Photopolymer
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Photopolymer
A photopolymer or light-activated resin is a polymer that changes its properties when exposed to light, often in the ultraviolet or visible region of the electromagnetic spectrum. These changes are often manifested structurally, for example hardening of the material occurs as a result of cross-linking when exposed to light. An example is shown below depicting a mixture of monomers, oligomers, and photoinitiators that conform into a hardened polymeric material through a process called curing. A wide variety of technologically useful applications rely on photopolymers; for example, some enamels and varnishes depend on photopolymer formulation for proper hardening upon exposure to light. In some instances, an enamel can cure in a fraction of a second when exposed to light, as opposed to thermally cured enamels which can require half an hour or longer. Curable materials are widely used for medical, printing, and photoresist technologies. Changes in structural and chemical propert ...
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Polymerization
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many forms of polymerization and different systems exist to categorize them. In chemical compounds, polymerization can occur via a variety of reaction mechanisms that vary in complexity due to the functional groups present in the reactants and their inherent steric effects. In more straightforward polymerizations, alkenes form polymers through relatively simple radical reactions; in contrast, reactions involving substitution at a carbonyl group require more complex synthesis due to the way in which reactants polymerize. As alkenes can polymerize in somewhat straightforward radical reactions, they form useful compounds such as polyethylene and polyvinyl chloride (PVC), which are produced in high tonnages each year due to their usefulnes ...
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Photoinitiator
In chemistry, a photoinitiator is a molecule that creates reactive species (free radicals, cations or anions) when exposed to radiation (Ultraviolet, UV or Visible spectrum, visible). Synthetic photoinitiators are key components in photopolymers (for example, photo-curable coatings, adhesives and dental restoratives). Some small molecules in the Atmosphere of Earth, atmosphere can also act as photoinitiators by decomposing to give free radicals (in photochemical smog). For instance, nitrogen dioxide () is produced in large quantities by gasoline-burning internal combustion engines. in the troposphere gives smog its brown coloration and Catalysis, catalyzes production of toxic ground-level ozone (). Molecular oxygen () also serves as a photoinitiator in the stratosphere, breaking down into atomic oxygen and combining with in order to form the ozone in the ozone layer. Reactions Photoinitators can create reactive species by different pathways including photodissociation and elec ...
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Photoresist
A photoresist (also known simply as a resist) is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface. This process is crucial in the electronics industry. The process begins by coating a substrate with a light-sensitive organic material. A patterned mask is then applied to the surface to block light, so that only unmasked regions of the material will be exposed to light. A solvent, called a developer, is then applied to the surface. In the case of a positive photoresist, the photo-sensitive material is degraded by light and the developer will dissolve away the regions that were exposed to light, leaving behind a coating where the mask was placed. In the case of a negative photoresist, the photosensitive material is strengthened (either polymerized or cross-linked) by light, and the developer will dissolve away only the regions that were not exposed to light, leaving behind a coating in areas w ...
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Polymer
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compound (chemistry), compounds, produces unique physical property, physical properties including toughness, high rubber elasticity, elasticity, viscoelasticity, and a tendency to form Amorphous solid, amorphous and crystallization of polymers, semicrystalline structures rath ...
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Acrylate
Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid. The acrylate ion is the anion . Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate. These acrylates contain vinyl groups. These compounds are of interest because they are bifunctional: the vinyl group is susceptible to polymerization and the carboxylate group carries myriad functionalities. Monomers Acrylates are defined by the formula , where R can be many groups: * Acrylic acid * Methyl acrylate * Ethyl acrylate * 2-Chloroethyl vinyl ether * 2-Ethylhexyl acrylate * Butyl acrylate * Trimethylolpropane triacrylate (TMPTA) The versatility of the resulting polymers is owed to the range of R groups. File:Acrylate-anion.svg, The acrylate anion File:Trimethylolpropane triacrylate.svg, Trimethylolpropane triacrylate (TMPTA), a trifunctional acrylate ester File:Methylacrylat.svg, Methyl acrylate, an acrylic ester File:Hexandioldiacrylat.svg ...
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Lasers
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word ''laser'' originated as an acronym for light amplification by stimulated emission of radiation. The first laser was built in 1960 by Theodore Maiman at Hughes Research Laboratories, based on theoretical work by Charles H. Townes and Arthur Leonard Schawlow and the optical amplifier patented by Gordon Gould. A laser differs from other sources of light in that it emits light that is coherence (physics), ''coherent''. Spatial coherence allows a laser to be focused to a tight spot, enabling uses such as optical communication, laser cutting, and Photolithography#Light sources, lithography. It also allows a laser beam to stay narrow over great distances (collimated light, collimation), used in laser pointers, lidar, and free-space optical communication. Lasers can also have high temporal coherence, which permits them to emit light ...
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Functional Group
In organic chemistry, a functional group is any substituent or moiety (chemistry), moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest of the molecule's composition. This enables systematic prediction of chemical reactions and behavior of chemical compounds and the design of chemical synthesis. The Reactivity (chemistry), reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive Chemical property, chemical properties, regardless of the other atoms in the molecule. The atoms in a functional group are linked to each other and to the rest of the molecule by covalent bonds. For repeating units of polymers, functional groups attach to their Chemical polarity, nonp ...
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Styrene
Styrene is an organic compound with the chemical formula C6H5CH=CH2. Its structure consists of a vinyl group as substituent on benzene. Styrene is a colorless, oily liquid, although aged samples can appear yellowish. The compound evaporates easily and has a sweet smell, although high concentrations have a less pleasant odor. Styrene is the precursor to polystyrene and several copolymers, and is typically made from benzene for this purpose. Approximately 25 million tonnes of styrene were produced in 2010, increasing to around 35 million tonnes by 2018. Natural occurrence Styrene is named after storax balsam (often commercially sold as ''styrax''), the resin of Liquidambar trees of the Altingiaceae plant family. Styrene occurs naturally in small quantities in some plants and foods (cinnamon, coffee beans, balsam tree (other), balsam trees and peanuts) and is also found in coal tar. History In 1839, the German apothecary Eduard Simon isolated a volatile liquid from t ...
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Light
Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequency, frequencies of 750–420 terahertz (unit), terahertz. The visible band sits adjacent to the infrared (with longer wavelengths and lower frequencies) and the ultraviolet (with shorter wavelengths and higher frequencies), called collectively ''optical radiation''. In physics, the term "light" may refer more broadly to electromagnetic radiation of any wavelength, whether visible or not. In this sense, gamma rays, X-rays, microwaves and radio waves are also light. The primary properties of light are intensity (physics), intensity, propagation direction, frequency or wavelength spectrum, and polarization (waves), polarization. Its speed of light, speed in vacuum, , is one of the fundamental physi ...
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Intro Scheme1
Introduction, The Introduction, Intro, or The Intro may refer to: General use * Introduction (music), an opening section of a piece of music * Introduction (writing), a beginning section to a book, article or essay which states its purpose and goals ** Foreword, a beginning section * Introduction (British House of Commons), a ceremonial seating for members elected in by-elections * Introduction (House of Lords), a ceremonial seating for some new members * Intro (demoscene), in the demoscene, a short computer program produced for promotion or to meet competition requirements * Introduced species or introduction, a species established by humans outside its natural range * Right of initiative (legislative), the ability of an entity to introduce a bill or other proposed legislation before a Legislature. * Product launch, the introduction of a new product to market Music Performers * Introduction (band), a Swedish rock group * Intro (group), an American R&B trio Albums * ''Intro ...
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Branching (polymer Chemistry)
In polymer chemistry, branching is the regular or irregular attachment of side chains to a polymer's backbone chain. It occurs by the replacement of a substituent (e.g. a hydrogen atom) on a monomer subunit by another covalently-bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiple-branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard it can be used as the bit in a smoking pipe. Polycarbonate chains can be crosslinked to form the hardest, most impact-resistant thermosetting plastic, used in safety glasses. Branching may result from the formation of carbon-carbon or vario ...
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UV Curing
UV curing (ultraviolet curing) is the process by which ultraviolet light initiates a photochemical reaction that generates a crosslinked network of polymers through radical polymerization or cationic polymerization. UV curing is adaptable to inkjet printing, printing, coating, decorating, stereolithography, and in the assembly of a variety of products and materials. UV curing is a low-temperature, high speed, and solventless process as curing occurs via polymerization. Originally introduced in the 1960s, this technology has streamlined and increased automation in many industries in the manufacturing sector. Applications UV curing is used for converting or curing Ink, inks, Adhesive, adhesives, and Coating, coatings. UV-cured adhesive has become a high speed replacement for two-part adhesives, eliminating the need for solvent removal, ratio mixing, and potential life concern. It is used in flexography, flexographic, offset printing, offset, pad printing, pad, and screen printin ...
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