Kenneth T. Gillen
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Kenneth T. Gillen
Kenneth T. Gillen is a retired Sandia National Labs researcher noted for contributions to service life prediction methods for elastomers Education Gillen completed his PhD in chemistry at University of Wisconsin - Madison in 1970 under advisor Joseph H. Noggle. Career Gillen joined Sandia National Labs in 1974, working on elastomeric seals in nuclear weapons and satellites. His research has focused on the prediction of the service life of polymers under exposure to temperature, radiation, humidity and mechanical stress. His most highly cited published work was the development of testing and analysis methods for the combined effects of diffusion and oxidation in polymers. His methods overcame limitations of earlier, less accurate methods based on the Arrhenius equation. His development of a technique for profiling of oxidation-induced stiffness gradients in aged elastomers was applied in the tire industry. Gillen served as an editor of the Elsevier journal Polymer Degrada ...
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Sandia National Labs
Sandia National Laboratories (SNL), also known as Sandia, is one of three research and development laboratories of the United States Department of Energy's National Nuclear Security Administration (NNSA). Headquartered in Kirtland Air Force Base in Albuquerque, New Mexico, it has a second principal facility next to Lawrence Livermore National Laboratory in Livermore, California, and a test facility in Waimea, Kauai, Hawaii. Sandia is owned by the U.S. federal government but privately managed and operated by National Technology and Engineering Solutions of Sandia, a wholly owned subsidiary of Honeywell International. Established in 1949, SNL is a "multimission laboratory" with the primary goal of advancing U.S. national security by developing various science-based technologies. Its work spans roughly 70 areas of activity, including nuclear deterrence, arms control, nonproliferation, hazardous waste disposal, and climate change. Sandia hosts a wide variety of research in ...
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University Of Wisconsin - Madison
A university () is an institution of tertiary education and research which awards academic degrees in several academic disciplines. ''University'' is derived from the Latin phrase , which roughly means "community of teachers and scholars". Universities typically offer both undergraduate and postgraduate programs. The first universities in Europe were established by Catholic monks. The University of Bologna (), Italy, which was founded in 1088, is the first university in the sense of: *being a high degree-awarding institute. *using the word (which was coined at its foundation). *having independence from the ecclesiastic schools and issuing secular as well as non-secular degrees (with teaching conducted by both clergy and non-clergy): grammar, rhetoric, logic, theology, canon law and notarial law.Hunt Janin: "The university in medieval life, 1179–1499", McFarland, 2008, , p. 55f.de Ridder-Symoens, Hilde''A History of the University in Europe: Volume 1, Universities in the Middl ...
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Nuclear Weapons
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either nuclear fission, fission (fission or atomic bomb) or a combination of fission and nuclear fusion, fusion reactions (thermonuclear weapon), producing a nuclear explosion. Both bomb types release large quantities of energy from relatively small amounts of matter. Nuclear bombs have had Nuclear weapon yield, yields between 10 tons (the W54) and 50 megatons for the Tsar Bomba (see TNT equivalent). Yields in the low kilotons can devastate cities. A thermonuclear weapon weighing as little as can release energy equal to more than 1.2 megatons of TNT (5.0 Petajoule, PJ). Apart from the blast, Effects of nuclear explosions, effects of nuclear weapons include Firestorm, firestorms, extreme Thermal radiation, heat and ionizing radiation, radioactive nuclear fallout, an Nuclear electromagnetic pulse, electromagnetic pulse, and a radar blackout. The first nuclear weapons were deve ...
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Arrhenius Equation
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining the rate of chemical reactions and for calculation of Activation energy, energy of activation. Arrhenius provided a physical justification and interpretation for the formula.Keith J. Laidler, Laidler, K. J. (1987) ''Chemical Kinetics'', Third Edition, Harper & Row, p. 42 Currently, it is best seen as an empirical relationship.Kenneth Connors, Chemical Kinetics, 1990, VCH Publishers It can be used to model the temperature variation of Mass diffusivity, diffusion coefficients, population of Vacancy defect, crystal ...
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Elsevier
Elsevier ( ) is a Dutch academic publishing company specializing in scientific, technical, and medical content. Its products include journals such as ''The Lancet'', ''Cell (journal), Cell'', the ScienceDirect collection of electronic journals, ''Trends (journals), Trends'', the ''Current Opinion (Elsevier), Current Opinion'' series, the online citation database Scopus, the SciVal tool for measuring research performance, the ClinicalKey search engine for clinicians, and the ClinicalPath evidence-based cancer care service. Elsevier's products and services include digital tools for Data management platform, data management, instruction, research analytics, and assessment. Elsevier is part of the RELX Group, known until 2015 as Reed Elsevier, a publicly traded company. According to RELX reports, in 2022 Elsevier published more than 600,000 articles annually in over 2,800 journals. As of 2018, its archives contained over 17 million documents and 40,000 Ebook, e-books, with over one b ...
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Polymer Degradation And Stability
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compound (chemistry), compounds, produces unique physical property, physical properties including toughness, high rubber elasticity, elasticity, viscoelasticity, and a tendency to form Amorphous solid, amorphous and crystallization of polymers, semicrystalline structures rath ...
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