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Sulfur Dye
Sulfur dyes are the most commonly used dyes manufactured for cotton in terms of volume. They are inexpensive, generally have good wash-fastness, and are easy to apply. Sulfur dyes are predominantly black, brown, and dark blue. Red sulfur dyes are unknown, although a pink or lighter scarlet color is available. Organic Chemistry Sulfur linkages are the integral part of chromophore in sulfur dyes. They are organosulfur compounds consisting of sulfide (–S–), disulfide (–S–S–) and polysulfide (–Sn–) links in heterocyclic rings. They feature thiazoles, thiazone, thianthrene, and phenothiazonethioanthrone subunits. Being nonionic, sulfur dyes are insoluble in water. Process Dyeing includes a few stages, viz. reduction, dyeing, washing, oxidation, soaping, and final washing. The anion is developed on reducing and solubilising at boil when it shows affinity for cellulose. Sodium sulfide (Na2S), the reducing and solubilising agent, performs both reduction and solubilisati ...
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Cotton
Cotton (), first recorded in ancient India, is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor percentages of waxes, fats, pectins, and water. Under natural conditions, the cotton bolls will increase the dispersal of the seeds. The plant is a shrub native to tropical and subtropical regions around the world, including the Americas, Africa, Egypt and India. The greatest diversity of wild cotton species is found in Mexico, followed by Australia and Africa. Cotton was independently domesticated in the Old and New Worlds. The fiber is most often spun into yarn or thread and used to make a soft, breathable, and durable textile. The use of cotton for fabric is known to date to prehistoric times; fragments of cotton fabric dated to the fifth millennium BC have been found in the Indus Valley civilizat ...
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Indophenol
Indophenol is an organic compound with the formula OC6H4NC6H4OH. It is deep blue dye that is the product of the Berthelot's reaction, a common test for ammonia. The indophenol group, with various substituents in place of O''H'' and various ring substitutions, is found in many dyes used in hair coloring and textiles. Indophenol is used in hair dyes, lubricants, redox materials, liquid crystal displays, fuel cells and chemical-mechanical polishing. It is an environmental pollutant and is toxic to fish. Berthelot test In the Berthelot test (1859), a sample suspected of containing ammonia is treated with sodium hypochlorite and phenol. The formation of indophenol is used to determine ammonia and paracetamol by spectrophotometry. Other phenols can be used. Dichlorophenol-indophenol (DCPIP), a form of indophenol, is often used to determine the presence of vitamin C Vitamin C (also known as ascorbic acid and ascorbate) is a water-soluble vitamin found in citrus and ot ...
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Glucose
Glucose is a sugar with the Chemical formula#Molecular formula, molecular formula , which is often abbreviated as Glc. It is overall the most abundant monosaccharide, a subcategory of carbohydrates. It is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using energy from sunlight. It is used by plants to make cellulose, the most abundant carbohydrate in the world, for use in cell walls, and by all living Organism, organisms to make adenosine triphosphate (ATP), which is used by the cell as energy. In energy metabolism, glucose is the most important source of energy in all organisms. Glucose for metabolism is stored as a polymer, in plants mainly as amylose and amylopectin, and in animals as glycogen. Glucose circulates in the blood of animals as blood sugar. The naturally occurring form is -glucose, while its Stereoisomerism, stereoisomer L-glucose, -glucose is produced synthetically in comparatively small amounts and is less biologicall ...
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Effluent
Effluent is wastewater from sewers or industrial outfalls that flows directly into surface waters, either untreated or after being treated at a facility. The term has slightly different meanings in certain contexts, and may contain various pollutants depending on the source. Definition Effluent is defined by the United States Environmental Protection Agency (EPA) as "wastewater–treated or untreated–that flows out of a treatment plant, sewer, or industrial outfall. Generally refers to wastes discharged into surface waters". The ''Compact Oxford English Dictionary'' defines effluent as "liquid waste or sewage discharged into a river or the sea". Wastewater is not usually described as effluent while being recycled, re-used, or treated until it is released to surface water. Wastewater percolated or injected into groundwater may not be described as effluent if soil is assumed to perform treatment by filtration or ion exchange; although concealed flow through fractured ...
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Sodium Bromate
Sodium bromate, the inorganic compound with the chemical formula of NaBrO3, is the sodium salt of bromic acid. It is a strong oxidant. Uses Sodium bromate is mainly used in continuous or batch dyeing processes involving sulfur or vat dyes and as a hair-permagent, chemical agent, or gold solvent in gold mines when used with sodium bromide. Production Sodium bromate can be produced from a solution of sodium carbonate and bromine using chlorine gas as the oxidising agent. : It may also be produced by the electrolytic oxidation of aqueous sodium bromide. Human health issues Bromate in drinking water is undesirable because it is a suspected human carcinogen. Its presence in Coca-Cola's Dasani Dasani () is a brand of bottled water created by the Coca-Cola Company, launched in 1999. It is one of many List of Coca-Cola brands, brands of Coca-Cola bottled water sold around the world. The product is filtered and bottled. Marketing Un ... bottled water forced a recall of tha ...
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Hydrogen Peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscosity, viscous than Properties of water, water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as both a monopropellant and an oxidizer in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes slowly into water and elemental oxygen when exposed to light, and rapidly in the presence of organic or reactive compounds. It is typically stored with a Stabilizer (chemistry), stabilizer in a weakly acidic solution in an opaque bottle. Hydrogen peroxide is found in biological systems including the human body. Enzymes that u ...
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Sodium Hydrosulfide
Sodium hydrosulfide is the chemical compound with the formula NaSH. This compound is the product of the half-neutralization of hydrogen sulfide () with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar purposes. Solid NaSH is colorless. The solid has an odor of owing to hydrolysis by atmospheric moisture. In contrast with sodium sulfide (), which is insoluble in organic solvents, NaSH, being a 1:1 electrolyte, is more soluble. Structure and properties Crystalline NaSH undergoes two phase transitions. At temperatures above 360 K, NaSH adopts the NaCl structure, which implies that the behaves as a spherical anion owing to its rapid rotation, leading to equal occupancy of eight equivalent positions. Below 360 K, a rhombohedral structure forms, and the sweeps out a discoidal shape. Below 114 K, the structure becomes monoclinic. The analogous rubidium and potassium compounds behave similarly. NaSH has a relatively low melting p ...
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Sodium Sulfide
Sodium sulfide is a chemical compound with the formula Na2 S, or more commonly its hydrate Na2S·9 H2O. Both the anhydrous and the hydrated salts are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides. It is commonly supplied as a crystalline mass, in flake form, or as a fused solid. They are water-soluble, giving strongly alkaline solutions. When exposed to moisture, Na2S immediately hydrates to give sodium hydrosulfide. Sodium sulfide has an unpleasant rotten egg smell due to the hydrolysis to hydrogen sulfide in moist air. Some commercial samples are described as Na2S·''x''H2O, where a weight percentage of Na2S is specified. Commonly available grades have around 60% Na2S by weight, which means that ''x'' is around 3. These grades of sodium sulfide are often marketed as 'sodium sulfide flakes'. These samples consist of NaSH, NaOH, and water. Structure The structures of sodium sulfides have bee ...
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Benzothiazole
Benzothiazole, or more specifically 1,3-benzothiazole, is an aromatic heterocyclic compound with the chemical formula . It is colorless, slightly viscous liquid. Although the parent compound, benzothiazole is not widely used, many of its derivatives are found in commercial products or in nature. Firefly luciferin can be considered a derivative of benzothiazole. It has a sulfurous odor and meaty flavor. The three structural isomers of benzothizaole are 1,3-benzothiazole, 1,2-benzothiazole and 2,1-benzothiazole. Structure and reactivity Benzothiazoles consist of a 5-membered 1,3- thiazole ring fused to a benzene ring. The nine atoms of the bicycle and the attached substituents are coplanar. The heterocyclic core of the molecule is readily substituted at the methyne (CH) centre in the thiazole ring. Thiazole is electron-withdrawing. Synthesis and biosynthesis Benzothiazoles are typically prepared by treatment of 2-mercaptoaniline. For example, acid chlorides are effective: :C6 ...
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Diaminotoluene
Toluenediamine may refer to these isomeric organic compounds with the formula C6H3(NH2)2(CH3): *2,4-Diaminotoluene, precursor to toluene diisocyanate and azo dye. *2,6-Diaminotoluene, a common impurity in 2,4-diaminotoluene *2,5-Diaminotoluene, precursor to hair dyes. {{Chemistry index Toluenes ...
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