Galenite
   HOME

TheInfoList



OR:

Galena, also called lead glance, is the natural mineral form of
lead(II) sulfide Lead(II) sulfide (also spelled '' sulphide'') is an inorganic compound with the formula Pb S. Galena is the principal ore and the most important compound of lead. It is a semiconducting material with niche uses. Formation, basic properties, rel ...
(PbS). It is the most important
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
of
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
and an important source of
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
. Galena is one of the most abundant and widely distributed
sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide () as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenide mineral, selenides, the tell ...
s. It crystallizes in the
cubic Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system w ...
crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups ...
often showing
octahedral In geometry, an octahedron (: octahedra or octahedrons) is any polyhedron with eight faces. One special case is the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at each vertex. Many types of i ...
forms. It is often associated with the minerals
sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...
,
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
and
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
. As a pure specimen held in the hand, under
standard temperature and pressure Standard temperature and pressure (STP) or standard conditions for temperature and pressure are various standard sets of conditions for experimental measurements used to allow comparisons to be made between different sets of data. The most used ...
, galena is insoluble in water and so is almost non-toxic. Handling galena under these specific conditions (such as in a museum or as part of geology instruction) poses practically no risk; however, as lead(II) sulfide is reasonably reactive in a variety of environments, it can be highly toxic if swallowed or inhaled, particularly under prolonged or repeated exposure.


Occurrence

Galena is the main ore of
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
, used since ancient times, since lead can be
smelted Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead and zinc. Sm ...
from galena in an ordinary wood fire. Galena typically is found in
hydrothermal vein In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation. The hydraulic flow involved i ...
s in association with
sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...
,
marcasite The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
,
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 ...
,
cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was ...
,
anglesite Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and ...
, dolomite,
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
,
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
, and
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
. It is also found in association with sphalerite in low-temperature lead-
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
deposits within
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
beds. Minor amounts are found in
contact metamorphic Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
zones, in
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
s, and disseminated in sedimentary rock. In some deposits, the galena contains up to 0.5%
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
, a byproduct that far surpasses the main lead ore in revenue. In these deposits significant amounts of silver occur as included
silver sulfide Silver sulfide is an inorganic compound with the formula . A dense black solid, it is the only sulfide of silver. It is useful as a photosensitizer in photography. It constitutes the tarnish that forms over time on silverware and other silver ob ...
mineral phases or as limited silver in
solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...
within the galena structure. These argentiferous galenas have long been an important ore of silver. Silver-bearing galena is almost entirely of hydrothermal origin; galena in lead-zinc deposits contains little silver. Galena deposits are found worldwide in various environments. Noted deposits include those at
Freiberg Freiberg () is a university and former mining town in Saxony, Germany, with around 41,000 inhabitants. The city lies in the foreland of the Ore Mountains, in the Saxon urbanization axis, which runs along the northern edge of the Elster and ...
in
Saxony Saxony, officially the Free State of Saxony, is a landlocked state of Germany, bordering the states of Brandenburg, Saxony-Anhalt, Thuringia, and Bavaria, as well as the countries of Poland and the Czech Republic. Its capital is Dresden, and ...
;
Cornwall Cornwall (; or ) is a Ceremonial counties of England, ceremonial county in South West England. It is also one of the Celtic nations and the homeland of the Cornish people. The county is bordered by the Atlantic Ocean to the north and west, ...
, the Mendips in
Somerset Somerset ( , ), Archaism, archaically Somersetshire ( , , ) is a Ceremonial counties of England, ceremonial county in South West England. It is bordered by the Bristol Channel, Gloucestershire, and Bristol to the north, Wiltshire to the east ...
,
Derbyshire Derbyshire ( ) is a ceremonial county in the East Midlands of England. It borders Greater Manchester, West Yorkshire, and South Yorkshire to the north, Nottinghamshire to the east, Leicestershire to the south-east, Staffordshire to the south a ...
, and
Cumberland Cumberland ( ) is an area of North West England which was historically a county. The county was bordered by Northumberland to the north-east, County Durham to the east, Westmorland to the south-east, Lancashire to the south, and the Scottish ...
in
England England is a Countries of the United Kingdom, country that is part of the United Kingdom. It is located on the island of Great Britain, of which it covers about 62%, and List of islands of England, more than 100 smaller adjacent islands. It ...
; the Linares mines in Spain were worked from before the Roman times until the end of the 20th century; the Madan and
Rhodope Mountains The Rhodopes (; , ; , ''Rodopi''; ) are a mountain range in Southeastern Europe, and the largest by area in Bulgaria, with over 83% of its area in the southern part of the country and the remainder in Greece. Golyam Perelik is its highest peak ...
in
Bulgaria Bulgaria, officially the Republic of Bulgaria, is a country in Southeast Europe. It is situated on the eastern portion of the Balkans directly south of the Danube river and west of the Black Sea. Bulgaria is bordered by Greece and Turkey t ...
; the
Sullivan Mine The Sullivan Mine is a now-closed conventional–mechanized underground mine located in Kimberley, British Columbia, Canada. The ore body is a complex, sediment-hosted, sedimentary exhalative deposit consisting primarily of zinc, lead, and iro ...
of
British Columbia British Columbia is the westernmost Provinces and territories of Canada, province of Canada. Situated in the Pacific Northwest between the Pacific Ocean and the Rocky Mountains, the province has a diverse geography, with rugged landscapes that ...
;
Broken Hill Broken Hill is a city in the Far West (New South Wales), far west region of outback New South Wales, Australia. An inland mining city, it is near the border with South Australia on the crossing of the Barrier Highway (A32) and the Silver City Hi ...
and
Mount Isa Mount Isa ( ) is a city in the Gulf Country region of Queensland, Australia. It came into existence because of the vast mineral deposits found in the area. Mount Isa Mines (MIM) is one of the most productive mines in world history, based on co ...
in
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
; and the ancient mines of Sardinia. In the
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
, it occurs most notably as lead-zinc ore in the Mississippi Valley type deposits of the
Lead Belt The Southeast Missouri Lead District, commonly called the Lead Belt, is a lead mining district in the southeastern part of Missouri. Counties in the Lead Belt include Saint Francois County, Missouri, Saint Francois, Crawford County, Misso ...
in southeastern
Missouri Missouri (''see #Etymology and pronunciation, pronunciation'') is a U.S. state, state in the Midwestern United States, Midwestern region of the United States. Ranking List of U.S. states and territories by area, 21st in land area, it border ...
, which is the largest known deposit, and in the
Driftless Area The Driftless Area, also known as Bluff Country and the Paleozoic Plateau, is a topographic and cultural region in the Midwestern United States that comprises southwestern Wisconsin, southeastern Minnesota, northeastern Iowa, and the extreme ...
of
Illinois Illinois ( ) is a U.S. state, state in the Midwestern United States, Midwestern United States. It borders on Lake Michigan to its northeast, the Mississippi River to its west, and the Wabash River, Wabash and Ohio River, Ohio rivers to its ...
,
Iowa Iowa ( ) is a U.S. state, state in the upper Midwestern United States, Midwestern region of the United States. It borders the Mississippi River to the east and the Missouri River and Big Sioux River to the west; Wisconsin to the northeast, Ill ...
and
Wisconsin Wisconsin ( ) is a U.S. state, state in the Great Lakes region, Great Lakes region of the Upper Midwest of the United States. It borders Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake Michigan to the east, Michig ...
, providing the origin of the name of
Galena, Illinois Galena is the largest city in Jo Daviess County, Illinois, United States, and its county seat. It had a population of 3,308 at the 2020 United States census, 2020 census. A section of the city is listed on the National Register of Historic Plac ...
, a historical settlement known for the material. Galena also was a major mineral of the
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
-lead mines of the
tri-state district The Tri-State district was a historic lead-zinc mining district located in present-day southwest Missouri, southeast Kansas and northeast Oklahoma. The district produced lead and zinc for over 100 years. Production began in the 1850s and 1860s ...
around Joplin in southwestern Missouri and the adjoining areas of
Kansas Kansas ( ) is a landlocked U.S. state, state in the Midwestern United States, Midwestern region of the United States. It borders Nebraska to the north; Missouri to the east; Oklahoma to the south; and Colorado to the west. Kansas is named a ...
and
Oklahoma Oklahoma ( ; Choctaw language, Choctaw: , ) is a landlocked U.S. state, state in the South Central United States, South Central region of the United States. It borders Texas to the south and west, Kansas to the north, Missouri to the northea ...
. Galena is also an important ore mineral in the silver mining regions of
Colorado Colorado is a U.S. state, state in the Western United States. It is one of the Mountain states, sharing the Four Corners region with Arizona, New Mexico, and Utah. It is also bordered by Wyoming to the north, Nebraska to the northeast, Kansas ...
,
Idaho Idaho ( ) is a landlocked U.S. state, state in the Pacific Northwest and Mountain states, Mountain West subregions of the Western United States. It borders Montana and Wyoming to the east, Nevada and Utah to the south, and Washington (state), ...
,
Utah Utah is a landlocked state in the Mountain states, Mountain West subregion of the Western United States. It is one of the Four Corners states, sharing a border with Arizona, Colorado, and New Mexico. It also borders Wyoming to the northea ...
and
Montana Montana ( ) is a landlocked U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Idaho to the west, North Dakota to the east, South Dakota to the southeast, Wyoming to the south, an ...
. Of the latter, the Coeur d'Alene district of northern Idaho was most prominent. Australia is the world's leading producer of lead as of 2021, most of which is extracted as galena. Argentiferous galena was accidentally discovered at
Glen Osmond Glen Osmond is a suburb of Adelaide, South Australia in the City of Burnside which is in the foothills of the Adelaide Hills. It is well known for the road intersection on the western side of the suburb, where the South Eastern Freeway (National ...
in 1841, and additional deposits were discovered near
Broken Hill Broken Hill is a city in the Far West (New South Wales), far west region of outback New South Wales, Australia. An inland mining city, it is near the border with South Australia on the crossing of the Barrier Highway (A32) and the Silver City Hi ...
in 1876 and at
Mount Isa Mount Isa ( ) is a city in the Gulf Country region of Queensland, Australia. It came into existence because of the vast mineral deposits found in the area. Mount Isa Mines (MIM) is one of the most productive mines in world history, based on co ...
in 1923. Most galena in Australia is found in hydrothermal deposits emplaced around 1680 million years ago, which have since been heavily metamorphosed. The largest documented crystal of galena is composite cubo-octahedra from the
Great Laxey Mine The Great Laxey Mine was a silver, lead ore and zinc mine in Laxey, in the parish of Lonan (parish), Lonan, Isle of Man. The mine exceeded a depth of and consisted primarily of three shafts: the Welsh Shaft, the 's Shaft and the Engine Shaft; e ...
,
Isle of Man The Isle of Man ( , also ), or Mann ( ), is a self-governing British Crown Dependency in the Irish Sea, between Great Britain and Ireland. As head of state, Charles III holds the title Lord of Mann and is represented by a Lieutenant Govern ...
, measuring . This specimen is on permanent display in the minerals gallery of the
Natural History Museum, London The Natural History Museum in London is a museum that exhibits a vast range of specimens from various segments of natural history. It is one of three major museums on Exhibition Road in South Kensington, the others being the Science Museum (Lo ...
.


Importance

Galena is the official state mineral of the U.S. states of Kansas, Missouri, and Wisconsin; the former mining communities of
Galena, Kansas Galena is a city in Cherokee County, Kansas, United States. As of the 2020 census, the population of the city was 2,761. History Although the railroad was built through the territory of Galena in 1871, the community did not start until the ...
,
Galena, Illinois Galena is the largest city in Jo Daviess County, Illinois, United States, and its county seat. It had a population of 3,308 at the 2020 United States census, 2020 census. A section of the city is listed on the National Register of Historic Plac ...
, Galena, South Dakota and
Galena, Alaska Galena () (''Notaalee Denh'' in Koyukon) is a city in the Yukon-Koyukuk Census Area in the U.S. state of Alaska. At the 2020 census the population was 472, slightly up from 470 in 2010. Galena was established in 1918, and a military airfield ...
,state.ak.us
/ref> take their names from deposits of this mineral.


Structure

Galena belongs to the
octahedral In geometry, an octahedron (: octahedra or octahedrons) is any polyhedron with eight faces. One special case is the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at each vertex. Many types of i ...
sulfide group of minerals that have metal
ions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
in octahedral positions, such as the iron sulfide
pyrrhotite Pyrrhotite (''Pyrrhus of Epirus, pyrrhos'' in Greek language, Greek meaning "flame-coloured"'')'' is an iron sulfide mineral with the formula Fe(1−x)S (x = 0 to 0.125). It is a nonstoichiometric compound, nonstoichiometric variant of FeS, th ...
and the nickel arsenide
niccolite Nickeline or niccolite is the mineral form of nickel arsenide. The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly. Small quantities of sulfur, iron and cobalt ...
. The galena group is named after its most common member, with other
isometric The term ''isometric'' comes from the Greek for "having equal measurement". isometric may mean: * Cubic crystal system, also called isometric crystal system * Isometre, a rhythmic technique in music. * "Isometric (Intro)", a song by Madeon from ...
members that include
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
bearing
alabandite Alabandite or alabandine, formerly known as ''manganese blende'' or ''bluemenbachite'' is a rarely occurring manganese sulfide mineral. It crystallizes in the cubic crystal system with the chemical composition Mn2+ S and develops commonly massiv ...
and
niningerite Niningerite is a magnesium–iron–manganese sulfide mineral with the chemical formula MgS that is found in enstatite chondrite meteorites. Niningerite is the magnesium-dominant analog of keilite. This mineral is named after Harvey H. Nininger. ...
. Divalent lead (Pb)
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
s and
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
(S)
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s form a close-packed cubic
unit cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector In mathematics, a unit vector i ...
much like the mineral
halite Halite ( ), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pi ...
of the
halide mineral Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have Polyatomic ion, polyatomic anions. Examples include the following: *Atacamite *Avogadrite (K,Cs)BF *Bararite (β) *Bischofite * ...
group. Zinc,
cadmium Cadmium is a chemical element; it has chemical symbol, symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Like z ...
,
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
,
antimony Antimony is a chemical element; it has chemical symbol, symbol Sb () and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (). Antimony compounds have been known since ancient t ...
,
arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...
,
bismuth Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs nat ...
and
selenium Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...
also occur in variable amounts in galena. Selenium substitutes for sulfur in the structure constituting a solid solution series. The lead telluride mineral
altaite Altaite, or lead telluride, is a yellowish white mineral with an isometric crystal structure. Altaite is in the galena group of minerals as it shares many of properties of galena. Altaite has an unusually high density for a light-colored mineral ...
has the same crystal structure as galena.


Geochemistry

Within the
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
or
oxidation Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
zone galena alters to anglesite (lead sulfate) or cerussite (lead carbonate). Galena exposed to
acid mine drainage Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines and coal mines. Acid rock drainage occurs naturally within some environments as part of the rock weatherin ...
can be oxidized to anglesite by naturally occurring
bacteria Bacteria (; : bacterium) are ubiquitous, mostly free-living organisms often consisting of one Cell (biology), biological cell. They constitute a large domain (biology), domain of Prokaryote, prokaryotic microorganisms. Typically a few micr ...
and
archaea Archaea ( ) is a Domain (biology), domain of organisms. Traditionally, Archaea only included its Prokaryote, prokaryotic members, but this has since been found to be paraphyletic, as eukaryotes are known to have evolved from archaea. Even thou ...
, in a process similar to
bioleaching Bioleaching is the extraction or liberation of metals from their ores through the use of living organisms. Bioleaching is one of several applications within biohydrometallurgy and several methods are used to treat ores or concentrates containing ...
.


Uses

One of the oldest uses of galena was to produce
kohl Kohl may refer to: *Kohl (cosmetics), an ancient eye cosmetic *Kohl (surname), including a list of people with the surname *Kohl's Kohl's Corporation (Kohl's is stylized in all caps) is an American department store retail chain store, chain. ...
, an eye cosmetic now regarded as toxic due to the risk of
lead poisoning Lead poisoning, also known as plumbism and saturnism, is a type of metal poisoning caused by lead in the body. Symptoms may include abdominal pain, constipation, headaches, irritability, memory problems, infertility, numbness and paresthesia, t ...
. In
Ancient Egypt Ancient Egypt () was a cradle of civilization concentrated along the lower reaches of the Nile River in Northeast Africa. It emerged from prehistoric Egypt around 3150BC (according to conventional Egyptian chronology), when Upper and Lower E ...
, this was applied around the eyes to reduce the glare of the desert sun and to repel flies, which were a potential source of disease. In
pre-Columbian In the history of the Americas, the pre-Columbian era, also known as the pre-contact era, or as the pre-Cabraline era specifically in Brazil, spans from the initial peopling of the Americas in the Upper Paleolithic to the onset of European col ...
North America, galena was used by
indigenous peoples There is no generally accepted definition of Indigenous peoples, although in the 21st century the focus has been on self-identification, cultural difference from other groups in a state, a special relationship with their traditional territ ...
as an ingredient in decorative paints and cosmetics, and widely traded throughout the eastern United States. Traces of galena are frequently found at the
Mississippian Mississippian may refer to: * Mississippian (geology), a subperiod of the Carboniferous period in the geologic timescale, roughly 360 to 325 million years ago * Mississippian cultures, a network of precontact cultures across the midwest and Easte ...
city at
Kincaid Mounds The Kincaid Mounds Historic Site ( 11MX2-11; 11PO2-10) , is a Mississippian culture archaeological site located at the southern tip of present-day U.S. state of Illinois, along the Ohio River. Kincaid Mounds has been notable for both its si ...
in present-day Illinois. The galena used at the site originated from deposits in southeastern and central Missouri and the Upper Mississippi Valley. Galena is the primary ore of lead, and is often mined for its silver content. It is used as a source of lead in
ceramic glaze Ceramic glaze, or simply glaze, is a glassy coating on ceramics. It is used for decoration, to ensure the item is impermeable to liquids and to minimize the adherence of pollutants. Glazing renders earthenware impermeable to water, sealing th ...
.Glaze
thepotteries.org
Galena is a
semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
with a small
band gap In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to t ...
of about 0.4  eV, which found use in early
wireless Wireless communication (or just wireless, when the context allows) is the transfer of information (''telecommunication'') between two or more points without the use of an electrical conductor, optical fiber or other continuous guided transm ...
communication systems. It was used as the crystal in crystal radio receivers, in which it was used as a point-contact
diode A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...
capable of rectifying alternating current to detect the radio signals. The galena crystal was used with a sharp wire, known as a "
cat's whisker A crystal detector is an obsolete electronic component used in some early 20th century radio receivers. It consists of a piece of crystalline mineral that rectifies an alternating current radio signal. It was employed as a detector (demodula ...
", in contact with it. In modern times, galena is primarily used to extract its constituent minerals. In addition to silver, it is the most important source of lead, for uses such as in lead-acid batteries.


See also

*
List of minerals This is a list of minerals which have Wikipedia articles. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a mineral speci ...
*
Lead smelter Plants for the production of lead are generally referred to as lead smelters. Primary lead production begins with sintering. Concentrated lead ore is fed into a sintering machine with iron, silica, limestone fluxes, coke, soda ash, pyrite, zinc, ...


References


External links


Case Studies in Environmental Medicine (CSEM): Lead Toxicity.

ToxFAQs: Lead.


entry for lead. {{Authority control Lead minerals Galena group Alchemical substances Cubic minerals Glances Minerals in space group 225 History of radio technology Wisconsin culture Symbols of Wisconsin Symbols of Missouri