Antlerite
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Antlerite is a greenish hydrous
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
, with the formula Cu3(SO4)(OH)4. It occurs in tabular, acicular, or fibrous crystals with a vitreous luster. Originally believed to be a rare mineral, antlerite was found to be the primary ore of the oxidised zones in several copper mines across the world, including the
Chuquicamata Chuquicamata ( ; referred to as Chuqui for short) is the largest open-pit mining, open pit copper Mining, mine in terms of excavated volume in the world. It is located in the north of Chile, just outside Calama, Chile, Calama, at above sea level. ...
mine in
Chile Chile, officially the Republic of Chile, is a country in western South America. It is the southernmost country in the world and the closest to Antarctica, stretching along a narrow strip of land between the Andes, Andes Mountains and the Paci ...
, and the Antler mine in
Arizona Arizona is a U.S. state, state in the Southwestern United States, Southwestern region of the United States, sharing the Four Corners region of the western United States with Colorado, New Mexico, and Utah. It also borders Nevada to the nort ...
, US from which it takes its name. It is chemically and optically similar in many respects to other copper minerals such as
malachite Malachite () is a copper Carbonate mineral, carbonate hydroxide mineral, with the chemical formula, formula Basic copper carbonate, Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often for ...
and
brochantite Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy (mineralogist), Armand Lévy for his ...
, though it can be distinguished from the former by a lack of
effervescence Effervescence is the escape of gas from an aqueous solution and the foaming or fizzing that results from that release. The word effervescence is derived from the Latin verb ''fervere'' (to boil), preceded by the adverb ''ex''. It has the same l ...
in
hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
. Antlerite is a common corrosion product on bronze sculptures located in urban areas, where atmospheric
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
(a common pollutant) is present. Antlerite forms mainly in sheltered areas where weathering is low, which permits accumulation of copper ions and enhancement in the acidity of water films.Leygraf C, Graedel TE. Atmospheric corrosion. New York: Wiley-Interscience; 2000. In exposed areas, the main corrosion product is
brochantite Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy (mineralogist), Armand Lévy for his ...
. File:Antlerite-21367.jpg, File:Antlerite.jpg, File:Mineraly.sk_-_antlerit_2.jpg, Antlerite, Piesky,
Slovakia Slovakia, officially the Slovak Republic, is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the west, and the Czech Republic to the northwest. Slovakia's m ...


References

Copper(II) minerals Sulfate minerals Orthorhombic minerals Minerals in space group 62 {{sulfate-mineral-stub