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Photoelectrochemical Cell
A "photoelectrochemical cell" is one of two distinct classes of device. The first produces electrical energy similarly to a dye-sensitized photovoltaic cell, which meets the standard definition of a photovoltaic cell. The second is a photoelectrolytic cell, that is, a device which uses light incident on a photosensitizer, semiconductor, or aqueous metal immersed in an electrolytic solution to directly cause a chemical reaction, for example to produce hydrogen via the electrolysis of water. Both types of device are varieties of solar cell, in that a photoelectrochemical cell's function is to use the photoelectric effect (or, very similarly, the photovoltaic effect) to convert electromagnetic radiation (typically sunlight) either directly into electrical power, or into something which can itself be easily used to produce electrical power (hydrogen, for example, can be burned to create electrical power, see photohydrogen). Two principles The standard photovoltaic effect, ...
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Electricity Generation
Electricity generation is the process of generating electric power from sources of primary energy. For electric utility, utilities in the electric power industry, it is the stage prior to its Electricity delivery, delivery (Electric power transmission, transmission, Electric power distribution, distribution, etc.) to end users or its Grid energy storage, storage, using for example, the Pumped-storage hydroelectricity, pumped-storage method. Consumable electricity is not freely available in nature, so it must be "produced", transforming other forms of energy to electricity. Production is carried out in power stations, also called "power plants". Electricity is most often generated at a power plant by electromechanical electric generator, generators, primarily driven by heat engines fueled by combustion or nuclear fission, but also by other means such as the kinetic energy of flowing water and wind. Other energy sources include solar photovoltaics and geothermal power. There are ex ...
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Semiconductors
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easily in one ...
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Corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen, or hydroxide. Rusting, the formation of red-orange iron oxides, is a well-known example of electrochemical corrosion. This type of corrosion typically produces oxides or salts of the original metal and results in a distinctive coloration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including mechanical strength, appearance, and permeability to liquids and ga ...
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Economic Efficiency
In microeconomics, economic efficiency, depending on the context, is usually one of the following two related concepts: * Allocative or Pareto efficiency: any changes made to assist one person would harm another. * Productive efficiency: no additional output of one good can be obtained without decreasing the output of another good, and production proceeds at the lowest possible average total cost. These definitions are not equivalent: a market or other economic system may be allocatively but not productively efficient, or productively but not allocatively efficient. There are also other definitions and measures. All characterizations of economic efficiency are encompassed by the more general engineering concept that a system is efficient or optimal when it maximizes desired outputs (such as utility) given available inputs. Standards of thought There are two main standards of thought on economic efficiency, which respectively emphasize the distortions created by ''governme ...
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Greenwood Publishing Group
Greenwood Publishing Group, Inc. (GPG) was an educational and academic publisher (middle school through university level) which was part of ABC-Clio. Since 2021, ABC-Clio and its suite of imprints, including GPG, are collectively imprints of British publishing house Bloomsbury Publishing. The Greenwood name stopped being used for new books in 2023. Established in 1967 as Greenwood Press, Inc., and based in Westport, Connecticut, GPG published reference works under its Greenwood Press imprint; and scholarly, professional, and general-interest books under its related imprint, Praeger Publishers (). Also part of GPG was Libraries Unlimited, which published professional works for librarians and teachers. Both of the latter became stand-alone imprints of ABC-Clio, in 2008–2009, after its purchase of GPG. History 1967–1999 The company was founded as Greenwood Press, Inc. (GPI) in 1967 by Harold Mason, a librarian and antiquarian bookseller, and Harold Schwartz, who had a b ...
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Water Splitting
Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen: Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy. A version of water splitting occurs in photosynthesis, but hydrogen is not produced. The reverse of water splitting is the basis of the hydrogen fuel cell. Water splitting using solar radiation has not been commercialized. Electrolysis Electrolysis of water is the decomposition of water (H2O) into oxygen (O2) and hydrogen (H2): Production of hydrogen from water is energy intensive. Usually, the electricity consumed is more valuable than the hydrogen produced, so this method has not been widely used. In contrast with low-temperature electrolysis, high-temperature electrolysis (HTE) of water converts more of the initial heat energy into chemical energy (hydrogen), potentially doubling efficiency to about 50%. Because some of the energy in HTE is supplied in th ...
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Photocatalysis
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a photocatalyst, the excited state of which "repeatedly interacts with the reaction partners forming reaction intermediates and regenerates itself after each cycle of such interactions." In many cases, the catalyst is a solid that upon irradiation with UV- or visible light generates electron–hole pairs that generate free radicals. Photocatalysts belong to three main groups; heterogeneous, homogeneous, and plasmonic antenna-reactor catalysts. The use of each catalysts depends on the preferred application and required catalysis reaction. History Early mentions (1911–1938) The earliest mention came in 1911, when German chemist Dr. Alexander Eibner integrated the concept in his research of the illumination of zinc oxide (ZnO) on the bleaching of the dark blue pigment, Prussian blue. Around this time, Bruner and Kozak published an article discussing the deterioration of oxalic acid in ...
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Photochemistry
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 Nanometre, nm), visible light, visible (400–750 nm), or infrared radiation (750–2500 nm). In nature, photochemistry is of immense importance as it is the basis of photosynthesis, vision, and the formation of vitamin D with sunlight. It is also responsible for the appearance of DNA mutations leading to skin cancers. Photochemical reactions proceed differently than temperature-driven reactions. Photochemical paths access high-energy intermediates that cannot be generated thermally, thereby overcoming large Activation energy, activation barriers in a short period of time, and allowing reactions otherwise inaccessible by thermal processes. Photochemistry can also be destructive, as illustrated by the photodegradation of plastics. Concept Grotthuss–Dra ...
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National Renewable Energy Laboratory
The National Renewable Energy Laboratory (NREL) in the US specializes in the research and development of renewable energy, energy efficiency, energy systems integration, and sustainable transportation. NREL is a federally funded research and development center sponsored by the Department of Energy and operated by the Alliance for Sustainable Energy, a joint venture between MRIGlobal and Battelle. Located in Golden, Colorado, NREL is home to the National Center for Photovoltaics, the National Bioenergy Center, and the National Wind Technology Center. History Establishment During the 1973 oil crisis, soaring energy prices caused gasoline shortages and contributed significantly to inflation. US President Gerald Ford openly recognized the need for greater energy independence at the September 1974 World Energy Conference in Detroit. A month later, the Solar Energy Research, Development and Demonstration Act of 1974 was signed. Section 10 of the bill explicitly outlined ...
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Solar Energy
Solar energy is the radiant energy from the Sun's sunlight, light and heat, which can be harnessed using a range of technologies such as solar electricity, solar thermal energy (including solar water heating) and solar architecture. It is an essential source of renewable energy, and its technologies are broadly characterized as either passive solar or active solar depending on how they capture and distribute solar energy or convert it into solar power. Active solar techniques include the use of photovoltaic systems, concentrated solar power, and solar water heating to harness the energy. Passive solar techniques include designing a building for better daylighting (architecture), daylighting, selecting materials with favorable thermal mass or light-dispersing properties, and organizing spaces that ventilation (architecture), naturally circulate air. In 2011, the International Energy Agency said that "the development of affordable, inexhaustible and clean solar energy technolo ...
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