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Thermoelectric Generator
A thermoelectric generator (TEG), also called a Seebeck generator, is a solid state device that converts heat (driven by temperature differences) directly into electrical energy through a phenomenon called the '' Seebeck effect'' (a form of thermoelectric effect). Thermoelectric generators function like heat engines, but are less bulky and have no moving parts. However, TEGs are typically more expensive and less efficient. When the same principle is used in reverse to create a heat gradient from an electric current, it is called a thermoelectric (or Peltier) cooler. Thermoelectric generators could be used in power plants and factories to convert waste heat into additional electrical power and in automobiles as automotive thermoelectric generators (ATGs) to increase fuel efficiency. Radioisotope thermoelectric generators use radioisotopes to generate the required temperature difference to power space probes. Thermoelectric generators can also be used alongside solar panels. H ...
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Solid-state Electronics
Solid-state electronics are semiconductor electronics: electronic equipment that use semiconductor devices such as transistors, diodes and integrated circuits (ICs). The term is also used as an adjective for devices in which semiconductor electronics that have no moving parts replace devices with moving parts, such as the solid-state relay, in which transistor switches are used in place of a moving-arm electromechanical relay, or the solid-state drive (SSD), a type of semiconductor memory used in computers to replace hard disk drives, which store data on a rotating disk. History The term ''solid-state'' became popular at the beginning of the semiconductor era in the 1960s to distinguish this new technology. A semiconductor device works by controlling an electric current consisting of electrons or holes moving within a solid crystalline piece of semiconducting material such as silicon, while the thermionic vacuum tubes it replaced worked by controlling a current of elect ...
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Jean Charles Athanase Peltier
Jean Charles Athanase Peltier ( ; ; 22 February 1785 – 27 October 1845) was a French physicist. He was originally a watch dealer, but at the age of 30 began experiments and observations in physics. Peltier was the author of numerous papers in different departments of physics. His name is specially associated with the thermal effects at junctions in a voltaic circuit, the Peltier effect. Peltier introduced the concept of electrostatic induction (1840), based on the modification of the distribution of electric charge in a material under the influence of a second object closest to it and its own electrical charge. Biography Peltier trained as a watchmaker; until his 30s he was a watch dealer. He worked with Abraham Louis Breguet in Paris. Later, he conducted various experiments on electrodynamics and noticed that in an electronic element when current flows through, a temperature gradient or temperature difference is generated at a current flow. In 1836 he published his work a ...
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Semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called " metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easil ...
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Seebeck Coefficient
The Seebeck coefficient (also known as thermopower, thermoelectric power, and thermoelectric sensitivity) of a material is a measure of the magnitude of an induced thermoelectric voltage in response to a temperature difference across that material, as induced by the Seebeck effect. The SI unit of the Seebeck coefficient is volts per kelvin (V/K), although it is more often given in microvolts per kelvin (μV/K). The use of materials with a high Seebeck coefficient is one of many important factors for the efficient behaviour of thermoelectric generators and thermoelectric coolers. More information about high-performance thermoelectric materials can be found in the Thermoelectric materials article. In thermocouples the Seebeck effect is used to measure temperatures, and for accuracy it is desirable to use materials with a Seebeck coefficient that is stable over time. Physically, the magnitude and sign of the Seebeck coefficient can be approximately understood as being given by the en ...
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Thermal Conductivity
The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials such as mineral wool or Styrofoam. Metals have this high thermal conductivity due to free electrons facilitating heat transfer. Correspondingly, materials of high thermal conductivity are widely used in heat sink applications, and materials of low thermal conductivity are used as thermal insulation. The reciprocal of thermal conductivity is called thermal resistivity. The defining equation for thermal conductivity is \mathbf = - k \nabla T, where \mathbf is the heat flux, k is the thermal conductivity, and \nabla ...
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Electrical Conductivity
Electrical resistivity (also called volume resistivity or specific electrical resistance) is a fundamental specific property of a material that measures its electrical resistance or how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek alphabet, Greek letter  (Rho (letter), rho). The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the Electrical resistance, resistance between these contacts is , then the resistivity of the material is . Electrical conductivity (or specific conductance) is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter  (Sigma (letter), sigma), but  (kappa) (especially in electrical engineering) and  (gamma) are sometimes used. ...
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Thermoelectric Figure Of Merit
Thermoelectric materials show the thermoelectric effect in a strong or convenient form. The ''thermoelectric effect'' refers to phenomena by which either a temperature difference creates an electric potential or an electric current creates a temperature difference. These phenomena are known more specifically as the Seebeck effect (creating a voltage from temperature difference), Peltier effect (driving heat flow with an electric current), and Thomson effect (reversible heating or cooling within a conductor when there is both an electric current and a temperature gradient). While all materials have a nonzero thermoelectric effect, in most materials it is too small to be useful. However, low-cost materials that have a sufficiently strong thermoelectric effect (and other required properties) are also considered for applications including power generation and refrigeration. The most commonly used thermoelectric material is based on bismuth telluride (). Thermoelectric materials ar ...
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Moving Parts
Machines include both fixed and moving parts. The moving parts have controlled and constrained motions. Moving parts are machine components excluding any moving fluids, such as fuel, coolant or hydraulic fluid. Moving parts also do not include any mechanical locks, switches, nuts and bolts, screw caps for bottles etc. A system with no moving parts is described as " solid state". Mechanical efficiency and wear The amount of moving parts in a machine is a factor in its mechanical efficiency. The greater the number of moving parts, the greater the amount of energy lost to heat by friction between those parts. For example, in a modern automobile engine, roughly 7% of the total power obtained from burning the engine's fuel is lost to friction between the engine's moving parts. Conversely, the fewer the number of moving parts, the greater the efficiency. Machines with no moving parts at all can be very efficient. An electrical transformer, for example, has no moving parts, a ...
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Dynamo
"Dynamo Electric Machine" (end view, partly section, ) A dynamo is an electrical generator that creates direct current using a commutator. Dynamos employed electromagnets for self-starting by using residual magnetic field left in the iron cores of electromagnets (i.e. field coils). If dynamo were never run before it was usual to use a separate battery to excite or ''flash the field'' of the electromagnets to enable self-starting. Dynamos were the first practical electrical generators capable of delivering power for industry, and the foundation upon which many other later electric-power conversion devices were based, including the electric motor, the alternating-current alternator, and the rotary converter. Today, the simpler and more reliable alternator dominates large scale power generation, for efficiency, reliability and cost reasons. A dynamo has the disadvantages of a mechanical commutator. Also, converting alternating to direct current using rectifiers (such as va ...
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Lead Telluride
Lead telluride is a compound of lead (element), lead and tellurium (PbTe). It crystallizes in the NaCl crystal structure with Pb atoms occupying the cation and Te forming the anionic lattice. It is a narrow gap semiconductor with a band gap of 0.32 eV. It occurs naturally as the mineral altaite. Properties * Dielectric constant ~1000. * Electron Effective mass (solid-state physics), Effective mass ~ 0.01Electron rest mass, ''m''e * Hole mobility, μp = 600 cm2 V−1 s−1 (0 K); 4000 cm2 V−1 s−1 (300 K) * Seebeck coefficient: ~326 μV/K (undoped, at 300K), ~200 μV/K (Ag-doped) Applications PbTe has proven to be a very important intermediate Thermoelectric materials, thermoelectric material. The performance of thermoelectric materials can be evaluated by the figure of merit, ZT=S^2\sigma T/\kappa, in which S is the Seebeck coefficient, \sigma is the Electrical resistivity and conductivity, electrical conducti ...
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Bismuth Telluride
Bismuth telluride () is a gray powder that is a compound of bismuth and tellurium also known as bismuth(III) telluride. It is a semiconductor, which, when alloyed with antimony or selenium, is an efficient thermoelectric material for refrigeration or portable power generation. is a topological insulator, and thus exhibits thickness-dependent physical properties. Properties as a thermoelectric material Bismuth telluride is a narrow-gap layered semiconductor with a trigonal unit cell. The valence and conduction band structure can be described as a many-ellipsoidal model with 6 constant-energy ellipsoids that are centered on the reflection planes. cleaves easily along the trigonal axis due to Van der Waals bonding between neighboring tellurium atoms. Due to this, bismuth-telluride-based materials used for power generation or cooling applications must be polycrystalline. Furthermore, the Seebeck coefficient of bulk becomes compensated around room temperature, forcing the material ...
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