion, meaning it is a measure of how far a set of number ...
of measurement
, i.e., measuring the number of particles in a Fock state always returns a definite value with no fluctuation.
Example using two particles
For any final state
, any Fock state of two identical particles given by
, and any
operator
Operator may refer to:
Mathematics
* A symbol indicating a mathematical operation
* Logical operator or logical connective in mathematical logic
* Operator (mathematics), mapping that acts on elements of a space to produce elements of another ...
, we have the following condition for
indistinguishability:
:
.
So, we must have
where
for
bosons and
for
fermions. Since
and
are arbitrary, we can say,
:
for bosons and
:
for fermions.
[
Note that the number operator does not distinguish bosons from fermions; indeed, it just counts particles without regard to their symmetry type. To perceive any difference between them, we need other operators, namely the creation and annihilation operators.
]
Bosonic Fock state
Boson
In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer s ...
s, which are particles with integer spin, follow a simple rule: their composite eigenstate is symmetric under operation by an exchange operator. For example, in a two particle system in the tensor product representation we have .
Boson creation and annihilation operators
We should be able to express the same symmetric property in this new Fock space representation. For this we introduce non-Hermitian bosonic creation and annihilation operators, denoted by and respectively. The action of these operators on a Fock state are given by the following two equations:
* Creation operator :
*:
* Annihilation operator :
*:
Non-Hermiticity of creation and annihilation operators
The bosonic Fock state creation and annihilation operators are not Hermitian operators.
Operator identities
The commutation relations of creation and annihilation operators in a bosonic system are
:
:
where