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Kröhnkite
Kröhnkite ( Na2Cu(SO4)2•2H2O ) is a rare copper sulfate mineral named after B. Kröhnke who first researched it. Kröhnkite may be replaced by Saranchinaite, the anhydrous form of the mineral, if heated to temperatures above 200 °C (392 °F). Crystallography Kröhnkite has monoclinic symmetry (2/m). Monoclinic symmetry implies that the mineral contains three axes of differing length (typically labeled a, b, and c), two of which intersect each other at 90° and one that intersects at an acute angle. Specifically, it belongs to the 2/m symmetry class meaning, the mineral has a 2-fold rotation axis about the b axis. It also has a unique motif of sulfate tetrahedra chains and copper octahedra aligned along the c axis and linked together by sodium atoms. Kröhnkite exhibits the optical property birefringence; the difference in the two refractive indices of a mineral. Because this mineral is birefringent, it must be anisotropic. Anisotropic minerals cause the velocity of ...
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Sulfate Mineral
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal Vein (geology), veins and as secondary minerals in the Redox, oxidizing zone of sulfide mineral deposits. The Chromate ion, chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 **Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O **Kieserite MgSO4·H2O **Starkeyite MgSO4·4H2O **Hexahydrite MgSO4·6H2O **Epsomite MgSO4·7H2O **Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O **Antlerite ...
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Type Locality (geology)
Type locality, also called type area, is the locality where a particular rock type, stratigraphic unit or mineral species is first identified. If the stratigraphic unit in a locality is layered, it is called a stratotype, whereas the standard of reference for unlayered rocks is the type locality. The concept is similar to type site in archaeology. Examples of geological type localities Rocks and minerals * Aragonite: Molina de Aragón, Guadalajara, Spain * Autunite: Autun, France * Benmoreite: Ben More (Mull), Scotland * Blairmorite: Blairmore, Alberta, Canada * Boninite: Bonin Islands, Japan * Comendite: Comende, San Pietro Island, Sardinia * Cummingtonite: Cummington, Massachusetts * Dunite: Dun Mountain, New Zealand * Essexite: Essex County, Massachusetts, US * Fayalite: Horta, Fayal Island, Azores, Portugal * Harzburgite: Bad Harzburg, Germany * Icelandite: Thingmuli (Þingmúli), Iceland * Ijolite: Iivaara, Kuusamo, Finland * Kimberlite: ...
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Copper(II) Minerals
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable, unalloyed metallic form. This means that copper is a native metal. This led to very early human use in several regions, from . Thousands of years later, it was the first metal to be smelted from sulfide ores, ; the first metal to be cast into a shape in a mold, ; and the first metal to be purposely alloyed with another metal, tin, to create bronze, . ...
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Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates ** Barite BaSO4 ** Celestite SrSO4 ** Anglesite PbSO4 ** Anhydrite CaSO4 ** Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates ** Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O ** Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O ** Hexahydrite MgSO4·6H2O ** Epsomite MgSO4·7H2O ** Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O ** Antlerite Cu3SO4(OH)4 ** ...
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Oxidized Zone
Gossan (eiserner hut or eisenhut) is intensely oxidized, weathered or decomposed rock, usually the upper and exposed part of an ore deposit or mineral vein. In the ''classic'' gossan or iron cap all that remains is iron oxides and quartz, often in the form of boxworks (which are quartz-lined cavities retaining the shape of the dissolved ore minerals). In other cases, quartz and iron oxides, limonite, goethite, and jarosite, exist as pseudomorphs, replacing the pyrite and primary ore minerals. Frequently, gossan appears as a red "stain" against the background rock and soil, due to the abundance of oxidized iron; the gossan may be a topographic positive area due to the abundance of erosion-resistant quartz and iron oxides. Although most gossans are red, orange, or yellow, black gossans from manganese oxides such as pyrolusite, manganite, and especially psilomelane form at the oxidized portion of manganese-rich mineral deposits. In the 19th and 20th centuries, gossans were important ...
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Antlerite
Antlerite is a greenish hydrous copper sulfate mineral, with the formula Cu3(SO4)(OH)4. It occurs in tabular, Acicular (crystal habit), acicular, or fibrous crystals with a vitreous lustre, vitreous luster. Originally believed to be a rare mineral, antlerite was found to be the primary ore of the Gossan, oxidised zones in several copper extraction, copper mines across the world, including the Chuquicamata mine in Chile, and the Antler mine in Arizona, United States of America, US from which it takes its name. It is chemically and optically similar in many respects to other copper minerals such as malachite and brochantite, though it can be distinguished from the former by a lack of effervescence in hydrochloric acid. Antlerite is a common corrosion product on bronze sculptures located in urban areas, where atmospheric sulfur dioxide (a common pollutant) is present. Antlerite forms mainly in sheltered areas where weathering is low, which permits accumulation of copper ions and enha ...
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Chalcanthite
Chalcanthite (, ) is a richly colored blue-green water-soluble sulfate mineral . It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanthite is more common in arid regions. Chalcanthite is a hydrate, pentahydrate and the most common member of a group of similar hydrated sulfates, the chalcanthite group. These other sulfates are identical in chemical composition to chalcanthite, with the exception of replacement of the copper ion by either manganese as jokokuite, iron as melanterite, or magnesium as pentahydrite. Other names include ''blue stone'', ''blue vitriol'', and ''copper vitriol''. Uses of chalcanthite As chalcanthite is a copper mineral, it can be used as an ore of copper. However, its ready solubility in water means that it tends to crystallize, dissolve, and recrystallize as crusts over any mine surface in more humid regions. Therefore, chalcanthite is only found in the most arid regions in sufficiently large ...
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Atacamite
Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1802 by Dmitri de Gallitzin. The Atacama Desert is also the namesake of the mineral. Occurrence Atacamite is polymorphous with botallackite, clinoatacamite, and paratacamite. Atacamite is a comparatively rare mineral, formed from primary copper minerals in the oxidation or weathering zone of arid climates. It has also been reported as a volcanic sublimate from fumarole deposits, as sulfide alteration products in black smokers. The mineral has also been found naturally on oxidized copper deposits in Chile, China, Russia, Czech Republic, Arizona, and Australia. It occurs in association with cuprite, brochantite, linarite, caledonite, malachite, chrysocolla and its polymorphs. Synthetic Occurrence Atacamite has been discovered in the patina of the Statue of Liberty, and as alteration of ancient bronze and copp ...
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Atacama
The Atacama Desert () is a desert plateau located on the Pacific coast of South America, in the north of Chile. Stretching over a strip of land west of the Andes Mountains, it covers an area of , which increases to if the barren lower slopes of the Andes are included. The Atacama Desert is the driest nonpolar desert in the world, and the second driest overall, behind some specific spots within the McMurdo Dry Valleys. It is the only true desert to receive less precipitation than polar deserts, and the largest fog desert in the world. The area has been used as an experimentation site for Mars expedition simulations due to its similarities to the Martian environment. The constant temperature inversion caused by the cool north-flowing Humboldt ocean current and the strong Pacific anticyclone contribute to the extreme aridity of the desert. The most arid region of the Atacama Desert is situated between two mountain chains, the Andes and the Chilean Coast Range, which are high ...
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Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism (geometry), prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal class ...
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