An air separation plant separates atmospheric air into its primary components, typically

nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...

and

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

, and sometimes also

argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...

and other rare

inert gas An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent u ...

es. The most common method for air separation is

fractional distillation Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation ...

. Cryogenic air separation units (ASUs) are built to provide nitrogen or oxygen and often co-produce argon. Other methods such as membrane,

pressure swing adsorption Pressure swing adsorption (PSA) is a technique used to separate some gas species from a mixture of gases (typically air) under pressure according to the species' molecular characteristics and affinity for an adsorbent material. It operates at ne ...

(PSA) and vacuum pressure swing adsorption (VPSA) are commercially used to separate a single component from ordinary air. High purity

, and

, used for

semiconductor device fabrication Semiconductor device fabrication is the process used to manufacture semiconductor devices, typically integrated circuits (ICs) such as microprocessors, microcontrollers, and memories (such as Random-access memory, RAM and flash memory). It is a ...

, require cryogenic distillation. Similarly, the only viable source of the

rare gases The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some cases, oganesson (Og). U ...

neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...

krypton Krypton (from 'the hidden one') is a chemical element; it has symbol (chemistry), symbol Kr and atomic number 36. It is a colorless, odorless noble gas that occurs in trace element, trace amounts in the Earth's atmosphere, atmosphere and is of ...

xenon Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...

is the distillation of air using at least two distillation columns.

Helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...

is also recovered in advanced air separation processes.

Cryogenic distillation process

Pure gases can be separated from air by first cooling it until it liquefies, then selectively

distilling Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixt ...

the components at their various boiling temperatures. The process can produce high purity gases but is energy-intensive. This process was pioneered by

Carl von Linde Carl Paul Gottfried von Linde (11 June 1842 – 16 November 1934) was a German scientist, engineer, and businessman. He discovered the refrigeration cycle and invented the first industrial-scale air separation and gas liquefaction processes, ...

in the early 20th century and is still used today to produce high purity gases. He developed it in the year 1895; the process remained purely academic for seven years before it was used in industrial applications for the first time (1902). Coldbox

The cryogenic separation process requires a very tight integration of heat exchangers and separation columns to obtain a good efficiency and all the energy for refrigeration is provided by the compression of the air at the inlet of the unit. To achieve the low distillation temperatures, an air separation unit requires a

refrigeration cycle Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and mathematical models for heat pump, air conditioning and refrigeration systems. A heat pump is a mechanical system that transmits heat from one location (the "source") a ...

that operates by means of the

Joule–Thomson effect In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a Real gas, ''real'' gas or liquid (as differentiated from an ideal gas) when it is expanding; ty ...

. The separated products are sometimes supplied by pipeline to large industrial users near the production plant. Long distance transportation of products is by shipping liquid product for large quantities or as dewar flasks or

gas cylinder A gas cylinder is a pressure vessel for storage and containment of gases at above atmospheric pressure. Gas storage cylinders may also be called ''bottles''. Inside the cylinder the stored contents may be in a state of compressed gas, vapor ov ...

s for small quantities.

Non-cryogenic processes

Pressure swing adsorption Pressure swing adsorption (PSA) is a technique used to separate some gas species from a mixture of gases (typically air) under pressure according to the species' molecular characteristics and affinity for an adsorbent material. It operates at ne ...

provides separation of oxygen or nitrogen from air without liquefaction. The process operates around ambient temperature; a

zeolite Zeolites are a group of several microporous, crystalline aluminosilicate minerals commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a meta ...

(molecular sponge) is exposed to high pressure air, then the air is released and an adsorbed film of the desired gas is released. The size of compressor is much reduced over a liquefaction plant, and portable oxygen concentrators are made in this manner to provide oxygen-enriched air for medical purposes.

Vacuum swing adsorption Pressure swing adsorption (PSA) is a technique used to separate some gas species from a mixture of gases (typically air) under pressure according to the species' molecular characteristics and affinity for an adsorbent material. It operates at ne ...

is a similar process; the product gas is evolved from the zeolite at sub-atmospheric pressure. Membrane nitrogen generator

Membrane technologies can provide alternate, lower-energy approaches to air separation. For example, a number of approaches are being explored for oxygen generation. Polymeric membranes operating at ambient or warm temperatures, for example, may be able to produce oxygen-enriched air (25-50% oxygen). Ceramic membranes can provide high-purity oxygen (90% or more) but require higher temperatures (800-900 deg C) to operate. These ceramic membranes include ion transport membranes (ITM) and oxygen transport membranes (OTM). Air Products and Chemicals Inc and Praxair are developing flat ITM and tubular OTM systems. Membrane gas separation is used to provide oxygen-poor and nitrogen-rich gases instead of air to fill the fuel tanks of jet liners, thus greatly reducing the chances of accidental fires and explosions. Conversely, membrane gas separation is currently used to provide oxygen-enriched air to pilots flying at great altitudes in aircraft without pressurized cabins. Oxygen-enriched air can be obtained exploiting the different solubility of oxygen and nitrogen. Oxygen is more soluble than nitrogen in water, so if air is degassed from water, a stream of 35% oxygen can be obtained.

Applications

Rocketry

Liquid oxygen for companies such as

SpaceX Space Exploration Technologies Corp., commonly referred to as SpaceX, is an America, American space technology company headquartered at the SpaceX Starbase, Starbase development site in Starbase, Texas. Since its founding in 2002, the compa ...

Medical

Pure oxygen is delivered to large hospitals for use with patients.

Steel

steelmaking Steelmaking is the process of producing steel from iron ore and/or scrap. Steel has been made for millennia, and was commercialized on a massive scale in the 1850s and 1860s, using the Bessemer process, Bessemer and open hearth furnace, Siemens-M ...

, oxygen is required for the

basic oxygen steelmaking Basic oxygen steelmaking (BOS, BOP, BOF, or OSM), also known as Linz-Donawitz steelmaking or the oxygen converter process,Brock and Elzinga, p. 50. is a method of primary steelmaking in which carbon-rich molten pig iron is made into steel. Blowin ...

process. Modern basic oxygen steelmaking uses almost two tons of oxygen per ton of steel.

Ammonia

Nitrogen used in the

Haber process The Haber process, also called the Haber–Bosch process, is the main industrial procedure for the ammonia production, production of ammonia. It converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using finely di ...

to make

ammonia Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...

Coal gas

Large amounts of oxygen are required for

coal gasification In industrial chemistry, coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (), carbon dioxide (), methane (), and water vapour ()—from coal and water, air and/or oxygen. H ...

projects; cryogenic plants producing 3000 tons/day are found in some projects.

Inert gas

Inerting with nitrogen storage tanks of ships and tanks for petroleum products, or for protecting edible oil products from

oxidation Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...

References

External links

{{Commons category
Simulation of air separation plants
Thermodynamic processes Gas separation Industrial processes Industrial gases Gas technologies de:Luftzerlegung