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Chrozophoridine
Chrozophoridin is a chemical used as a dye. It is derived from the plant ''Chrozophora tinctoria'' (commonly known as dyer's croton, giradol, or turnsole), which is a species native to the Mediterranean, the Middle East, India, Pakistan, and Central Asia. ''Chrozophora tinctoria'' produced the blue-purple colorant "turnsole" (also known as katasol or folium) used in medieval illuminated manuscripts and as a food colorant in Dutch cheese and certain liquors. The color comes from the plant's fruit, specifically its dry outer coat. The colorant is also obtained from the translucent sap contained in the plant cells when the leaves of the plant are broken off and exposed to the air., s.v. ''Chrozophora tinctoria'' Different shades of blue and purple may also be obtained when the juice extracts are exposed to the vapors emitted from ammonia (NH3), and which in France, during the late 19th century, was produced by applying fresh horse manure and urine to the fabric that was soaked with ...
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Chrozophora Tinctoria
''Chrozophora tinctoria'' (commonly known as dyer's croton, giradol, turnsole or dyer's litmus plant) is a plant species native to the Mediterranean, the Middle East, India, Pakistan, and Central Asia. It is also present as a weed in North America and Australia. Description It is an annual, typically found in nutrient-poor ground. It develops a large taproot. The plant is erect and covered with wool-like hairs. The ash-green leaves are alternate. The tiny monecious flowers are grouped in a raceme. The lower, female flowers lack petals and the upper male flowers have five small yellow petals. Pollination is by ants. The fruits are conspicuous and consist of three dark green conjoined spheres. Their surface is decorated with white scales and warty structures. Each sphere contains three seeds, which are propelled away from the plant by the mechanical force of the mature fruit twisting as it opens. Use for dye ''Chrozophora tinctoria'' produced the blue-purple colorant " turnsol ...
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Levant
The Levant () is an approximation, approximate historical geography, historical geographical term referring to a large area in the Eastern Mediterranean region of Western Asia. In its narrowest sense, which is in use today in archaeology and other cultural contexts, it is equivalent to a stretch of land bordering the Mediterranean in South-western Asia,Gasiorowski, Mark (2016). ''The Government and Politics of the Middle East and North Africa''. }, ), meaning "the eastern place, where the Sun rises". In the 13th and 14th centuries, the term ''levante'' was used for Italian maritime commerce in the Eastern Mediterranean, including Greece, Anatolia, Syria (region), Syria-Palestine, and Egypt, that is, the lands east of Republic of Venice, Venice. Eventually the term was restricted to the Muslim countries of Syria-Palestine and Egypt. In 1581, England set up the Levant Company to monopolize commerce with the Ottoman Empire. The name ''Levant States'' was used to refer to the Ma ...
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Methoxy Compounds
In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen. This alkoxy group has the formula . On a benzene ring, the Hammett equation classifies a methoxy substituent at the ''para'' position as an electron-donating group, but as an electron-withdrawing group if at the ''meta'' position. At the ''ortho'' position, steric effects are likely to cause a significant alteration in the Hammett equation prediction which otherwise follows the same trend as that of the ''para'' position. Occurrence The simplest of methoxy compounds are methanol and dimethyl ether. Other methoxy ethers include anisole and vanillin. Many alkoxides contain methoxy groups, e.g. tetramethyl orthosilicate and titanium methoxide. Such compounds are often classified as methoxides. Esters with a methoxy group can be referred to as methyl esters, and the —COOCH3 substituent is called a methoxycarbonyl. Biosynthesis In nature, methoxy groups are found on nucleo ...
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Dyes
A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and may require a mordant to improve the fastness of the dye on the fiber. There are two broad categories of dyes: natural and synthetic; Natural dyes are dyes extracted from plants, Insects, or minerals. The majority of natural dyes are vegetable dyes derived from plant sources such as roots, berries, bark, leaves, and wood, as well as other biological sources like fungi. Synthetic dyes are also referred to as "coal tar dyes" because they are derived from substances that, until recently, could only be extracted from coal tar. A synthetic dye consists of a chromophore and an auxochrome added to a benzene derivative. Both dyes and pigments are colored, because they absorb only some wavelengths of visible light. Dyes are usually soluble i ...
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Atropisomer
Atropisomers are stereoisomers arising because of hindered rotation about a single bond, where energy differences due to steric strain or other contributors create a barrier to rotation that is high enough to allow for isolation of individual conformers. They occur naturally and are important in pharmaceutical design. When the substituents are achiral, these conformers are enantiomers (''atropoenantiomers''), showing axial chirality; otherwise they are diastereomers (''atropodiastereomers''). Etymology and history The word ''atropisomer'' ( el, άτροπος, , meaning "without turn") was coined in application to a theoretical concept by German biochemist Richard Kuhn for Karl Freudenberg's seminal ''Stereochemie'' volume in 1933. Atropisomerism was first experimentally detected in a tetra substituted biphenyl, a diacid, by George Christie and James Kenner in 1922. Michinori Ōki further refined the definition of atropisomers taking into account the temperature-dependence ...
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Glucose
Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using energy from sunlight, where it is used to make cellulose in cell walls, the most abundant carbohydrate in the world. In energy metabolism, glucose is the most important source of energy in all organisms. Glucose for metabolism is stored as a polymer, in plants mainly as starch and amylopectin, and in animals as glycogen. Glucose circulates in the blood of animals as blood sugar. The naturally occurring form of glucose is -glucose, while -glucose is produced synthetically in comparatively small amounts and is less biologically active. Glucose is a monosaccharide containing six carbon atoms and an aldehyde group, and is therefore an aldohexose. The glucose molecule can exist in an open-chain (acyclic) as well as ring (cyclic) form. ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia i ...
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Mediterranean
The Mediterranean Sea is a sea connected to the Atlantic Ocean, surrounded by the Mediterranean Basin and almost completely enclosed by land: on the north by Western and Southern Europe and Anatolia, on the south by North Africa, and on the east by the Levant. The Sea has played a central role in the history of Western civilization. Geological evidence indicates that around 5.9 million years ago, the Mediterranean was cut off from the Atlantic and was partly or completely desiccated over a period of some 600,000 years during the Messinian salinity crisis before being refilled by the Zanclean flood about 5.3 million years ago. The Mediterranean Sea covers an area of about , representing 0.7% of the global ocean surface, but its connection to the Atlantic via the Strait of Gibraltar—the narrow strait that connects the Atlantic Ocean to the Mediterranean Sea and separates the Iberian Peninsula in Europe from Morocco in Africa—is only wide. The Mediterr ...
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Illuminated Manuscript
An illuminated manuscript is a formally prepared document where the text is often supplemented with flourishes such as borders and miniature illustrations. Often used in the Roman Catholic Church for prayers, liturgical services and psalms, the practice continued into secular texts from the 13th century onward and typically include proclamations, enrolled bills, laws, charters, inventories and deeds. While Islamic manuscripts can also be called illuminated, and use essentially the same techniques, comparable Far Eastern and Mesoamerican works are described as ''painted''. The earliest illuminated manuscripts in existence come from the Kingdom of the Ostrogoths and the Eastern Roman Empire and date from between 400 and 600 CE. Examples include the Codex Argenteus and the Rossano Gospels, both of which are from the 6th century. The majority of extant manuscripts are from the Middle Ages, although many survive from the Renaissance, along with a very limited number from Late ...
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Turnsole
Turnsole or folium was a dyestuff prepared from the annual plant ''Chrozophora tinctoria''. History Turnsole became a mainstay of medieval manuscript illuminators starting with the development of the technique for extracting it in the thirteenth century, when it joined the vegetable-based woad and indigo in the illuminator's repertory. Its use was mostly as substitute of the more expensive Tyrian purple, the famous dye obtained from Murex molluscs. However, the queen of blue colorants was always the expensive lapis lazuli or its substitute azurite, ground to the finest powders. Turnsole was downgraded to a shading glaze and fell out of use in the illuminator's palette by the turn of the seventeenth century, with the easier availability of less fugitive mineral-derived blue pigments. According to its method of preparation, turnsole produced a range of translucent colors from blue, through purple to red, depending on its reaction to the acidity or alkalinity of its environment, in a ...
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