Fluoride Volatility
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Fluoride volatility is the tendency of highly fluorinated molecules to
vaporize Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenomen ...
at comparatively low temperatures.
Heptafluoride Heptafluoride typically refers to compounds with the formula RnMx F7y− or RnMxF7y+, where n, x, and y are independent variables and R any substituent. Binary heptafluorides The only binary heptafluorides are iodine heptafluoride (IF7), rhenium ...
s,
hexafluoride A hexafluoride is a chemical compound with the general formula QXnF6, QXnF6m−, or QXnF6m+. Many molecules fit this formula. An important hexafluoride is hexafluorosilicic acid (H2SiF6), which is a byproduct of the mining of phosphate rock. In t ...
s and
pentafluoride Pentafluoride may refer to: *Antimony pentafluoride, *Arsenic pentafluoride, *Bismuth pentafluoride, *Bromine pentafluoride, *Chlorine pentafluoride, *Chromium pentafluoride, *Gold pentafluoride, *Iodine pentafluoride, *Iridium pentafluorid ...
s have much lower boiling points than the lower- valence fluorides. Most
difluoride Difluorides are chemical compounds with two fluorine atoms per molecule (or per formula unit). Metal difluorides are all ionic compound, ionic. Despite being highly ionic, the alkaline earth metal difluorides generally have extremely high latti ...
s and
trifluoride Trifluorides are compounds in which one atom or ion has three fluorine atoms or ions associated. Many metals form trifluorides, such as iron, the rare-earth elements, and the metals in the groups 3, 13 and 15 of the periodic table. Most metal tri ...
s have high boiling points, while most
tetrafluoride A tetrafluoride is a chemical compound with four fluorines in its formula. List of tetrafluorides *Argon tetrafluoride, (hypothetical) *Americium tetrafluoride, *Berkelium tetrafluoride, *Californium tetrafluoride, *Carbon tetrafluoride (tetraf ...
s and
monofluoride A monofluoride is a chemical compound with one fluoride per formula unit. For a binary compound, this is the formula XF. Organofluorine compounds Common monofluoride are organofluorine compounds such as methyl fluoride and fluorobenzene. Inorg ...
s fall in between. The term "fluoride volatility" is
jargon Jargon, or technical language, is the specialized terminology associated with a particular field or area of activity. Jargon is normally employed in a particular Context (language use), communicative context and may not be well understood outside ...
used particularly in the context of separation of
radionuclide A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
s.


Volatility and valence

Valences for the majority of elements are based on the highest known fluoride. However, elements with high valence tend to reach higher oxidation state in compounds with oxygen rather than fluorine. Roughly, fluoride volatility can be used to remove elements with a valence of 5 or greater:
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
,
neptunium Neptunium is a chemical element; it has chemical symbol, symbol Np and atomic number 93. A radioactivity, radioactive actinide metal, neptunium is the first transuranic element. It is named after Neptune, the planet beyond Uranus in the Solar Syste ...
,
plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
,
metalloids A metalloid is a chemical element which has a preponderance of properties in between, or that are a mixture of, those of metals and nonmetals. The word metalloid comes from the Latin ''metallum'' ("metal") and the Greek ''oeides'' ("resembling ...
(
tellurium Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally fou ...
,
antimony Antimony is a chemical element; it has chemical symbol, symbol Sb () and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (). Antimony compounds have been known since ancient t ...
),
nonmetals In the context of the periodic table, a nonmetal is a chemical element that mostly lacks distinctive metallic properties. They range from colorless gases like hydrogen to shiny crystals like iodine. Physically, they are usually lighter (less ...
(
selenium Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...
),
halogens The halogens () are a group (periodic table), group in the periodic table consisting of six chemically related chemical element, elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and ten ...
(
iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
,
bromine Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between th ...
), and the middle
transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. The lanthanide and actinid ...
s (
niobium Niobium is a chemical element; it has chemical symbol, symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and Ductility, ductile transition metal. Pure niobium has a Mohs scale of mineral hardness, Mohs h ...
,
molybdenum Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...
,
technetium Technetium is a chemical element; it has Symbol (chemistry), symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and promethium are the only radioactive elements whose neighbours in the sense ...
,
ruthenium Ruthenium is a chemical element; it has symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is unreactive to most chem ...
, and possibly
rhodium Rhodium is a chemical element; it has symbol Rh and atomic number 45. It is a very rare, silvery-white, hard, corrosion-resistant transition metal. It is a noble metal and a member of the platinum group. It has only one naturally occurring isot ...
). This fraction includes the actinides most easily reusable as nuclear fuel in a
thermal reactor A thermal-neutron reactor is a nuclear reactor that uses slow or thermal neutrons. ("Thermal" does not mean hot in an absolute sense, but means in thermal equilibrium with the medium it is interacting with, the reactor's fuel, moderator and stru ...
, and the two
long-lived fission product Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity, it is necessary to isolate them from hum ...
s best suited to disposal by transmutation,
Tc-99 Technetium-99 (99Tc) is an isotope of technetium that decays with a half-life of 211,000 years to stable ruthenium-99, emitting beta particles, but no gamma rays. It is the most significant long-lived fission product of uranium fission, producin ...
and I-129, as well as Se-79.
Noble gases The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some cases, oganesson (Og) ...
(
xenon Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
,
krypton Krypton (from 'the hidden one') is a chemical element; it has symbol (chemistry), symbol Kr and atomic number 36. It is a colorless, odorless noble gas that occurs in trace element, trace amounts in the Earth's atmosphere, atmosphere and is of ...
) are volatile even without fluoridation, and will not condense except at much lower temperatures. Left behind are
alkali metals The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...
(
caesium Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only f ...
,
rubidium Rubidium is a chemical element; it has Symbol (chemistry), symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have ...
),
alkaline earth metals The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are a ...
(
strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...
,
barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
),
lanthanides The lanthanide () or lanthanoid () series of chemical elements comprises at least the 14 Metal, metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium ...
, the remaining
actinides The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
(
americium Americium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element e ...
,
curium Curium is a synthetic chemical element; it has symbol Cm and atomic number 96. This transuranic actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first inten ...
), remaining
transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. The lanthanide and actinid ...
s (
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
,
zirconium Zirconium is a chemical element; it has Symbol (chemistry), symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyis ...
,
palladium Palladium is a chemical element; it has symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1802 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas (formally 2 Pallas), ...
,
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
) and
post-transition metal The metallic elements in the periodic table located between the transition metals to their left and the chemically weak nonmetallic metalloids to their right have received many names in the literature, such as post-transition metals, poor metal ...
s (
tin Tin is a chemical element; it has symbol Sn () and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, a bar of tin makes a sound, the ...
,
indium Indium is a chemical element; it has Symbol (chemistry), symbol In and atomic number 49. It is a silvery-white post-transition metal and one of the softest elements. Chemically, indium is similar to gallium and thallium, and its properties are la ...
,
cadmium Cadmium is a chemical element; it has chemical symbol, symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Like z ...
). This fraction contains the fission products that are radiation hazards on a scale of decades (
Cs-137 Caesium-137 (), cesium-137 (US), or radiocaesium, is a radioactive isotope of caesium that is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nuclear ...
,
Sr-90 Strontium-90 () is a radioactive isotope of strontium produced by nuclear fission, with a half-life of 28.79 years. It undergoes β− decay into yttrium-90, with a decay energy of 0.546 MeV. Strontium-90 has applications in medicine and ...
, Sm-151), the four remaining
long-lived fission product Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity, it is necessary to isolate them from hum ...
s
Cs-135 Caesium (55Cs) has 41 known isotopes, ranging in mass number from 112 to 152. Only one isotope, 133Cs, is stable. The longest-lived radioisotopes are 135Cs with a half-life of 1.33 million years, with a half-life of 30.1671 years and 134Cs with a ...
,
Zr-93 Naturally occurring zirconium (40Zr) is composed of four stable isotopes (of which one may in the future be found radioactive), and one very long-lived radioisotope (96Zr), a primordial nuclide that decays via double beta decay with an observed h ...
,
Pd-107 Natural palladium (Pd) is composed of six stable isotopes, Pd, Pd, Pd, Pd, Pd, and Pd, although Pd and Pd are theoretically unstable. The most stable radioisotopes are Pd with a half-life of 6.5 million years, Pd with a half-life of 17 days, and P ...
, Sn-126 of which only the last emits strong radiation, most of the
neutron poison In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable ef ...
s, and the higher actinides (
americium Americium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element e ...
,
curium Curium is a synthetic chemical element; it has symbol Cm and atomic number 96. This transuranic actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first inten ...
,
californium Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
) that are radiation hazards on a scale of hundreds or thousands of years and are difficult to work with because of gamma radiation but are fissionable in a
fast reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV, on average), as opposed to slow t ...
. Americium finds use in ionization smoke detectors while californium is used as a
spontaneous fission Spontaneous fission (SF) is a form of radioactive decay in which a heavy atomic nucleus splits into two or more lighter nuclei. In contrast to induced fission, there is no inciting particle to trigger the decay; it is a purely probabilistic proc ...
based
neutron source A neutron source is any device that emits neutrons, irrespective of the mechanism used to produce the neutrons. Neutron sources are used in physics, engineering, medicine, nuclear weapons, petroleum exploration, biology, chemistry, and nuclear p ...
. Curium has only very limited uses outside nuclear reactors.
Fissionable In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal chain reaction can only be achieved with fissile material. The predominant neutron energy in ...
but non-fissile actinoids can be used or disposed of in a subcritical nuclear reactor using an external neutron source such as an Accelerator Driven System.


Reprocessing methods

Uranium oxide Uranium oxide is an oxide of the element uranium. The metal uranium forms several oxides: * Uranium dioxide or uranium(IV) oxide (UO2, the mineral uraninite or pitchblende) * Diuranium pentoxide or uranium(V) oxide (U2O5) * Uranium trioxide or ...
s react with fluorine to form gaseous
uranium hexafluoride Uranium hexafluoride, sometimes called hex, is the inorganic compound with the formula . Uranium hexafluoride is a volatile, white solid that is used in enriching uranium for nuclear reactors and nuclear weapons. Preparation Uranium dioxide is co ...
, most of the
plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
reacts to form gaseous plutonium hexafluoride, a majority of
fission product Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
s (especially electropositive elements:
lanthanide The lanthanide () or lanthanoid () series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium (el ...
s,
strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...
,
barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
,
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
,
caesium Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only f ...
) form nonvolatile fluorides. Few metals in the fission products (the
transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. The lanthanide and actinid ...
s
niobium Niobium is a chemical element; it has chemical symbol, symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and Ductility, ductile transition metal. Pure niobium has a Mohs scale of mineral hardness, Mohs h ...
,
ruthenium Ruthenium is a chemical element; it has symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is unreactive to most chem ...
,
technetium Technetium is a chemical element; it has Symbol (chemistry), symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and promethium are the only radioactive elements whose neighbours in the sense ...
,
molybdenum Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...
, and the
halogen The halogens () are a group in the periodic table consisting of six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and tennessine (Ts), though some authors would ...
iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
) form volatile (boiling point <200 °C) fluorides that accompany the uranium and plutonium hexafluorides, together with
inert gas An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent u ...
es.
Distillation Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixt ...
is then used to separate the uranium hexafluoride from the mixture. The nonvolatile alkaline
fission product Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
s and
minor actinides Minor may refer to: Common meanings * Minor (law), a person not under the age of certain legal activities. * Academic minor, a secondary field of study in undergraduate education Mathematics * Minor (graph theory), a relation of one graph to an ...
fraction is most suitable for further processing with 'dry'
electrochemical Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an electronically conducting phase (typi ...
processing ( pyrochemical) non-aqueous methods. The
lanthanide The lanthanide () or lanthanoid () series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium (el ...
fluorides are difficult to dissolve in the
nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
used for aqueous reprocessing methods, such as
PUREX PUREX (plutonium uranium reduction extraction) is a chemical method used to purify fuel for nuclear reactors or nuclear weapons. It is based on liquid–liquid extraction ion-exchange. PUREX is the '' de facto'' standard aqueous nuclear reproc ...
, DIAMEX and
SANEX Sanex is a brand of personal care products owned by Colgate-Palmolive. It is sold in European countries (including United Kingdom, Netherlands, Belgium, France, Spain, Portugal, Denmark, Greece, Poland, Norway and Croatia) and South Africa. In ...
, which use
solvent extraction A solvent (from the Latin language, Latin ''wikt:solvo#Latin, solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a Solution (chemistry), solution. A solvent is usually a liquid but can also be a solid, a gas ...
. Fluoride volatility is only one of several pyrochemical processes designed to reprocess used nuclear fuel. Th
Řež nuclear research institute
at
Řež Řež () is a village and administrative part of Husinec (Prague-East District), Husinec in the Central Bohemian Region of the Czech Republic. Řež is the site of a nuclear physics, nuclear research centre, where the first nuclear reactor in the ...
in the
Czech Republic The Czech Republic, also known as Czechia, and historically known as Bohemia, is a landlocked country in Central Europe. The country is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the south ...
tested screw dosers that fed ground uranium oxide (simulating used fuel pellets) into a fluorinator where the particles were burned in fluorine gas to form
uranium hexafluoride Uranium hexafluoride, sometimes called hex, is the inorganic compound with the formula . Uranium hexafluoride is a volatile, white solid that is used in enriching uranium for nuclear reactors and nuclear weapons. Preparation Uranium dioxide is co ...
.
Hitachi () is a Japanese Multinational corporation, multinational Conglomerate (company), conglomerate founded in 1910 and headquartered in Chiyoda, Tokyo. The company is active in various industries, including digital systems, power and renewable ener ...
has developed a technology, called FLUOREX, which combines fluoride volatility, to extract uranium, with more traditional solvent extraction (PUREX), to extract plutonium and other transuranics. The FLUOREX-based fuel cycle is intended for use with the
Reduced moderation water reactor The Reduced-Moderation Water Reactor (RMWR), also referred to as the Resource-renewable BWR, is a proposed type of light water moderated nuclear power reactor, featuring some characteristics of a fast neutron reactor, thereby combining the establi ...
. Some fluorides are water soluble while others aren't (see the
solubility table The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitre ...
) and can be separated in aqueous solution. However, all aqueous processes that take place without complete removal of
tritium Tritium () or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.33 years. The tritium nucleus (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of the ...
(a common product of
ternary fission Ternary fission is a comparatively rare (0.2 to 0.4% of events) type of nuclear fission in which three charged products are produced rather than two. As in other nuclear fission processes, other uncharged particles such as multiple neutrons and ...
) prior to addition of water will contaminate the water with
tritiated water Tritiated water is a radioactive form of water in which the usual protium atoms are replaced with tritium atoms. In its pure form it may be called tritium oxide (T2O or 3H2O) or super-heavy water. Pure T2O is a colorless liquid, and it is cor ...
which is difficult to remove from water. Some elements which form soluble florides form insoluble chlorides. Addition of a suitable soluble chloride (e.g.
sodium chloride Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs a ...
) will salt out those cations. One example is silver (I) fluoride (water soluble) which forms
silver chloride Silver chloride is an inorganic chemical compound with the chemical formula Ag Cl. This white crystalline solid is well known for its low solubility in water and its sensitivity to light. Upon illumination or heating, silver chloride converts ...
precipitate In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemic ...
upon addition of a soluble chloride. : Some fluorides react aggressively with water and may form highly corrosive
hydrogen fluoride Hydrogen fluoride (fluorane) is an Inorganic chemistry, inorganic compound with chemical formula . It is a very poisonous, colorless gas or liquid that dissolves in water to yield hydrofluoric acid. It is the principal industrial source of fluori ...
. This needs to be taken into account if aqueous processes involving fluorides are to be used. If desired, a series of further anion-additions similar to the :de:Kationentrennungsgang can be used to separate out different cations for disposal, further processing or use.


Table of relevant properties


See also

*
FLiNaK FLiNaK is the name of the ternary eutectic alkaline metal fluoride salt mixture LiF- NaF- KF (46.5-11.5-42 mol %). It has a melting point of 462 °C and a boiling point of 1570 °C. It is used as electrolyte for the electroplatin ...
*
Molten salt reactor A molten-salt reactor (MSR) is a class of nuclear fission reactor in which the primary nuclear reactor coolant and/or the fuel is a mixture of molten salt with a fissile material. Two research MSRs operated in the United States in the mid-20th ...


Notes

*Missing top fluorides: **PrF4 (because it decomposes at 90 °C) **TbF4 (because it decomposes at 300 °C) **CeF4 (because it decomposes at 600 °C) *Without stable fluorides: KrPrecious metal refining with fluorine gas – Patent 5076839
Freepatentsonline.com. Retrieved on 2010-11-14.


References


External links


Study of Electrochemical Processes for Separation of the Actinides and Lanthanides in Molten Fluoride Media
(
PDF Portable document format (PDF), standardized as ISO 32000, is a file format developed by Adobe Inc., Adobe in 1992 to present documents, including text formatting and images, in a manner independent of application software, computer hardware, ...
) *{{cite web , url=http://www.fjfi.cvut.cz/con_adtt99/papers/P-g5.pdf , title=Separation and purification of UF6 from volatile fluorides by rectification , archiveurl=https://web.archive.org/web/20050113100054/http://www.fjfi.cvut.cz/con_adtt99/papers/P-g5.pdf , archivedate=13 January 2005
Low-pressure distillation of a portion of the fuel carrier salt from the Molten Salt Reactor Experiment
(PDF)
Use of the Fluoride Volatility Process to Extract Technetium from Transmuted Spent Nuclear Fuel
(PDF)
A Peer Review of the Strategy for Characterizing Transuranics and Technetium Contamination in Depleted Uranium Hexafluoride Tails Cylinders
(PDF)
PHYSICAL CONSTANTS OF INORGANIC COMPOUNDS
(PDF) Nuclear reprocessing Nuclear chemistry Fluorides