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A fermionic condensate or Fermi–Dirac condensate is a
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
phase formed by
fermion In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
ic particles at low
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on ...
s. It is closely related to the
Bose–Einstein condensate In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low densities is cooled to temperatures very close to absolute zero (−273.15 °C or −459.67&n ...
, a superfluid phase formed by
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer s ...
ic atoms under similar conditions. The earliest recognized fermionic condensate described the state of
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s in a superconductor; the physics of other examples including recent work with fermionic
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
s is analogous. The first atomic fermionic condensate was created by a team led by Deborah S. Jin using
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosp ...
-40 atoms at the
University of Colorado Boulder The University of Colorado Boulder (CU Boulder, CU, or Colorado) is a public research university in Boulder, Colorado. Founded in 1876, five months before Colorado became a state, it is the flagship university of the University of Colorado s ...
in 2003.


Background


Superfluidity

Fermionic condensates are attained at lower temperatures than Bose–Einstein condensates. Fermionic condensates are a type of
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
. As the name suggests, a superfluid possesses fluid properties similar to those possessed by ordinary
liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, an ...
s and gases, such as the lack of a definite shape and the ability to flow in response to applied forces. However, superfluids possess some properties that do not appear in ordinary matter. For instance, they can flow at high velocities without dissipating any energy—i.e. zero
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...
. At lower velocities, energy is dissipated by the formation of quantized vortices, which act as "holes" in the medium where superfluidity breaks down. Superfluidity was originally discovered in liquid
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consis ...
whose atoms are
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer s ...
s, not fermions.


Fermionic superfluids

It is far more difficult to produce a fermionic superfluid than a bosonic one, because the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulated ...
prohibits fermions from occupying the same
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in ...
. However, there is a well-known mechanism by which a superfluid may be formed from fermions: That mechanism is the BCS transition, discovered in 1957 by J. Bardeen, L.N. Cooper, and R. Schrieffer for describing superconductivity. These authors showed that, below a certain temperature, electrons (which are fermions) can pair up to form bound pairs now known as
Cooper pair In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Coope ...
s. As long as collisions with the ionic lattice of the solid do not supply enough energy to break the Cooper pairs, the electron fluid will be able to flow without dissipation. As a result, it becomes a superfluid, and the material through which it flows a superconductor. The BCS theory was phenomenally successful in describing superconductors. Soon after the publication of the BCS paper, several theorists proposed that a similar phenomenon could occur in fluids made up of fermions other than electrons, such as
helium-3 Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is th ...
atoms. These speculations were confirmed in 1971, when experiments performed by D.D. Osheroff showed that helium-3 becomes a superfluid below 0.0025 K. It was soon verified that the superfluidity of helium-3 arises from a BCS-like mechanism.


Creation of the first fermionic condensates

When
Eric Cornell Eric Allin Cornell (born December 19, 1961) is an American physicist who, along with Carl E. Wieman, was able to synthesize the first Bose–Einstein condensate in 1995. For their efforts, Cornell, Wieman, and Wolfgang Ketterle shared the Nobe ...
and
Carl Wieman Carl Edwin Wieman (born March 26, 1951) is an American physicist and educationist at Stanford University, and currently the A.D White Professor at Large at Cornell University. In 1995, while at the University of Colorado Boulder, he and Eric A ...
produced a Bose–Einstein condensate from
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density hig ...
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
s in 1995, there naturally arose the prospect of creating a similar sort of condensate made from fermionic atoms, which would form a superfluid by the BCS mechanism. However, early calculations indicated that the temperature required for producing Cooper pairing in atoms would be too cold to achieve. In 2001, Murray Holland at
JILA JILA, formerly known as the Joint Institute for Laboratory Astrophysics, is a physical science research institute in the United States. JILA is located on the University of Colorado Boulder campus. JILA was founded in 1962 as a joint institute ...
suggested a way of bypassing this difficulty. He speculated that fermionic atoms could be coaxed into pairing up by subjecting them to a strong
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and t ...
. In 2003, working on Holland's suggestion,
Deborah Jin Deborah Shiu-lan Jin (; November 15, 1968 – September 15, 2016) was an American physicist and fellow with the National Institute of Standards and Technology (NIST); Professor Adjunct, Department of Physics at the University of Colorado; and ...
at JILA, Rudolf Grimm at the
University of Innsbruck The University of Innsbruck (german: Leopold-Franzens-Universität Innsbruck; la, Universitas Leopoldino Franciscea) is a public research university in Innsbruck, the capital of the Austrian federal state of Tyrol, founded on October 15, 1669. ...
, and
Wolfgang Ketterle Wolfgang Ketterle (; born 21 October 1957) is a German physicist and professor of physics at the Massachusetts Institute of Technology (MIT). His research has focused on experiments that trap and cool atoms to temperatures close to absolute zer ...
at MIT managed to coax fermionic atoms into forming molecular bosons, which then underwent Bose–Einstein condensation. However, this was not a true fermionic condensate. On December 16, 2003, Jin managed to produce a condensate out of fermionic atoms for the first time. The experiment involved 500,000 
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosp ...
-40 atoms cooled to a temperature of 5×10−8 K, subjected to a time-varying magnetic field.


Examples


Chiral condensate

A chiral condensate is an example of a fermionic condensate that appears in theories of massless fermions with
chiral symmetry A chiral phenomenon is one that is not identical to its mirror image (see the article on mathematical chirality). The spin of a particle may be used to define a handedness, or helicity, for that particle, which, in the case of a massless particle ...
breaking, such as the theory of quarks in
Quantum Chromodynamics In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a ty ...
.


BCS theory

The
BCS theory BCS theory or Bardeen–Cooper–Schrieffer theory (named after John Bardeen, Leon Cooper, and John Robert Schrieffer) is the first microscopic theory of superconductivity since Heike Kamerlingh Onnes's 1911 discovery. The theory describes su ...
of
superconductivity Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlik ...
has a fermion condensate. A pair of
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s in a
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typi ...
with opposite spins can form a scalar
bound state Bound or bounds may refer to: Mathematics * Bound variable * Upper and lower bounds, observed limits of mathematical functions Physics * Bound state, a particle that has a tendency to remain localized in one or more regions of space Geography * ...
called a
Cooper pair In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Coope ...
. The bound states themselves then form a condensate. Since the Cooper pair has
electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respecti ...
, this fermion condensate breaks the electromagnetic
gauge symmetry In physics, a gauge theory is a type of field theory in which the Lagrangian (and hence the dynamics of the system itself) does not change (is invariant) under local transformations according to certain smooth families of operations (Lie groups ...
of a superconductor, giving rise to the wonderful electromagnetic properties of such states.


QCD

In
quantum chromodynamics In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a ty ...
(QCD) the chiral condensate is also called the quark condensate. This property of the QCD vacuum is partly responsible for giving masses to hadrons (along with other condensates like the
gluon condensate In quantum chromodynamics (QCD), the gluon condensate is a non-perturbative property of the QCD vacuum which could be partly responsible for giving masses to light mesons. If the gluon field tensor is represented as Gμν, then the gluon condensat ...
). In an approximate version of QCD, which has vanishing quark masses for ''N'' quark
flavour Flavor or flavour is either the sensory perception of taste or smell, or a flavoring in food that produces such perception. Flavor or flavour may also refer to: Science *Flavors (programming language), an early object-oriented extension to Lisp ...
s, there is an exact chiral symmetry of the theory. The QCD vacuum breaks this symmetry to SU(''N'') by forming a quark condensate. The existence of such a fermion condensate was first shown explicitly in the lattice formulation of QCD. The quark condensate is therefore an
order parameter In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states ...
of transitions between several phases of quark matter in this limit. This is very similar to the
BCS theory BCS theory or Bardeen–Cooper–Schrieffer theory (named after John Bardeen, Leon Cooper, and John Robert Schrieffer) is the first microscopic theory of superconductivity since Heike Kamerlingh Onnes's 1911 discovery. The theory describes su ...
of superconductivity. The Cooper pairs are analogous to the pseudoscalar mesons. However, the vacuum carries no charge. Hence all the gauge symmetries are unbroken. Corrections for the masses of the
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All common ...
s can be incorporated using
chiral perturbation theory Chiral perturbation theory (ChPT) is an effective field theory constructed with a Lagrangian consistent with the (approximate) chiral symmetry of quantum chromodynamics (QCD), as well as the other symmetries of parity and charge conjugation.
.


Helium-3 superfluid

A
helium-3 Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is th ...
atom is a
fermion In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
and at very low temperatures, they form two-atom
Cooper pair In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Coope ...
s which are bosonic and condense into a
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
. These Cooper pairs are substantially larger than the interatomic separation.


See also

*
Fermi gas An ideal Fermi gas is a state of matter which is an ensemble of many non-interacting fermions. Fermions are particles that obey Fermi–Dirac statistics, like electrons, protons, and neutrons, and, in general, particles with half-integer s ...
* Bose gas


Footnotes


References


Sources

* * *
* {{Phase of matter American inventions Condensed matter physics Phases of matter Quantum field theory Exotic matter Quantum phases Superfluidity