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Superhydrophilicity
Superhydrophilicity refers to the phenomenon of excess hydrophilicity, or attraction to water; in superhydrophilic materials, the contact angle of water is equal to zero degrees. This effect was discovered in 1995 by the Research Institute of Toto Ltd. for titanium dioxide irradiated by sunlight. Under light irradiation, water dropped onto titanium dioxide forms no contact angle (almost 0 degrees). Superhydrophilic material has various advantages. For example, it can defog glass, and it can also enable oil spots to be swept away easily with water. Such materials are already commercialized as door mirrors for cars, coatings for buildings, self-cleaning glass, etc. Several mechanisms of this superhydrophilicity have been proposed by researchers. One is the change of the surface structure to a metastable structure, and another is cleaning the surface by the photodecomposition of dirt such as organic compounds adsorbed Adsorption is the adhesion of atoms, ions or molecules from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superhydrophobicity
Ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing. Theory In 1805, Thomas Young defined the contact angle ''θ'' by analysing the forces acting on a fluid droplet resting on a smooth solid surface surrounded by a gas. :\gamma_\ =\gamma_+\gamma_\cos where :\gamma_\ = Interfacial tension between the solid and gas :\gamma_\ = Interfacial tension between the solid and liquid :\gamma_\ = Interfacial tension between the liquid and gas ''θ'' can be measured using a contact angle goniometer. Wenz ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titanium Dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insoluble to water, although mineral forms can appear black. As a pigment, it has a wide range of applications, including paint, sunscreen, and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million tonnes. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide have been valued at a price of $13.2 billion. Structure In all three of its main dioxides, titanium exhibits octahedral geometry, being bonded to six oxide anions. The oxides in turn are bonded to three Ti centers. The overall crystal structure of rutile is tetragonal in symmetry whereas anatase and brookite are orthorhombic. The oxygen substructures are all slight dist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrophilicity
A hydrophile is a molecule or other molecular entity that is attracted to water molecules and tends to be dissolved by water.Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon'' Oxford: Clarendon Press. In contrast, hydrophobes are not attracted to water and may seem to be repelled by it. Hygroscopics ''are'' attracted to water, but are not dissolved by water. Molecules A hydrophilic molecule or portion of a molecule is one whose interactions with water and other polar substances are more thermodynamically favorable than their interactions with oil or other hydrophobic solvents. They are typically charge-polarized and capable of hydrogen bonding. This makes these molecules soluble not only in water but also in other polar solvents. Hydrophilic molecules (and portions of molecules) can be contrasted with hydrophobic molecules (and portions of molecules). In some cases, both hydrophilic and hydrophobic properties occur in a single molecule. An example of these amphiphi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Toto Ltd
Toto may refer to: Arts and entertainment Fictional characters Pets * Toto (''Oz''), a dog in the novel and film ''The Wonderful Wizard of Oz'' * Toto, in Japanese ''The Cat Returns'' Characters of agency * a character in '' Le château à Toto'' (Toto’s castle), 1868 opéra bouffe * the title character of '' Princess Toto'', 1876 comic opera by W. S. Gilbert and Frederic Clay * the title character of ''Toto of Arabia'', 1965 Italian-Spanish adventure-comedy film * Toto, the main character of '' Toto Forever'', 2010 short film * Toto, a Gamera character from ''Gamera the Brave'' * Toto, the main character in ''Stories Toto Told Me'' and ''In His Own Image'' by Frederick Rolfe Other uses in arts and entertainment * ''Toto'' (1933 film), a 1933 French film directed by Jacques Tourneur * Toto (band) ** ''Toto'' (album), their debut album * '' Toto!: The Wonderful Adventure'', Japanese manga series Gaming and gambling * Football pools, called "toto" in several languages * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sunlight
Sunlight is a portion of the electromagnetic radiation given off by the Sun, in particular infrared, visible, and ultraviolet light. On Earth, sunlight is scattered and filtered through Earth's atmosphere, and is obvious as daylight when the Sun is above the horizon. When direct solar radiation is not blocked by clouds, it is experienced as sunshine, a combination of bright light and radiant heat. When blocked by clouds or reflected off other objects, sunlight is diffused. Sources estimate a global average of between 164 watts to 340 watts per square meter over a 24-hour day; this figure is estimated by NASA to be about a quarter of Earth's average total solar irradiance. The ultraviolet radiation in sunlight has both positive and negative health effects, as it is both a requisite for vitamin D3 synthesis and a mutagen. Sunlight takes about 8.3 minutes to reach Earth from the surface of the Sun. A photon starting at the center of the Sun and changing direction ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Self-cleaning Glass
Self-cleaning glass is a specific type of glass with a surface that keeps itself free of dirt and grime. The field of self-cleaning coatings on glass is divided into two categories: hydrophobic and hydrophilic. These two types of coating both clean themselves through the action of water, the former by rolling droplets and the latter by sheeting water that carries away dirt. Hydrophilic coatings based on titania (titanium dioxide), however, have an additional property: they can chemically break down absorbed dirt in sunlight. The requirements for a self-cleaning hydrophobic surface are a very high static water contact angle θ, the condition often quoted is θ>160°, and a very low roll-off angle, i.e. the minimum inclination angle necessary for a droplet to roll off the surface. Self-cleaning surfaces Several techniques are known for the patterning of hydrophobic surfaces through the use of moulded polymers and waxes, by physical processing methods such as ion etching and compre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metastability
In chemistry and physics, metastability denotes an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is only slightly pushed, it will settle back into its hollow, but a stronger push may start the ball rolling down the slope. Bowling pins show similar metastability by either merely wobbling for a moment or tipping over completely. A common example of metastability in science is isomerisation. Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by (possibly large) barriers in the potential energy. During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values. In isolation: *the state of least energy is the only one the system will inhabit for an indefinite length of time, until more external energy is added to the system (unique "ab ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photodecomposition
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by photons. It is defined as the interaction of one or more photons with one target molecule. Photodissociation is not limited to visible light. Any photon with sufficient energy can affect the chemical bonds of a chemical compound. Since a photon's energy is inversely proportional to its wavelength, electromagnetic radiations with the energy of visible light or higher, such as ultraviolet light, x-rays, and gamma rays can induce such reactions. Photolysis in photosynthesis Photolysis is part of the light-dependent reaction or light phase or photochemical phase or Hill reaction of photosynthesis. The general reaction of photosynthetic photolysis can be given in terms of photons as: :\ce + 2 \text \longrightarrow \ce The chemical nature of "A" depends on the type of organism. Purple sulfur bacteria oxidize hydrogen sulfide ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Liv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adsorption
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). Adsorption is a '' surface phenomenon'', while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term '' sorption'' encompasses both processes, while '' desorption'' is the reverse of it. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Properties
A chemical property is any of a material's properties that becomes evident during, or after, a chemical reaction; that is, any quality that can be established only by changing a substance's chemical identity.William L. Masterton, Cecile N. Hurley, "Chemistry: Principles and Reactions", 6th edition. Brooks/Cole Cengage Learning, 2009, p.1(Google books)/ref> Simply speaking, chemical properties cannot be determined just by viewing or touching the substance; the substance's internal structure must be affected greatly for its chemical properties to be investigated. When a substance goes under a chemical reaction, the properties will change drastically, resulting in chemical change. However, a catalytic property would also be a chemical property. Chemical properties can be contrasted with physical properties, which can be discerned without changing the substance's structure. However, for many properties within the scope of physical chemistry, and other disciplines at the boundary betwe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
