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Smithsonite
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate ( Zn CO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion. The distinct mineral smithsonite was named in 1832 by François Sulpice Beudant in honor of English scientist James Smithson (c. 1765–1829), who first identified the mineral in 1802. Smithsonite is a variably colored trigonal mineral which only rarely is found in well formed crystals. The typical habit is as earthy botryoidal masses. It has a Mohs hardness of 4.5 and a specific gravity of 4.4 to 4.5. Smithsonite occurs as a secondary mineral in the weathering or oxidation zone of zinc-bearing ore deposits. It sometimes occurs as replacement bodies in carbonate rocks and as such may constitute zinc ore. It commonly occurs in association with hemimorp ...
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Carbonate Mineral
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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Calamine (mineral)
Calamine is a historic name for an ore of zinc. The name ''calamine'' was derived from ''lapis calaminaris'', a Latin correption of Greek ''cadmia (καδμία)'', the old name for zinc ores in general. The name of the Belgium, Belgian town of Kelmis, ''La Calamine'' in French language, French, which was home to a zinc mine, comes from this. In the 18th and 19th centuries large ore mines could be found near the Germany, German village of Breinigerberg. During the early 19th century it was discovered that what had been thought to be one ore was actually two distinct minerals: * Zinc carbonate ZnCarbon, COxygen, O3 or smithsonite and * Zinc silicate Zn4Silicon, Si2O7(OHydrogen, H)2·H2O or hemimorphite. Although chemically and crystallographically quite distinct, the two minerals exhibit similar massive or botryoidal external form and are not readily distinguished without detailed chemical or physical analysis. The first person to separate the minerals was the Great Britain, Bri ...
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James Smithson
James Smithson (c. 1765 – 27 June 1829) was a British chemist and mineralogist. He published numerous scientific papers for the Royal Society during the early 1800s as well as defining Calamine (mineral), calamine, which would eventually be renamed after him as "smithsonite". He was the founding donor of the Smithsonian Institution, which also bears his name. Born in Paris, France, as the illegitimate child of Elizabeth Hungerford Keate Macie and Hugh Percy, 1st Duke of Northumberland, Hugh Percy (born Hugh Smithson), the 1st Duke of Northumberland, he was given the French name Jacques-Louis Macie. His birth date was not recorded and the exact location of his birth is unknown; it is possibly in the Pentemont Abbey. Shortly after his birth he British nationality law, naturalized to Britain where his name was Anglicisation, anglicized to James Louis Macie. He adopted his father's original surname of Smithson in 1800, following his mother's death. He attended university at Pembr ...
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Hydrozincite
Hydrozincite, also known as zinc bloom or marionite, is a white carbonate mineral consisting of Zn5( CO3)2( OH)6. It is usually found in massive rather than crystalline form. It occurs as an oxidation product of zinc ores and as post mine incrustations. It occurs associated with smithsonite, hemimorphite, willemite, cerussite, aurichalcite, calcite and limonite. It was first described in 1853 for an occurrence in Bad Bleiberg, Carinthia, Austria Austria, formally the Republic of Austria, is a landlocked country in Central Europe, lying in the Eastern Alps. It is a federation of nine Federal states of Austria, states, of which the capital Vienna is the List of largest cities in Aust ... and named for its chemical content. References Mineral galleries data External links * Carbonate minerals Luminescent minerals Minerals described in 1853 Minerals in space group 12 Monoclinic minerals Zinc minerals {{carbonate-mineral-stub ...
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Willemite
Willemite is a zinc silicate mineral () and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a variant in which part of the zinc is partly replaced by manganese, it occurs in solid brown masses. It was discovered in 1829 in the Belgian Vieille-Montagne mine. Armand Lévy was shown samples by a student at the university where he was teaching. Lévy named it after William I of the Netherlands (it is occasionally spelled villemite). The troostite variety is named after Dutch-American mineralogist Gerard Troost. Occurrence Willemite is usually formed as an alteration of previously existing sphalerite ore bodies, and is usually associated with limestone. It is also found in marble and may be the result of a metamorphism of earlier hemimorphite or smithsonite. Crystals have the form of hexagonal prisms terminated by rhombohedral planes: ...
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Greenockite
Greenockite, also ''cadmium blende'' or ''cadmium ochre'' (obsolete) is a rare cadmium bearing metal sulfide mineral consisting of cadmium sulfide (CdS) in crystalline form. Greenockite crystallizes in the hexagonal system. It occurs as massive encrustations and as hemimorphic six-sided pyramidal crystals which vary in color from a honey yellow through shades of red to brown. The Mohs hardness is 3 to 3.5 and the specific gravity is 4.8 to 4.9. Greenockite belongs to the wurtzite group and is isostructural with it at high temperatures. It is also isostructural with sphalerite at low temperatures. It occurs with other sulfide minerals such as sphalerite and galena, and is the only ''ore mineral'' of cadmium. Most cadmium is recovered as a byproduct of copper, zinc, and lead mining. It is also known from the lead-zinc districts of the central United States. It was first recognized in 1840 in Bishopton, Scotland, during the cutting of a tunnel for the Glasgow, Paisley and Greenoc ...
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Siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly substitute for the iron, resulting in the siderite-smithsonite, siderite-magnesite, and siderite-rhodochrosite solid solution series. Siderite has Mohs hardness of 3.75 to 4.25, a specific gravity of 3.96, a white streak and a vitreous or pearly luster. Siderite is antiferromagnetic below its Néel temperature of that can assist in its identification. It crystallizes in the trigonal crystal system; crystals are rhombohedral in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese. Siderite is commonly found in hydrothermal veins, and is associated with barite, fluorite, galena, and others. It is also a common ...
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Iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most abundant element in the Earth's crust, being mainly deposited by meteorites in its metallic state. Extracting usable metal from iron ores requires kilns or furnaces capable of reaching , about 500 °C (900 °F) higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BC and the use of iron tools and weapons began to displace copper alloys – in some regions, only around 1200 BC. That event is considered the transition from the Bronze Age to the Iron Age. In the modern world, iron alloys, such as steel, stainless steel, cast iron and special steels, are by far the most common industrial metals, due to their mechan ...
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Rhodochrosite
Rhodochrosite is a manganese carbonate mineral with chemical composition Manganese(II) carbonate, MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It Streak (mineralogy), streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal system, trigonal, with a structure and Cleavage (crystal), cleavage in the carbonate rhombohedral system. The carbonate ions () are arranged in a triangular planar configuration, and the manganese ions (Mn2+) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Ameri ...
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Manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent, as a rubber additive, and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese is commonly found in labo ...
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Solid Solution
A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" is used to describe the intimate mixing of components at the atomic level and distinguishes these homogeneous materials from physical mixtures of components. Two terms are mainly associated with solid solutions – ''solvents'' and ''solutes,'' depending on the relative abundance of the atomic species. In general if two compounds are isostructural then a solid solution will exist between the end members (also known as parents). For example sodium chloride and potassium chloride have the same cubic crystal structure so it is possible to make a pure compound with any ratio of sodium to potassium (Na1-xKx)Cl by dissolving that ratio of NaCl and KCl in water and then evaporating the solution. A member of this family is sold under the bra ...
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Anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and therefore has a high specific gravity of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure. It was first recognized as a mineral species by William Withering in 1783, who discovered it in the Parys copper-mine in Anglesey; the name anglesite, from this locality, was given by F. S. Beudant in 1832. The crystals from Anglesey, which were formerly found abundantly on a matrix of dull limonite, are small in size and simple in form, being usually bounded by four faces of a prism and four faces of a dome; they are brownish-yellow in colour owing to a stain of limonite. Crystals from some other localities, notably from in Sardinia, are transparent a ...
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