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Tafel Equation
The Tafel equation is an equation in electrochemical kinetics relating the rate of an Electrochemistry, electrochemical reaction to the overpotential. The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel.It describes how the electrical current through an electrode depends on the voltage difference between the electrode and the bulk electrolyte for a simple, unimolecular redox reaction. : Ox + n e^- \leftrightarrows Red Where an electrochemical reaction occurs in two half reactions on separate electrodes, the Tafel equation is applied to each electrode separately. On a single electrode the Tafel equation can be stated as: where * the plus sign under the exponent refers to an anodic reaction, and a minus sign to a cathodic reaction, * \eta : overpotential, [V] * A : "Butler–Volmer equation#The limiting cases, Tafel slope", [V] * i : current density, [A/m2] * i_0 : "exch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
100905 Tafel Plot Nl
1 (one, unit, unity) is a number, Numeral (linguistics), numeral, and glyph. It is the first and smallest Positive number, positive integer of the infinite sequence of natural numbers. This fundamental property has led to its unique uses in other fields, ranging from science to sports, where it commonly denotes the first, leading, or top thing in a group. 1 is the unit (measurement), unit of counting or measurement, a determiner for singular nouns, and a gender-neutral pronoun. Historically, the representation of 1 evolved from ancient Sumerian and Babylonian symbols to the modern Arabic numeral. In mathematics, 1 is the multiplicative identity, meaning that any number multiplied by 1 equals the same number. 1 is by convention not considered a prime number. In Digital electronics, digital technology, 1 represents the "on" state in binary code, the foundation of computing. Philosophically, 1 symbolizes the ultimate reality or source of existence in various traditions. In math ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nernst Equation
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction ( half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing reduction and oxidation respectively. It was named after Walther Nernst, a German physical chemist who formulated the equation. Expression General form with chemical activities When an oxidized species () accepts a number ''z'' of electrons () to be converted in its reduced form (), the half-reaction is expressed as: : Ox + ze- -> Red The reaction quotient ('), also often called the ion activity product (''IAP''), is the ratio between the chemical activities (''a'') of the reduced form (the reductant, ) and the oxidized form (the oxidant, ). The chemical activity of a dissolved spe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History The pioneering work of chemical kinetics was done by German chemist Ludwig Wilhelmy in 1850. He experimentally studied the rate of inversion of sucrose and he used integrated rate law for the determination of the reaction kinetics of this reaction. His work was noticed 34 years later by Wilhelm Ostwald. In 1864, Peter Waage and Cato Guldberg published the law ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday's Laws Of Electrolysis
Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass () of a substance deposited or liberated at an electrode is directly proportional to the charge (, for which the SI unit is the ampere-second or coulomb). m \propto Q \quad \implies \quad \frac = Z Here, the constant of proportionality, , is called the electro-chemical equivalent (ECE) of the substance. Thus, the ECE can be defined as the mass of the substance deposited or liberated per unit charge. Second law Faraday discovered that when the same amount of electric current is passed through different electrolytes connected in series, the masses of the substances deposited or liberated at the electrodes are directly proportional to their respective chemical equivalent/ equivalent weight (). This turns out to be the molar mass () divided by the valence () : \begin & m \propto E; \quad ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faradaic Current
In electrochemistry, the faradaic current is the electric current generated by the reduction or oxidation of some chemical substance at an electrode. The net faradaic current is the algebraic sum of all the faradaic currents flowing through an indicator electrode or working electrode. Limiting current The limiting current in electrochemistry is the limiting value of a faradaic current that is approached as the rate of charge transfer to an electrode is increased. The limiting current can be approached, for example, by increasing the electric potential or decreasing the rate of mass transfer to the electrode. It is independent of the applied potential over a finite range, and is usually evaluated by subtracting the appropriate residual current from the measured total current. A limiting current can have the character of an adsorption, catalytic, diffusion, or kinetic current, and may include a migration current. Migration current The difference between the current that is actuall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrocatalyst
An electrocatalyst is a catalyst that participates in electrochemical reactions. Electrocatalysts are a specific form of catalysts that function at electrode surfaces or, most commonly, may be the electrode surface itself. An electrocatalyst can be heterogeneous such as a platinized electrode. Homogeneous electrocatalysts, which are soluble, assist in transferring electrons between the electrode and reactants, and/or facilitate an intermediate chemical transformation described by an overall half reaction. Major challenges in electrocatalysts focus on fuel cells. Background and theory An electrocatalyst lowers the activation energy required for an electrochemical reaction. Some electrocatalysts change the potential at which oxidation and reduction processes occur. In other cases, an electrocatalyst can impart selectivity by favoring specific chemical interaction at an electrode surface. Given that electrochemical reactions occur when electrons are passed from one chemical sp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Overpotential
In electrochemistry, overpotential is the potential difference (voltage) between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. The term is directly related to a cell's ''voltage efficiency''. In an electrolytic cell the existence of overpotential implies that the cell requires more energy than thermodynamically expected to drive a reaction. In a galvanic cell the existence of overpotential means less energy is recovered than thermodynamics predicts. In each case the extra/missing energy is lost as heat. The quantity of overpotential is specific to each cell design and varies across cells and operational conditions, even for the same reaction. Overpotential is experimentally determined by measuring the potential at which a given current density (typically small) is achieved. Thermodynamics The four possible polarities of overpotentials are listed below. * An electrolytic cell' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Double Layer (surface Science)
Double layer may refer to: * Double layer (biospecific), the surface where two different phases of matter are in contact * Double layer (plasma physics), a structure in a plasma and consists of two parallel layers with opposite electrical charge * Double layer (surface science), a structure that appears on the surface of an object when it is placed into a liquid * Double layer forces, which occur between charged objects across liquids * Double layer potential, a solution of Laplace's equation * Double layer suturing, two layers of sutures, first in a deep level of a tissue and then at a more superficial level * DVD+R DL or Double layer, a DVD format {{disambig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen, or hydroxide. Rusting, the formation of red-orange iron oxides, is a well-known example of electrochemical corrosion. This type of corrosion typically produces oxides or salts of the original metal and results in a distinctive coloration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including mechanical strength, appearance, and permeability to liquids and ga ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ohm's Law
Ohm's law states that the electric current through a Electrical conductor, conductor between two Node (circuits), points is directly Proportionality (mathematics), proportional to the voltage across the two points. Introducing the constant of proportionality, the Electrical resistance, resistance, one arrives at the three mathematical equations used to describe this relationship: V = IR \quad \text\quad I = \frac \quad \text\quad R = \frac where is the current through the conductor, ''V'' is the voltage measured across the conductor and ''R'' is the electrical resistance, resistance of the conductor. More specifically, Ohm's law states that the ''R'' in this relation is constant, independent of the current. If the resistance is not constant, the previous equation cannot be called ''Ohm's law'', but it can still be used as a definition of Electrical resistance and conductance#Static and differential resistance, static/DC resistance. Ohm's law is an empirical law, empirical rel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Universal Gas Constant
The molar gas constant (also known as the gas constant, universal gas constant, or ideal gas constant) is denoted by the symbol or . It is the molar equivalent to the Boltzmann constant, expressed in units of energy per temperature, temperature increment per amount of substance, rather than energy per temperature increment per ''particle''. The constant is also a combination of the constants from Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. It is a physical constant that is featured in many fundamental equations in the physical sciences, such as the ideal gas law, the Arrhenius equation, and the Nernst equation. The gas constant is the constant of proportionality that relates the energy scale in physics to the temperature scale and the scale used for amount of substance. Thus, the value of the gas constant ultimately derives from historical decisions and accidents in the setting of units of energy, temperature and amount of substance. The Boltzmann constan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Constant
In physical chemistry, the Faraday constant (symbol , sometimes stylized as ℱ) is a physical constant defined as the quotient of the total electric charge () by the amount () of elementary charge carriers in any given sample of matter: it is expressed in units of coulombs per mole (C/mol). As such, it represents the " molar elementary charge", that is, the electric charge of one mole of elementary carriers (e.g., protons). It is named after the English scientist Michael Faraday. Since the 2019 revision of the SI, the Faraday constant has an exactly defined value, the product of the elementary charge (, in coulombs) and the Avogadro constant (, in reciprocal moles): : Derivation The Faraday constant can be thought of as the proportionality factor between the charge in coulombs (used in physics and in practical electrical measurements) and the amount of substance in moles (used in chemistry), and is therefore of particular use in electrochemistry, particularly in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
