Magnetochromism
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Magnetochromism
Magnetochromism is the term applied when a chemical compound changes colour under the influence of a magnetic field. In particular the magneto-optical effects exhibited by complex mixed metal compounds are called magnetochromic when they occur in the visible region of the spectrum. Examples include K2V3O8, lithium molybdenum purple bronze Li0.9Mo6O17, and related mixed oxides. Reported magnetochromic compounds are multiferroic manganese tungsten oxide and multiferroic bismuth ferrite Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as .... Magnetically–induced color change can also occur in aqueous solutions of colloidal Fe3O4 nanoparticles that are ~10 nm in diameter. Paramagnetic Fe3O4 particles are extracted from a petroleum–based ferrofluid or synthesized in a laboratory and th ...
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Lithium Molybdenum Purple Bronze
Lithium molybdenum purple bronze is a chemical compound with formula , that is, a mixed oxide of molybdenum and lithium. It can be obtained as flat crystals with a purple-red color and metallic sheen (hence the "purple bronze" name). This compound is one of several molybdenum bronzes with general formula where A is an alkali metal or thallium Tl. It stands out among them (and also among the sub-class of "purple" molybdenum bronzes) for its peculiar electrical properties, including a marked anisotropy that makes it a "quasi-1D" conductor, and a metal-to-insulator transition as it is cooled below 30 K. Preparation The compound was first obtained by Martha Greenblatt and others by a temperature gradient flux technique. In a typical preparation, a stoichometric melt of , and is maintained in a temperature gradient from 490 to 640 °C oven 15 cm in vacuum over several days. Excess reagents are dissolved with a hot potassium carbonate solution releasing metallic-purple pl ...
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Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken or new bonds formed or both. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, usin ...
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Colour
Color (or colour in Commonwealth English; see spelling differences) is the visual perception based on the electromagnetic spectrum. Though color is not an inherent property of matter, color perception is related to an object's light absorption, emission, reflection and transmission. For most humans, colors are perceived in the visible light spectrum with three types of cone cells ( trichromacy). Other animals may have a different number of cone cell types or have eyes sensitive to different wavelengths, such as bees that can distinguish ultraviolet, and thus have a different color sensitivity range. Animal perception of color originates from different light wavelength or spectral sensitivity in cone cell types, which is then processed by the brain. Colors have perceived properties such as hue, colorfulness (saturation), and luminance. Colors can also be additively mixed (commonly used for actual light) or subtractively mixed (commonly used for materials). If the ...
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Magnetic Field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, electric currents, and electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function (mathematics), function assigning a Euclidean vector, vector to each point of space, ...
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Magneto-optical Effect
A magneto-optic effect is any one of a number of phenomena in which an electromagnetic wave propagates through a medium that has been altered by the presence of a quasistatic magnetic field. In such a medium, which is also called gyrotropic or gyromagnetic, left- and right-rotating elliptical polarizations can propagate at different speeds, leading to a number of important phenomena. When light is transmitted through a layer of magneto-optic material, the result is called the Faraday effect: the plane of polarization can be rotated, forming a Faraday rotator. The results of reflection from a magneto-optic material are known as the magneto-optic Kerr effect (not to be confused with the nonlinear Kerr effect). In general, magneto-optic effects break time reversal symmetry locally (i.e., when only the propagation of light, and not the source of the magnetic field, is considered) as well as Lorentz reciprocity, which is a necessary condition to construct devices such as optical i ...
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Metal
A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated with having electrons available at the Fermi level, as against nonmetallic materials which do not. Metals are typically ductile (can be drawn into a wire) and malleable (can be shaped via hammering or pressing). A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polythiazyl, polymeric sulfur nitride. The general science of metals is called metallurgy, a subtopic of materials science; aspects of the electronic and thermal properties are also within the scope of condensed matter physics and solid-state chemistry, it is a multidisciplinary topic. In colloquial use materials such as steel alloys are referred to as metals, while others such as polymers, wood or ceramics are nonmetallic ...
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Visible Spectrum
The visible spectrum is the spectral band, band of the electromagnetic spectrum that is visual perception, visible to the human eye. Electromagnetic radiation in this range of wavelengths is called ''visible light'' (or simply light). The optical spectrum is sometimes considered to be the same as the visible spectrum, but some authors define the term more broadly, to include the ultraviolet and infrared parts of the electromagnetic spectrum as well, known collectively as ''optical radiation''. A typical human eye will respond to wavelengths from about 380 to about 750 nanometers. In terms of frequency, this corresponds to a band in the vicinity of 400–790 Terahertz (unit), terahertz. These boundaries are not sharply defined and may vary per individual. Under optimal conditions, these limits of human perception can extend to 310 nm (ultraviolet) and 1100 nm (near infrared). The spectrum does not contain all the colors that the human visual system can distinguish. ...
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Bismuth Ferrite
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction (\langle 111\rangle_c) with a magnitude of 90–95 μC/cm2. Sample Preparation Bismuth ferrite is not a naturally occurring mineral and several synthesis routes to obtain the compound have been developed. Solid state synthesis In the solid state reaction method bismuth oxide (Bi2O3) and iron oxide (Fe2O3) in a 1:1 mole ratio are mixed with a mortar or by ball milling and then fired at elevated temp ...
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