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Number Operator
In quantum mechanics, for systems where the total number of particles may not be preserved, the number operator is the observable that counts the number of particles. The following is in bra–ket notation: The number operator acts on Fock space. Let , \Psi\rangle_\nu=, \phi_1,\phi_2,\cdots,\phi_n\rangle_\nu be a Fock state, composed of single-particle states , \phi_i\rangle drawn from a basis of the underlying Hilbert space of the Fock space. Given the corresponding creation and annihilation operators a^(\phi_i) and a(\phi_i)\, we define the number operator by \hat \ \stackrel\ a^(\phi_i)a(\phi_i) and we have \hat, \Psi\rangle_\nu=N_i, \Psi\rangle_\nu where N_i is the number of particles in state , \phi_i\rangle. The above equality can be proven by noting that \begin a(\phi_i) , \phi_1,\phi_2,\cdots,\phi_,\phi_i,\phi_,\cdots,\phi_n\rangle_\nu &=& \sqrt , \phi_1,\phi_2,\cdots,\phi_,\phi_,\cdots,\phi_n\rangle_\nu \\ a^(\phi_i) , \phi_1,\phi_2,\cdots,\phi_,\phi_,\cdots,\phi ...
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Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ...
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Particle Number
In thermodynamics, the particle number (symbol ) of a thermodynamic system is the number of constituent particles in that system. The particle number is a fundamental thermodynamic property which is conjugate to the chemical potential. Unlike most physical quantities, the particle number is a dimensionless quantity, specifically a countable quantity. It is an extensive property, as it is directly proportional to the size of the system under consideration and thus meaningful only for closed systems. A constituent particle is one that cannot be broken into smaller pieces at the scale of energy involved in the process (where is the Boltzmann constant and is the temperature). For example, in a thermodynamic system consisting of a piston containing water vapour, the particle number is the number of water molecules in the system. The meaning of constituent particles, and thereby of particle numbers, is thus temperature-dependent. Determining the particle number The concept of pa ...
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Observable
In physics, an observable is a physical property or physical quantity that can be measured. In classical mechanics, an observable is a real-valued "function" on the set of all possible system states, e.g., position and momentum. In quantum mechanics, an observable is an operator, or gauge, where the property of the quantum state can be determined by some sequence of operations. For example, these operations might involve submitting the system to various electromagnetic fields and eventually reading a value. Physically meaningful observables must also satisfy transformation laws that relate observations performed by different observers in different frames of reference. These transformation laws are automorphisms of the state space, that is bijective transformations that preserve certain mathematical properties of the space in question. Quantum mechanics In quantum mechanics, observables manifest as self-adjoint operators on a separable complex Hilbert space ...
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Bra–ket Notation
Bra–ket notation, also called Dirac notation, is a notation for linear algebra and linear operators on complex vector spaces together with their dual space both in the finite-dimensional and infinite-dimensional case. It is specifically designed to ease the types of calculations that frequently come up in quantum mechanics. Its use in quantum mechanics is quite widespread. Bra–ket notation was created by Paul Dirac in his 1939 publication ''A New Notation for Quantum Mechanics''. The notation was introduced as an easier way to write quantum mechanical expressions. The name comes from the English word "bracket". Quantum mechanics In quantum mechanics and quantum computing, bra–ket notation is used ubiquitously to denote quantum states. The notation uses angle brackets, and , and a vertical bar , to construct "bras" and "kets". A ket is of the form , v \rangle. Mathematically it denotes a vector, \boldsymbol v, in an abstract (complex) vector space V, and physicall ...
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Fock Space
The Fock space is an algebraic construction used in quantum mechanics to construct the quantum states space of a variable or unknown number of identical particles from a single particle Hilbert space . It is named after V. A. Fock who first introduced it in his 1932 paper "Konfigurationsraum und zweite Quantelung" (" Configuration space and second quantization"). M.C. Reed, B. Simon, "Methods of Modern Mathematical Physics, Volume II", Academic Press 1975. Page 328. Informally, a Fock space is the sum of a set of Hilbert spaces representing zero particle states, one particle states, two particle states, and so on. If the identical particles are bosons, the -particle states are vectors in a symmetrized tensor product of single-particle Hilbert spaces . If the identical particles are fermions, the -particle states are vectors in an antisymmetrized tensor product of single-particle Hilbert spaces (see symmetric algebra and exterior algebra respectively). A general state in Fock ...
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Fock State
In quantum mechanics, a Fock state or number state is a quantum state that is an element of a Fock space with a well-defined number of particles (or quanta). These states are named after the Soviet physicist Vladimir Fock. Fock states play an important role in the second quantization formulation of quantum mechanics. The particle representation was first treated in detail by Paul Dirac for bosons and by Pascual Jordan and Eugene Wigner for fermions. The Fock states of bosons and fermions obey useful relations with respect to the Fock space creation and annihilation operators. Definition One specifies a multiparticle state of ''N'' non-interacting identical particles by writing the state as a sum of tensor products of ''N'' one-particle states. Additionally, depending on the integrality of the particles' spin, the tensor products must be alternating (anti-symmetric) or symmetric products of the underlying one-particle Hilbert spaces. Specifically: * Fermions, having half- ...
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Basis (linear Algebra)
In mathematics, a Set (mathematics), set of elements of a vector space is called a basis (: bases) if every element of can be written in a unique way as a finite linear combination of elements of . The coefficients of this linear combination are referred to as components or coordinates of the vector with respect to . The elements of a basis are called . Equivalently, a set is a basis if its elements are linearly independent and every element of is a linear combination of elements of . In other words, a basis is a linearly independent spanning set. A vector space can have several bases; however all the bases have the same number of elements, called the dimension (vector space), dimension of the vector space. This article deals mainly with finite-dimensional vector spaces. However, many of the principles are also valid for infinite-dimensional vector spaces. Basis vectors find applications in the study of crystal structures and frame of reference, frames of reference. De ...
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Creation And Annihilation Operators
Creation operators and annihilation operators are Operator (mathematics), mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilation operator (usually denoted \hat) lowers the number of particles in a given state by one. A creation operator (usually denoted \hat^\dagger) increases the number of particles in a given state by one, and it is the Hermitian adjoint, adjoint of the annihilation operator. In many subfields of physics and chemistry, the use of these operators instead of wavefunctions is known as second quantization. They were introduced by Paul Dirac. Creation and annihilation operators can act on states of various types of particles. For example, in quantum chemistry and many-body theory the creation and annihilation operators often act on electron states. They can also refer specifically to the ladder operators for the quantum harmonic oscillator. In the la ...
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Harmonic Oscillator
In classical mechanics, a harmonic oscillator is a system that, when displaced from its equilibrium position, experiences a restoring force ''F'' proportional to the displacement ''x'': \vec F = -k \vec x, where ''k'' is a positive constant. The harmonic oscillator model is important in physics, because any mass subject to a force in stable equilibrium acts as a harmonic oscillator for small vibrations. Harmonic oscillators occur widely in nature and are exploited in many manmade devices, such as clocks and radio circuits. If ''F'' is the only force acting on the system, the system is called a simple harmonic oscillator, and it undergoes simple harmonic motion: sinusoidal oscillations about the equilibrium point, with a constant amplitude and a constant frequency (which does not depend on the amplitude). If a frictional force ( damping) proportional to the velocity is also present, the harmonic oscillator is described as a damped oscillator. Depending on the friction ...
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Quantum Harmonic Oscillator
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point, it is one of the most important model systems in quantum mechanics. Furthermore, it is one of the few quantum-mechanical systems for which an exact, analytical solution is known. One-dimensional harmonic oscillator Hamiltonian and energy eigenstates The Hamiltonian of the particle is: \hat H = \frac + \frac k ^2 = \frac + \frac m \omega^2 ^2 \, , where is the particle's mass, is the force constant, \omega = \sqrt is the angular frequency of the oscillator, \hat is the position operator (given by in the coordinate basis), and \hat is the momentum operator (given by \hat p = -i \hbar \, \partial / \partial x in the coordinate basis). The first term in the Hamiltonian represents the kinetic energy of the particle, and the second ...
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Second Quantization
Second quantization, also referred to as occupation number representation, is a formalism used to describe and analyze quantum many-body systems. In quantum field theory, it is known as canonical quantization, in which the fields (typically as the wave functions of matter) are thought of as field operators, in a manner similar to how the physical quantities (position, momentum, etc.) are thought of as operators in first quantization. The key ideas of this method were introduced in 1927 by Paul Dirac, and were later developed, most notably, by Pascual Jordan and Vladimir Fock. In this approach, the quantum many-body states are represented in the Fock state basis, which are constructed by filling up each single-particle state with a certain number of identical particles. The second quantization formalism introduces the creation and annihilation operators to construct and handle the Fock states, providing useful tools to the study of the quantum many-body theory. Quantum many- ...
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Quantum Field Theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and in condensed matter physics to construct models of quasiparticles. The current standard model of particle physics is based on QFT. History Quantum field theory emerged from the work of generations of theoretical physicists spanning much of the 20th century. Its development began in the 1920s with the description of interactions between light and electrons, culminating in the first quantum field theory—quantum electrodynamics. A major theoretical obstacle soon followed with the appearance and persistence of various infinities in perturbative calculations, a problem only resolved in the 1950s with the invention of the renormalization procedure. A second major barrier came with QFT's apparent inabili ...
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