Erich Hückel
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Erich Hückel
Erich Armand Arthur Joseph Hückel (August 9, 1896, Berlin – February 16, 1980, Marburg) was a German physicist and physical chemist. He is mainly known for the Debye–Hückel theory of electrolytic solutions and the Hückel method of approximate molecular orbital (MO) calculations on π electron systems. Hückel was born in the Charlottenburg suburb of Berlin. He studied physics and mathematics from 1914 to 1921 at the University of Göttingen. On receiving his doctorate, he became an assistant at Göttingen, but soon became an assistant to Peter Debye at Zürich. It was there that he and Debye developed their theory (the Debye–Hückel theory, in 1923) of electrolytic solutions, elucidating the behavior of strong electrolytes by considering interionic forces, in order to account for their electrical conductivity and their thermodynamic activity coefficients. After spending 1928 and 1929 in England and Denmark, working briefly with Niels Bohr, Hückel joined the faculty ...
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Berlin
Berlin ( ; ) is the Capital of Germany, capital and largest city of Germany, by both area and List of cities in Germany by population, population. With 3.7 million inhabitants, it has the List of cities in the European Union by population within city limits, highest population within its city limits of any city in the European Union. The city is also one of the states of Germany, being the List of German states by area, third smallest state in the country by area. Berlin is surrounded by the state of Brandenburg, and Brandenburg's capital Potsdam is nearby. The urban area of Berlin has a population of over 4.6 million and is therefore the most populous urban area in Germany. The Berlin/Brandenburg Metropolitan Region, Berlin-Brandenburg capital region has around 6.2 million inhabitants and is Germany's second-largest metropolitan region after the Rhine-Ruhr region, as well as the List of EU metropolitan areas by GDP, fifth-biggest metropolitan region by GDP in the European Union. ...
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Charlottenburg
Charlottenburg () is a Boroughs and localities of Berlin, locality of Berlin within the borough of Charlottenburg-Wilmersdorf. Established as a German town law, town in 1705 and named after Sophia Charlotte of Hanover, Queen consort of Kingdom of Prussia, Prussia, it is best known for Charlottenburg Palace - the largest surviving such royal palace in Berlin - and the adjacent museums. Charlottenburg was an independent city to the west of Berlin until 1920 when it was incorporated into "Greater Berlin Act, Groß-Berlin" (Greater Berlin) and transformed into a borough. In the course of Berlin's 2001 administrative reform it was merged with the former borough of Wilmersdorf becoming a part of a new borough called Charlottenburg-Wilmersdorf. Later, in 2004, the new borough's districts were rearranged, dividing the former borough of Charlottenburg into the localities of Charlottenburg proper, Westend (Berlin), Westend and Charlottenburg-Nord. Geography Charlottenburg is located in ...
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International Academy Of Quantum Molecular Science
The International Academy of Quantum Molecular Science (IAQMS) is an international scientific learned society covering all applications of quantum theory to chemistry and chemical physics. It was created in Menton in 1967. The founding members were Raymond Daudel, Per-Olov Löwdin, Robert G. Parr, John Pople and Bernard Pullman. Its foundation was supported by Louis de Broglie. Originally, the academy had 25 regular members under 65 years of age. This was later raised to 30, and then to 35. There is no limit on the number of members over 65 years of age. The members are "chosen among the scientists of all countries who have distinguished themselves by the value of their scientific work, their role of pioneer or leader of a school in the broad field of quantum chemistry, i.e. the application of quantum mechanics to the study of molecules and macromolecules". As of 2006, the academy consisted of 90 members. The academy organizes the International Congress of Quantum Chemistry eve ...
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University Of Marburg
The Philipps University of Marburg () is a public research university located in Marburg, Germany. It was founded in 1527 by Philip I, Landgrave of Hesse, which makes it one of Germany's oldest universities and the oldest still operating Protestant university in the world. It is now a public university of the state of Hesse, without religious affiliation. The University of Marburg has about 23,500 students and 7,500 employees and is located in Marburg, a town of 76,000 inhabitants, with university buildings dotted in or around the town centre. About 14% of the students are international, the highest percentage in Hesse. It offers an international summer university programme and offers student exchanges through the Erasmus programme. History In 1609, the University of Marburg established the world's first professorship in chemistry. In 2012 it opened the first German interactive chemistry museum, called '. Its experimental course programme is aimed at encouraging young people ...
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Stuttgart
Stuttgart (; ; Swabian German, Swabian: ; Alemannic German, Alemannic: ; Italian language, Italian: ; ) is the capital city, capital and List of cities in Baden-Württemberg by population, largest city of the States of Germany, German state of Baden-Württemberg. It is located on the Neckar river in a fertile valley known as the ''Stuttgarter Kessel'' (Stuttgart Cauldron) and lies an hour from the Swabian Jura and the Black Forest. Stuttgart has a population of 632,865 as of 2022, making it the list of cities in Germany by population, sixth largest city in Germany, while over 2.8 million people live in the city's administrative region and nearly 5.5 million people in Stuttgart Metropolitan Region, its metropolitan area, making it the metropolitan regions in Germany, fourth largest metropolitan area in Germany. The city and metropolitan area are consistently ranked among the List of EU metropolitan regions by GDP#2021 ranking of top four German metropolitan regions, top 5 Europea ...
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University Of Stuttgart
The University of Stuttgart () is a research university located in Stuttgart, Germany. It was founded in 1829 and is organized into 10 faculties. It is one of the oldest technical universities in Germany with programs in civil, mechanical, industrial and electrical engineering, among others. It is a member of TU9, an incorporated society of the largest and most notable German institutes of technology. History From 1770 to 1794, the Karlsschule was the first university in Stuttgart. The University of Hohenheim in Stuttgart-Hohenheim, founded in 1818 and Stuttgart's oldest still existing university, is not related to the University of Stuttgart, except for some joint activities. What is now the University of Stuttgart was founded in 1829, and celebrated its 175th anniversary in 2004. Because of the increasing importance of the technical sciences and instruction in these fields, from 1876 the university was known as the Technische Hochschule Stuttgart (Stuttgart Institute of ...
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Niels Bohr
Niels Henrik David Bohr (, ; ; 7 October 1885 – 18 November 1962) was a Danish theoretical physicist who made foundational contributions to understanding atomic structure and old quantum theory, quantum theory, for which he received the Nobel Prize in Physics in 1922. Bohr was also a philosopher and a promoter of scientific research. Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been supplanted by other models, its underlying principles remain valid. He conceived the principle of Complementarity (physics), complementarity: that items could be separately analysed in terms of contradictory properties, like behaving as a Wave–particle duality, wave or a stream of particles. The notion of complementarity dominated Bohr's thinking in both science and philoso ...
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Activity Coefficient
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures can be expressed directly in terms of simple concentrations or partial pressures of the substances present e.g. Raoult's law. Deviations from ideality are accommodated by modifying the concentration by an ''activity coefficient''. Analogously, expressions involving gases can be adjusted for non-ideality by scaling partial pressures by a fugacity coefficient. The concept of activity coefficient is closely linked to that of activity in chemistry. Thermodynamic definition The chemical potential, \mu_\mathrm, of a substance B in an ideal mixture of liquids or an ideal solution is given ...
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Conductivity (electrolytic)
Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. For example, the measurement of product conductivity is a typical way to monitor and continuously trend the performance of water purification systems. In many cases, conductivity is linked directly to the total dissolved solids (TDS). High-quality deionized water has a conductivity of : \kappa = 0.05501 \pm 0.0001 μS/cm at 25 °C. This corresponds to a specific resistivity of : \rho = 18.18 \pm 0.03 MΩ⋅cm. The preparation of salt solutions often takes place in unsealed beakers. In this case the conductivity of purified water often is 10 to 20 times higher. A discussion can be found below. Typical drinking water is ...
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Zürich
Zurich (; ) is the list of cities in Switzerland, largest city in Switzerland and the capital of the canton of Zurich. It is in north-central Switzerland, at the northwestern tip of Lake Zurich. , the municipality had 448,664 inhabitants. The Urban agglomeration, urban area was home to 1.45 million people (2020), while the Zurich Metropolitan Area, Zurich metropolitan area had a total population of 2.1 million (2020). Zurich is a hub for railways, roads, and air traffic. Both Zurich Airport and Zürich Hauptbahnhof, Zurich's main railway station are the largest and busiest in the country. Permanently settled for over 2,000 years, Zurich was founded by the Roman Empire, Romans, who called it '. However, early settlements have been found dating back more than 6,400 years (although this only indicates human presence in the area and not the presence of a town that early). During the Middle Ages, Zurich gained the independent and privileged status of imperial immediacy and, in 1519 ...
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Peter Debye
Peter Joseph William Debye ( ; born Petrus Josephus Wilhelmus Debije, ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born in Maastricht, Netherlands, Debye enrolled in the Aachen University of Technology in 1901. In 1905, he completed his first degree in electrical engineering. He published his first paper, a mathematically elegant solution of a problem involving eddy currents, in 1907. At Aachen, he studied under the theoretical physicist Arnold Sommerfeld, who later claimed that his most important discovery was Peter Debye. In 1906, Sommerfeld received an appointment at Munich, Bavaria, and took Debye with him as his assistant. Debye got his Ph.D. with a dissertation on radiation pressure in 1908. In 1910, he derived the Planck radiation formula using a method which Max Planck agreed was simpler than his own. In 1911, when Albert Einstein took an appointment as a profes ...
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Doctor Of Philosophy
A Doctor of Philosophy (PhD, DPhil; or ) is a terminal degree that usually denotes the highest level of academic achievement in a given discipline and is awarded following a course of Postgraduate education, graduate study and original research. The name of the degree is most often abbreviated PhD (or, at times, as Ph.D. in North American English, North America), pronounced as three separate letters ( ). The University of Oxford uses the alternative abbreviation "DPhil". PhDs are awarded for programs across the whole breadth of academic fields. Since it is an earned research degree, those studying for a PhD are required to produce original research that expands the boundaries of knowledge, normally in the form of a Thesis, dissertation, and, in some cases, defend their work before a panel of other experts in the field. In many fields, the completion of a PhD is typically required for employment as a university professor, researcher, or scientist. Definition In the context o ...
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