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PBDE
Polybrominated diphenyl ethers or PBDEs, are a class of organobromine compounds that are used as flame retardants. Like other brominated flame retardants, PBDEs have been used in a wide array of products, including building materials, electronics, furnishings, motor vehicles, airplanes, plastics, polyurethane foams, and textiles. They are structurally akin to polychlorinated diphenyl ethers (PCDEs), polychlorinated biphenyls (PCBs) and other polyhalogenated compounds, consisting of two halogenated aromatic rings. PBDEs are classified according to the average number of bromine atoms in the molecule. The health hazards of these chemicals have attracted increasing scrutiny, and they have been shown to reduce fertility in humans at levels found in households. Because of their toxicity and persistence, the industrial production of some PBDEs is restricted under the Stockholm Convention, a treaty to control and phase out major persistent organic pollutants (POPs). Classes of PBDEs ...
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Flame Retardant
The term flame retardants subsumes a diverse group of chemicals that are added to manufactured materials, such as plastics and textiles, and surface finishes and coatings. Flame retardants are activated by the presence of an ignition source and are intended to prevent or slow the further development of ignition by a variety of different physical and chemical methods. They may be added as a copolymer during the polymerisation process, or later added to the polymer at a moulding or extrusion process or (particularly for textiles) applied as a topical finish. Mineral flame retardants are typically additive while organohalogen and organophosphorus compounds can be either reactive or additive. Classes Both Reactive and Additive Flame retardants types, can be further separated into four distinct classes: * Minerals such as aluminium hydroxide (ATH), magnesium hydroxide (MDH), huntite and hydromagnesite, various hydrates, red phosphorus, and boron compounds, mostly borates. ...
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Decabromodiphenyl Ether
Decabromodiphenyl ether (also known as decaBDE, deca-BDE, DBDE, deca, decabromodiphenyl oxide, DBDPO, or bis(pentabromophenyl) ether) is a brominated flame retardant which belongs to the group of polybrominated diphenyl ethers (PBDEs). Composition, uses, and production Commercial decaBDE is a technical mixture of different PBDE congeners, with PBDE congener number 209 (decabromodiphenyl ether) and nonabromodiphenyl ether being the most common.Joint Research Centre European inventory of Existing Commercial chemical Substances The term decaBDE alone refers to only decabromodiphenyl ether, the single "fully brominated" PBDE.Agency for Toxic Substances and Disease RegistryToxicological Profile for Polybrominated Biphenyls and Polybrominated Diphenyl Ethers (PBBs and PBDEs).Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service, September 2004. DecaBDE is a flame retardant. The chemical "is always used in conjunction with antimony trioxide" in polymers, m ...
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Brominated Flame Retardant
Brominated flame retardants (BFRs) are organobromine compounds that have an inhibitory effect on combustion chemistry and tend to reduce the flammability of products containing them. The brominated variety of commercialized chemical flame retardants comprise approximately 19.7% of the market. They are effective in plastics and textile applications like electronics, clothes and furniture. Types of compounds Many different BFRs are produced synthetically with widely varying chemical properties. There are several groups: * Polybrominated diphenyl ethers (PBDEs): DecaBDE, OctaBDE (not manufactured anymore), PentaBDE (not manufactured anymore, the first BFR, commercialized in the 1950s) * Polybrominated biphenyl (PBB), not manufactured anymore * Brominated cyclohydrocarbons * Other brominated flame retardants with different properties and mechanisms Decabromodiphenyl ether (''Deca-BDE'' or ''DeBDE'') - In August 2012, the UK authorities proposed decabromodiphenyl ether (Deca-BDE o ...
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Pentabromodiphenyl Ether
Pentabromodiphenyl ether (also known as pentabromodiphenyl oxide) is a brominated flame retardant which belongs to the group of polybrominated diphenyl ethers (PBDEs). Because of their toxicity and persistence, their industrial production is to be eliminated under the Stockholm Convention, a treaty to control and phase out major persistent organic pollutants (POP). Composition, uses, and production Commercial pentaBDE is a technical mixture of different PBDE congeners, with BDE-47 (2,2',4,4'- tetrabromodiphenyl ether) and BDE-99 (2,2',4,4',5-pentabromodiphenyl ether) as the most abundant.Persistent Organic Pollutants Review Committee of the Stockholm ConventionCommercial Pentabromodiphenyl Ether: Risk Management Evaluation.United Nations Environment Programme, August 2007. The term pentaBDE alone refers to isomers of pentabromodiphenyl ether (PBDE congener numbers 82-127).Agency for Toxic Substances and Disease RegistryToxicological Profile for Polybrominated Biphenyls and Polybro ...
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Octabromodiphenyl Ether
Octabromodiphenyl ether (octaBDE, octa-BDE, OBDE, octa, octabromodiphenyl oxide, OBDPO) is a brominated flame retardant which belongs to the group of polybrominated diphenyl ethers (PBDEs). Composition, uses, and production Commercial octaBDE (also known as "Octabrom") is a technical mixture of different PBDE congeners having an average of 7.2 to 7.7 bromine atoms per molecule of diphenyl ether.United States Patent and Trademark OfficeMelting point enhancement of partially brominated diphenyl oxide mixtures.US Patent 5,000,879 issued on March 19, 1991. The predominant congeners in commercial octaBDE are those of heptabromodiphenyl ether and octaBDE.Ad hoc working group on C-Octabromodiphenyl ether under the Persistent Organic Pollutants Review Committee of the Stockholm ConventionDraft risk profile: commercial octabromodiphenyl ether.United Nations Environment Programme, August 2007. The term octaBDE alone refers to isomers of octabromodiphenyl ether (PBDE congener numbers 194–2 ...
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Polyhalogenated Compound
Polyhalogenated compounds (PHCs) are any compounds with multiple substitutions of halogens. They are of particular interest and importance because they bioaccumulate in humans, and comprise a superset of which has many toxic and carcinogenic industrial chemicals as members. PBDEs, PCBs, dioxins (PCDDs) and PFCs are all polyhalogenated compounds. They are generally non-miscible in organic solvents or water, but miscible in some hydrocarbons from which they often derive. Uses PHCs are used in a vast array of manufactured products, from wood treatments to cookware coatings, to non-stick, waterproof, and fire-resistant coatings, cosmetics, medicine, electronic fluids, food containers, and wrappings, in everything from furniture and furnishings, automobiles, airplanes, plastics, clothing and cloth, surgery, insulation, adhesives, paints, sealants, lubricating oils, polyurethane foams, cancer therapy, and medical imaging. They are also heavily used in pest control. Safety PHCs i ...
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Congener (chemistry)
In chemistry, congeners are chemical substances "related to each other by origin, structure, or function". Common origin and structure Any significant quantity of a polyhalogenated compound is by default a blend of multiple molecule types because each molecule forms independently, and chlorine and bromine do not strongly select which site(s) they bond to. * Polychlorinated biphenyls (PCBs) are a family of 209 congeners. * Polybrominated biphenyls and polychlorinated diphenyl ethers are also families of 209 congeners. Similarly polychlorinated dibenzodioxins, polychlorinated dibenzofurans, polychlorinated terphenyls, polychlorinated naphthalene, polychloro phenoxy phenol, and polybrominated diphenyl ethers (PBDEs) (pentabromodiphenyl ether, octabromodiphenyl ether, decabromodiphenyl ether), etc. are also groups of congeners. Common origin * Congener (alcohol), substances other than alcohol (desirable or undesirable) also produced during fermentation. *Congeners of oleic a ...
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Persistent Organic Pollutants
Persistent organic pollutants (POPs), sometimes known as "forever chemicals", are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. They are toxic chemicals that adversely affect human health and the environment around the world. Because they can be transported by wind and water, most POPs generated in one country can and do affect people and wildlife far from where they are used and released. The effect of POPs on human and environmental health was discussed, with intention to eliminate or severely restrict their production, by the international community at the Stockholm Convention on Persistent Organic Pollutants in 2001. Most POPs are pesticides or insecticides, and some are also solvents, pharmaceuticals, and industrial chemicals. Although some POPs arise naturally (e.g. from volcanoes), most are man-made. The "dirty dozen" POPs identified by the Stockholm Convention include aldrin, chlordane, die ...
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Halogen
The halogens () are a group in the periodic table consisting of five or six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), astatine (At), and tennessine (Ts). In the modern IUPAC nomenclature, this group is known as group 17. The word "halogen" means "salt former" (or "salt maker"). When halogens react with metals, they produce a wide range of salts, including calcium fluoride, sodium chloride (common table salt), silver bromide and potassium iodide. The group of halogens is the only periodic table group that contains elements in three of the main states of matter at standard temperature and pressure. All of the halogens form acids when bonded to hydrogen. Most halogens are typically produced from minerals or salts. The middle halogens—chlorine, bromine, and iodine—are often used as disinfectants. Organobromides are the most important class of flame retardants, while elemental halogens are dangerous and can be toxic. Hist ...
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Marine Mammal
Marine mammals are aquatic mammals that rely on the ocean and other marine ecosystems for their existence. They include animals such as Pinniped, seals, Cetacea, whales, Sirenia, manatees, sea otters and polar bears. They are an informal group, unified only by their reliance on marine environments for feeding and survival. Marine mammal adaptation to an aquatic lifestyle varies considerably between species. Both Cetacea, cetaceans and Sirenia, sirenians are fully aquatic and therefore are obligate water dwellers. Seals and sea-lions are semiaquatic; they spend the majority of their time in the water but need to return to land for important activities such as mating, breeding in the wild, breeding and molting. In contrast, both otters and the polar bear are much less adapted to aquatic living. The diets of marine mammals vary considerably as well; some eat zooplankton, others eat fish, squid, shellfish, or sea-grass, and a few eat other mammals. While the number of marine mammals ...
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Canada
Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by total area. Its southern and western border with the United States, stretching , is the world's longest binational land border. Canada's capital is Ottawa, and its three largest metropolitan areas are Toronto, Montreal, and Vancouver. Indigenous peoples have continuously inhabited what is now Canada for thousands of years. Beginning in the 16th century, British and French expeditions explored and later settled along the Atlantic coast. As a consequence of various armed conflicts, France ceded nearly all of its colonies in North America in 1763. In 1867, with the union of three British North American colonies through Confederation, Canada was formed as a federal dominion of four provinces. This began an accretion of provinces and ...
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