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Compressibility Factor Generalized Diagram
In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility or, if the temperature is held constant, the isothermal compressibility) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change. In its simple form, the compressibility \kappa (denoted in some fields) may be expressed as :\beta =-\frac\frac, where is volume and is pressure. The choice to define compressibility as the negative of the fraction makes compressibility positive in the (usual) case that an increase in pressure induces a reduction in volume. The reciprocal of compressibility at fixed temperature is called the isothermal bulk modulus. Definition The specification above is incomplete, because for any object or system the magnitude of the compressibility depends strongly on whether the process is isentropic or isothermal. Accordingly, isothermal compressibility is defined: :\beta_T=-\fr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Material Properties (thermodynamics)
The thermodynamic properties of materials are intensive thermodynamic parameters which are specific to a given material. Each is directly related to a second order differential of a thermodynamic potential. Examples for a simple 1-component system are: * Compressibility (or its inverse, the bulk modulus) :* Isothermal compressibility ::\kappa_T=-\frac\left(\frac\right)_T \quad = -\frac\,\frac :* Adiabatic compressibility ::\kappa_S=-\frac\left(\frac\right)_S \quad = -\frac\,\frac * Specific heat (Note - the extensive analog is the heat capacity) :* Specific heat at constant pressure ::c_P=\frac\left(\frac\right)_P \quad = -\frac\,\frac :* Specific heat at constant volume ::c_V=\frac\left(\frac\right)_V \quad = -\frac\,\frac * Coefficient of thermal expansion ::\alpha=\frac\left(\frac\right)_P \quad = \frac\,\frac where ''P'' is pressure, ''V'' is volume, ''T'' is temperature, ''S'' is entropy, and ''N'' is the number of particles. For a single comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Speed Of Sound
The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elasticity (solid mechanics), elastic medium. More simply, the speed of sound is how fast vibrations travel. At , the speed of sound in air is about , or in or one mile in . It depends strongly on temperature as well as the medium through which a sound wave is propagating. At , the speed of sound in dry air (sea level 14.7 psi) is about . The speed of sound in an ideal gas depends only on its temperature and composition. The speed has a weak dependence on frequency and pressure in dry air, deviating slightly from ideal behavior. In colloquial speech, ''speed of sound'' refers to the speed of sound waves in Earth's atmosphere, air. However, the speed of sound varies from substance to substance: typically, sound travels most slowly in gases, faster in liquids, and fastest in solids. For example, while sound travels at in air, it travels at in water (almost 4.3 times a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Real Gas
Real gases are non-ideal gases whose molecules occupy space and have interactions; consequently, they do not adhere to the ideal gas law. To understand the behaviour of real gases, the following must be taken into account: * compressibility effects; *variable specific heat capacity; *van der Waals forces; *non-equilibrium thermodynamic effects; *issues with molecular dissociation and elementary reactions with variable composition For most applications, such a detailed analysis is unnecessary, and the ideal gas approximation can be used with reasonable accuracy. On the other hand, real-gas models have to be used near the condensation point of gases, near critical points, at very high pressures, to explain the Joule–Thomson effect, and in other less usual cases. The deviation from ideality can be described by the compressibility factor Z. Models Van der Waals model Real gases are often modeled by taking into account their molar weight and molar volume RT = \left(p + \frac\r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Properties
In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state. Some constants, such as the ideal gas constant, , do not describe the state of a system, and so are not properties. On the other hand, some constants, such as (the freezing point depression constant, or cryoscopic constant), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties. "Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive or extensive). Regarding work and heat Work and heat are not thermodynamic properties, but rather ''process quantities:'' flows of energy across a system boundary. Systems do not ''co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Potential
In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of Thermodynamic free energy, free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial Molar concentration, molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in a wide variety of fields such as biology, neuroscience, computer science Computer science is the study of computation, information, and automation. Computer science spans Theoretical computer science, theoretical disciplines (such as algorithms, theory of computation, and information theory) to Applied science, ..., information theory and sociology. Its main purpose is to clarify the properties of matter in aggregate, in terms of physical laws governing atomic motion. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Pressure Coefficient
In thermodynamics, thermal pressure (also known as the thermal pressure coefficient) is a measure of the relative pressure change of a fluid or a solid as a response to a temperature change at constant volume. The concept is related to the Pressure-Temperature Law, also known as Amontons's law or Gay-Lussac's law. In general pressure, (P) can be written as the following sum: P_\text(V,T) = P_\text(V,T) + \Delta P_\text(V,T). P_\text is the pressure required to compress the material from its volume V_0 to volume V at a constant temperature T_0. The second term expresses the change in thermal pressure \Delta P_\text . This is the pressure change at constant volume due to the temperature difference between T_0 and T. Thus, it is the pressure change along an Isochoric process, isochore of the material. The thermal pressure \gamma_v is customarily expressed in its simple form as \gamma_v =\left( \frac \right)_. Thermodynamic definition Because of the equivalences between many proper ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coefficient Of Thermal Expansion
Thermal expansion is the tendency of matter to increase in length, area, or volume, changing its size and density, in response to an increase in temperature (usually excluding phase transitions). Substances usually contract with decreasing temperature (thermal contraction), with rare exceptions within limited temperature ranges ('' negative thermal expansion''). Temperature is a monotonic function of the average molecular kinetic energy of a substance. As energy in particles increases, they start moving faster and faster, weakening the intermolecular forces between them and therefore expanding the substance. When a substance is heated, molecules begin to vibrate and move more, usually creating more distance between themselves. The relative expansion (also called strain) divided by the change in temperature is called the material's coefficient of linear thermal expansion and generally varies with temperature. Prediction If an equation of state is available, it can be used t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Capacity Ratio
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure () to heat capacity at constant volume (). It is sometimes also known as the '' isentropic expansion factor'' and is denoted by (gamma) for an ideal gasγ first appeared in an article by the French mathematician, engineer, and physicist Siméon Denis Poisson: * On p. 332, Poisson defines γ merely as a small deviation from equilibrium which causes small variations of the equilibrium value of the density ρ. In Poisson's article of 1823 – * γ was expressed as a function of density D (p. 8) or of pressure P (p. 9). Meanwhile, in 1816 the French mathematician and physicist Pierre-Simon Laplace had found that the speed of sound depends on the ratio of the specific heats. * However, he didn't denote the ratio as γ. In 1825, Laplace stated that the speed of sound i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Course Of Theoretical Physics
The ''Course of Theoretical Physics'' is a ten-volume series of books covering theoretical physics that was initiated by Lev Landau and written in collaboration with his student Evgeny Lifshitz starting in the late 1930s. It is said that Landau composed much of the series in his head while in an NKVD prison in 1938–1939. However, almost all of the actual writing of the early volumes was done by Lifshitz, giving rise to the witticism, "not a word of Landau and not a thought of Lifshitz". The first eight volumes were finished in the 1950s, written in Russian and translated into English in the late 1950s by John Stewart Bell, together with John Bradbury Sykes, M. J. Kearsley, and W. H. Reid. The last two volumes were written in the early 1980s. and Lev Pitaevskii also contributed to the series. The series is often referred to as "Landau and Lifshitz", "Landafshitz" (Russian: "Ландафшиц"), or "Lanlifshitz" (Russian: "Ланлифшиц") in informal settings. Impact The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isentropic
An isentropic process is an idealized thermodynamic process that is both adiabatic and reversible. The work transfers of the system are frictionless, and there is no net transfer of heat or matter. Such an idealized process is useful in engineering as a model of and basis of comparison for real processes. This process is idealized because reversible processes do not occur in reality; thinking of a process as both adiabatic and reversible would show that the initial and final entropies are the same, thus, the reason it is called isentropic (entropy does not change). Thermodynamic processes are named based on the effect they would have on the system (ex. isovolumetric: constant volume, isenthalpic: constant enthalpy). Even though in reality it is not necessarily possible to carry out an isentropic process, some may be approximated as such. The word "isentropic" derives from the process being one in which the entropy of the system remains unchanged. In addition to a process wh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
