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Exergy Tour
Exergy, often referred to as "available energy" or "useful work potential", is a fundamental concept in the field of thermodynamics and engineering. It plays a crucial role in understanding and quantifying the quality of energy within a system and its potential to perform useful work. Exergy analysis has widespread applications in various fields, including energy engineering, environmental science, and industrial processes. From a scientific and engineering perspective, second-law-based exergy analysis is valuable because it provides a number of benefits over energy analysis alone. These benefits include the basis for determining energy quality (or exergy content), enhancing the understanding of fundamental physical phenomena, and improving design, performance evaluation and optimization efforts. In thermodynamics, the exergy of a System (thermodynamics), system is the maximum useful work (thermodynamics), work that can be produced as the system is brought into Thermodynamic equili ...
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Energy
Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and light. Energy is a Conservation law, conserved quantity—the law of conservation of energy states that energy can be Energy transformation, converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a Classical field theory, field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, the internal energy contained within a thermodynamic system, and rest energy associated with an object's rest mass. These are not mutual ...
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Thermodynamic Potential
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ...
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Internal Energy
The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization. It excludes the kinetic energy of motion of the system as a whole and the potential energy of position of the system as a whole, with respect to its surroundings and external force fields. It includes the thermal energy, ''i.e.'', the constituent particles' kinetic energies of motion relative to the motion of the system as a whole. Without a thermodynamic process, the internal energy of an isolated system cannot change, as expressed in the law of conservation of energy, a foundation of the first law of thermodynamics. The notion has been introduced to describe the systems characterized by temperature variations, te ...
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Extensive Quantity
Physical or chemical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes. The terms "intensive and extensive quantities" were introduced into physics by German mathematician Georg Helm in 1898, and by American physicist and chemist Richard C. Tolman in 1917. According to International Union of Pure and Applied Chemistry (IUPAC), an intensive property or intensive quantity is one whose magnitude is independent of the size of the system. An intensive property is not necessarily homogeneously distributed in space; it can vary from place to place in a body of matter and radiation. Examples of intensive properties include temperature, ''T''; refractive index, ''n''; density, ''ρ''; and hardness, ''η''. By contrast, an extensive property or extensive quantity is one whose magnitude is additive for subsystems. Examples include mass, volume and Gi ...
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Second Law Of Thermodynamics
The second law of thermodynamics is a physical law based on Universal (metaphysics), universal empirical observation concerning heat and Energy transformation, energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient). Another statement is: "Not all heat can be converted into Work (thermodynamics), work in a cyclic process."Young, H. D; Freedman, R. A. (2004). ''University Physics'', 11th edition. Pearson. p. 764. The second law of thermodynamics establishes the concept of entropy as a physical property of a thermodynamic system. It predicts whether processes are forbidden despite obeying the requirement of conservation of energy as expressed in the first law of thermodynamics and provides necessary criteria for spontaneous processes. For example, the first law allows the process of a cup falling off a table and breaking on the floor, as well as allowi ...
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Thermodynamic Limit
In statistical mechanics, the thermodynamic limit or macroscopic limit, of a system is the Limit (mathematics), limit for a large number of particles (e.g., atoms or molecules) where the volume is taken to grow in proportion with the number of particles.S.J. Blundell and K.M. Blundell, "Concepts in Thermal Physics", Oxford University Press (2009) The thermodynamic limit is defined as the limit of a system with a large volume, with the particle density held fixed: : N \to \infty,\, V \to \infty,\, \frac N V =\text In this limit, macroscopic thermodynamics is valid. There, thermal fluctuations in global quantities are negligible, and all List of thermodynamic properties, thermodynamic quantities, such as pressure and energy, are simply functions of the thermodynamic variables, such as temperature and density. For example, for a large volume of gas, the fluctuations of the total internal energy are negligible and can be ignored, and the average internal energy can be predicted fro ...
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Isolated System
In physical science, an isolated system is either of the following: # a physical system so far removed from other systems that it does not interact with them. # a thermodynamic system enclosed by rigid immovable walls through which neither mass nor energy can pass. Though subject internally to its own gravity, an isolated system is usually taken to be outside the reach of external gravitational and other long-range forces. This can be contrasted with what (in the more common terminology used in thermodynamics) is called a closed system, being enclosed by selective walls through which energy can pass as heat or work, but not matter; and with an open system, which both matter and energy can enter or exit, though it may have variously impermeable walls in parts of its boundaries. An isolated system obeys the conservation law that its total energy–mass stays constant. Most often, in thermodynamics, mass and energy are treated as separately conserved. Because of the requir ...
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Carnot Heat Engine
A Carnot heat engine is a theoretical heat engine that operates on the Carnot cycle. The basic model for this engine was developed by Nicolas Léonard Sadi Carnot in 1824. The Carnot engine model was graphically expanded by Benoît Paul Émile Clapeyron in 1834 and mathematically explored by Rudolf Clausius in 1857, work that led to the fundamental thermodynamic concept of entropy. The Carnot engine is the most efficient heat engine which is theoretically possible. The efficiency depends only upon the absolute temperatures of the hot and cold heat reservoirs between which it operates. A heat engine acts by transferring energy from a warm region to a cool region of space and, in the process, converting some of that energy to mechanical work. The cycle may also be reversed. The system may be worked upon by an external force, and in the process, it can transfer thermal energy from a cooler system to a warmer one, thereby acting as a refrigerator or heat pump rather than a heat en ...
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Reversible Process (thermodynamics)
In thermodynamics, a reversible process is a process, involving a system and its surroundings, whose direction can be reversed by infinitesimal changes in some properties of the surroundings, such as pressure or temperature. Throughout an entire reversible process, the system is in thermodynamic equilibrium, both physical and chemical, and ''nearly'' in pressure and temperature equilibrium with its surroundings. This prevents unbalanced forces and acceleration of moving system boundaries, which in turn avoids friction and other dissipation. To maintain equilibrium, reversible processes are extremely slow ( ''quasistatic''). The process must occur slowly enough that after some small change in a thermodynamic parameter, the physical processes in the system have enough time for the other parameters to self-adjust to match the new, changed parameter value. For example, if a container of water has sat in a room long enough to match the steady temperature of the surrounding air, for ...
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Reversible Computing
Reversible computing is any model of computation where every step of the process is time-reversible. This means that, given the output of a computation, it's possible to perfectly reconstruct the input. In systems that progress deterministically from one state to another, a key requirement for reversibility is a one-to-one correspondence between each state and its successor. Reversible computing is considered an unconventional approach to computation and is closely linked to quantum computing, where the principles of quantum mechanics inherently ensure reversibility (as long as quantum states are not measured or " collapsed"). Reversibility There are two major, closely related types of reversibility that are of particular interest for this purpose: physical reversibility and logical reversibility. A process is said to be ''physically reversible'' if it results in no increase in physical entropy; it is isentropic. There is a style of circuit design ideally exhibiting thi ...
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Information Theory
Information theory is the mathematical study of the quantification (science), quantification, Data storage, storage, and telecommunications, communication of information. The field was established and formalized by Claude Shannon in the 1940s, though early contributions were made in the 1920s through the works of Harry Nyquist and Ralph Hartley. It is at the intersection of electronic engineering, mathematics, statistics, computer science, Neuroscience, neurobiology, physics, and electrical engineering. A key measure in information theory is information entropy, entropy. Entropy quantifies the amount of uncertainty involved in the value of a random variable or the outcome of a random process. For example, identifying the outcome of a Fair coin, fair coin flip (which has two equally likely outcomes) provides less information (lower entropy, less uncertainty) than identifying the outcome from a roll of a dice, die (which has six equally likely outcomes). Some other important measu ...
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Carnot's Theorem (thermodynamics)
Carnot's theorem, also called Carnot's rule or Carnot's law, is a principle of thermodynamics developed by Nicolas Léonard Sadi Carnot in 1824 that specifies limits on the maximum efficiency that any heat engine can obtain. Carnot's theorem states that all heat engines operating between the same two thermal or heat reservoirs cannot have efficiencies greater than a reversible heat engine operating between the same reservoirs. A corollary of this theorem is that every reversible heat engine operating between a pair of heat reservoirs is equally efficient, regardless of the working substance employed or the operation details. Since a Carnot heat engine is also a reversible engine, the efficiency of all the reversible heat engines is determined as the efficiency of the Carnot heat engine that depends solely on the temperatures of its hot and cold reservoirs. The maximum efficiency (i.e., the Carnot heat engine efficiency) of a heat engine operating between hot and cold reservoi ...
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