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Catagenesis (geology)
Catagenesis is a term used in petroleum geology to describe the cracking process which results in the conversion of organic kerogens into hydrocarbons. Theoretical reaction Catagenesis is the second stage of maturation of organic carbon on the path to becoming graphitic. This geologic process accounts for very significant changes in the biogenic materials that make up the carbonaceous sediment. During catagenesis, the temperature increases, the pressure increases, and both organic and inorganic constituents “adjust” their phase or form to compensate. The process of “lithification” begins during this stage. Generally speaking, a rise in temperature results in the volatization of unstable species or elements that are weakly attached to carbon atoms. Increased temperature and pressure also result in the cessation of biogenic processes. One way to express these changes is to look at the ratio of oxygen to carbon, or hydrogen to carbon as the sediment matures. In almost all ca ...
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Petroleum Geology
Petroleum geology is the study of the origins, occurrence, movement, accumulation, and exploration of hydrocarbon fuels. It refers to the specific set of geological disciplines that are applied to the search for hydrocarbons ( oil exploration). Sedimentary basin analysis Petroleum geology is principally concerned with the evaluation of seven key elements in sedimentary basins: * Source * Reservoir * Seal * Trap * Timing * Maturation * Migration In general, all these elements must be assessed via a limited 'window' into the subsurface world, provided by one (or possibly more) exploration wells. These wells present only a one-dimensional segment through the Earth, and the skill of inferring three-dimensional characteristics from them is one of the most fundamental in petroleum geology. Recently, the availability of inexpensive, high-quality 3D seismic data (from reflection seismology) and data from various electromagnetic geophysical techniques (such as magnetotellur ...
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Reaction Rate Constant
In chemical kinetics, a reaction rate constant or reaction rate coefficient () is a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants. For a reaction between reactants A and B to form a product C, where :A and B are reactants :C is a product :''a'', ''b'', and ''c'' are stoichiometric coefficients, the reaction rate is often found to have the form: r = k mathrmm mathrm Here is the reaction rate constant that depends on temperature, and and are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution. (For a reaction taking place at a boundary, one would use moles of A or B per unit area instead.) The exponents ''m'' and ''n'' are called partial orders of reaction and are ''not'' generally equal to the stoichiometric coefficients ''a'' and ''b''. Instead they depend on the reacti ...
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Metamorphic Reaction
A metamorphic reaction is a chemical reaction that takes place during the geological process of metamorphism wherein one assemblage of minerals is transformed into a second assemblage which is stable under the new temperature/pressure conditions resulting in the final stable state of the observed metamorphic rock. Examples include the production of talc under varied metamorphic conditions: :'' serpentine + carbon dioxide → talc + magnesite + water'' :''chlorite + quartz → kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure Polymorphism (materials science), polymorph of andalusite and sillimanite, and the presence of kyani ... + talc + water'' Polymorphic transformations Exsolution reactions Devolatilization reactions Continuous reactions Ion exchange reactions Oxidation/reduction reactions Reactions involving dissolved species Chemograp ...
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Fossil Fuel
A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geological formations. Reservoirs of such compound mixtures, such as coal, petroleum and natural gas, can be extracted and burnt as fuel for human consumption to provide energy for direct use (such as for cooking, heating or lighting), to power heat engines (such as steam or internal combustion engines) that can propel vehicles, or to generate electricity via steam turbine generators. Some fossil fuels are further refined into derivatives such as kerosene, gasoline and diesel, or converted into petrochemicals such as polyolefins ( plastics), aromatics and synthetic resins. The origin of fossil fuels is the anaerobic decomposition of buried dead organisms. The conversion from these organic materials to high-carbon fossil fuels is ty ...
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Diagenesis
Diagenesis () is the process of physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion (clay sediments), while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens. The process of diagenesis excludes surface alteration (weathering) and deep metamorphism. There is no sharp boundary between diagenesis and metamorphism, but the latter occurs at higher temperatures and pressures. Hydrothermal solutions, meteoric groundwater, rock porosity, permeability, dissolu ...
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Order Of Reaction
In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. For many reactions, the initial rate is given by a power law such as :v_0\; =\; k mathrmx mathrmy where and are the molar concentrations of the species and usually in moles per liter (molarity, ). The exponents and are the partial ''orders of reaction'' for and , respectively, and the ''overall'' reaction order is the sum of the exponents. These are often positive integers, but they may also be zero, fractional, or negative. The order of reaction is a number which quantifies the degree to which the rate of a chemical reaction depends on concentrations of the reactants. In other words, the order of reaction is the exponent to which the concentrati ...
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Drilling Mud
In geotechnical engineering, drilling fluid, also known as drilling mud, is used to aid the drilling of boreholes into the earth. Used while drilling oil well, oil and natural gas wells and on exploration drilling rigs, drilling fluids are also used for much simpler boreholes, such as water wells. The two main categories of drilling fluids are water-based muds (WBs), which can be dispersed and non-dispersed, and non-aqueous muds, usually called oil-based muds (OBs). Along with their formatives, these are used along with appropriate polymer and clay additives for drilling various oil and gas formations. Gaseous drilling fluids, typically utilizing air or natural gas, sometimes with the addition of foaming agents, can be used when downhole conditions permit. The main functions of liquid drilling fluids are to exert hydrostatic pressure to prevent formation fluids from entering into the well bore, and carrying out drill cuttings as well as suspending the drill cuttings while d ...
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Arrhenius Equation
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining the rate of chemical reactions and for calculation of Activation energy, energy of activation. Arrhenius provided a physical justification and interpretation for the formula.Keith J. Laidler, Laidler, K. J. (1987) ''Chemical Kinetics'', Third Edition, Harper & Row, p. 42 Currently, it is best seen as an empirical relationship.Kenneth Connors, Chemical Kinetics, 1990, VCH Publishers It can be used to model the temperature variation of Mass diffusivity, diffusion coefficients, population of Vacancy defect, crystal ...
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Cracking (chemistry)
In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon–carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of large hydrocarbons into smaller, more useful alkanes and alkenes. Simply put, hydrocarbon cracking is the process of breaking long-chain hydrocarbons into short ones. This process requires high temperatures. More loosely, outside the field of petroleum chemistry, the term "cracking" is used to describe any type of splitting of molecules under the influence of heat, catalysts and solvents, such as in processes of destructive distillation or pyrolysis. Fluid catalytic cracking produces a high yield of petrol and LPG, while hydrocracking is a major source of ...
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Concentration
In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', '' molar concentration'', '' number concentration'', and '' volume concentration''. The concentration can refer to any kind of chemical mixture, but most frequently refers to solutes and solvents in solutions. The molar (amount) concentration has variants, such as normal concentration and osmotic concentration. Dilution is reduction of concentration, e.g. by adding solvent to a solution. The verb to concentrate means to increase concentration, the opposite of dilute. Etymology ''Concentration-'', ''concentratio'', action or an act of coming together at a single place, bringing to a common center, was used in post-classical Latin in 1550 or earlier, similar terms attested in Italian (1589), Spanish (1589), English (1606), French (1632). Qualitative description Often in informal, non- ...
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Pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and even by industry. Further, both spellings are often used ''within'' a particular industry or country. Industries in British English-speaking countries typically use the "gauge" spelling. is the pressure relative to the ambient pressure. Various #Units, units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the International System of Units, SI unit of pressure, the Pascal (unit), pascal (Pa), for example, is one newton (unit), newton per square metre (N/m2); similarly, the Pound (force), pound-force per square inch (Pound per square inch, psi, symbol lbf/in2) is the traditional unit of pressure in the imperial units, imperial and United States customary units, US customary systems. Pressure ma ...
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