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Tunable Diode Laser Absorption Spectroscopy
Tunable diode laser absorption spectroscopy (TDLAS, sometimes referred to as TDLS, TLS or TLAS) is a technique for measuring the concentration of certain species such as methane, water vapor and many more, in a gaseous mixture using tunable diode lasers and laser absorption spectrometry. The advantage of TDLAS over other techniques for concentration measurement is its ability to achieve very low detection limits (of the order of ppb). Apart from concentration, it is also possible to determine the temperature, pressure, velocity and mass flux of the gas under observation. TDLAS is by far the most common laser based absorption technique for quantitative assessments of species in gas phase. Working A basic TDLAS setup consists of a tunable diode laser light source, transmitting (i.e. beam shaping) optics, optically accessible absorbing medium, receiving optics and detector/s. The emission wavelength of the tunable diode laser, viz. VCSEL, DFB, etc., is tuned over the characteristic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it poses technical challenges due to its gaseous state under normal conditions for temperature and pressure. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane. The Earth's atmospheric methane concentration has increased by about 150% since 1750, and it accounts for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases. It has also been detected on other ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mole (unit)
The mole, symbol mol, is the unit of amount of substance in the International System of Units (SI). The quantity amount of substance is a measure of how many elementary entities of a given substance are in an object or sample. The mole is defined as containing exactly elementary entities. Depending on what the substance is, an elementary entity may be an atom, a molecule, an ion, an ion pair, or a subatomic particle such as an electron. For example, 10 moles of water (a chemical compound) and 10 moles of mercury (a chemical element), contain equal amounts of substance and the mercury contains exactly one atom for each molecule of the water, despite the two having different volumes and different masses. The number of elementary entities in one mole is known as the Avogadro number, which is the approximate number of nucleons (protons or neutrons) in one gram of ordinary matter. The previous definition of a mole was simply the number of elementary entities equal to that of 12 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scramjet
A scramjet (supersonic combustion ramjet) is a variant of a ramjet airbreathing jet engine in which combustion takes place in supersonic airflow. As in ramjets, a scramjet relies on high vehicle speed to compress the incoming air forcefully before combustion (hence ''ram''jet), but whereas a ramjet decelerates the air to subsonic velocities before combustion using shock cones, a scramjet has no shock cone and slows the airflow using shockwaves produced by its ignition source in place of a shock cone. This allows the scramjet to operate efficiently at extremely high speeds. History Before 2000 The Bell X-1 attained supersonic flight in 1947 and, by the early 1960s, rapid progress toward faster aircraft suggested that operational aircraft would be flying at "hypersonic" speeds within a few years. Except for specialized rocket research vehicles like the North American X-15 and other rocket-powered spacecraft, aircraft top speeds have remained level, generally in the range of M ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hypersonic Speed
In aerodynamics, a hypersonic speed is one that exceeds 5 times the speed of sound, often stated as starting at speeds of Mach 5 and above. The precise Mach number at which a craft can be said to be flying at hypersonic speed varies, since individual physical changes in the airflow (like molecular dissociation and ionization) occur at different speeds; these effects collectively become important around Mach 5-10. The hypersonic regime can also be alternatively defined as speeds where specific heat capacity changes with the temperature of the flow as kinetic energy of the moving object is converted into heat. Characteristics of flow While the definition of hypersonic flow can be quite vague and is generally debatable (especially due to the absence of discontinuity between supersonic and hypersonic flows), a hypersonic flow may be characterized by certain physical phenomena that can no longer be analytically discounted as in supersonic flow. The peculiarity in hypersonic flows ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Noise-Immune Cavity-Enhanced Optical-Heterodyne Molecular Spectroscopy
Noise-immune cavity-enhanced optical-heterodyne molecular spectroscopy (NICE-OHMS) is an ultra-sensitive laser-based absorption technique that utilizes laser light to assess the concentration or the amount of a species in gas phase by absorption spectrometry (AS). Principles The NICE-OHMS technique combines cavity enhanced absorption spectrometry (CEAS) for prolonged interaction length with the sample with frequency modulation (fm) spectrometry FMS for reduction of 1/f noise. By choosing the fm-modulation frequency equal to the free spectral range (FSR) of the cavity, all components of the spectral fm-triplet are transmitted through the cavity in an identical manner. Therefore, the cavity does not compromise the balance of the fm-triplet, which otherwise would give rise to fm-background signals. It also does not convert any fluctuations of the laser frequency with respect to the transmission mode of the cavity to intensity modulation, which would deteriorate the detectability by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cavity Ring-down Spectrometry
Cavity ring-down spectroscopy (CRDS) is a highly sensitive optical spectroscopic technique that enables measurement of absolute optical extinction by samples that scatter and absorb light. It has been widely used to study gaseous samples which absorb light at specific wavelengths, and in turn to determine mole fractions down to the parts per trillion level. The technique is also known as cavity ring-down laser absorption spectroscopy (CRLAS). A typical CRDS setup consists of a laser that is used to illuminate a high-finesse optical cavity, which in its simplest form consists of two highly reflective mirrors. When the laser is in resonance with a cavity mode, intensity builds up in the cavity due to constructive interference. The laser is then turned off in order to allow the measurement of the exponentially decaying light intensity leaking from the cavity. During this decay, light is reflected back and forth thousands of times between the mirrors giving an effective path length ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
White Cell (spectroscopy)
Multiple-pass or long path absorption cells are commonly used in spectroscopy to measure low-concentration components or to observe weak spectra in gases or liquids. Several important advances were made in this area beginning in the 1930s, and research into a wide range of applications continues to the present day. Functional Overview Generally the goal of this type of sample cell is to improve detection sensitivity by increasing the total optical path length that travels through a small, constant sample volume. In principle, a longer path length results in greater detection sensitivity. Focusing mirrors must be used to redirect the beam at each reflection point, resulting in the beam being restricted to a predefined space along a controlled path until it exits the optical cavity. The output of the cell is the input of an optical detector (a specialized type of transducer), which senses specific changes in the properties of the beam that occur during interaction with the test sam ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gas In Scattering Media Absorption Spectroscopy
Gas in scattering media absorption spectroscopy (GASMAS) is an optical technique for sensing and analysis of gas located within porous and highly scattering solids, e.g. powders, ceramics, wood, fruit, translucent packages, pharmaceutical tablets, foams, human paranasal sinuses etc. It was introduced in 2001 by Prof. Sune Svanberg and co-workers at Lund University (Sweden). The technique is related to conventional high-resolution laser spectroscopy for sensing and spectroscopy of gas (e.g. tunable diode laser absorption spectroscopy, TDLAS), but the fact that the gas here is "hidden" inside solid materials give rise to important differences. Basic Principles Free gases exhibit very sharp spectral features, and different gas species have their own unique spectral fingerprints. At atmospheric pressure, absorption linewidths are typically on the order of 0.1 cm−1 (i.e. ~3 GHz in optical frequency or 0.006 nm in wavelength), while solid media have dull spectral behavi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Multipass Spectroscopic Absorption Cells
Multiple-pass or long path absorption cells are commonly used in spectroscopy to measure low-concentration components or to observe weak spectra in gases or liquids. Several important advances were made in this area beginning in the 1930s, and research into a wide range of applications continues to the present day. Functional Overview Generally the goal of this type of sample cell is to improve detection sensitivity by increasing the total optical path length that travels through a small, constant sample volume. In principle, a longer path length results in greater detection sensitivity. Focusing mirrors must be used to redirect the beam at each reflection point, resulting in the beam being restricted to a predefined space along a controlled path until it exits the optical cavity. The output of the cell is the input of an optical detector (a specialized type of transducer), which senses specific changes in the properties of the beam that occur during interaction with the test sam ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pink Noise
Pink noise or noise is a signal or process with a frequency spectrum such that the power spectral density (power per frequency interval) is inversely proportional to the frequency of the signal. In pink noise, each octave interval (halving or doubling in frequency) carries an equal amount of noise energy. Pink noise sounds like a waterfall. It is often used to tune loudspeaker systems in professional audio. Pink noise is one of the most commonly observed signals in biological systems. The name arises from the pink appearance of visible light with this power spectrum. This is in contrast with white noise which has equal intensity per frequency interval. Definition Within the scientific literature, the term 1/f noise is sometimes used loosely to refer to any noise with a power spectral density of the form S(f) \propto \frac, where ''f'' is frequency, and 0 < α < 2, with exponent α usually close to 1. One-dimensional signals with α = 1 are usually called pink noise. T ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absorption Spectrometry
Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum. Absorption spectroscopy is employed as an analytical chemistry tool to determine the presence of a particular substance in a sample and, in many cases, to quantify the amount of the substance present. Infrared and ultraviolet–visible spectroscopy are particularly common in analytical applications. Absorption spectroscopy is also employed in studies of molecular and atomic physics, astronomical spectroscopy and remote sensing. There is a wide range of experimental approaches for measuring absorption spectra. The most common arrangement is to dire ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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