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Cholesteryl Benzoate
Cholesteryl benzoate, also called 5-cholesten-3-yl benzoate, is an organic chemical, an ester of cholesterol and benzoic acid. It is a liquid crystal material forming cholesteric liquid crystals with helical structure. It can be used with cholesteryl nonanoate and cholesteryl oleyl carbonate in some thermochromic liquid crystals. It is used in some hair colors, make-ups, and some other cosmetic preparations. It can be also used as a component of the liquid crystals used for liquid crystal displays. Cholesteryl benzoate was the first material in which liquid crystal properties were discovered. In the late 1880s Friedrich Reinitzer, an Austrian botanist Botany, also called plant science, is the branch of natural science and biology studying plants, especially Plant anatomy, their anatomy, Plant taxonomy, taxonomy, and Plant ecology, ecology. A botanist or plant scientist is a scientist who s ..., while studying the chemicals in plants, heated cholesteryl benzoate. At 145 ...
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Organic Chemical
Some chemical authorities define an organic compound as a chemical compound that contains a Carbon–hydrogen bond, carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-containing compounds such as alkanes (e.g. methane ) and its derivatives are universally considered organic, but many others are sometimes considered Inorganic compound, inorganic, such as certain compounds of carbon with nitrogen and oxygen (e.g. cyanide ion , hydrogen cyanide , chloroformic acid , carbon dioxide , and carbonate ion ). Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e ...
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Liquid Crystal Display
A liquid-crystal display (LCD) is a flat-panel display or other Electro-optic modulator, electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers to display information. Liquid crystals do not emit light directly but instead use a backlight or Reflector (photography), reflector to produce images in color or Monochrome monitor, monochrome. LCDs are available to display arbitrary images (as in a general-purpose computer display) or fixed images with low information content, which can be displayed or hidden: preset words, digits, and seven-segment displays (as in a digital clock) are all examples of devices with these displays. They use the same basic technology, except that arbitrary images are made from a matrix of small pixels, while other displays have larger elements. LCDs are used in a wide range of applications, including LCD televisions, computer monitors, Dashboard, instrument panels, flight instrument ...
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Cholestanes
Cholestane is a Saturated and unsaturated compounds, saturated tetracyclic steroid biosynthetically derived from triterpenoids. This 27-carbon biomarker is produced by diagenesis of cholesterol and is one of the most abundant biomarkers in the rock record. Presence of cholestane, its derivatives and related chemical compounds in environmental samples is commonly interpreted as an indicator of animal life and/or traces of O2, as animals are known for exclusively producing cholesterol, and thus has been used to draw evolutionary relationships between ancient organisms of unknown phylogenetic origin and modern metazoan taxa. Cholesterol is made in low abundance by other organisms (e.g., Red algae, rhodophytes, Embryophyte, land plants), but because these other organisms produce a variety of sterols it cannot be used as a conclusive indicator of any one taxon. It is often found in analysis of organic compounds in petroleum. Background Cholestane is a Saturated and unsaturated compoun ...
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Chemical Crystallography Before X-rays
Chemical crystallography before X-rays describes how chemical crystallography developed as a science up to the discovery of X-rays by Wilhelm Conrad Röntgen in 1895. In the period before X-rays, crystallography can be divided into three broad areas: geometric crystallography culminating in the discovery of the 230 space groups in 1891–4, Physical crystallography before X-rays, physical crystallography and chemical crystallography. Up until 1800 neither crystallography nor chemistry were established sciences in the modern sense; as the 19th century progressed both sciences developed in parallel. In the 18th century chemistry was in a transitional period as it moved from the mystical and philosophical approach of the alchemists, to the experimental and logical approach of the scientific chemists such as Antoine Lavoisier, Humphry Davy and John Dalton. Before X-rays, chemical crystallographic research involved observation using a goniometer, a microscope, and reference to Crystall ...
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Otto Lehmann (physicist)
Otto Lehmann (13 January 1855 in Konstanz, Germany – 17 June 1922 in Karlsruhe) was a German physicist and "father" of liquid crystal. Life Otto was the son of Franz Xavier Lehmann, a mathematics teacher in the Baden-Wurtemberg school system, with a strong interest in microscopes. Otto learned to experiment and keep records of this findings. Between 1872 and 1877, Lehmann studied natural sciences at the University of Strassburg and obtained the Ph.D. under crystallographer Paul Groth. Otto used polarizers in a microscope so that he might watch for birefringence appearing in the process of crystallization. Initially becoming a school teacher for physics, mathematics and chemistry in Mülhausen ( Alsace-Lorraine), he started university teaching at the RWTH Aachen University in 1883. In 1889, he succeeded Heinrich Hertz as head of the Institute of Physics in Karlsruhe. Lehmann received a letter from Friedrich Reinitzer asking for confirmation of some unusual observations. As D ...
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Botanist
Botany, also called plant science, is the branch of natural science and biology studying plants, especially Plant anatomy, their anatomy, Plant taxonomy, taxonomy, and Plant ecology, ecology. A botanist or plant scientist is a scientist who specialises in this field. "Plant" and "botany" may be defined more narrowly to include only land plants and their study, which is also known as phytology. Phytologists or botanists (in the strict sense) study approximately 410,000 species of Embryophyte, land plants, including some 391,000 species of vascular plants (of which approximately 369,000 are flowering plants) and approximately 20,000 bryophytes. Botany originated as history of herbalism#Prehistory, prehistoric herbalism to identify and later cultivate plants that were edible, poisonous, and medicinal, making it one of the first endeavours of human investigation. Medieval physic gardens, often attached to Monastery, monasteries, contained plants possibly having medicinal benefit. ...
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Austria
Austria, formally the Republic of Austria, is a landlocked country in Central Europe, lying in the Eastern Alps. It is a federation of nine Federal states of Austria, states, of which the capital Vienna is the List of largest cities in Austria, most populous city and state. Austria is bordered by Germany to the northwest, the Czech Republic to the north, Slovakia to the northeast, Hungary to the east, Slovenia and Italy to the south, and Switzerland and Liechtenstein to the west. The country occupies an area of and has Austrians, a population of around 9 million. The area of today's Austria has been inhabited since at least the Paleolithic, Paleolithic period. Around 400 BC, it was inhabited by the Celts and then annexed by the Roman Empire, Romans in the late 1st century BC. Christianization in the region began in the 4th and 5th centuries, during the late Western Roman Empire, Roman period, followed by the arrival of numerous Germanic tribes during the Migration Period. A ...
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Friedrich Reinitzer
Friedrich Richard Reinitzer (25 February 1857 in Prague – 16 February 1927 in Graz) was an Austrian botanist and chemist. In late 1880s, experimenting with cholesteryl benzoate, he discovered properties of liquid crystals (named later by Otto Lehmann). Reinitzer was born into a German Bohemian family in Prague. He studied chemistry at the German technical university in Prague; in 1883 he was habilitated there as a private docent. From 1888-1901 he was a professor at Karl-Ferdinands-Universität, then professor at technical university in Graz. During 1909 - 1910 he served as the rector of the university. While at Karl-Ferdinands-Universität in 1888 he discovered a strange behaviour of what would later be called liquid crystals. For the explanation of their behaviour he collaborated with the physicist Otto Lehmann from Aachen. The discovery received plenty of attention at the time but no practical uses were apparent and the interest dropped soon. Selected works * F. Reini ...
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National Library Of Medicine
The United States National Library of Medicine (NLM), operated by the United States federal government, is the world's largest medical library. Located in Bethesda, Maryland, the NLM is an institute within the National Institutes of Health. Its collections include more than seven million books, journals, technical reports, manuscripts, microfilms, photographs, and images on medicine and related sciences, including some of the world's oldest and rarest works. the acting director of the NLM was Stephen Sherry. History The precursor of the National Library of Medicine, established in 1836, was the Library of the Surgeon General's Office, a part of the office of the Surgeon General of the United States Army. The Armed Forces Institute of Pathology and its Medical Museum were founded in 1862 as the Army Medical Museum. Throughout their history the Library of the Surgeon General's Office and the Army Medical Museum often shared quarters. From 1866 to 1887, they were ho ...
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Ester
In chemistry, an ester is a compound derived from an acid (either organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group () of that acid is replaced by an organyl group (R). These compounds contain a distinctive functional group. Analogues derived from oxygen replaced by other chalcogens belong to the ester category as well. According to some authors, organyl derivatives of acidic hydrogen of other acids are esters as well (e.g. amides), but not according to the IUPAC. Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. Lactones are cyclic carboxylic esters; naturally occurring lactones are mainly 5- and 6-membered ring lactones. Lactones contribute to the aroma of fruits, butter, cheese, vegetables like celery and other foods. Esters can be formed from oxoacids (e.g. esters of acetic acid, carbonic acid ...
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Thermochromic
Thermochromism is the property of Chemical substance, substances to change color due to a change in temperature. A mood ring is an example of this property used in a consumer product although thermochromism also has more practical uses, such as baby bottles, which change to a different color when cool enough to drink, or kettles which change color when water is at or near boiling point. Thermochromism is one of several types of chromism. Organic materials Thermochromatic liquid crystals The two common approaches are based on liquid crystals and leuco dyes. Liquid crystals are used in precision applications, as their responses can be engineered to accurate temperatures, but their color range is limited by their principle of operation. Leuco dyes allow wider range of colors to be used, but their response temperatures are more difficult to set with accuracy. Some liquid crystals are capable of displaying different colors at different temperatures. This change is dependent on sele ...
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Cholesteryl Oleyl Carbonate
Cholesteryl oleyl carbonate (COC) is an organic chemical, a carbonate ester of cholesterol and oleyl alcohol with carbonic acid. It is a liquid crystal material forming cholesteric liquid crystals with helical structure. It is a transparent liquid, or a soft crystalline material with melting point around 20 °C. It can be used with cholesteryl nonanoate and cholesteryl benzoate in some thermochromic liquid crystals. It is used in some hair colors, make-ups, and some other cosmetic preparations. It can be also used as a component of the liquid crystals used for liquid crystal display A liquid-crystal display (LCD) is a flat-panel display or other Electro-optic modulator, electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers to display information. Liq ...s. References {{reflist Cholestanes Liquid crystals Carbonate esters ...
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