Frenesy (physics)
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Frenesy (physics)
Frenesy is a concept in statistical physics that measures the dynamical activity of a system's microscopic trajectories under nonequilibrium conditions. It complements the notion of entropy production, which measures time-antisymmetric aspects associated with irreversibility. Frenesy reflects how frequently states are visited or how many transitions occur over time and can be thought of as the "busyness" of the system's trajectories. It relates to reactivities, escape rates and residence times of a physical state. Origin and context The notion of frenesy was introduced in 2006 in the study of nonequilibrium processes by Christian Maes and collaborators, and has been discussed in various studies since then. In systems described by trajectory ensembles or path-space measures (e.g. originating in ''Markov processes'' or ''Langevin dynamics''), frenesy is associated with the time-symmetric part of the action functional, containing trajectory-dependent terms such as escape rates, ...
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Statistical Physics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in a wide variety of fields such as biology, neuroscience, computer science, information theory and sociology. Its main purpose is to clarify the properties of matter in aggregate, in terms of physical laws governing atomic motion. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. While classical thermodynamics is primarily concerned with thermodynamic equilibrium, statistical mechanics has been applied in non-equilibrium stat ...
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Negative Differential Resistance
In electronics, negative resistance (NR) is a property of some electrical circuits and devices in which an increase in voltage across the device's terminals results in a decrease in electric current through it. This is in contrast to an ordinary resistor, in which an increase in applied voltage causes a proportional increase in current in accordance with Ohm's law, resulting in a positive resistance. Under certain conditions, negative resistance can increase the power of an electrical signal, amplifying it. Negative resistance is an uncommon property which occurs in a few nonlinear electronic components. In a nonlinear device, two types of resistance can be defined: 'static' or 'absolute resistance', the ratio of voltage to current v / i, and ''differential resistance'', the ratio of a change in voltage to the resulting change in current \Delta v/\Delta i. The term negative resistance means negative differential resistance (NDR), \Delta v / \Delta i < 0. In general, a ...
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Stochastic Thermodynamics
Overview When a microscopic machine (e.g. a Microelectromechanical systems, MEM) performs useful work it generates heat and entropy as a byproduct of the process, however it is also predicted that this machine will operate in "reverse" or "backwards" over appreciable short periods. That is, heat energy from the surroundings will be converted into useful work. For larger engines, this would be described as a violation of the second law of thermodynamics, as entropy is consumed rather than generated. Loschmidt's paradox states that in a time reversible system, for every trajectory there exists a time-reversed anti-trajectory. As the entropy production of a trajectory and its equal anti-trajectory are of identical magnitude but opposite sign, then, so the argument goes, one cannot prove that entropy production is positive. For a long time, exact results in thermodynamics were only possible in linear systems capable of reaching equilibrium, leaving other questions like the Loschmidt p ...
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Nonequilibrium Thermodynamics
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport phenomena, transport processes and with the rates of chemical reactions. Almost all systems found in nature are not in thermodynamic equilibrium, for they are changing or can be triggered to change over time, and are continuously and discontinuously subject to flux of matter and energy to and from other systems and to chemical reactions. Many systems and processes can, however, be considered to be in equilibrium locally, thus allowing description by currently known equilibrium thermodynamics. Nevertheless, some natural systems and processes remain beyond the scope of equilibrium thermodynamic meth ...
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Stochastic Thermodynamics
Overview When a microscopic machine (e.g. a Microelectromechanical systems, MEM) performs useful work it generates heat and entropy as a byproduct of the process, however it is also predicted that this machine will operate in "reverse" or "backwards" over appreciable short periods. That is, heat energy from the surroundings will be converted into useful work. For larger engines, this would be described as a violation of the second law of thermodynamics, as entropy is consumed rather than generated. Loschmidt's paradox states that in a time reversible system, for every trajectory there exists a time-reversed anti-trajectory. As the entropy production of a trajectory and its equal anti-trajectory are of identical magnitude but opposite sign, then, so the argument goes, one cannot prove that entropy production is positive. For a long time, exact results in thermodynamics were only possible in linear systems capable of reaching equilibrium, leaving other questions like the Loschmidt p ...
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Fluctuation Theorem
The fluctuation theorem (FT), which originated from statistical mechanics, deals with the relative probability that the Entropy (statistical thermodynamics), entropy of a system which is currently away from thermodynamic equilibrium (i.e., maximum entropy) will increase or decrease over a given amount of time. While the second law of thermodynamics predicts that the entropy of an isolated system should tend to increase until it reaches equilibrium, it became apparent after the discovery of statistical mechanics that the second law is only a statistical one, suggesting that there should always be some nonzero probability that the entropy of an isolated system might spontaneously ''decrease''; the fluctuation theorem precisely quantifies this probability. Statement Roughly, the fluctuation theorem relates to the probability distribution of the time-averaged irreversible entropy production, denoted \overline_t. The theorem states that, in systems away from equilibrium over a fi ...
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Climate System
Earth's climate system is a complex system with five interacting components: the Atmosphere of Earth, atmosphere (air), the hydrosphere (water), the cryosphere (ice and permafrost), the lithosphere (earth's upper rocky layer) and the biosphere (living things).IPCC, 2013Annex III: Glossary[Planton, S. (ed.)]. InClimate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change[Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA. ''Climate'' is the statistical characterization of the climate system. It represents the average weather, typically over a period of 30 years, and is determined by a combination of processes, such as Ocean current, ocean currents and wind patterns. Circulation in the atmosphere and oceans transports heat from the tro ...
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Kinetic Proofreading
Kinetic proofreading (or kinetic amplification) is a mechanism for error correction in biochemical reactions, proposed independently by John Hopfield (1974) and Jacques Ninio (1975). Kinetic proofreading allows enzymes to discriminate between two possible reaction pathways leading to correct or incorrect products with an accuracy higher than what one would predict based on the difference in the activation energy between these two pathways. Increased specificity is obtained by introducing an irreversible step exiting the pathway, with reaction intermediates leading to incorrect products more likely to prematurely exit the pathway than reaction intermediates leading to the correct product. If the exit step is fast relative to the next step in the pathway, the specificity can be increased by a factor of up to the ratio between the two exit rate constants. (If the next step is fast relative to the exit step, specificity will not be increased because there will not be enough time for ...
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Active Matter
Active matter is matter composed of large numbers of active "agents", each of which consumes energy in order to move or to exert mechanical forces. Such systems are intrinsically out of thermal equilibrium. Unlike thermal systems relaxing towards equilibrium and systems with boundary conditions imposing steady currents, active matter systems break time reversal symmetry because energy is being continually dissipated by the individual constituents. Most examples of active matter are biological in origin and span all the scales of the living, from bacteria and self-organising bio-polymers such as microtubules and actin (both of which are part of the cytoskeleton of living cells), to schools of fish and flocks of birds. However, a great deal of current experimental work is devoted to synthetic systems such as artificial self-propelled particles. Active matter is a relatively new material classification in soft matter: the most extensively studied model, the Vicsek model, dates fr ...
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Phase Transition
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic State of matter, states of matter: solid, liquid, and gas, and in rare cases, plasma (physics), plasma. A phase of a thermodynamic system and the states of matter have uniform physical property, physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition States of matter Phase transitions commonly refer to when a substance tran ...
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Anderson Localization
In condensed matter physics, Anderson localization (also known as strong localization) is the absence of diffusion of waves in a ''disordered'' medium. This phenomenon is named after the American physicist P. W. Anderson, who was the first to suggest that electron localization is possible in a lattice potential, provided that the degree of randomness (disorder) in the lattice is sufficiently large, as can be realized for example in a semiconductor with impurities or defects. Anderson localization is a general wave phenomenon that applies to the transport of electromagnetic waves, acoustic waves, quantum waves, spin waves, etc. This phenomenon is to be distinguished from weak localization, which is the precursor effect of Anderson localization (see below), and from Mott localization, named after Sir Nevill Mott, where the transition from metallic to insulating behaviour is ''not'' due to disorder, but to a strong mutual Coulomb repulsion of electrons. Introduction In the ...
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Jamming (physics)
Jamming is the physical process by which the viscosity of some Mesoscopic physics, mesoscopic materials, such as granular materials, glasses, foams, polymers, emulsions, and other complex fluids, increases with increasing particle density. The jamming transition has been proposed as a new type of phase transition, with similarities to a glass transition but very different from the formation of crystalline solids. While a glass transition occurs when the liquid state is cooled, the jamming transition happens when the density, or the packing fraction of the particles, is increased. This crowding of the constituent particles prevents them from flowing under an applied stress and from exploring phase space, thus making the aggregate material behave as a solid. The system may be able to unjam if Packing density, volume fraction is decreased, or external stresses are applied such that they exceed the yield stress. This transition is interesting because it is Nonlinear system, nonlinea ...
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