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Lithium Molybdenum Purple Bronze
Lithium molybdenum purple bronze is a chemical compound with formula , that is, a mixed oxide of molybdenum and lithium. It can be obtained as flat crystals with a purple-red color and metallic sheen (hence the "purple bronze" name). This compound is one of several molybdenum bronzes with general formula where A is an alkali metal or thallium Tl. It stands out among them (and also among the sub-class of "purple" molybdenum bronzes) for its peculiar electrical properties, including a marked anisotropy that makes it a "quasi-1D" conductor, and a metal-to-insulator transition as it is cooled below 30 K. Preparation The compound was first obtained by Martha Greenblatt and others by a temperature gradient flux technique. In a typical preparation, a stoichometric melt of , and is maintained in a temperature gradient from 490 to 640 °C oven 15 cm in vacuum over several days. Excess reagents are dissolved with a hot potassium carbonate solution releasing metallic-purple pl ...
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Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken or new bonds formed or both. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, usin ...
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Gram
The gram (originally gramme; SI unit symbol g) is a Physical unit, unit of mass in the International System of Units (SI) equal to one thousandth of a kilogram. Originally defined in 1795 as "the absolute Mass versus weight, weight of a volume of pure water equal to Cube (algebra), the cube of the hundredth part of a metre [1 Cubic centimetre, cm3], and at Melting point of water, the temperature of Melting point, melting ice", the defining temperature (0 °C) was later changed to the temperature of maximum density of water (approximately 4 °C). Subsequent redefinitions agree with this original definition to within 30 Parts-per notation, parts per million (0.003%), with the maximum density of water remaining very close to 1 g/cm3, as shown by modern measurements. By the late 19th century, there was an effort to make the Base unit (measurement), base unit the kilogram and the gram a derived unit. In 1960, the new International System of Units defined a '' ...
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Thermal Conductivity
The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials such as mineral wool or Styrofoam. Metals have this high thermal conductivity due to free electrons facilitating heat transfer. Correspondingly, materials of high thermal conductivity are widely used in heat sink applications, and materials of low thermal conductivity are used as thermal insulation. The reciprocal of thermal conductivity is called thermal resistivity. The defining equation for thermal conductivity is \mathbf = - k \nabla T, where \mathbf is the heat flux, k is the thermal conductivity, and \nabla ...
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Spin–charge Separation
In condensed matter physics, spin–charge separation is an unusual behavior of electrons in some materials in which they 'split' into three independent particles, the spinon, the orbiton and the holon (or chargon). The electron can always be theoretically considered as a bound state of the three, with the spinon carrying the spin of the electron, the orbiton carrying the orbital degree of freedom and the chargon carrying the charge, but in certain conditions they can behave as independent quasiparticles. The theory of spin–charge separation originates with the work of Sin-Itiro Tomonaga who developed an approximate method for treating one-dimensional interacting quantum systems in 1950. This was then developed by Joaquin Mazdak Luttinger in 1963 with an exactly solvable model which demonstrated spin–charge separation. In 1981 F. Duncan M. Haldane generalized Luttinger's model to the Tomonaga–Luttinger liquid concept whereby the physics of Luttinger's model was shown th ...
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Exciton
An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb's law, Coulomb force resulting from their opposite charges. It is an electrically neutral quasiparticle regarded as an elementary excitation primarily in condensed matter, such as Electrical insulation, insulators, semiconductors, some metals, and in some liquids. It transports energy without transporting net electric charge. An exciton can form when an electron from the valence band of a crystal is promoted in energy to the conduction band e.g., when a material absorbs a photon. Promoting the electron to the conduction band leaves a positively charged hole in the valence band. Here 'hole' represents the unoccupied quantum mechanical electron state with a positive charge, an analogue in crystal of a positron. Because of the attractive coulomb force between the electron and the hole, a bound state is formed, akin to that of the electron and proton in a ...
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Conduction Electrons
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states. On a graph of the electronic band structure of a semiconducting material, the valence band is located below the Fermi level, while the conduction band is located above it. The distinction between the valence and conduction bands is meaningless in metals, because conduction occurs in one or more partially filled bands that take on the properties of both the valence and conduction bands. Band gap In semiconductors and insulators the two bands are separated by a band gap, while in conductors the bands overlap. A band gap is an energy range in a solid where no electron states can exist due to the ...
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Charge Density Wave
A charge density wave (CDW) is an ordered quantum fluid of electrons in a linear chain compound or layered crystal. The electrons within a CDW form a standing wave pattern and sometimes collectively carry an electric current. The electrons in such a CDW, like those in a superconductor, can flow through a linear chain compound en masse, in a highly correlated fashion. Unlike a superconductor, however, the electric CDW current often flows in a jerky fashion, much like water dripping from a faucet, due to its electrostatic properties. In a CDW, the combined effects of pinning (due to impurities) and electrostatic interactions (due to the net electric charges of any CDW kinks) likely play critical roles in the CDW current's jerky behavior, as discussed in sections 4 & 5 below. Most CDW's in metallic crystals form due to the wave-like nature of electrons – a manifestation of quantum mechanical wave–particle duality – causing the electronic charge density to become spatially mo ...
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Electrical Resistivity And Conductivity
Electrical resistivity (also called volume resistivity or specific electrical resistance) is a fundamental specific property of a material that measures its electrical resistance or how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek alphabet, Greek letter  (Rho (letter), rho). The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the Electrical resistance, resistance between these contacts is , then the resistivity of the material is . Electrical conductivity (or specific conductance) is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter  (Sigma (letter), sigma), but  (kappa) (especially in electrical engineering) and  (gamma) are sometimes used. ...
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Ohm Centimetre
Ohm (symbol Ω) is a unit of electrical resistance named after Georg Ohm. Ohm or OHM may also refer to: People * Georg Ohm (1789–1854), German physicist and namesake of the term ''ohm'' * Germán Ohm (born 1936), Mexican boxer * Jörg Ohm (1944–2020), former East German football player * Martin Ohm (1792–1872), German mathematician * Rebecca Ohm, United States Air Force officer and fighter pilot * Rune Ohm (born 1980), Danish handball player * Thorsten Ohm, CEO of VDM Publishing * Pawat Chittsawangdee, Thai actor, nicknamed Ohm * Thitiwat Ritprasert, Thai actor, nicknamed Ohm Places Germany * Ohm (river), right tributary of the Lahn near Cölbe * Zwester Ohm, left tributary of the Lahn near Fronhausen Outer space * 24750 Ohm, an outer main belt asteroid * Ohm (crater) on the Moon Science and technology * Acoustic ohm, a unit of measurement of acoustic impedance * Ohm's law, law that relates electrical resistance, current, and voltage * OHM ( Observe. Hack. Make.), a 20 ...
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Resistivity
Electrical resistivity (also called volume resistivity or specific electrical resistance) is a fundamental specific property of a material that measures its electrical resistance or how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek letter  (rho). The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is , then the resistivity of the material is . Electrical conductivity (or specific conductance) is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter  (sigma), but  (kappa) (especially in electrical engineering) and  (gamma) are sometimes used. The SI unit of electrical conductivity is siemens per metre (S/m ...
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