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Carbonate Minerals
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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Strontianite
Strontianite (Strontium, SrCarbon, COxygen, O3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group. Aragonite group members: aragonite (CaCO3), witherite (BaCO3), strontianite (SrCO3), cerussite (PbCO3) The ideal formula of strontianite is SrCO3, with molar mass 147.63 g, but calcium (Ca) can substitute for up to 27% of the strontium (Sr) Ion, cations, and barium (Ba) up to 3.3%. The mineral was named in 1791 for the locality, Strontian, Argyllshire, Scotland, where the element strontium had been discovered the previous year. Although good mineral specimens of strontianite are rare, strontium is a fairly common Chemical element, element, with abundance in the Crust (geology), Earth's crust of 370 parts per million by weight, 87 parts per million by Mole (unit), moles, much more common than copper with only 60 parts per million by weight, 19 by moles. Stro ...
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Azurite
Azurite or '' Azure spar''''Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0. ''(in Russian)'' is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's '' Natural History'' under the Greek name (κυανός: "deep blue," root of English cyan) and the Latin name '' caeruleum''. Copper (Cu2+) gives it its blue color. Mineralogy Azurite has the formula Cu3(CO3)2(OH)2, with the copper(II) cations linked to two different anions, carbonate and hydroxide. It is one of two relatively common basic copper(II) carbonate minerals, the other being bright green malach ...
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Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism (geometry), prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal class ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group  of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is naturally produced ...
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Barytocalcite
Barytocalcite is an anhydrous barium calcium carbonate mineral with the chemical formula Ba Ca( C O3)2. It is trimorphous with alstonite and paralstonite, that is to say the three minerals have the same formula but different structures. Baryte and quartz pseudomorphs after barytocalcite have been observed. Barytocalcite crystallizes in the monoclinic crystal system, typically as massive to druzy accumulations of transparent white to yellow to grey aggregates of slender prismatic crystals. It has a Mohs hardness of 4 and a specific gravity of 3.64 to 3.71. It was first described in 1824 for an occurrence in the Blagill Mine in North Pennines, Cumbria (Cumberland), England, and named for its composition. Structure The mineral crystallises in the monoclinic crystal system. Most sources put it in the prismatic class 2/m, with space group P21/m, but Webmin puts it in the sphenoidal class 2 with space group P21. The structure is similar to that of dolomite, but with two crysta ...
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Minrecordite
Minrecordite, CaZn(CO3)2, is a very rare mineral belonging to the Dolomite (mineral), dolomite group, the member with Ca and Zn. It was discovered, associated with dioptase, in a specimen from the Tsumeb, Tsumeb mine (Namibia), which is consequently its type locality. Its name is a tribute to ''The Mineralogical Record'' magazine, representing the collaboration between professional and amateur mineralogists. In this locality it is associated primarily with dioptase, and less frequently with duftite, calcite and malachite. It is a rare mineral, which has been found only in a few deposits in the world. In addition to the type locality, it appears in the Preguiça mine, in Moura, Portugal, Moura, Beja District, district of Beja (Portugal). References

Carbonate minerals Zinc minerals Minerals described in 1982 {{carbonate-mineral-stub ...
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Huntite
Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today the most common industrial use of huntite is as a natural mixture with hydromagnesite as a flame retardant or fire retardant additive for polymers. Discovery In 1953, a paper by George Faust announced the discovery of a new carbonate mineral found in Currant Creek, Nevada (US). Faust acknowledged that the mineral probably had been discovered previously, but it had been misidentified as impure magnesite by W. E. Ford in 1917. Faust named the new mineral "huntite" in honour of his former teacher, Walter Frederick Hunt (1882–1975), Professor of Petrology at the University of Michigan. Faust carried out analyses of the mineral, and found amongst others that in differential thermal analysis huntite showed two endothermic peaks, which could ...
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Dolomite (mineral)
Dolomite () is an anhydrous carbonate mineral composed of calcium magnesium carbonate, ideally The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite (see Dolomite (rock)). An alternative name sometimes used for the dolomitic rock type is dolostone. History As stated by Nicolas-Théodore de Saussure the mineral dolomite was probably first described by Carl Linnaeus in 1768. In 1791, it was described as a rock by the French natural history, naturalist and geologist Déodat Gratet de Dolomieu (1750–1801), first in buildings of the old city of Rome, and later as samples collected in the County_of_Tyrol, Tyrolean Alps. Nicolas-Théodore de Saussure first named the mineral (after Dolomieu) in March 1792. Properties The mineral dolomite crystallizes in the trigonal, trigonal-rhombohedral system. It forms white, tan, gray, or pink crystals. Dolomite is a double carbonate, having an alternating structural arrangement of calcium and magnesium ...
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Ankerite
Ankerite, also known as '' brown spar''礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese Academy of Sciences, 1956. — 279 p. () is a calcium, iron, magnesium, manganese carbonate mineral of the group of rhombohedral carbonates with the chemical formula . In composition it is closely related to dolomite, but differs from this in having magnesium replaced by varying amounts of iron(II) and manganese. It forms a series with dolomite and kutnohorite. Name and history It was first recognized as a distinct species by Wilhelm von Haidinger in 1825, and named for Matthias Joseph Anker (1771–1843) of Styria, an Austrian mineralogist. In 19th-century mineralogy, as well as in mining and among geologists, ankerite and its close analogues from the dolomite series were more often known by the capacious, expansive name of ″brow ...
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