Aeolis Quadrangle
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The Aeolis quadrangle is one of a series of 30 quadrangle maps of Mars used by the
United States Geological Survey The United States Geological Survey (USGS), founded as the Geological Survey, is an agency of the U.S. Department of the Interior whose work spans the disciplines of biology, geography, geology, and hydrology. The agency was founded on Mar ...
(USGS)
Astrogeology Research Program The Astrogeology Science Center is the entity within the United States Geological Survey concerned with the study of planetary geology and planetary cartography. It is housed in the Shoemaker Building in Flagstaff, Arizona. The Center was esta ...
. The Aeolis quadrangle is also referred to as MC-23 (Mars Chart-23). The Aeolis quadrangle covers 180° to 225° W and 0° to 30° south on
Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...
, and contains parts of the regions
Elysium Planitia Elysium Planitia, located in the Elysium and Aeolis quadrangles, is a broad plain that straddles the equator of Mars, centered at . It lies to the south of the volcanic province of Elysium, the second largest volcanic region on the planet, af ...
and
Terra Cimmeria Terra Cimmeria is a large Martian region, centered at and covering at its broadest extent. It covers latitudes 15 N to 75 S and longitudes 170 to 260 W. It lies in the Eridania quadrangle. Terra Cimmeria is one part of the heavily cratered, ...
. A small part of the Medusae Fossae Formation lies in this quadrangle. The name refers to the name of a floating western island of Aeolus, the ruler of the winds. In Homer's account, Odysseus received the west wind Zephyr here and kept it in bags, but the wind got out. It is famous as the site of two spacecraft landings: the ''Spirit'' rover landing site () in
Gusev crater Gusev is a crater on the planet Mars and is located at and is in the Aeolis quadrangle. The crater is about 166 kilometers in diameter and formed approximately three to four billion years ago. It was named after Russian astronomer Matvey Guse ...
(January 4, 2004), and the ''Curiosity'' rover in
Gale Crater Gale is a crater, and probable dry lake, at in the northwestern part of the Aeolis quadrangle on Mars. It is in diameter and estimated to be about 3.5–3.8 billion years old. The crater was named after Walter Frederick Gale, an amateur a ...
() (August 6, 2012). A large, ancient river valley, called Ma'adim Vallis, enters at the south rim of Gusev Crater, so Gusev Crater was believed to be an ancient lake bed. However, it seems that a volcanic flow covered up the lakebed sediments. Apollinaris Patera, a large volcano, lies directly north of Gusev Crater.U.S. department of the Interior U.S. Geological Survey, Topographic Map of the Eastern Region of Mars M 15M 0/270 2AT, 1991 Gale Crater, in the northwestern part of the Aeolis quadrangle, is of special interest to geologists because it contains a high mound of layered sedimentary rocks, named "Mount Sharp" by NASA in honor of Robert P. Sharp (1911–2004), a planetary scientist of early Mars missions. More recently, on 16 May 2012, "Mount Sharp" was officially named
Aeolis Mons Mount Sharp, officially Aeolis Mons (), is a mountain on Mars. It forms the central peak within Gale crater and is located around , rising high from the valley floor. Its ID in the United States Geological Survey's Gazetteer of Planetary Nomenc ...
by the USGS and
IAU The International Astronomical Union (IAU; , UAI) is an international non-governmental organization (INGO) with the objective of advancing astronomy in all aspects, including promoting astronomical research, outreach, education, and developmen ...
. Some regions in the Aeolis quadrangle show inverted relief. In these locations, a stream bed may be a raised feature, instead of a valley. The inverted former stream channels may be caused by the deposition of large rocks or due to cementation. In either case erosion would erode the surrounding land but leave the old channel as a raised ridge because the ridge will be more resistant to erosion Yardangs are another feature found in this quadrangle. They are generally visible as a series of parallel linear ridges, caused by the direction of the prevailing wind.


''Spirit'' rover discoveries

The rocks on the plains of Gusev are a type of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
. They contain the
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
,
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
,
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
, and magnetite, and they look like volcanic basalt as they are fine-grained with irregular holes (geologists would say they have vesicles and vugs). Much of the soil on the plains came from the breakdown of the local rocks. Fairly high levels of
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
were found in some soils; probably from
meteorites A meteorite is a rock that originated in outer space and has fallen to the surface of a planet or moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical interactions with the atmospheri ...
. Analysis shows that the rocks have been slightly altered by tiny amounts of water. Outside coatings and cracks inside the rocks suggest water deposited minerals, maybe
bromine Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between th ...
compounds. All the rocks contain a fine coating of dust and one or more harder kinds of material. One type can be brushed off, while another needed to be ground off by the
Rock Abrasion Tool The Rock Abrasion Tool (RAT) is a grinding and brushing installation on NASA’s twin Mars Exploration Rovers, '' Spirit'' (MER-A) and '' Opportunity'' (MER-B), which landed on Mars in January 2004. It was designed, developed and continues to be o ...
(RAT). There are a variety of rocks in the Columbia Hills, some of which have been altered by water, but not by very much water. The dust in Gusev Crater is the same as dust all around the planet. All the dust was found to be magnetic. Moreover, ''Spirit'' found the
magnetism Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, ...
was caused by the mineral
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
, especially magnetite that contained the element
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
. One magnet was able to completely divert all dust hence all Martian dust is thought to be magnetic. The spectra of the dust was similar to spectra of bright, low thermal inertia regions like
Tharsis Tharsis () is a vast volcanic plateau centered near the equator in the western hemisphere of Mars. The region is home to the largest volcanoes in the Solar System, including the three enormous shield volcanoes Arsia Mons, Pavonis Mons, and A ...
and Arabia that have been detected by orbiting satellites. A thin layer of dust, maybe less than one millimeter thick, covers all surfaces. Something in it contains a small amount of chemically bound water.Bell, J (ed.) ''The Martian Surface''. 2008. Cambridge University Press.


Plains

Observations of rocks on the plains show they contain the minerals pyroxene, olivine, plagioclase, and magnetite. These rocks can be classified in different ways. The amounts and types of minerals make the rocks primitive basalts—also called picritic basalts. The rocks are similar to ancient terrestrial rocks called basaltic komatiites. Rocks of the plains also resemble the basaltic shergottites, meteorites which came from Mars. One classification system compares the amount of alkali elements to the amount of silica on a graph; in this system, Gusev plains rocks lie near the junction of basalt, picrobasalt, and tephite. The Irvine-Barager classification calls them basalts.McSween, etal. 2004. "Basaltic Rocks Analyzed by the Spirit Rover in Gusev Crater". ''Science'' : 305. 842–845 Plain's rocks have been very slightly altered, probably by thin films of water because they are softer and contain veins of light colored material that may be bromine compounds, as well as coatings or rinds. It is thought that small amounts of water may have gotten into cracks inducing mineralization processes. Coatings on the rocks may have occurred when rocks were buried and interacted with thin films of water and dust. One sign that they were altered was that it was easier to grind these rocks compared to the same types of rocks found on Earth. The first rock that ''Spirit'' studied was Adirondack. It turned out to be typical of the other rocks on the plains.


Columbia Hills

Scientists found a variety of rock types in the Columbia Hills, and they placed them into six different categories. The six are: Clovis, Wishbone, Peace, Watchtower, Backstay, and Independence. They are named after a prominent rock in each group. Their chemical compositions, as measured by APXS, are significantly different from each other. Most importantly, all of the rocks in Columbia Hills show various degrees of alteration due to aqueous fluids. They are enriched in the elements phosphorus, sulfur, chlorine, and bromine—all of which can be carried around in water solutions. The Columbia Hills' rocks contain basaltic glass, along with varying amounts of olivine and
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
s.Schroder, C., et al. (2005) European Geosciences Union, General Assembly, Geophysical Research abstr., Vol. 7, 10254, 2005 The olivine abundance varies inversely with the amount of sulfates. This is exactly what is expected because water destroys olivine but helps to produce sulfates. Acid fog is believed to have changed some of the Watchtower rocks. This was in a 200 meter long section of Cumberland Ridge and the Husband Hill summit. Certain places became less crystalline and more amorphous. Acidic water vapor from volcanoes dissolved some minerals forming a gel. When water evaporated, a cement formed and produced small bumps. This type of process has been observed in the lab when basalt rocks are exposed to sulfuric and
hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
s. The Clovis group is especially interesting because the Mössbauer spectrometer (MB) detected
goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α- polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
in it. Goethite forms only in the presence of water, so its discovery is the first direct evidence of past water in the Columbia Hills's rocks. In addition, the MB spectra of rocks and outcrops displayed a strong decline in olivine presence, although the rocks probably once contained much olivine. Olivine is a marker for the lack of water because it easily decomposes in the presence of water. Sulfate was found, and it needs water to form. Wishstone contained a great deal of plagioclase, some olivine, and
anhydrate An acidic oxide is an oxide that either produces an acidic solution upon addition to water, or acts as an acceptor of hydroxide ions effectively functioning as a Lewis acid. Acidic oxides will typically have a low pKa and may be inorganic or or ...
(a sulfate). Peace rocks showed
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
and strong evidence for bound water, so hydrated sulfates are suspected. Watchtower class rocks lack olivine consequently they may have been altered by water. The Independence class showed some signs of clay (perhaps montmorillonite a member of the smectite group). Clays require fairly long term exposure to water to form. One type of soil, called Paso Robles, from the Columbia Hills, may be an evaporate deposit because it contains large amounts of sulfur,
phosphorus Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...
,
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
, and
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
. Also, MB found that much of the iron in Paso Robles soil was of the oxidized, Fe3+ form, which would happen if water had been present. Towards the middle of the six-year mission (a mission that was supposed to last only 90 days), large amounts of pure
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
were found in the soil. The silica could have come from the interaction of soil with acid vapors produced by volcanic activity in the presence of water or from water in a hot spring environment. After ''Spirit'' stopped working scientists studied old data from the Miniature Thermal Emission Spectrometer, or Mini-TES and confirmed the presence of large amounts of
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
-rich rocks, which means that regions of the planet may have once harbored water. The carbonates were discovered in an outcrop of rocks called "Comanche". In summary, ''Spirit'' found evidence of slight weathering on the plains of Gusev, but no evidence that a lake was there. However, in the Columbia Hills there was clear evidence for a moderate amount of aqueous weathering. The evidence included sulfates and the minerals goethite and carbonates which only form in the presence of water. It is believed that Gusev crater may have held a lake long ago, but it has since been covered by igneous materials. All the dust contains a magnetic component which was identified as magnetite with some titanium. Furthermore, the thin coating of dust that covers everything on Mars is the same in all parts of Mars.


Ma'adim Vallis

Recent studies lead scientists to believe that the water that formed Ma'adim Vallis originated in a complex of lakes. The largest lake is located at the source of the Ma'adim Vallis outflow channel and extends into Eridania quadrangle and the
Phaethontis quadrangle The Phaethontis quadrangle is one of a series of list of quadrangles on Mars, 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Phaethontis quadrangle (geography), quadrangle is also ...
. When the largest lake spilled over the low point in its boundary, a torrential flood would have moved north, carving the sinuous Ma'adim Vallis. At the north end of Ma'adim Vallis, the flood waters would have run into
Gusev Crater Gusev is a crater on the planet Mars and is located at and is in the Aeolis quadrangle. The crater is about 166 kilometers in diameter and formed approximately three to four billion years ago. It was named after Russian astronomer Matvey Guse ...
. There is enormous evidence that water once flowed in river valleys on Mars. Images of curved channels have been seen in images from Mars spacecraft dating back to the early 1970s with the
Mariner 9 Mariner 9 (Mariner Mars '71 / Mariner-I) was a robotic spacecraft that contributed greatly to the exploration of Mars and was part of the NASA Mariner program. Mariner 9 was launched toward Mars on May 30, 1971, from Spaceport Florida Launch Comp ...
orbiter. ''Vallis'' (plural ''valles'') is the
Latin Latin ( or ) is a classical language belonging to the Italic languages, Italic branch of the Indo-European languages. Latin was originally spoken by the Latins (Italic tribe), Latins in Latium (now known as Lazio), the lower Tiber area aroun ...
word for "
valley A valley is an elongated low area often running between hills or mountains and typically containing a river or stream running from one end to the other. Most valleys are formed by erosion of the land surface by rivers or streams over ...
". It is used in
planetary geology Planetary geology, alternatively known as astrogeology or exogeology, is a planetary science discipline concerned with the geology of celestial bodies such as planets and their moons, asteroids, comets, and meteorites. Although the geo- prefix t ...
for the naming of
landform A landform is a land feature on the solid surface of the Earth or other planetary body. They may be natural or may be anthropogenic (caused or influenced by human activity). Landforms together make up a given terrain, and their arrangement ...
features on other planets, including what could be old river valleys that were discovered on Mars, when probes were first sent to Mars. The Viking Orbiters caused a revolution in our ideas about
water on Mars Although very small amounts of liquid water may occur transiently on the surface of Mars, limited to traces of dissolved moisture from the atmosphere and thin films, large quantities of ice are present on and under the surface. Small amounts of ...
; huge river valleys were found in many areas. Space craft cameras showed that floods of water broke through dams, carved deep valleys, eroded grooves into bedrock, and traveled thousands of kilometers. Some valles on Mars ( Mangala Vallis, Athabasca Vallis, Granicus Vallis, and Tinjar Valles) clearly begin at graben. On the other hand, some of the large
outflow channels Outflow channels are extremely long, wide swathes of scoured ground on Mars.Carr, M.H. (2006), ''The Surface of Mars''. Cambridge Planetary Science Series, Cambridge University Press. They extend many hundreds of kilometers in length and are typi ...
begin in rubble-filled low areas called chaos or chaotic terrain. It has been suggested that massive amounts of water were trapped under pressure beneath a thick cryosphere (layer of frozen ground), then the water was suddenly released, perhaps when the cryosphere was broken by a fault.


Gale Crater

Gale Crater Gale is a crater, and probable dry lake, at in the northwestern part of the Aeolis quadrangle on Mars. It is in diameter and estimated to be about 3.5–3.8 billion years old. The crater was named after Walter Frederick Gale, an amateur a ...
, in the northwestern part of the Aeolis quadrangle, is of special interest to geologists because it contains a high mound of layered sedimentary rocks. On 28 March 2012 this mound was named "Mount Sharp" by
NASA The National Aeronautics and Space Administration (NASA ) is an independent agencies of the United States government, independent agency of the federal government of the United States, US federal government responsible for the United States ...
in honor of Robert P. Sharp (1911–2004), a
planetary scientist Planetary science (or more rarely, planetology) is the scientific study of planets (including Earth), celestial bodies (such as moons, asteroids, comets) and planetary systems (in particular those of the Solar System) and the processes of their ...
of early Mars missions. More recently, on 16 May 2012, Mount Sharp was officially named
Aeolis Mons Mount Sharp, officially Aeolis Mons (), is a mountain on Mars. It forms the central peak within Gale crater and is located around , rising high from the valley floor. Its ID in the United States Geological Survey's Gazetteer of Planetary Nomenc ...
by the
USGS The United States Geological Survey (USGS), founded as the Geological Survey, is an government agency, agency of the United States Department of the Interior, U.S. Department of the Interior whose work spans the disciplines of biology, geograp ...
and
IAU The International Astronomical Union (IAU; , UAI) is an international non-governmental organization (INGO) with the objective of advancing astronomy in all aspects, including promoting astronomical research, outreach, education, and developmen ...
. The mound extends higher than the rim of the crater, so perhaps the layering covered an area much larger than the crater. These layers are a complex record of the past. The rock layers probably took millions of years to be laid down within the crater, then more time to be eroded to make them visible. The 5 km high mound is probably the thickest single succession of sedimentary rocks on Mars. The lower formation may date from near the Noachian age, while the upper layer, separated by an erosional unconformity, may be as young as the Amazonian period. The lower formation may have formed the same time as parts of Sinus Meridiani and Mawrth Vallis. The mound that lies in the center of Gale Crater was created by winds. Because the winds eroded the mound on one side more than another, the mound is skewed to one side, rather than being symmetrical. The upper layer may be similar to layers in Arabia Terra. Sulfates and Iron oxides have been detected in the lower formation and anhydrous phases in the upper layer. There is evidence that the first phase of erosion was followed by more cratering and more rock formation. Also of interest in Gale Crater is Peace Vallis, officially named by the IAU on September 26, 2012, which 'flows' down out of the Gale Crater hills to the
Aeolis Palus Aeolis Palus is a plain between the northern wall of Gale crater and the northern foothills of Aeolis Mons (Mount Sharp) on Mars. It is located at . The NASA Mars Science Laboratory mission landed the ''Curiosity'' rover on Aeolis Palus in Aug ...
below, and which seems to have been carved by flowing
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
. On December 9, 2013, NASA reported that, based on evidence from ''
Curiosity Curiosity (from Latin , from "careful, diligent, curious", akin to "care") is a quality related to inquisitive thinking, such as exploration, investigation, and learning, evident in humans and other animals. Curiosity helps Developmental psyc ...
'' studying Aeolis Palus, Gale Crater contained an ancient freshwater lake which could have been a hospitable environment for
microbial life A microorganism, or microbe, is an organism of microscopic scale, microscopic size, which may exist in its unicellular organism, single-celled form or as a Colony (biology)#Microbial colonies, colony of cells. The possible existence of unseen ...
. Gale Crater contains a number of fans and deltas that provide information about lake levels in the past. These formations are: Pancake Delta, Western Delta, Farah Vallis delta and the Peace Vallis Fan.


Other craters

Impact craters generally have a rim with ejecta around them, in contrast volcanic craters usually do not have a rim or ejecta deposits. As craters get larger (greater than 10 km in diameter) they usually have a central peak. The peak is caused by a rebound of the crater floor following the impact. Sometimes craters will display layers. Since the collision that produces a crater is like a powerful explosion, rocks from deep underground are tossed onto the surface. Hence, craters can show us what lies deep under the surface.


Mars Science Laboratory discoveries

The aim of the
Mars Science Laboratory Mars Science Laboratory (MSL) is a robotic spacecraft, robotic space probe mission to Mars launched by NASA on November 26, 2011, which successfully landed ''Curiosity (rover), Curiosity'', a Mars rover, in Gale (crater), Gale Crater on Augus ...
mission, and its surface robotic payload ''Curiosity'' rover, is to search for signs of ancient life. It is hoped that a later mission could then return samples that the laboratory identified as probably containing remains of life. To safely bring the craft down, a 12 mile wide, smooth, flat circle was needed. Geologists hoped to examine places where water once ponded and to examine sedimentary layers. On August 6, 2012, the Mars Science Laboratory landed on
Aeolis Palus Aeolis Palus is a plain between the northern wall of Gale crater and the northern foothills of Aeolis Mons (Mount Sharp) on Mars. It is located at . The NASA Mars Science Laboratory mission landed the ''Curiosity'' rover on Aeolis Palus in Aug ...
near
Aeolis Mons Mount Sharp, officially Aeolis Mons (), is a mountain on Mars. It forms the central peak within Gale crater and is located around , rising high from the valley floor. Its ID in the United States Geological Survey's Gazetteer of Planetary Nomenc ...
in
Gale Crater Gale is a crater, and probable dry lake, at in the northwestern part of the Aeolis quadrangle on Mars. It is in diameter and estimated to be about 3.5–3.8 billion years old. The crater was named after Walter Frederick Gale, an amateur a ...
. The landing was from the target (), closer than any previous rover landing and well within the target area. On September 27, 2012, NASA scientists announced that ''
Curiosity Curiosity (from Latin , from "careful, diligent, curious", akin to "care") is a quality related to inquisitive thinking, such as exploration, investigation, and learning, evident in humans and other animals. Curiosity helps Developmental psyc ...
'' found evidence for an ancient streambed suggesting a "vigorous flow" of
water on Mars Although very small amounts of liquid water may occur transiently on the surface of Mars, limited to traces of dissolved moisture from the atmosphere and thin films, large quantities of ice are present on and under the surface. Small amounts of ...
. On October 17, 2012, at Rocknest, the first
X-ray diffraction analysis X-ray crystallography is the experimental science of determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract in specific directions. By measuring the angles and ...
of
Martian soil Martian regolith is the fine blanket of unconsolidated, loose, heterogeneous superficial deposits covering the surface of Mars. The term ''Martian soil'' typically refers to the finer fraction of regolith. So far, no samples have been returned to ...
was performed. The results revealed the presence of several minerals, including
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
,
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
s and
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
, and suggested that the Martian soil in the sample was similar to the weathered basaltic soils of Hawaiian volcanoes. The sample used is composed of
dust Dust is made of particle size, fine particles of solid matter. On Earth, it generally consists of particles in the atmosphere that come from various sources such as soil lifted by wind (an aeolian processes, aeolian process), Types of volcan ...
distributed from global dust storms and local fine sand. So far, the materials ''Curiosity'' has analyzed are consistent with the initial ideas of deposits in Gale Crater recording a transition through time from a wet to dry environment. On December 3, 2012, NASA reported that ''Curiosity'' performed its first extensive soil analysis, revealing the presence of water molecules,
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
and
chlorine Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
in the Martian soil. The presence of
perchlorates A perchlorate is a chemical compound containing the perchlorate ion, , the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation ...
in the sample seems highly likely. The presence of
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
and
sulfide Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families o ...
is also likely because
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
and
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
were detected. Small amounts of
chloromethane Chloromethane, also called methyl chloride, Refrigerant-40, R-40 or HCC 40, is an organic compound with the chemical formula . One of the haloalkanes, it is a colorless, sweet-smelling, flammable gas. Methyl chloride is a crucial reagent in indu ...
,
dichloromethane Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula . This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with ...
and
trichloromethane Chloroform, or trichloromethane (often abbreviated as TCM), is an organochloride with the chemical formula, formula and a common solvent. It is a Volatility (chemistry), volatile, colorless, sweet-smelling, dense liquid produced on a large scale ...
were detected. The source of the carbon in these molecules is unclear. Possible sources include contamination of the instrument, organics in the sample and inorganic
carbonates A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group . ...
. On March 18, 2013, NASA reported evidence of
mineral hydration In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a ''hydrate''. In geological terms, the process of mineral hydration is known as ''re ...
, likely hydrated
calcium sulfate Calcium sulfate (or calcium sulphate) is an inorganic salt with the chemical formula . It occurs in several hydrated forms; the anhydrous state (known as anhydrite) is a white crystalline solid often found in evaporite deposits. Its dihydrate ...
, in several rock samples including the broken fragments of "Tintina" rock and "Sutton Inlier" rock as well as in
veins Veins () are blood vessels in the circulatory system of humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are those of the pulmonary and fetal c ...
and
nodules Nodule may refer to: *Nodule (geology), a small rock or mineral cluster *Manganese nodule, a metallic concretion found on the seafloor *Nodule (medicine), a small aggregation of cells *Root nodule Root nodules are found on the roots of plants, p ...
in other rocks like "Knorr" rock and "Wernicke" rock. Analysis using the rover's DAN instrument provided evidence of subsurface water, amounting to as much as 4% water content, down to a depth of , in the rover's traverse from the
Bradbury Landing Bradbury Landing is the August 6, 2012, landing site within Gale (crater), Gale crater on planet Mars of the Mars Science Laboratory (MSL) Curiosity rover, ''Curiosity'' rover. On August 22, 2012, on what would have been his 92nd birthday, NAS ...
site to the Yellowknife Bay area in the Glenelg terrain. In March 2013, NASA reported ''Curiosity'' found evidence that
geochemical Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the ...
conditions in Gale Crater were once suitable for
microbial life A microorganism, or microbe, is an organism of microscopic scale, microscopic size, which may exist in its unicellular organism, single-celled form or as a Colony (biology)#Microbial colonies, colony of cells. The possible existence of unseen ...
after analyzing the first drilled sample of Martian rock, "John Klein" rock at Yellowknife Bay in Gale Crater. The rover detected water, carbon dioxide, oxygen, sulfur dioxide and hydrogen sulfide. Chloromethane and dichloromethane were also detected. Related tests found results consistent with the presence of smectite clay minerals. In the journal ''Science'' from September 2013, researchers described a different type of rock called '' Jake M'' (or ''Jake Matijevic'') It was the first rock analyzed by the
Alpha Particle X-ray Spectrometer :''APXS is also an abbreviation for APache eXtenSion tool, an extension for Apache web servers.'' An alpha particle X-ray spectrometer (APXS) is a spectrometer that analyses the chemical element composition of a sample from scattered alpha parti ...
(APXS) instrument on the ''Curiosity'' rover, and it was different from other known martian igneous rocks as it is alkaline (>15% normative nepheline) and relatively fractionated. Jake M is similar to terrestrial mugearites, a rock type typically found at ocean islands and continental rifts. Jake M's discovery may mean that alkaline magmas may be more common on Mars than on Earth and that ''Curiosity'' could encounter even more fractionated alkaline rocks (for example, phonolites and trachytes). On December 9, 2013, NASA researchers described, in a series of six articles in the journal ''Science'', many new discoveries from the ''Curiosity'' rover. Possible organics were found that could not be explained by contamination. Although the organic carbon was probably from Mars, it can all be explained by dust and meteorites that have landed on the planet. Because much of the carbon was released at a relatively low temperature in ''Curiosity''s
Sample Analysis at Mars Sample Analysis at Mars (SAM) is a suite of instruments on the Mars Science Laboratory Curiosity (rover), ''Curiosity'' rover. The SAM instrument suite analyzed Organic compound, organics and gases from both atmospheric and solid samples. It was ...
(SAM) instrument package, it probably did not come from carbonates in the sample. The carbon could be from organisms, but this has not been proven. This organic-bearing material was obtained by drilling 5 centimeters deep in a site called Yellowknife Bay into a rock called “ Sheepbed mudstone”. The samples were named John Klein and
Cumberland Cumberland ( ) is an area of North West England which was historically a county. The county was bordered by Northumberland to the north-east, County Durham to the east, Westmorland to the south-east, Lancashire to the south, and the Scottish ...
. Microbes could be living on Mars by obtaining energy from chemical imbalances between minerals in a process called
chemolithotrophy Lithotrophs are a diverse group of organisms using an inorganic substrate (usually of mineral origin) to obtain reducing equivalents for use in biosynthesis (e.g., carbon dioxide fixation) or energy conservation (i.e., ATP production) via aerob ...
which means “eating rock.” However, in this process only a very tiny amount of carbon is involved—much less than was found at ''Yellowknife Bay''. Using SAM's
mass spectrometer Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a '' mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is us ...
, scientists measured
isotopes Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), but ...
of
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
,
neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...
, and
argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
that
cosmic rays Cosmic rays or astroparticles are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar ...
produce as they go through rock. The fewer of these isotopes they find, the more recently the rock has been exposed near the surface. The four-billion-year-old lakebed rock drilled by ''Curiosity'' was uncovered between 30 million and 110 million years ago by winds which sandblasted away two meters of overlying rock. Next, they hope to find a site tens of millions of years younger by drilling close to an overhanging outcrop. The absorbed dose and dose equivalent from galactic cosmic rays and
solar energetic particle Solar energetic particles (SEP), formerly known as solar cosmic rays, are high-energy, charged particles originating in the solar atmosphere and solar wind. They consist of protons, electrons and heavy ions with energies ranging from a few tens ...
s on the Martian surface for ~300 days of observations during the current solar maximum was measured. These measurements are necessary for human missions to the surface of Mars, to provide microbial survival times of any possible extant or past life, and to determine how long potential organic
biosignature A biosignature (sometimes called chemical fossil or molecular fossil) is any substance – such as an element, isotope, molecule, or phenomenon – that provides scientific evidence of past or present life on a planet. Measurable ...
s can be preserved. This study estimates that a one-meter depth drill is necessary to access possible viable radioresistant microbe cells. The actual absorbed dose measured by the Radiation Assessment Detector (RAD) is 76 mGy/yr at the surface. Based on these measurements, for a round trip Mars surface mission with 180 days (each way) cruise, and 500 days on the Martian surface for this current solar cycle, an astronaut would be exposed to a total mission dose equivalent of ~1.01
sievert The sievert (symbol: SvPlease note there are two non-SI units that use the same Sv abbreviation: the sverdrup and svedberg.) is a derived unit in the International System of Units (SI) intended to represent the stochastic health risk of ionizin ...
. Exposure to one sievert is associated with a five percent increase in risk for developing fatal cancer. NASA's current lifetime limit for increased risk for its astronauts operating in low-Earth orbit is three percent. Maximum shielding from galactic cosmic rays can be obtained with about 3 meters of Martian soil. The samples examined were probably once mud that for millions to tens of millions of years could have hosted living organisms. This wet environment had neutral pH, low
salinity Salinity () is the saltiness or amount of salt (chemistry), salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensio ...
, and variable
redox Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is t ...
states of both iron and sulfur species. These types of iron and sulfur could have been used by living organisms. Carbon, hydrogen, oxygen, sulfur, nitrogen, and phosphorus were measured directly as key biogenic elements, and by inference, phosphorus is assumed to have been available. The two samples, John Klein and Cumberland, contain basaltic minerals, Ca-sulfates, Fe oxide/hydroxides, Fe-sulfides, amorphous material, and trioctahedral
smectite A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secon ...
s (a type of clay). Basaltic minerals in the
mudstone Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from ''shale'' by its lack of fissility.Blatt, H., and R.J. Tracy, 1996, ''Petrology.'' New York, New York, ...
are similar to those in nearby aeolian deposits. However, the mudstone has far less Fe-
forsterite Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich Endmember, end-member of the olivine solid solution series. It is Isomorphism (crystallography), isomorphous with the iron-rich end-member, fayalit ...
plus
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
, so Fe-forsterite (type of olivine) was probably altered to form smectite (a type of clay) and magnetite. A Late
Noachian The Noachian is a system (stratigraphy), geologic system and early geologic timescale, time period on the planet Mars characterized by high rates of meteorite and asteroid Impact event, impacts and the possible presence of abundant surface water. ...
/Early
Hesperian The Hesperian is a system (stratigraphy), geologic system and geologic timescale, time period on the planet Mars characterized by widespread Volcanology of Mars, volcanic activity and catastrophic flooding that carved immense outflow channels acr ...
or younger age indicates that clay mineral formation on Mars extended beyond Noachian time; therefore, in this location neutral pH lasted longer than previously thought. In a press conference on December 8, 2014, Mars scientists discussed observations by ''Curiosity'' rover that show Mars' Mount Sharp was built by sediments deposited in a large lake bed over tens of millions of years. This finding suggests the climate of ancient Mars could have produced long-lasting lakes at many places on the Planet. Rock layers indicate that a huge lake was filled and evaporated many times. The evidence was many deltas that were stacked upon each other. Also in December 2014, it was announced that ''Curiosity'' had detected sharp increases in methane four times out of twelve during a 20-month period with the Tunable Laser Spectrometer (TLS) of the Sample Analysis at Mars instrument (SAM). Methane levels were ten times the usual amount. Due to the temporary nature of the methane spike, researchers believe the source is localized. The source may be biological or non-biological. On December 16, 2014, a team of researchers described how they have concluded that
organic compounds Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co ...
have been found on Mars by ''Curiosity''. The compounds were found in samples from drilling into Sheepbed mudstone. Chlorobenzene and several dichloroalkanes, such as dichloroethane, dichloropropane and dichlorobutane were discovered in the samples. On March 24, 2015, a paper was released describing the discovery of nitrates in three samples analyzed by ''Curiosity''. The nitrates are believed to have been created from diatomic nitrogen in the atmosphere during meteorite impacts. Nitrogen is needed for all forms of life because it is used in the building blocks of larger molecules like DNA and RNA. Nitrates contain nitrogen in a form that can be used by living organisms; nitrogen in the air can not be used by organisms. This discovery of nitrates adds to the evidence that Mars once had life. The
Jet Propulsion Laboratory The Jet Propulsion Laboratory (JPL) is a Federally funded research and development centers, federally funded research and development center (FFRDC) in La Cañada Flintridge, California, Crescenta Valley, United States. Founded in 1936 by Cali ...
(JPL) announced in April 2015 the discovery of a network of two-tone mineral veins at an area called "Garden City" on lower Mount Sharp. The veins stand about 2.5 inches above the surface and are composed of two different minerals formed from at least two different fluid flows. In Pahrump Hills, an area about 39 feet lower, the minerals
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
,
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
,
jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct dur ...
,
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
, and
cristobalite Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, Si O2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members o ...
were found. Measurements made by ''Curiosity'' allowed researchers to determine that Mars has liquid water at times. Because the humidity goes to 100% at night, salts, like
calcium perchlorate Calcium perchlorate is classified as a metal perchlorate salt with the molecular formula . It is an inorganic compound that is a yellow-white crystalline solid in appearance. As a strong oxidizing agent, it reacts with reducing agents when heated t ...
, will absorb water from the air and form a brine in the soil. This process in which a salt absorbs water from the air is called
deliquescence Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance' ...
. Liquid water results even though the temperature is very low, as salts lower the freezing point of water. This principle is used when salt is spread on roads to melt snow/ice. The liquid brine produced in the night evaporates after sunrise. Much more liquid water is expected in higher latitudes where the colder temperature and more water vapor can result in higher levels of humidity more often. The researchers cautioned that the amount of water was not enough to support life, but it could allow salts to move around in the soil. The brines would occur mostly in the upper 5 cm of the surface; however, there is evidence that the effects of liquid water can be detected down to 15 cm. Chlorine-bearing brines are corrosive; therefore design changes may need to be made for future landers. French and U.S. scientists found a type of
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
by studying images and chemical results of 22 rock fragments. The composition of the rocks was determined with the ChemCam instrument. These pale rocks are rich in
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
and may contain some quartz. The rocks are similar to Earth's granitic continental crust. They are like rocks called TTG (Tonalite-Trondhjemite-Granodiorite). On the Earth, TTG was common in the terrestrial continental crust in the Archean era (more than 2.5 billion years ago). By landing in Gale crater, ''Curiosity'' was able to sample a variety of rocks because the crater dug deep into the crust, thus exposing old rocks, some of which may be about 3.6 billion years old. For many years, Mars was thought to be composed of the dark, igneous rock
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
, so this is a significant discovery. On October 8, 2015, a large team of scientists confirmed the existence of long-lasting lakes in Gale Crater. The conclusion of Gale having lakes was based on evidence of old streams with coarser gravel in addition to places where streams appear to have emptied out into bodies of standing water. If lakes were once present, Curiosity would start seeing water-deposited, fine-grained rocks closer to Mount Sharp. That is exactly what happened. Finely laminated mudstones were discovered by ''Curiosity''; this lamination represents the settling of plumes of fine sediment through a standing body of water. Sediment deposited in a lake formed the lower portion of Mount Sharp, the mountain in Gale crater. At a press conference in San Francisco at the
American Geophysical Union The American Geophysical Union (AGU) is a 501(c)(3) nonprofit organization of Earth, Atmospheric science, atmospheric, Oceanography, ocean, Hydrology, hydrologic, Astronomy, space, and Planetary science, planetary scientists and enthusiasts that ...
meeting, a group of scientists told of a discovery of very high concentrations of
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
at some sites, along with the first ever discovery of a silica mineral called
tridymite Tridymite is a high-temperature polymorphism (materials science), polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is sili ...
. The scientific team believes that water was involved with putting the silica in place. Acidic water would tend transport other ingredients away and leave silica behind, whereas alkaline or neutral water could carry in dissolved silica that would be deposited. This finding used measurements from ChemCam, the Alpha Particle X-ray Spectrometer (APXS), and the Chemistry and Mineralogy (CheMin) instrument inside the rover. Tridymite was found in a rock named "Buckskin". ChemCam and APXS measurements displayed high silica in pale zones along fractures in the bedrock beyond Marias Pass; hence silica may have been deposited by fluids that flowed through the fractures. CheMin found high silica levels in drilled material from a target called "Big Sky" and in another rock called "Greenhorn". As of the beginning of 2016, ''Curiosity'' had discovered seven hydrous minerals. The minerals are
actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite i ...
,
montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite grou ...
,
saponite Saponite is a trioctahedral mineral of the smectite group. Its chemical formula is . It is soluble in sulfuric acid. It was first described in 1840 by Lars Fredrik Svanberg, Svanberg. Varieties of saponite are griffithite, bowlingite and sobotk ...
, jarosite,
halloysite Halloysite is an aluminosilicate clay mineral with the empirical formula Al2Si2O5(OH)4. Its main constituents are oxygen (55.78%), silicon (21.76%), aluminium (20.90%), and hydrogen (1.56%). It is a member of the kaolinite group. Halloysite typic ...
, szomolnokite and
magnesite Magnesite is a mineral with the chemical formula ( magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts. Occurrence Magnesite occurs as veins in and an alteration product of ultramafic r ...
. In some places the total concentration of all hydrous minerals was 40 vol%. Hydrous minerals help us understand the early water environment and possible biology on Mars. By using ''Curiosity''s laser-firing device (ChemCam), scientists found manganese oxides in mineral veins in the "Kimberley" region of Gale Crater. These minerals need lots of water and oxidizing conditions to form; hence this discovery points to a water-rich, oxygen-rich past. A study of the kinds of minerals in veins examined with ''Curiosity'' found that evaporating lakes were present in the past in Gale crater. The Sheepbed Member mudstones of Yellowknife Bay (YKB) were examined in this research. Frost probably has formed in three locations in the first 1000 sols of the mission of the ''Curiosity'' exploration according to research published in Icarus in 2016. This frost can cause weathering. Frost formation can explain the widespread detection of hydrated materials from orbit with the OMEGA instrument; it also can explain the hydrated component measured by ''Curiosity'' in Martian soil. Researchers in December 2016 announced the discovery of the element boron on Mars by ''Curiosity'' in mineral veins. For boron to be present there must have been a temperature between 0–60 degrees Celsius and a neutral-to-alkaline pH." The temperature, pH, and dissolved minerals of the groundwater support a habitable environment. Moreover, boron has been suggested to be necessary for life to form. Its presence stabilizes the sugar ribose which is an ingredient in
RNA Ribonucleic acid (RNA) is a polymeric molecule that is essential for most biological functions, either by performing the function itself (non-coding RNA) or by forming a template for the production of proteins (messenger RNA). RNA and deoxyrib ...
. Details of the discovery of Boron on Mars were given in a paper written by a large number of researchers and published in Geophysical Research Letters. Researchers have concluded that Gale Crater has experienced many episodes of groundwater with changes in the groundwater chemistry. These chemical changes would support life. In January 2017, JPL scientists announced the discovery of
mud cracks on Mars In January 2017, scientists announced the possible discovery of mud cracks in Gale Crater on Mars. The Curiosity Rover imaged what may be the first mud cracks (desiccation cracks) ever found on Mars. They may have been formed from drying mud. The ...
. This find adds more evidence that Gale Crater was wet in the past. Studies of the wind around the ''Curiosity'' rover over a period of 3 billion years has shown that the Mount Sharp, the mound inside Gale Crater was created when winds removed material over billions of years and left material in the middle that is Mount Sharp. The researchers calculated that about 15,000 cubic miles (64,000 cubic kilometers) of material was removed from the crater. ''Curiosity'' has seen
dust devil A dust devil (also known regionally as a dirt devil) is a strong, well-formed, and relatively short-lived whirlwind. Its size ranges from small (18 in/half a metre wide and a few yards/metres tall) to large (more than 30 ft/10 m ...
s in action in the distance. Also, changes were visible as a dust devil passed close to the rover. Ripples in the sand below ''Curiosity'' were observed to move about in just one day. CheMin found feldspar, mafic igneous minerals, iron oxides, crystalline
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
,
phyllosilicates Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
, sulfate minerals in mudstone of Gale Crater. Some of the trends in these minerals at different levels suggested that at least part of the time the lake had near-neutral pH. An analysis of a large amount of data from ChemCam and APXS showed that most of the material encountered by ''Curiosity'' consists of just two major igneous rock types and traces of three others. One chief type is classified as a subalkaline, Mg-rich basalt (similar to MER Spirit basalt) and the other was a more evolved, higher Si, Al, lower Mg basalt. A large group of researchers discovered halos around fractures that they water existed in the ground long after water disappeared from Gale crater. Groundwater, carrying dissolved silica, moved in fractures and deposited silica there. This silica enrichment went across young and old rocks. Research of chemicals in layers in Gale Crater, published in 2017, suggest that the lake in Gale Crater had a neutral pH for much of the time. The mudstone in the Murray formation at the base of Mount Sharp indicated deposition in a lake environment. After the layers were deposited, an acid solution may have moved through the rock, which contained olivine and
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
, dissolving some minerals like magnetite and forming new ones like hematite and
jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct dur ...
. The elements
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
(Mg),
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
(Fe),
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
(Mn), nickel (Ni), and
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
(Zn) were carried down. Eventually, Ni, Zn, and Mn coated (
adsorbed Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a f ...
onto) clay particles. Iron-oxides, Mg, and
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
produced sulfates. The Murray formation was sampled at several locations for this research: Confidence Hills, Mojave 2, Telegraph peak, and Buckskin. Research presented in a June 2018 press conference described the detection of more organic molecules in a drill sample analyzed by Curiosity. Some of the organic molecules found were thiophenes,
benzene Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hyd ...
,
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon with the chemical formula , often abbreviated as , where Ph stands for the phenyl group. It is a colorless, water Water is an inorganic compound with the c ...
, and small carbon chains, such as
propane Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
or
butane Butane () is an alkane with the formula C4H10. Butane exists as two isomers, ''n''-butane with connectivity and iso-butane with the formula . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at ro ...
. At least 50 nanomoles of organic carbon are still in the sample, but were not specifically determined. The remaining organic material probably exists as macromolecules organic sulfur molecules. Organic matter was from lacustrine mudstones at the base of the ~3.5-billion-year-old Murray formation at Pahrump Hills, by the Sample Analysis at Mars instrument suite. With two full Martian years (five Earth years) of measurements, scientists found that the annual average concentration of methane in Mars' atmosphere is 0.41 ppb. However, methane levels rise and fall with the seasons, going from 0.24 ppb in winter to 0.65 ppb in summer. The researchers also saw relatively large methane spikes, up to about 7 ppb, at random intervals. The existence of methane in the Martian atmosphere is exciting because on Earth, most methane is produced by living organisms. Methane on Mars does not prove that life exists there, but it is consistent with life. Ultraviolet radiation from the sun destroys methane does not last long; consequently, something must have been creating or releasing it. Using date gathered with Mastcam, a team of researchers have found what they believe to be iron meteorites. These meteorites stand out in multispectral observations as not possessing the usual ferrous or ferric absorption features as the surrounding surface. Emily Lakdaealla wrote a detailed 2018 book about the ''Curiosity'' rover's instruments and history. She listed the minerals that ''Curiosity''s CheMin has discovered. CheMin has discovered olivine, pyroxene, feldspar, quartz, magnetite,
iron sulfide Iron sulfide or iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals By increasing order of stability: * Iron(II) sulfide, FeS * Greigite, Fe3S4 (cubic) * Pyrrhotite, Fe1−xS (where x = 0 to 0.2) (monocli ...
s (
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
and
pyrrhotite Pyrrhotite (''Pyrrhus of Epirus, pyrrhos'' in Greek language, Greek meaning "flame-coloured"'')'' is an iron sulfide mineral with the formula Fe(1−x)S (x = 0 to 0.125). It is a nonstoichiometric compound, nonstoichiometric variant of FeS, th ...
),
akaganeite Akaganeite, also written as the deprecated Akaganéite,Ernst A.J. Burke (2008):Tidying up Mineral Names: an IMA-CNMNC Scheme for Suffixes, Hyphens and Diacritical marks. ''Mineralogical Record'', volume 39, issue 2. is a chloride-containing iro ...
, jarosite, and calcium sulfates (
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
,
anhydrite Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the ...
,
basanite Basanite () is an igneous, volcanic ( extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and calcic plagioclase and forms from magma low in silica and enriched in alkali metal ox ...
) Research presented in 2018 at the Geological Society of America Annual Meeting in Indianapolis, Indiana described evidence for huge floods in Gale Crater. One rock unit examined by ''Curiosity'' contains the rock conglomerate with particles up to 20 centimeters across. To create such a type of rock water must have been 10 to 20 meters in depth. Between two million years to 12,000 years ago, Earth experienced these types of floods. Using various gravity measurements, a team of scientists concluded that Mount Sharp may have formed right where it is, as it is. The authors stated, "Mount Sharp formed largely in its current form as a free-standing mound within Gale." One idea was that it was part of material that covered a wide region and then eroded, leaving Mount Sharp. However, if that were the case, the layers on the bottom would be fairly dense. This gravity data show that the bottom layers are quite porous. Had they been under many layers of rock they would be compressed and be more dense. Intensity of the gravity was obtained by using data from ''Curiosity''s accelerometers. Researched published in ''Nature Geoscience'' in October 2019 described how Gale crater underwent many wet and dry cycles as its lake waters disappeared. Sulfate salts from evaporated water showed that pools of salty water once existed in Gale Crater. These ponds could have supported organisms. Basalts could have produced the calcium and magnesium sulfates that were found. Because of its low solubility, calcium sulfate is deposited early on as a lake dries up. However, the discovery of magnesium sulfate salts means that the lake must have almost totally evaporated. The remaining pools of water would have been very salty—such lakes on Earth contain organisms that are salt tolerant or "halotolerant". These minerals were found along the edges of what were lakes in the younger parts of Gale Crater. When Curiosity was exploring deeper in the crater, clays found there showed that a lake existed for a long time, these new findings of sulfates the lake dried up and then get wetter over and over. Sulfate salts have been detected in other places in Gale as white veins caused by groundwater moving through cracks in the rocks. Curiosity has found oxygen going into the air in Gale Crater. Measurements over three Martian years (almost six Earth years) by an instrument in the Sample Analysis at Mars (SAM) portable chemistry lab revealed that the level of oxygen went up throughout spring and summer by as much as 30%, and then dropped back to normal levels by fall. Each spring this occurred. These oxygen seasonal variations suggest some unknown process in the atmosphere or the surface is occurring. Evidence of life on Mars was published on January 19, 2022. Rover's Tunable Laser Spectrometer (TLS) determined the abundance of carbon
isotopes Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), but ...
in 24 samples. In many of the samples the relative amount of
carbon-12 Carbon-12 (12C) is the most abundant of the two stable isotopes of carbon ( carbon-13 being the other), amounting to 98.93% of element carbon on Earth; its abundance is due to the triple-alpha process by which it is created in stars. Carbon-1 ...
compared to
carbon-13 Carbon-13 (13C) is a natural, stable isotope of carbon with a nucleus containing six protons and seven neutrons. As one of the environmental isotopes, it makes up about 1.1% of all natural carbon on Earth. Detection by mass spectrometry A m ...
suggested organisms altered the isotopes. In July 2024 the Rover cracked open a rock with its wheel and found crystals of
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
. Minerals containing sulfur were discovered, but never the pure element. It was found in Gediz Vallis. Eventuality, Curiosity Rover found some iron carbonates. CheMin measurements of rocks found crystalline siderite (FeCO3). One rock contained over 10 % of the mineral. The rocks also were composed of plagioclase with the elements sodium (Na)–, Ca-, and aluminum (Al)–, as well as Ca- and Mg-bearing silicate mineral pyroxene. Other minerals found were calcium sulfates, magnesium sulfates, different amounts of iron oxyhydroxides, and an unidentified x-ray amorphous material. Rover’s Chemistry and Mineralogy (CheMin) instrument uses x-ray diffraction to determine sample mineralogy. The names of the rock formations and drill sites are CA, Canaima; TC, Tapo Caparo; UB, Ubajara; and SQ, Sequoia. V


Inverted relief

Some places on Mars show
inverted relief Inverted relief, inverted topography, or topographic inversion refers to landscape features that have reversed their elevation relative to other features. It most often occurs when low areas of a landscape become filled with lava or sediment t ...
. In these locations, a stream bed may be a raised feature, instead of a valley. The inverted former stream channels may be caused by the deposition of large rocks or due to cementation. In either case erosion would erode the surrounding land but leave the old channel as a raised ridge because the ridge will be more resistant to erosion. An image below, taken with
HiRISE High Resolution Imaging Science Experiment is a camera on board the '' Mars Reconnaissance Orbiter'' which has been orbiting and studying Mars since 2006. The 65 kg (143 lb), US$40 million instrument was built under the direction ...
shows sinuous ridges that may be old channels that have become inverted.


Fretted terrain

Parts of the Aeolis quadrangle contain
fretted terrain Fretted terrain is a type of surface feature common to certain areas of Mars and was discovered in Mariner 9 images. It lies between two different types of terrain. The surface of Mars can be divided Martian dichotomy, into two parts: low, young, ...
which is characterized by cliffs,
mesas A mesa is an isolated, flat-topped elevation, ridge, or hill, bounded from all sides by steep escarpments and standing distinctly above a surrounding plain. Mesas consist of flat-lying soft sedimentary rocks, such as shales, capped by a r ...
, buttes, and straight-walled
canyons A canyon (; archaic British English spelling: ''cañon''), gorge or chasm, is a deep cleft between escarpments or cliffs resulting from weathering and the erosive activity of a river over geologic time scales. Rivers have a natural tendency t ...
. It contains scarps or cliffs that are 1 to 2 km in height.


Layered terrain

Researchers, writing in Icarus, have described layered units in the Aeolis quadrangle at Aeolis Dorsa. A deposit that contains yardang was formed after several other deposits. The yardangs contain a layered deposit called "rhythmite" which was thought to be formed with regular changes in the climate. Because the layers appear harden, a damp or wet environment probably existed at the time. The authors correlate these layered deposits to the upper layers of Gale crater's mound (Mt. Sharp). Many places on Mars show rocks arranged in layers. Sometimes the layers are of different colors. Light-toned rocks on Mars have been associated with hydrated minerals like
sulfates The sulfate or sulphate ion is a Polyatomic ion, polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salt (chemistry), ...
. The
Mars rover A Mars rover is a remote-controlled motor vehicle designed to travel on the surface of Mars. Rovers have several advantages over stationary landers: they examine more territory, they can be directed to interesting features, they can place them ...
''
Opportunity Opportunity may refer to: Places * Opportunity, Montana, an unincorporated community, United States * Opportunity, Nebraska, an unincorporated community, United States * Opportunity, Washington, a former census-designated place, United States * ...
'' examined such layers close-up with several instruments. Some layers are probably made up of fine particles because they seem to break up into find dust. Other layers break up into large boulders so they are probably much harder.
Basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
, a volcanic rock, is thought to in the layers that form boulders. Basalt has been identified on Mars in many places. Instruments on orbiting spacecraft have detected
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
(also called
phyllosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
) in some layers. Recent research with an orbiting near-infrared
spectrometer A spectrometer () is a scientific instrument used to separate and measure Spectrum, spectral components of a physical phenomenon. Spectrometer is a broad term often used to describe instruments that measure a continuous variable of a phenomeno ...
, which reveals the types of minerals present based on the wavelengths of light they absorb, found evidence of layers of both clay and sulfates in Columbus crater. This is exactly what would appear if a large lake had slowly evaporated. Moreover, because some layers contained
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
, a sulfate which forms in relatively fresh water, life could have formed in the crater. Scientists were excited about finding hydrated minerals such as sulfates and clays on Mars because they are usually formed in the presence of water. Places that contain clays and/or other hydrated minerals would be good places to look for evidence of life. Rock can form layers in a variety of ways. Volcanoes, wind, or water can produce layers. Layers can be hardened by the action of groundwater. Martian ground water probably moved hundreds of kilometers, and in the process it dissolved many minerals from the rock it passed through. When ground water surfaces in low areas containing sediments, water evaporates in the thin atmosphere and leaves behind minerals as deposits and/or cementing agents. Consequently, layers of dust could not later easily erode away since they were cemented together. On Earth, mineral-rich waters often evaporate forming large deposits of various types of
salts In chemistry, a salt or ionic compound is a chemical compound consisting of an assembly of positively charged ions ( cations) and negatively charged ions (anions), which results in a compound with no net electric charge (electrically neutral). ...
and other
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s. Sometimes water flows through Earth's aquifers, and then evaporates at the surface just as is hypothesized for Mars. One location this occurs on Earth is the
Great Artesian Basin The Great Artesian Basin (GAB) of Australia is the largest and deepest artesian basin in the world, extending over . Measured water temperatures range from . The basin provides the only source of fresh water through much of inland Australia. ...
of
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
. On Earth the hardness of many
sedimentary rock Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
s, like
sandstone Sandstone is a Clastic rock#Sedimentary clastic rocks, clastic sedimentary rock composed mainly of grain size, sand-sized (0.0625 to 2 mm) silicate mineral, silicate grains, Cementation (geology), cemented together by another mineral. Sand ...
, is largely due to the cement that was put in place as water passed through.


Linear ridge networks

Linear ridge networks are found in various places on Mars in and around craters. Ridges often appear as mostly straight segments. They are hundreds of meters long, tens of meters high, and several meters wide. It is thought that impacts created fractures in the surface, these fractures later acted as channels for fluids. Fluids cemented the structures. With the passage of time, surrounding material was eroded away, thereby leaving hard ridges behind. Since the ridges occur in locations with clay, these formations could serve as a marker for clay which requires water for its formation.


See also

* * * * * * * * * * * *


References


Further reading

* Grotzinger, J. and R. Milliken (eds.). 2012. ''Sedimentary Geology of Mars''. SEPM. * * Lakdawalla, E. 2018. The Design and Engineering of Curiosity: How the Mars Rover Performs its job. Springer Praxis Publishing. Chichester, UK


External links


Video (04:32) – Evidence: Water "Vigorously" Flowed On Mars – September, 2012

Lakes, Fans, Deltas and Streams: Geomorphic Constraints ...

Lakes on Mars – Nathalie Cabrol (SETI Talks)

Boron Discovered in Ancient Habitable Mars Groundwater

Steven Benner – Life originated on Mars? – 19th Annual International Mars Society Convention

John Grotzinger - Project Scientist, Curiosity - 20th Annual International Mars Society Convention

Gazetteer of Planetary Nomenclature International Astronomical Union (IAU) Working Group for Planetary System Nomenclature (WGPSN)
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