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Cyclovariegatin
Cyclovariegatin is a pigment. Its chemical name is 1,4-dihydro-2,7,8-trihydroxy-3-(3,4-dihydroxyphenyl)-l,4-dioxodibenzofuran. It is distinguishable by its UV-Vis spectra with maxima at 257, 296, and 430 nm. The variants cyclovariegatin-pentaacetate, cyclovariegatin-2,3',8-triacetate, and cyclovariegatin-2-acetate have also been described. It is derived from atromentin. It has been isolated from the browned skin of ''Suillus grevillei'' var. badius, and becomes the pigment thelephoric acid. See also * Pulvinic acid * Pulvinone * Vulpinic acid Vulpinic acid is a natural product first found in and important in the symbiosis underlying the biology of lichens. It is a simple methyl ester derivative of its parent compound, pulvinic acid, and a close relative of pulvinone, both of which d ... References {{Reflist, refs= Gill, M., and Steglich, W. (1987) Pigments of fungi (Macromycetes). Prog Chem Org Nat Prod 51: 1–317. Elisabeth Jägers, Elisabeth Hillen-Maske, Holger Sch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atromentin
Atromentin is a natural chemical compound found in Agaricomycetes fungi in the orders Agaricales and Thelephorales. It can also be prepared by laboratory synthesis. Chemically, it is a polyphenol and a benzoquinone. Occurrences Atromentin has been found in cultures of '' Clitocybe subilludens'' and in extracts of ''Hydnellum peckii''. The first enzymes in its biosynthesis have been characterized in '' Tapinella panuoides''. One of those is called atromentin synthetase. Biological activities A number of potential biological activities of atromentin have been studied ''in vitro''. Atromentin possesses ''in vitro'' antibacterial activity, inhibiting the enzyme enoyl-acyl carrier protein reductase (essential for the biosynthesis of fatty acids) in the bacteria ''Streptococcus pneumoniae''. Atromentin has been shown to be a smooth muscle stimulant. It also induces apoptosis in isolated human leukemia U937 cells. It is also an anticoagulant Anticoagulants, commonly kno ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Suillus Grevillei
''Suillus grevillei'', commonly known as Greville's bolete, tamarack jack, or larch bolete, is a mycorrhizal mushroom with a tight, brilliantly coloured cap, shiny and wet looking with its mucous slime layer. The hymenium easily separates from the flesh of the cap, with a central stalk that is quite slender. The species has a ring or a tight-fitting annular zone. Description ''Suillus grevillei'' is a mushroom with a 5–10 cm (2–4 in) cap colored from citrus yellow to burnt orange, that is at first hemispherical, then bell-shaped, and finally flattened. It has a sticky skin, often with veil remnants on the edge, short tubes of yellow (possibly staining brownish) which descend down to the bottom of its cylindrical stalk (6–10 x 1–2 cm), which is yellowish above the ring area with streaks of reddish brown below. The flesh is yellow, staining brown. The thin meat has consistency at first but then quickly becomes soft. It has an odor reminiscent of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thelephoric Acid
Thelephoric acid is a terphenylquinone pigment that is found in several fungi, such as '' Omphalotus subilludens'' and ''Polyozellus multiplex''. Thelephoric acid has been shown to inhibit prolyl endopeptidase, an enzyme that has a role in processing proteins (specifically, amyloid precursor protein) in Alzheimer's disease. Chemicals that inhibit prolyl endopeptidase have attracted research interest due to their potential therapeutic effects. It is derived from atromentin Atromentin is a natural chemical compound found in Agaricomycetes fungi in the orders Agaricales and Thelephorales. It can also be prepared by laboratory synthesis. Chemically, it is a polyphenol and a benzoquinone. Occurrences Atromentin has ..., and its precursor can be from cyclovariegatin. Fragmentation patterns have suggested that polymers of thelephoric acid exists. References {{Reflist, refs= {{Cite journal , vauthors=Hwang JS, Song KS, Kim WG, Lee TH, Koshino H, Yoo ID , title=Polyozellin, a new ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pulvinic Acid
Pulvinic acids are natural chemical pigments found in some lichens, derived biosynthetically from the aromatic amino acids phenylalanine and tyrosine, via dimerization and oxidative ring-cleavage of arylpyruvic acids, a process that also produces the related pulvinones. Hydroxypulvinic acid pigments (pulvinic acid type family of pigments) have been found in ''Boletus'' (e.g. '' Boletus erythropus''), '' Boletinus'', '' Chalciporus'', '' Gyrodon'', '' Leccinum'', '' Pulveroboletus'', '' Suillus'' (e.g. ''Suillus luteus'', '' Suillus bovinus'', and '' Suillus grevillei''), ''Paxillus'' (e.g. '' Paxillus involutus''), '' Serpula'' (e.g. '' Serpula lacrymans''), ''Xerocomus'' (e.g. '' Xerocomus chrysenteron''), '' Hygrophoropsis'' (e.g. '' Hygrophoropsis aurantiaca''), '' Retiboletus'' (e.g. '' Retiboletus nigerrimus''), '' Pulveroboletus'' (e.g. '' Pulveroboletus auriflammeus''), and are generally characteristic of Boletales. In addition to pulvinone, derivatives and related pigm ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pulvinone
Pulvinone, an organic compound belonging to the esters, lactones, alcohols and butenolides classes, is a yellow crystalline solid. Although the pulvinone is not a natural product, several naturally occurring hydroxylated derivatives are known. These hydroxylated pulvinones are produced by fungal species, such as the in Europe common Larch Bolete (''Boletus elegans'', also known as ''Suillus grevillei''), or by moulds such as ''Aspergillus terreus''. History Fungi (such as boleti), moulds and lichens produce a wide range of pigments made up of one (monomer) or several (oligomers) units of pulvinic acid. In 1831, in the course of a study of the constituents of lichens (''Cetraria Vulpina''), the French chemist and pharmacist Antoine Bebert discovered a compound named ''vulpinic acid'', the first known naturally occurring methyl ester of pulvinic acid. More details about the structure of this pigment were disclosed in 1860 by the German chemists Franz Möller and Adolph Strecker.'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vulpinic Acid
Vulpinic acid is a natural product first found in and important in the symbiosis underlying the biology of lichens. It is a simple methyl ester derivative of its parent compound, pulvinic acid, and a close relative of pulvinone, both of which derive from aromatic amino acids such as phenylalanine via secondary metabolism. The roles of vulpinic acid are not fully established, but may include properties that make it an antifeedant for herbivores. The compound is relatively toxic to mammals. Chemical description Vulpinic acid was first isolated from lichens in 1925. As an isolated, purified substance, it is bright yellow in color. Vulpinic acid is derived biosynthetically by esterification from pulvinic acid; pulvinate itself derives from the aromatic amino acids phenylalanine and tyrosine, via dimerization and oxidative ring-cleavage of arylpyruvic acids, a process that also produces the related pulvinones. There have been several chemical syntheses reported for vulpinic ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biological Pigments
Biological pigments, also known simply as pigments or biochromes, are substances produced by living organisms that have a color resulting from selective color absorption. Biological pigments include plant pigments and flower pigments. Many biological structures, such as skin, eyes, feathers, fur and hair contain pigments such as melanin in specialized cells called chromatophores. In some species, pigments accrue over very long periods during an individual's lifespan. Pigment color differs from structural color in that it is the same for all viewing angles, whereas structural color is the result of selective reflection or iridescence, usually because of multilayer structures. For example, butterfly wings typically contain structural color, although many butterflies have cells that contain pigment as well. Biological pigments See conjugated systems for electron bond chemistry that causes these molecules to have pigment. * Heme/porphyrin-based: chlorophyll, bilirubin, hem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyphenols
Polyphenols () are a large family of naturally occurring organic compounds characterized by multiples of phenol units. They are abundant in plants and structurally diverse. Polyphenols include flavonoids, tannic acid, and ellagitannin, some of which have been used historically as dyes and for tanning garments. Etymology The name derives from the Ancient Greek word (''polus'', meaning "many, much") and the word phenol which refers to a chemical structure formed by attaching to an aromatic benzenoid (phenyl) ring to a hydroxyl (-OH) group as is found in alcohols (hence the ''-ol'' suffix). The term polyphenol has been in use at least since 1894. Definition The term polyphenol is not well-defined, but is generally agreed that they are natural products "having a polyphenol structure (i.e., several hydroxyl groups on aromatic rings)" including four principal classes: "phenolic acids, flavonoids, stilbenes, and lignans". *Flavonoids include flavones, flavonols, flavanols ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Catechols
Catechol ( or ), also known as pyrocatechol or 1,2-dihydroxybenzene, is a toxic organic compound with the molecular formula . It is the ''ortho'' isomer of the three isomeric benzenediols. This colorless compound occurs naturally in trace amounts. It was first discovered by destructive distillation of the plant extract catechin. About 20,000 tonnes of catechol are now synthetically produced annually as a commodity organic chemical, mainly as a precursor to pesticides, flavors, and fragrances. Catechol occurs as feathery white crystals that are very rapidly soluble in water. Isolation and synthesis Catechol was first isolated in 1839 by Edgar Hugo Emil Reinsch (1809–1884) by distilling it from the solid tannic preparation catechin, which is the residuum of catechu, the boiled or concentrated juice of ''Mimosa catechu'' ('' Acacia catechu''). Upon heating catechin above its decomposition point, a substance that Reinsch first named ''Brenz-Katechusäure'' (burned catechu a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxygen Heterocycles
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heterocyclic Compounds With 3 Rings
A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). Heterocyclic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of these heterocycles. Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs, most biomass (cellulose and related materials), and many natural and synthetic dyes. More than half of known compounds are heterocycles. 59% of US FDA-approved drugs contain nitrogen heterocycles. Classification The study of heterocyclic chemistry focuses especially on unsaturated derivatives, and the preponderance of work and applications involves unstrained 5- and 6-membered rings. Included are pyridine, thiophene, pyrrole, and furan. Another large class of heterocycles refers to those fused to benzene rings. For example, the fused benzene derivatives of pyridine, thiophene, pyrrole, and furan are quin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
