Nils Johan Berlin
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Nils Johan Berlin (Nils Johannes Berlin) (18 February 1812 – 27 December 1891) was a Swedish
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...
and physician, who held various professorships at the
University of Lund Lund University () is a public research university in Sweden and one of Northern Europe's oldest universities. The university is located in the city of Lund in the Swedish province of Scania. The university was officially founded in 1666 on the ...
from 1843 to 1864. Berlin was the first chemist who took the initiative to write a textbook on elementary science, the purpose being to provide basic science education for the
general public In public relations and communication science, publics are groups of individual people, and the public (a.k.a. the general public) is the totality of such groupings. This is a different concept to the sociological concept of the ''Öffentlichkei ...
. His chemistry research emphasized the study of
minerals In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): M ...
, especially the newly-discovered
rare earths The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of ...
, having devised means of separating
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
and
erbium Erbium is a chemical element; it has Symbol (chemistry), symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare- ...
. The mineral
berlinite Berlinite ( aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quar ...
(a type of
aluminium phosphate Aluminium phosphate is a chemical compound. In nature it occurs as the mineral berlinite. Many synthetic forms of aluminium phosphate are known. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers o ...
) is named after him. Berlin became a member of the
Royal Swedish Academy of Sciences The Royal Swedish Academy of Sciences () is one of the Swedish Royal Academies, royal academies of Sweden. Founded on 2 June 1739, it is an independent, non-governmental scientific organization that takes special responsibility for promoting nat ...
in 1844.


Education

Berlin graduated from the
University of Uppsala Uppsala University (UU) () is a public research university in Uppsala, Sweden. Founded in 1477, it is the oldest university in Sweden and the Nordic countries still in operation. Initially founded in the 15th century, the university rose to s ...
with a
doctor of philosophy A Doctor of Philosophy (PhD, DPhil; or ) is a terminal degree that usually denotes the highest level of academic achievement in a given discipline and is awarded following a course of Postgraduate education, graduate study and original resear ...
in 1833, having studied under the tutelage of
Jöns Jacob Berzelius Baron Jöns Jacob Berzelius (; 20 August 1779 – 7 August 1848) was a Swedish chemist. Berzelius is considered, along with Robert Boyle, John Dalton, and Antoine Lavoisier, to be one of the founders of modern chemistry. Berzelius became a memb ...
. He completed a
doctor of medicine A Doctor of Medicine (abbreviated MD, from the Latin language, Latin ) is a medical degree, the meaning of which varies between different jurisdictions. In the United States, and some other countries, the ''MD'' denotes a professional degree of ph ...
degree in 1837, also at the University of Uppsala.


Academic career

Berlin held a number of faculty positions at the
University of Lund Lund University () is a public research university in Sweden and one of Northern Europe's oldest universities. The university is located in the city of Lund in the Swedish province of Scania. The university was officially founded in 1666 on the ...
, beginning in 1843 as a professor of
pharmacology Pharmacology is the science of drugs and medications, including a substance's origin, composition, pharmacokinetics, pharmacodynamics, therapeutic use, and toxicology. More specifically, it is the study of the interactions that occur betwee ...
. Subsequently he also became a professor of chemistry and mineralogy in 1847, then rector of the university, 1854-1855, and lastly professor of medical and physiological chemistry in 1862. He served as the Director of the National Board of Hygiene (''Sundhetskollegiet'') beginning in 1864.


Elementary science textbooks

Berlin was the first chemist to write a textbook for elementary science for the general population. Berlin published two popular textbooks, which emphasized description and practical knowledge over theory (of which there was relatively little at the time). ''Vext-chemien i sammandrag'' was published in 1835, and ''Elementar-lärobok i oorganisk kemi'' first appeared in 1857. It went through 15 editions, selling more than 450,000 copies. His textbooks helped to catalyze the teaching of science in elementary schools. They received praise and an award from the
Swedish parliament The Riksdag ( , ; also or , ) is the parliament and the supreme decision-making body of the Kingdom of Sweden. Since 1971, the Riksdag has been a unicameral parliament with 349 members (), elected proportionally and serving, since 1994, f ...
, and were translated into German and Finnish. The third edition of Berlin's textbook, which appeared in 1870, was heavily revised by
Christian Wilhelm Blomstrand Christian Wilhelm Blomstrand (20 October 1826 – 5 November 1897) was a Swedish mineralogist and chemist. He was a professor at the University of Lund from 1862-1895, where he isolated the element niobium in 1864. He developed an early version o ...
, who added his own systematization of the elements. Berlin's father was a
vicar A vicar (; Latin: '' vicarius'') is a representative, deputy or substitute; anyone acting "in the person of" or agent for a superior (compare "vicarious" in the sense of "at second hand"). Linguistically, ''vicar'' is cognate with the English p ...
. Berlin himself stated in his will that "Science and the thorough testing of its problems and results has never given me reason to doubt the truths of religion". As a scientist, and as a
popularizer of science Popular science (also called pop-science or popsci) is an interpretation of science intended for a general audience. While science journalism focuses on recent scientific developments, popular science is more broad ranging. It may be written ...
, Berlin situated scientific knowledge securely on a religious basis. This may have been an advantage when selling elementary science textbooks, since pastors often led the local school boards that chose the textbooks for their schools.


Research on rare earth elements

In 1787
Carl Axel Arrhenius Carl Axel Arrhenius (29 March 1757 – 20 November 1824) was a Swedish military officer, amateur geologist, and chemist. He is best known for his discovery of the mineral ytterbite (later called gadolinite) in 1787. The discovery of ytterbit ...
found a dark mineral in a
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
mine in the village of
Ytterby Ytterby () is a village on the Swedish island of Resarö, in Vaxholm Municipality in the Stockholm archipelago. Today the residential area is dominated by suburban homes. The name of the village translates to "outer village". Ytterby is the ...
,
Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...
. He sent a sample of this ytterbite to
Johan Gadolin Johan Gadolin (5 June 176015 August 1852) was a Finnish chemist, physicist and mineralogist. Gadolin discovered a " new earth" containing the first rare-earth compound yttrium, which was later determined to be a chemical element. He is also con ...
for further analysis. A number of researchers tried to identify elements composing the ore, which were particularly hard to separate due to their similar chemical properties. As a group, they were given the misnomer
rare-earth elements The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of ...
. (In fact, they are not rare, just difficult to extract.) Individually, they were discovered and named by various scientists, often using variants based on the word "Ytterby". The first two ores to be derived were called
ceria Cerium(IV) oxide, also known as ceric oxide, ceric dioxide, ceria, cerium oxide or cerium dioxide, is an oxide of the rare-earth metal cerium. It is a pale yellow-white powder with the chemical formula CeO2. It is an important commercial produc ...
and
yttria Yttrium oxide, also known as yttria, is Y2 O3. It is an air-stable, white solid substance. The thermal conductivity of yttrium oxide is 27 W/(m·K). Applications Phosphors Yttrium oxide is widely used to make Eu:YVO4 and Eu:Y2O3 phosphors that ...
. In the 1830s and 40s,
Carl Gustav Mosander Carl Gustaf Mosander (10 September 1797 – 15 October 1858) was a Swedish chemist. He discovered the rare earth elements lanthanum, erbium and terbium. Early life and education Born in Kalmar, Mosander attended school there until he move ...
derived several substances from these known ores. In 1843 Mosander was able to extract three metal oxides from ytteria, a whitish "earth" which he called pure ytteria, a pink or rose-colored oxide which he called
terbia Terbium(III) oxide, also known as terbium sesquioxide, is a sesquioxide of the rare earth metal terbium, having chemical formula . It is a p-type semiconductor, which conducts protons, which is enhanced when doped with calcium. It may be prepared ...
, and a yellowish
peroxide In chemistry, peroxides are a group of Chemical compound, compounds with the structure , where the R's represent a radical (a portion of a complete molecule; not necessarily a free radical) and O's are single oxygen atoms. Oxygen atoms are joined ...
which he called
erbia Erbium(III) oxide is the inorganic compound with the formula . It is a pink paramagnetic solid. It finds uses in various optical materials. Structure Erbium(III) oxide has a cubic structure resembling the bixbyite motif. The Er3+ centers are o ...
. Mosander was rightfully uncertain of their purity; they did however contain the elements
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
,
erbium Erbium is a chemical element; it has Symbol (chemistry), symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare- ...
, and
terbium Terbium is a chemical element; it has Symbol (chemistry), symbol Tb and atomic number 65. It is a silvery-white, rare earth element, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly ele ...
. Like scientists before him such as Mosander and Arrhenius, Berlin also worked on separation of ytteria ore into its constituent compounds. In 1860, Berlin successfully reported the identification of two substances, yttrium, and a pink salt which Berlin named erbium. Subsequent chemists followed Berlin's designation rather than Mosander's. The naming of ytteria's components became further complicated in 1862, when
Marc Delafontaine Marc Delafontaine (March 31, 1837/1838, Céligny, Switzerland–1911) was a Switzerland, Swiss chemist and spectroscopist who was involved in discovering and investigating some of the rare earth elements. Career Delafontaine studied with Jean C ...
reported its separation into yttrium and a yellow peroxide, which he first called mosandrum (after Mosander) and later terbium. In this way, the names originally given to erbium and terbium became switched.


References


External links


Nils Johan Berlin

Nils Johan Berlin
{{DEFAULTSORT:Berlin, Nils Johan 1812 births 1891 deaths Swedish chemists Academic staff of Lund University Members of the Royal Swedish Academy of Sciences Rare earth scientists People from Härnösand