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Nitrogen Trifluoride
Nitrogen trifluoride is the inorganic compound with the formula (). It is a colorless, non-flammable, toxic gas with a slightly musty odor. In contrast with ammonia, it is nonbasic. It finds increasing use within the manufacturing of flat-panel displays, photovoltaics, LEDs and other microelectronics. is a greenhouse gas, with a global warming potential (GWP) 17,200 times greater than that of when compared over a 100-year period. Synthesis and reactivity Nitrogen trifluoride can be prepared from the elements in the presence of an electric discharge. In 1903, Otto Ruff prepared nitrogen trifluoride by the electrolysis of a molten mixture of ammonium fluoride and hydrogen fluoride. It is far less reactive than the other nitrogen trihalides nitrogen trichloride, nitrogen tribromide, and nitrogen triiodide, all of which are explosive. Alone among the nitrogen trihalides it has a negative enthalpy of formation. It is prepared in modern times both by direct reaction of a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Critical Pressure
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas comes into a supercritical phase, and so cannot be liquefied by pressure alone. At the critical point, defined by a ''critical temperature'' ''T''c and a ''critical pressure'' ''p''c, phase boundaries vanish. Other examples include the liquid–liquid critical points in mixtures, and the ferromagnet–paramagnet transition ( Curie temperature) in the absence of an external magnetic field. Liquid–vapor critical point Overview For simplicity and clarity, the generic notion of ''critical point'' is best introduced by discussing a specific example, the vapor–liquid critical point. This was the first critical point to be discovered, and it is still the best known an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Toxicity
Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacteria, bacterium, or plant, as well as the effect on a substructure of the organism, such as a cell (biology), cell (cytotoxicity) or an organ such as the liver (hepatotoxicity). Sometimes the word is more or less synonymous with poison#Poisoning, poisoning in everyday usage. A central concept of toxicology is that the effects of a toxicant are Dose (biochemistry), dose-dependent; even water can lead to water intoxication when taken in too high a dose, whereas for even a very toxic substance such as snake venom there is a dose below which there is no detectable toxic effect. Toxicity is species-specific, making cross-species analysis problematic. Newer paradigms and metrics are evolving to bypass animal testing, while maintaining the concept of toxicity endpoints. Etymology In Ancient G ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Fluoride
Hydrogen fluoride (fluorane) is an Inorganic chemistry, inorganic compound with chemical formula . It is a very poisonous, colorless gas or liquid that dissolves in water to yield hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers such as polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils near room temperature, a much higher temperature than other hydrogen halides. Hydrogen fluoride is an extremely dangerous gas, forming corrosive and penetrating hydrofluoric acid upon contact with moisture. The gas can also cause blindness by rapid destruction of the corneas. History In 1771 Carl Wilhelm Scheele prepared the aqueous solution, hydrofluoric acid in large quantities, although hydrofluoric acid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Fluoride
Ammonium fluoride is the inorganic compound with the formula NH4F. It crystallizes as small colourless prisms, having a sharp saline taste, and is highly soluble in water. Like all fluoride salts, it is moderately toxic in both acute and chronic overdose. Crystal structure Ammonium fluoride adopts the wurtzite crystal structure, in which both the ammonium cations and the fluoride anions are stacked in ABABAB... layers, each being tetrahedrally surrounded by four of the other. There are N−H···F hydrogen bonds between the anions and cations. This structure is very similar to ice, and ammonium fluoride is the only substance which can form mixed crystals with water. Reactions On passing hydrogen fluoride gas (in excess) through the salt, ammonium fluoride absorbs the gas to form the addition compound ammonium bifluoride. The reaction occurring is: :NH4F + HF → NH4HF2 Ammonium fluoride sublimes when heated—a property common among ammonium salts. In the sublimation, the salt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Otto Ruff
Otto Ruff (30 December 1871 – 17 September 1939) was a German chemist. Life Otto Ruff was born in Schwäbisch Hall, Württemberg. After becoming a pharmacist under the supervision of Carl Magnus von Hell (known from the Hell-Volhard-Zelinsky halogenation) at the University of Stuttgart he joined the group of Hermann Emil Fischer at the University of Berlin. Fischer was noted for his work on carbohydrates (sugars) and so Ruff started his career as an organic chemist. In 1898 he published his work on the transformation of d-Glucose to d-Arabinose, later called the Ruff degradation. Supported by the far-sighted Fischer, who recognized that while organic chemistry was now mature, physical chemistry was growing rapidly, Ruff became head of the new inorganic department in Berlin, working alongside Alfred Stock who was five years his junior. This drastic change in subject benefited Ruff during his work on chlorides sulfur compounds. In 1902 he married Meta Richter, a pharmacist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
The New York Times
''The New York Times'' (''NYT'') is an American daily newspaper based in New York City. ''The New York Times'' covers domestic, national, and international news, and publishes opinion pieces, investigative reports, and reviews. As one of the longest-running newspapers in the United States, the ''Times'' serves as one of the country's Newspaper of record, newspapers of record. , ''The New York Times'' had 9.13 million total and 8.83 million online subscribers, both by significant margins the List of newspapers in the United States, highest numbers for any newspaper in the United States; the total also included 296,330 print subscribers, making the ''Times'' the second-largest newspaper by print circulation in the United States, following ''The Wall Street Journal'', also based in New York City. ''The New York Times'' is published by the New York Times Company; since 1896, the company has been chaired by the Ochs-Sulzberger family, whose current chairman and the paper's publ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Geophysical Research Letters
''Geophysical Research Letters'' is a biweekly peer-reviewed scientific journal of geoscience published by the American Geophysical Union that was established in 1974. The editor-in-chief iKristopher Karnauskas Aims and scope The journal aims for rapid publication of concise research reports on one or more of the disciplines covered by the American Geophysical Union, such as atmospheric sciences, solid Earth, space science, oceanography, hydrology, land surface processes, and the cryosphere. The journal also publishes invited reviews that cover advances achieved during the past two or three years. The target readership is the earth science community, the broader scientific community, and the general public. Abstracting and indexing This journal is abstracted and indexed in: According to the 2020 ''Journal Citation Reports'', the journal has a 2019 impact factor of 4.58. ''Geophysical Research Letters'' was also the 5th most cited publication on climate change Pres ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intergovernmental Panel On Climate Change
The Intergovernmental Panel on Climate Change (IPCC) is an intergovernmental body of the United Nations. Its job is to "provide governments at all levels with scientific information that they can use to develop climate policies". The World Meteorological Organization (WMO) and the United Nations Environment Programme (UNEP) set up the IPCC in 1988. The United Nations General Assembly, United Nations endorsed the creation of the IPCC later that year. It has a secretariat in Geneva, Switzerland, hosted by the WMO. It has 195 Member states of the United Nations, member states who govern the IPCC. The member states elect a bureau of scientists to serve through an assessment cycle. A cycle is usually six to seven years. The bureau selects experts in their fields to prepare IPCC reports. There is a formal nomination process by governments and observer organizations to find these experts. The IPCC has three working groups and a task force, which carry out its scientific work. The IPCC ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Global Warming Potential
Global warming potential (GWP) is a measure of how much heat a greenhouse gas traps in the atmosphere over a specific time period, relative to carbon dioxide (). It is expressed as a multiple of warming caused by the same mass of carbon dioxide (). Therefore, by definition has a GWP of 1. For other gases it depends on how strongly the gas absorbs thermal radiation, how quickly the gas leaves the atmosphere, and the time frame considered. For example, Methane emissions, methane has a GWP over 20 years (GWP-20) of 81.2. meaning that, a Fugitive gas emissions, leak of a tonne of methane is equivalent to emitting 81.2 tonnes of carbon dioxide measured over 20 years. As methane has a much shorter atmospheric lifetime than carbon dioxide, its GWP is much less over longer time periods, with a GWP-100 of 27.9 and a GWP-500 of 7.95. The carbon dioxide equivalent (e or eq or -e or -eq) can be calculated from the GWP. For any gas, it is the mass of that would warm the earth as much as the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Greenhouse Gas
Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. The Earth is warmed by sunlight, causing its surface to radiate heat, which is then mostly absorbed by greenhouse gases. Without greenhouse gases in the atmosphere, the average temperature of Earth's surface would be about , rather than the present average of .Le Treut, H., R. Somerville, U. Cubasch, Y. Ding, C. Mauritzen, A. Mokssit, T. Peterson and M. Prather, 2007:Chapter 1: Historical Overview of Climate Change. In:Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. olomon, S., D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M. Tignor and H.L. Miller (eds.) Cambridge University Press, Cambridge, United Kingdom and New Y ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microelectronics
Microelectronics is a subfield of electronics. As the name suggests, microelectronics relates to the study and manufacture (or microfabrication) of very small electronic designs and components. Usually, but not always, this means micrometre-scale or smaller. These devices are typically made from semiconductor materials. Many components of a normal electronic design are available in a microelectronic equivalent. These include transistors, capacitors, inductors, resistors, diodes and (naturally) insulators and conductors can all be found in microelectronic devices. Unique wiring techniques such as wire bonding are also often used in microelectronics because of the unusually small size of the components, leads and pads. This technique requires specialized equipment and is expensive. Digital integrated circuits (ICs) consist of billions of transistors, resistors, diodes, and capacitors. Analog circuits commonly contain resistors and capacitors as well. Inductors are u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
