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Surface Science
Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid– liquid interfaces, solid– gas interfaces, solid–vacuum interfaces, and liquid– gas interfaces. It includes the fields of '' surface chemistry'' and ''surface physics''. Some related practical applications are classed as surface engineering. The science encompasses concepts such as heterogeneous catalysis, semiconductor device fabrication, fuel cells, self-assembled monolayers, and adhesives. Surface science is closely related to interface and colloid science. Interfacial chemistry and physics are common subjects for both. The methods are different. In addition, interface and colloid science studies macroscopic phenomena that occur in heterogeneous systems due to peculiarities of interfaces. History The field of surface chemistry started with heterogeneous catalysis pioneered by Paul Sabatier on hydrogenation and Fritz Haber on the H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Macroscopic
The macroscopic scale is the length scale on which objects or phenomena are large enough to be visible with the naked eye, without magnifying optical instruments. It is the opposite of microscopic. Overview When applied to physical phenomena and bodies, the macroscopic scale describes things as a person can directly perceive them, without the aid of magnifying devices. This is in contrast to observations (microscopy) or theories ( microphysics, statistical physics) of objects of geometric lengths smaller than perhaps some hundreds of micrometers. A macroscopic view of a ball is just that: a ball. A microscopic view could reveal a thick round skin seemingly composed entirely of puckered cracks and fissures (as viewed through a microscope) or, further down in scale, a collection of molecules in a roughly spherical shape (as viewed through an electron microscope). An example of a physical theory that takes a deliberately macroscopic viewpoint is thermodynamics. An example of a top ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Low-energy Electron Diffraction
Low-energy electron diffraction (LEED) is a technique for the determination of the surface structure of single-crystalline materials by bombardment with a collimated beam of low-energy electrons (30–200 eV) and observation of diffracted electrons as spots on a fluorescent screen. LEED may be used in one of two ways: # Qualitatively, where the diffraction pattern is recorded and analysis of the spot positions gives information on the symmetry of the surface structure. In the presence of an adsorbate the qualitative analysis may reveal information about the size and rotational alignment of the adsorbate unit cell with respect to the substrate unit cell. # Quantitatively, where the intensities of diffracted beams are recorded as a function of incident electron beam energy to generate the so-called I–V curves. By comparison with theoretical curves, these may provide accurate information on atomic positions on the surface at hand. Historical perspective An electron-diffractio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Palladium
Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself named after the epithet of the Greek goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them. More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust ( hydrocarbons, carbon monoxide, and nitrogen dioxide) into nontoxic substances ( nitrogen, carbon dioxide and water vapor). Palladium is also used in electronics, dentistry, medicine, hydrogen purification, chemical applic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gerhard Ertl
Gerhard Ertl (; born 10 October 1936) is a German physicist and a Professor emeritus at the Department of Physical Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft in Berlin, Germany. Ertl's research laid the foundation of modern surface chemistry, which has helped explain how fuel cells produce energy without pollution, how catalytic converters clean up car exhausts and even why iron rusts, the Royal Swedish Academy of Sciences said. His work has paved the way for development of cleaner energy sources and will guide the development of fuel cells, said Astrid Graslund, secretary of the Nobel Committee for Chemistry. He was awarded the 2007 Nobel Prize in Chemistry for his studies of chemical processes on solid surfaces. The Nobel academy said Ertl provided a detailed description of how chemical reactions take place on surfaces. His findings applied in both academic studies and industrial development, the academy said. “Surface chemistry can even explain the destru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Langmuir Equation
The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes. This model even explains the effect of pressure i.e at these conditions the adsorbate's partial pressure, p_A, is related to the volume of it, , adsorbed onto a solid adsorbent. The adsorbent, as indicated in the figure, is assumed to be an ideal solid surface composed of a series of distinct sites capable of binding the adsorbate. The adsorbate binding is treated as a chemical reaction between the adsorbate gaseous molecule A_\text and an empty sorption site, . This reaction yields an adsorbed species A_\text with an associated equilibrium constant K_\text: : A_ + S A_ From these basic hypotheses the mathematical formulation of the Langmuir adsorption isotherm can be derived in various independent and complementary ways: by the kinetics, the thermodynamics, and the statistical me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Langmuir (journal)
''Langmuir'' is a peer-reviewed scientific journal that was established in 1985 and is published by the American Chemical Society. It is the leading journal focusing on the science and application of systems and materials in which the interface dominates structure and function. Research areas covered include surface and colloid chemistry. The total number of citations in 2021 is 129,693 and the 2021 Impact Factor is 4.331. Langmuir publishes original research articles, invited feature articles, perspectives, and editorials. The title honors Irving Langmuir, winner of the 1932 Nobel Prize for Chemistry. The founding editor-in-chief was Arthur W. Adamson. Abstracting and indexing ''Langmuir'' is indexed in Chemical Abstracts Service, Scopus, EBSCOhost, British Library, PubMed PubMed is a free search engine accessing primarily the MEDLINE database of references and abstracts on life sciences and biomedical topics. The United States National Library of Medicine (NLM) a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Irving Langmuir
Irving Langmuir (; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry. Langmuir's most famous publication is the 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure". Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuir's presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at General Electric from 1909 to 1950, Langmuir advanced several fields of physics and chemistry, inventing the gas-filled incandescent lamp and the hydrogen welding technique. The Langmuir Laboratory for Atmospheric Research near Socorro, New Mexico, was named in his honor, as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Haber Process
The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation process and is the main industrial procedure for the production of ammonia today. It is named after its inventors, the German chemists Fritz Haber and Carl Bosch, who developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using a metal catalyst under high temperatures and pressures: : \ce \quad \Delta H^\circ = -91.8~\text Though this reaction is exothermic (i.e. it releases energy, albeit not very much), it results in a decrease in entropy, which is the central reason why it is very challenging to carry out. Before the development of the Haber process, it had been difficult to produce ammonia on an industrial scale, with early methods, such as the Birkeland–Eyde process and the Frank–Caro process, all highly inefficient. During World War I, the Haber process provided Germany with a s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fritz Haber
Fritz Haber (; 9 December 186829 January 1934) was a German chemist who received the Nobel Prize in Chemistry in 1918 for his invention of the Haber–Bosch process, a method used in industry to synthesize ammonia from nitrogen gas and hydrogen gas. This invention is important for the large-scale synthesis of fertilisers and explosives. It is estimated that one-third of annual global food production uses ammonia from the Haber–Bosch process, and that this supports nearly half of the world's population. Haber, along with Max Born, proposed the Born–Haber cycle as a method for evaluating the lattice energy of an ionic solid. Haber, a known German nationalist, is also considered the "father of chemical warfare" for his years of pioneering work developing and weaponising chlorine and other poisonous gases during World War I, especially his actions during the Second Battle of Ypres. His work was later also used to develop Zyklon B, used for the murder of more than 1 million of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogenation
Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate organic compounds. Hydrogenation typically constitutes the addition of pairs of hydrogen atoms to a molecule, often an alkene. Catalysts are required for the reaction to be usable; non-catalytic hydrogenation takes place only at very high temperatures. Hydrogenation reduces double and triple bonds in hydrocarbons. Process Hydrogenation has three components, the unsaturated substrate, the hydrogen (or hydrogen source) and, invariably, a catalyst. The reduction reaction is carried out at different temperatures and pressures depending upon the substrate and the activity of the catalyst. Related or competing reactions The same catalysts and conditions that are used for hydrogenation reactions can also lead to isomerization of the alkenes from c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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