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Giuseppe Resnati
Giuseppe Resnati (born 26 August 1955) is an Italian chemist with interests in supramolecular chemistry and fluorine chemistry. He has a particular focus on self-assembly processes driven by halogen bonds, chalcogen bonds, and pnictogen bonds. His results on the attractive non-covalent interactions wherein atoms act as electrophiles thanks to the anisotropic distribution of the electron density typical for bonded atoms, prompted a systematic rationalization and categorization of many different weak bonds formed by many elements of the p- and d- blocks of the periodic table. Education and professional positions Resnati was born in Monza, Italy. He obtained his PhD in Industrial Chemistry at the University of Milan in 1988 with Prof. Carlo Scolastico and a thesis on asymmetric synthesis via chiral sulfoxides. After a period of activity at the Italian National Research Council, in 2001 he became professor of chemistry for materials at the Politecnico di Milano. Research interes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monza
Monza (, ; ; , locally ; ) is a city and ''comune'' (municipality) on the Lambro, River Lambro, a tributary of the Po (river), River Po, in the Lombardy region of Italy, about north-northeast of Milan. It is the capital of the province of Monza and Brianza. Monza is best known for its Grand Prix motor racing circuit, the , which hosts the Formula One Italian Grand Prix.On 11 June 2004, Monza was designated the capital of the new province of Monza and Brianza. The new administrative arrangement came fully into effect in summer 2009; previously, Monza was a ''comune'' within the province of Milan. Monza is the third-largest city of Lombardy and is the most important economic, industrial and administrative centre of the Brianza area, supporting a textile industry and a publishing trade. Monza also hosts a department of the University of Milano-Bicocca, a Court of Justice and several offices of regional administration. Monza Park is one of the largest urban parks in Europe. Geog ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrophile
In chemistry, an electrophile is a chemical species that forms bonds with nucleophiles by accepting an electron pair. Because electrophiles accept electrons, they are Lewis acids. Most electrophiles are positively Electric charge, charged, have an atom that carries a partial positive charge, or have an atom that does not have an octet of electrons. Electrophiles mainly interact with nucleophiles through Addition reaction, addition and Substitution reaction, substitution reactions. Frequently seen electrophiles in Organic synthesis, organic syntheses include cations such as Hydrogen ion, H+ and nitrosonium, NO+, polarized neutral molecules such as hydrogen chloride, HCl, alkyl halides, acyl halides, and carbonyl compounds, polarizable neutral molecules such as chlorine, Cl2 and bromine, Br2, oxidizing agents such as organic peracids, chemical species that do not satisfy the octet rule such as carbenes and Radical (chemistry), radicals, and some Lewis acids such as Borane, BH3 and Di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodine
Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a violet gas at . The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek , meaning 'violet'. Iodine occurs in many oxidation states, including iodide (I−), iodate (), and the various periodate anions. As the heaviest essential mineral nutrient, iodine is required for the synthesis of thyroid hormones. Iodine deficiency affects about two billion people and is the leading preventable cause of intellectual disabilities. The dominant producers of iodine today are Chile and Japan. Due to its high atomic number and ease of attachment to organic compounds, it has also found favour as a non-toxic radiocontrast material. Because of the spec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borromean Rings
In mathematics, the Borromean rings are three simple closed curves in three-dimensional space that are link (knot theory), topologically linked and cannot be separated from each other, but that break apart into two unknotted and unlinked loops when any one of the three is cut or removed. Most commonly, these rings are drawn as three circles in the plane, in the pattern of a Venn diagram, alternating link, alternatingly crossing over and under each other at the points where they cross. Other triples of curves are said to form the Borromean rings as long as they are topologically equivalent to the curves depicted in this drawing. The Borromean rings are named after the Italian House of Borromeo, who used the circular form of these rings as an element of their coat of arms, but designs based on the Borromean rings have been used in many cultures, including by the Norsemen and in Japan. They have been used in Christian symbolism as a sign of the Trinity, and in modern commerce as the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Engineering
Crystal engineering studies the design and synthesis of solid-state structures with desired properties through deliberate control of Intermolecular force, intermolecular interactions. It is an Interdisciplinarity, interdisciplinary academic field, bridging solid-state and supramolecular chemistry. The main engineering strategies currently in use are hydrogen bond, hydrogen- and halogen bonding and coordination bonding. These may be understood with key concepts such as the supramolecular synthon and the secondary building unit. History of term The term 'crystal engineering' was first used in 1955 by R. Pepinsky but the starting point is often credited to Gerhard Schmidt in connection with photodimerization reactions in crystalline cinnamic acids. Since this initial use, the meaning of the term has broadened considerably to include many aspects of solid state supramolecular chemistry. A useful modern definition is that provided by Gautam Radhakrishna Desiraju, Gautam Desiraju, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intermolecular Forces
An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles (e.g. atoms or ions). Intermolecular forces are weak relative to intramolecular forces – the forces which hold a molecule together. For example, the covalent bond, involving sharing electron pairs between atoms, is much stronger than the forces present between neighboring molecules. Both sets of forces are essential parts of force fields frequently used in molecular mechanics. The first reference to the nature of microscopic forces is found in Alexis Clairaut's work ''Théorie de la figure de la Terre,'' published in Paris in 1743. Other scientists who have contributed to the investigation of microscopic forces include: Laplace, Gauss, Maxwell, Boltzmann and Pauling. Attractive intermolecular forces are categorized into the following type ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic Resonance Imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to generate pictures of the anatomy and the physiological processes inside the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio waves to form images of the organs in the body. MRI does not involve X-rays or the use of ionizing radiation, which distinguishes it from computed tomography (CT) and positron emission tomography (PET) scans. MRI is a medical application of nuclear magnetic resonance (NMR) which can also be used for imaging in other NMR applications, such as NMR spectroscopy. MRI is widely used in hospitals and clinics for medical diagnosis, staging and follow-up of disease. Compared to CT, MRI provides better contrast in images of soft tissues, e.g. in the brain or abdomen. However, it may be perceived as less comfortable by patients, due to the usually longer and louder measurements with the subject in a long, confining tube, although ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contrast Agents
A contrast agent (or contrast medium) is a substance used to increase the contrast of structures or fluids within the body in medical imaging. Contrast agents absorb or alter external electromagnetism or ultrasound, which is different from radiopharmaceuticals, which emit radiation themselves. In X-ray imaging, contrast agents enhance the radiodensity in a target tissue or structure. In magnetic resonance imaging (MRI), contrast agents shorten (or in some instances increase) the relaxation times of nuclei within body tissues in order to alter the contrast in the image. Contrast agents are commonly used to improve the visibility of blood vessels and the gastrointestinal tract. The types of contrast agent are classified according to their intended imaging modalities. Radiocontrast media For radiography, which is based on X-rays, iodine and barium are the most common types of contrast agent. Various sorts of iodinated contrast agents exist, with variations occurring between the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxaziridine
An oxaziridine is an organic molecule that features a three-membered heterocycle containing oxygen, nitrogen, and carbon. In their largest industrial application, oxaziridines are intermediates in the production of hydrazine. Oxaziridine derivatives are also used as specialized organic chemistry reagents for a variety of enantioselective oxidations and aminations. Oxaziridines also serve as precursors to nitrones and participate in +2cycloadditions with various heterocumulenes to form substituted five-membered heterocycles. Some oxaziridines also have the property of a high barrier to inversion of the nitrogen, allowing for the possibility of chirality at the nitrogen center. History Oxaziridine derivatives were first reported in the mid-1950s by Emmons and subsequently by Krimm and Horner and Jürgens. All noted that oxaziridine underwent unusual reactions, with both nitrogen and oxygen acting contrary to their usual polarity. The peroxide process for the industria ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during chemical reaction, reactions with other chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the prop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Consiglio Nazionale Delle Ricerche
The National Research Council (Italian: ''Consiglio Nazionale delle Ricerche, CNR'') is the largest research council in Italy. As a public organisation, its remit is to support scientific and technological research. Its headquarters are in Rome. History The institution was founded in 1923. The first president was Vito Volterra, succeeded by Guglielmo Marconi. The process of improvement of the national scientific research, through the use of specific laws, (see Law 59/1997), affects many research organisations, and amongst them is CNR, whose "primary function is to carry on, through its own organs, advanced basic and applied research, both to develop and maintain its own scientific competitiveness, and to be ready to take part effectively in a timely manner in the strategic fields defined by the national planning system". On 23 December 1987, CNR registered the first Italian internet domain: cnr.it Reorganisation With the issuing of the legislative decree of 30 January 1999, n. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Italy
Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land border, as well as List of islands of Italy, nearly 800 islands, notably Sicily and Sardinia. Italy shares land borders with France to the west; Switzerland and Austria to the north; Slovenia to the east; and the two enclaves of Vatican City and San Marino. It is the List of European countries by area, tenth-largest country in Europe by area, covering , and the third-most populous member state of the European Union, with nearly 59 million inhabitants. Italy's capital and List of cities in Italy, largest city is Rome; other major cities include Milan, Naples, Turin, Palermo, Bologna, Florence, Genoa, and Venice. The history of Italy goes back to numerous List of ancient peoples of Italy, Italic peoples—notably including the ancient Romans, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
