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Dioxidanylium
Dioxidanylium, which is protonated molecular oxygen, or just protonated oxygen, is an ion with formula . It is formed when hydrogen containing substances combust, and exists in the ionosphere, and in plasmas that contain oxygen and hydrogen. Oxidation by O2 in superacids could be by way of the production of protonated molecular oxygen. It is the conjugate acid of dioxygen. The proton affinity of dioxygen (O2) is 4.4 eV. Significance Protonated molecular oxygen is of interest in trying to detect dioxygen in space. Because Earth's atmosphere is full of O2, its spectrum from a space object is impossible to observe from the ground. However should be much more detectable. Formation Reaction of dioxygenyl with hydrogen: : + H2 → + H• The reaction of the trihydrogen cation with dioxygen is approximately thermoneutral: :O2 + → + H2 When atomic hydrogen, created in an electric discharge is rapidly cooled with oxygen and condensed in solid neon, several reactive ion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dioxygenyl
The dioxygenyl ion, , has been studied in both the gas phase and in salts with anions that cannot be oxidized. The first synthesis was []. Rather than the triple bond of , the bond order is considered to be . Relative to most molecules, this ionization energy is very high at 1175 kJ/mol.Michael Clugston; Rosalind Flemming (2000). ''Advanced Chemistry'', Oxford University Press, , , p. 355. As a result, the scope of the chemistry of is quite limited, acting mainly as a 1-electron oxidiser. Structure and molecular properties has a bond order of 2.5, and a bond length of 112.3 pm in solid O2[AsF6]. It is isoelectronic with nitric oxide and is paramagnetic. The bond energy is 625.1 kJ mol−1 and the stretching frequency is 1858 wavenumber, cm−1, both of which are high relative to most of the molecules. Synthesis Neil Bartlett (chemist), Neil Bartlett demonstrated that dioxygenyl hexafluoroplatinate (O2PtF6), containing the dioxygenyl cation, can be prepared at room tempera ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reactive Oxygen Species
In chemistry and biology, reactive oxygen species (ROS) are highly Reactivity (chemistry), reactive chemicals formed from diatomic oxygen (), water, and hydrogen peroxide. Some prominent ROS are hydroperoxide (H2O2), superoxide (O2−), hydroxyl radical (OH.), and singlet oxygen(1O2). ROS are pervasive because they are readily produced from O2, which is abundant. ROS are important in many ways, both beneficial and otherwise. ROS function as signals, that turn on and off biological functions. They are intermediates in the redox behavior of O2, which is central to fuel cells. ROS are central to the photodegradation of organic pollutants in the atmosphere. Most often however, ROS are discussed in a biological context, ranging from their effects on aging and their role in causing dangerous genetic mutations. Inventory of ROS ROS are not uniformly defined. All sources include superoxide, singlet oxygen, and hydroxyl radical. Hydrogen peroxide is not nearly as reactive as these s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Band Head
In spectroscopy a band head is the abrupt edge of a spectroscopic band. When a band is described as degrading to the violet, it means that for wavelengths above the band head wavelength, the spectrum is dark as the band comes to a sudden stop(just above/after the head), and below the wavelength the brightness of the band weakens gradually. A band that degrades to the red, conversely means that the band head is a lower limit on wavelength for the band, and it fades off toward longer wavelengths, which in visible light is the red end of the spectrum. If a band spectrum A spectrum (: spectra or spectrums) is a set of related ideas, objects, or properties whose features overlap such that they blend to form a continuum. The word ''spectrum'' was first used scientifically in optics to describe the rainbow of co ... is examined at high resolution it consists of many lines. At a band head the numbers often increase to a limit, or otherwise a series of lines may approach from one sid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Tetroxide
Tetraoxidane is an inorganic compound of hydrogen and oxygen with the chemical formula . This is one of the unstable hydrogen polyoxides. Synthesis The compound is prepared by a chemical reaction between hydroperoxyl radicals () at low temperatures: : Physical properties This is the fourth member of the polyoxidanes. The first three are water mon)oxidane hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscosity, viscous than Properties of water, water. It is used as an oxidizer, bleaching agent, and antiseptic, usua ... (dioxidane), and trioxidane. Tetraoxidane is more unstable than the previous compounds. The term "tetraoxidane" extends beyond the parent compound to several daughter compounds of the general formula , where R can be hydrogen, halogen atoms, or various inorganic and organic monovalent radicals. The two Rs together can be replaced by a divalent radical, so heter ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscosity, viscous than Properties of water, water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as both a monopropellant and an oxidizer in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes slowly into water and elemental oxygen when exposed to light, and rapidly in the presence of organic or reactive compounds. It is typically stored with a Stabilizer (chemistry), stabilizer in a weakly acidic solution in an opaque bottle. Hydrogen peroxide is found in biological systems including the human body. Enzymes that u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroperoxyl
The hydroperoxyl radical, also known as the hydrogen superoxide, is the protonated form of superoxide with the chemical formula HO2, also written HOO•. This species plays an important role in the atmosphere and as a reactive oxygen species in cell biology. Structure and reactions The molecule has a bent structure. The superoxide anion, , and the hydroperoxyl radical exist in equilibrium in aqueous solution: : + + The p''K''a of HO2 is 4.88. Therefore, about 0.3% of any superoxide present in the cytosol of a typical cell is in the protonated form. It oxidizes nitric oxide to nitrogen dioxide: : + → + Reactive oxygen species in biology Together with its conjugate base superoxide, hydroperoxyl is an important reactive oxygen species. Unlike , which has reducing properties, can act as an oxidant in a number of biologically important reactions, such as the abstraction of hydrogen atoms from tocopherol and polyunstaturated fatty acids in the lipid bilayer. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trihydrogen Cation
The trihydrogen cation or protonated molecular hydrogen ( IUPAC name: hydrogen onium ion) is a cation (positive ion) with formula , consisting of three hydrogen nuclei (protons) sharing two electrons. The trihydrogen cation is one of the most abundant ions in the universe. It is stable in the interstellar medium (ISM) due to the low temperature and low density of interstellar space. The role that plays in the gas-phase chemistry of the ISM is unparalleled by any other polyatomic ion. The trihydrogen cation is the simplest triatomic molecule, because its two electrons are the only valence electrons in the system. It is also the simplest example of a three-center two-electron bond system. History was first discovered by J. J. Thomson in 1911. While using an early form of mass spectrometry to study the resultant species of plasma discharges, he discovered a large abundance of a polyatomic ion with a mass-to-charge ratio of 3. He stated that the only two possibilities were ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Proton Affinity
The proton affinity (PA, ''E''pa) of an anion or of a neutral atom or molecule is the negative of the enthalpy change in the reaction between the chemical species concerned and a proton in the gas phase: ::: A- + H+ -> HA ::: B + H+ -> BH+ These reactions are always exothermic in the gas phase, i.e. energy is released ( enthalpy is negative) when the reaction advances in the direction shown above, while the proton affinity is positive. This is the same sign convention used for electron affinity. The property related to the proton affinity is the gas-phase basicity, which is the negative of the Gibbs energy for above reactions, i.e. the gas-phase basicity includes entropic terms in contrast to the proton affinity. Acid/base chemistry The higher the proton affinity, the stronger the base and the weaker the conjugate acid ''in the gas phase''. The (reportedly) strongest known base is the ortho-diethynylbenzene dianion (''E''pa = 1843 kJ/mol), followed by the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ionosphere
The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays an important role in atmospheric electricity and forms the inner edge of the magnetosphere. It has practical importance because, among other functions, it influences radio propagation to distant places on Earth. Travel through this layer also impacts GPS signals, resulting in effects such as deflection in their path and delay in the arrival of the signal. History of discovery As early as 1839, the German mathematician and physicist Carl Friedrich Gauss postulated that an electrically conducting region of the atmosphere could account for observed variations of Earth's magnetic field. Sixty years later, Guglielmo Marconi received the first trans-Atlantic radio signal on December 12, 1901, in St. John's, Newfoundland (now in Canada) usin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dioxygen
There are several known allotropes of oxygen. The most familiar is molecular oxygen (), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (). Others are: * Atomic oxygen (), a free radical. * Singlet oxygen (), one of two metastable states of molecular oxygen. * Tetraoxygen (), another metastable form. * Solid oxygen, existing in six variously colored phases, of which one is octaoxygen (, red oxygen) and another one metallic (ζ-oxygen). Atomic oxygen Atomic oxygen, denoted O or O1, is very reactive, as the individual atoms of oxygen tend to quickly bond with nearby molecules. Its lowest-energy electronic state is a spin triplet, designated by the term symbol 3P. On Earth's surface, it exists naturally for a very short time. In outer space, the presence of ample ultraviolet radiation results in a low Earth orbit atmosphere in which 96% of the oxygen occurs in atomic form. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conjugate Acid
A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid gives a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as it loses a hydrogen ion in the reverse reaction. On the other hand, a conjugate base is what remains after an acid has donated a proton during a chemical reaction. Hence, a conjugate base is a substance formed by the removal of a proton from an acid, as it can gain a hydrogen ion in the reverse reaction. Because some acids can give multiple protons, the conjugate base of an acid may itself be acidic. In summary, this can be represented as the following chemical reaction: \text + \text \; \ce \; \text + \text Johannes Nicolaus Brønsted and Martin Lowry introduced the Brønsted–Lowry theory, which said that any compound that can give a proton to another compound is an acid, and the compound that receives the proton is a base. A proton is a subatomic particle in the n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
