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Fractional Crystallization (chemistry)
{{crystallization In chemistry, fractional crystallization is a stage-wise separation technique that relies on the liquid–solid phase change. This technique fractionates via differences in crystallization temperature and enables the purification of multi-component mixtures, as long as none of the constituents can act as solvents to the others. Due to the high selectivity of the solid–liquid equilibrium, very high purities can be achieved for the selected component. Principle of separation The crystallization process starts with the partial freezing of the initial liquid mixture by slowly decreasing its temperature. The frozen solid phase subsequently has a different composition than the remaining liquid. This is the fundamental physical principle behind the melt fractionating process and quite comparable to distillation, which operates between a liquid and the gas phase. The crystals will grow on a cooled surface or alternatively as a suspension in the liquid. The heat r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fractionation
Fractionation is a separation process in which a certain quantity of a mixture (of gasses, solids, liquids, enzymes, or isotopes, or a suspension) is divided during a phase transition, into a number of smaller quantities (fractions) in which the composition varies according to a gradient. Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run. This property sets it apart from other separation techniques. Fractionation is widely employed in many branches of science and technology. Mixtures of liquids and gasses are separated by fractional distillation by difference in boiling point. Fractionation of components also takes place in column chromatography by a difference in affinity between statio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anthracene
Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C14H10, consisting of three fused benzene rings. It is a component of coal tar. Anthracene is used in the production of the red dye alizarin and other dyes, as a scintillator to detect high energy particles, as production of pharmaceutical drugs. Anthracene is colorless but exhibits a blue (400–500 nm peak) fluorescence under ultraviolet radiation. History and etymology Crude anthracene (with a melting point of only 180°) was discovered in 1832 by Jean-Baptiste Dumas and Auguste Laurent who crystalized it from a fraction of coal tar later known as "anthracene oil". Since their (inaccurate) measurements showed the proportions of carbon and hydrogen of it to be the same as in naphthalene, Laurent called it ''paranaphtaline'' in his 1835 publication of the discovery, which is translated to English as paranaphthalene. Two years later, however, he decided to rename the compound to its modern name d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fractionation
Fractionation is a separation process in which a certain quantity of a mixture (of gasses, solids, liquids, enzymes, or isotopes, or a suspension) is divided during a phase transition, into a number of smaller quantities (fractions) in which the composition varies according to a gradient. Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run. This property sets it apart from other separation techniques. Fractionation is widely employed in many branches of science and technology. Mixtures of liquids and gasses are separated by fractional distillation by difference in boiling point. Fractionation of components also takes place in column chromatography by a difference in affinity between statio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Illinois Institute Of Technology
The Illinois Institute of Technology, commonly referred to as Illinois Tech and IIT, is a Private university, private research university in Chicago, Illinois, United States. Tracing its history to 1890, the present name was adopted upon the merger of the Armour Institute and Lewis Institute in 1940. The university has programs in architecture, business, communication studies, communications, design, engineering, industrial technology, information technology, law, psychology, and science. It is Carnegie Classification of Institutions of Higher Education, classified among "R2: Doctoral Universities – High research activity". The university's historic roots are in several 19th-century engineering and professional education institutions in the United States. In the mid 20th century, it became closely associated with trends in modernist architecture through the work of its Dean of Architecture Ludwig Mies van der Rohe, who designed its campus. The Institute of Design, Chicago-Ken ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Single Crystal
In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no Grain boundary, grain boundaries. The absence of the crystallographic defect, defects associated with grain boundaries can give monocrystals unique properties, particularly mechanical, optical and electrical, which can also be anisotropic, depending on the type of crystallography, crystallographic structure. These properties, in addition to making some gems precious, are industrially used in technological applications, especially in optics and electronics. Because entropy, entropic effects favor the presence of some imperfections in the microstructure of solids, such as impurity, impurities, inhomogeneous strain and crystallographic defects such as dislocations, perfect single crystals of meaningful size are exceedingly rare in nature. The necessary laboratory condi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Seed Crystal
A seed crystal is a small piece of single crystal or polycrystal material from which a large crystal of typically the same material is grown in a laboratory. Used to replicate material, the use of seed crystal to promote growth avoids the otherwise slow randomness of natural crystal growth, and allows manufacture on a scale suitable for industry. Crystal enlargement The large crystal can be grown by dipping the seed into a supersaturated solution, into molten material that is then cooled, or by growth on the seed face by passing vapor of the material to be grown over it. Theory The theory behind this effect is thought to derive from the physical intermolecular interaction that occurs between compounds in a supersaturated solution (or possibly vapor). In solution, liberated (soluble) molecules (solute) are free to move about in random flow. This random flow permits for the possibility of two or more molecular compounds to interact. This interaction can potentiate intermolecular ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Recrystallization (chemistry)
Recrystallization is a broad class of List of purification methods in chemistry , chemical purification techniques characterized by the dissolution of an impure sample in a solvent or solvent mixture, followed by some change in conditions that encourages the formation of pure isolate as solid crystals. Recrystallization as a purification technique is driven by spontaneous process , spontaneous processes of molecular self-assembly , self-assembly that leverage the highly ordered (i.e. low-entropy) and periodic characteristics of a crystal's molecular structure to produce purification. Basic principles The driving force of this purification emerges from the difference in molecular interactions between the isolate and the impurities: if a molecule of the desired isolate interacts with any isolate crystal present, it is likely the molecule Deposition (chemistry) , deposits on the crystal's ordered surface and contributes to the crystal's growth; if a molecule of the impurity inter ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pumpable Ice Technology
Pumpable ice technology (PIT) uses thin liquids, with the cooling capacity of ice. Pumpable ice is typically a slurry of ice crystals or particles ranging from 5 micrometers to 1 cm in diameter and transported in brine, seawater, food liquid, or gas bubbles of air, ozone, or carbon dioxide. Terminology Beyond generic terms, such as pumpable, jelly, or slurry ice, there are many trademark names for such coolant, like "Deepchill", "Beluga", "optim", "flow", "fluid", "jel", "binary", "liquid", "maxim", "whipped", and "bubble slurry" ice. These trademarks are authorized by industrial ice maker production companies in Australia, Canada, China, Germany, Iceland, Israel, Russia, Spain, United Kingdom, and the US. Technological process Pumpable ice can be produced in one of two ways: either by mixing crushed ice with a liquid or by freezing water within a liquid. *The primary way is to manufacture commonly used forms of crystal solid ice, such as plate, tube, shell or flake ice ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laser-heated Pedestal Growth
Laser-heated pedestal growth (LHPG) or laser floating zone (LFZ) is a crystal growth technique. A narrow region of a crystal is melted with a powerful Carbon-dioxide laser, CO2 or Nd:YAG laser. The laser and hence the zone melting, floating zone, is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it. This technique for growing crystals from the melt (liquid/solid phase transition) is used in materials research. Advantages The main advantages of this technique are the high pulling rates (60 times greater than the conventional Czochralski technique) and the possibility of growing materials with very high melting points. In addition, LHPG is a crucible-free technique, which allows single crystals to be grown with high purity and low stress. The geometric shape of the crystals (the technique can produce small diameters), and the low production cost, make the single-crystal fibers (SCF) produced by L ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fractional Freezing
Fractional freezing is a process used in process engineering and chemistry to separate substances with different melting points. It can be done by partial melting of a solid, for example in zone refining of silicon or metals A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. These properties are all associated with having electrons available at the Fermi level, as against no ..., or by partial crystallization of a liquid, as in freeze distillation, also called normal freezing or progressive freezing. The initial sample is thus fractionation, fractionated (separation process, separated into fraction (chemistry), fractions). Partial crystallization can also be achieved by adding a dilute solvent to the mixture, and cooling and concentrating the mixture by evaporating the solvent, a process called solution crystallization. Fractional freezing is generally used to produce ultra-pure so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fractional Crystallization (geology)
Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation. Fractional crystallization is also important in the formation of sedimentary evaporite rocks. Igneous rocks Fractional crystallization is the removal and segregation from a melt of mineral precipitates; except in special cases, removal of the crystals changes the composition of the magma. In essence, fractional crystallization is the removal of early formed crystals from an originally homogeneous magma (for example, by gravity settling) so that these crystals are prevented from further reaction with the residual melt. The composition of the remaining melt becomes relatively depleted in some components and enriched in others, resulting in the precipitation of a seque ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
