Catalytic Heater
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A catalytic heater is a flameless
heater Heating, ventilation, and air conditioning (HVAC ) is the use of various technologies to control the temperature, humidity, and purity of the air in an enclosed space. Its goal is to provide thermal comfort and acceptable indoor air quality. ...
which relies on catalyzed chemical reactions to break down
molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
s and produce calefaction (heat). When the catalyst, fuel (e.g., natural gas), and oxygen combine together, they react at a low enough temperature that a flame is not produced. This process keeps repeating itself until either oxygen or the fuel source is taken out of the equation.


Types

There are three main types of larger catalytic heaters: # Heated Enclosure Packages # Instrument Gas and Pilot Preheating Regulators # Space Heating Heated enclosure packages are used to protect pipes from rain and ice build-up by keeping the pipes heated. The catalytic heater is contained within the package which is usually made out of
stainless steel Stainless steel, also known as inox, corrosion-resistant steel (CRES), or rustless steel, is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Stainless steel's resistance to corrosion comes from its chromi ...
. Instrument gas and pilot preheating regulators are only used for freeze protection, and to heat up the gas before it reaches the
pilot An aircraft pilot or aviator is a person who controls the flight of an aircraft by operating its Aircraft flight control system, directional flight controls. Some other aircrew, aircrew members, such as navigators or flight engineers, are al ...
. It can also be used to heat a stream of gas that is used for measurement or
instrumentation Instrumentation is a collective term for measuring instruments, used for indicating, measuring, and recording physical quantities. It is also a field of study about the art and science about making measurement instruments, involving the related ...
. Space heating is a good substitution when heat is required but traditional means, such as electricity or safety concerns over explosive gas, cannot be used. Catalytic space heaters generate
infrared Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those ...
heat to raise the temperature in a given area. In addition to the larger catalytic heaters there are also small hand warmer or pocket heaters that use a catalyst combustion unit. Current units use a glass fiber substrate coated with platinum. Cheaper units may use other catalysts that do not work as well. Some older units used asbestos substrates. These hand warmers are for people who work or pursue leisure activities outdoors in very low temperatures, especially those that require manual dexterity that is not possible while wearing thick gloves or mittens. They date from the foundation of the Japanese Hakkunin company by Niichi Matoba, who founded to produce a hand warmer 'Hakkin Kairo' based on his Japanese patent of 1923. John W. Smith, President of Aladdin Laboratories, Inc. of Minneapolis was awarded a US patent for a product called the Jon-e (pronounced “Johnny”) catalytic hand warmer on December 25, 1951. Production peaked in the fifties and sixties, at 10,000 warmers a day. Aladdin went out of business in the 1970s. In 2010 the Zippo lighter company introduced an all-metal catalytic hand warmer, along with other outdoor products. There are other catalytic hand warmer brands like the South Korean S-Boston, the UK Whitby Warmer and also Chinese unbranded versions of designs based on the Hakkin 'Peacock' or the 'Jon-e' which date back to the manufacturing heyday of
Hong Kong Hong Kong)., Legally Hong Kong, China in international treaties and organizations. is a special administrative region of China. With 7.5 million residents in a territory, Hong Kong is the fourth most densely populated region in the wor ...
in the 1960s and 70s.


Chemistry

The following substances are able to help oxidize a fuel for a catalytic heater at a useful rate: *
Platinum Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...
can be used with natural gas, propane and butane. It generates a surface temperature of 300–550 °C, lower than the 760 °C ignition point. Pt heaters are the most common type. *
Palladium Palladium is a chemical element; it has symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1802 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas (formally 2 Pallas), ...
can be used with hydrogen gas. Pd-coated carbon was used in 2010 for a prototype heater built by the Sandia National Laboratory.


Functions

Catalytic heaters serve many functions, especially in the oil and gas industries.  They are useful where heat production is necessary at a controlled rate. Typically used in Thermoelectric Generators (TEG's or thermopiles) off of raw well gas or H2S to create enough electricity to operate the remote well site at great distances from their parent processing plants. They can also be used in
gas meter A gas meter is a specialized flow meter, used to measure the volume of fuel gases such as natural gas and liquefied petroleum gas. Gas meters are used at residential, commercial, and industrial buildings that consume fuel gas supplied by a g ...
s, regulators and
control valve A control valve is a valve used to control fluid flow by varying the size of the flow passage as directed by a signal from a controller. This enables the direct control of flow rate and the consequential control of process quantities such as pres ...
s, gas wellhead heaters, pipeline heaters, space heaters, separators, and compressor stations. Some other examples would include
soldering iron A soldering iron is a hand tool used in soldering. It supplies heat to melt solder so that it can flow into the joint between two workpieces. A soldering iron is composed of a heated metal tip (the ''bit'') and an insulated handle. Heating is o ...
s, hand warmers, and space-heating appliances. Catalytic heaters have high efficiency allowing smaller heaters to be used, therefore lowering initial costs and fuel consumption. These heaters typically use propane (LP) or
butane Butane () is an alkane with the formula C4H10. Butane exists as two isomers, ''n''-butane with connectivity and iso-butane with the formula . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at ro ...
fuel, whereas many older types use either liquid fuel or
alcohol Alcohol may refer to: Common uses * Alcohol (chemistry), a class of compounds * Ethanol, one of several alcohols, commonly known as alcohol in everyday life ** Alcohol (drug), intoxicant found in alcoholic beverages ** Alcoholic beverage, an alco ...
. Handheld catalytic hand warmers have traditionally only used
naphtha Naphtha (, recorded as less common or nonstandard in all dictionaries: ) is a flammable liquid hydrocarbon mixture. Generally, it is a fraction of crude oil, but it can also be produced from natural-gas condensates, petroleum distillates, and ...
-type liquid fuel.


Safety

Catalytic heaters can have several potential safety issues if incorrectly installed or placed in poorly ventilated areas, including fuel leakage and
carbon monoxide poisoning Carbon monoxide poisoning typically occurs from breathing in carbon monoxide (CO) at excessive levels. Symptoms are often described as " flu-like" and commonly include headache, dizziness, weakness, vomiting, chest pain, and confusion. Large ...
from insufficient exhaust extraction or improperly tuned reaction. The
American Gas Association The American Gas Association (AGA) is an American trade organization founded in 1918 representing and advocating on behalf of local energy companies which deliver natural gas throughout the United States. History The American Gas Association was ...
standards specify that the concentration in free air of carbon monoxide from a gas heater should not exceed 200
parts per million In science and engineering, the parts-per notation is a set of pseudo-units to describe the small values of miscellaneous dimensionless quantity, dimensionless quantities, e.g. mole fraction or mass fraction (chemistry), mass fraction. Since t ...
(ppm). Conversely, since catalytic heaters are flameless, there is a reduced fire risk.


See also

* Chemical heating pad


External links


References

{{reflist Heaters