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Superhydrophobicity
Ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing. Theory In 1805, Thomas Young defined the contact angle ''θ'' by analysing the forces acting on a fluid droplet resting on a smooth solid surface surrounded by a gas. :\gamma_\ =\gamma_+\gamma_\cos where :\gamma_\ = Interfacial tension between the solid and gas :\gamma_\ = Interfacial tension between the solid and liquid :\gamma_\ = Interfacial tension between the liquid and gas ''θ'' can be measured using a contact angle goniometer. Wenz ...
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Nelumbo
''Nelumbo'' is a genus of aquatic plants with large, showy flowers. Members are commonly called lotus, though the name is also applied to various other plants and plant groups, including the unrelated genus '' Lotus''. Members outwardly resemble those in the family Nymphaeaceae ("water lilies"), but ''Nelumbo'' is actually very distant to that family. There are only two known living species of lotus; ''Nelumbo nucifera'' is native to East Asia, South Asia, Southeast Asia and probably Australia, and is better-known. It is commonly cultivated; it is eaten and used in traditional Chinese medicine. The other lotus is '' Nelumbo lutea'', which is native to North America and the Caribbean. Horticultural hybrids have been produced between these two allopatric species. Description Ultrahydrophobicity The leaves of ''Nelumbo'' are highly water-repellent (i.e. they exhibit ultrahydrophobicity) and have given the name to what is called the lotus effect. Ultrahydrophobicity invol ...
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Hydrophobic
In chemistry, hydrophobicity is the physical property of a molecule that is seemingly repelled from a mass of water (known as a hydrophobe). In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to be nonpolar and, thus, prefer other neutral molecules and nonpolar solvents. Because water molecules are polar, hydrophobes do not dissolve well among them. Hydrophobic molecules in water often cluster together, forming micelles. Water on hydrophobic surfaces will exhibit a high contact angle. Examples of hydrophobic molecules include the alkanes, oils, fats, and greasy substances in general. Hydrophobic materials are used for oil removal from water, the management of oil spills, and chemical separation processes to remove non-polar substances from polar compounds. Hydrophobic is often used interchangeably with lipophilic, "fat-loving". However, the two terms are not synonymous. While hydrophobic substances are usually lipophilic, there are excepti ...
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Cassie's Law
Cassie's law, or the Cassie equation, describes the effective contact angle Theta, θc for a liquid on a chemically heterogeneous surface, i.e. the surface of a composite material consisting of different chemistries, that is non uniform throughout. Contact angles are important as they quantify a surface's Wetting, wettability, the nature of solid-fluid intermolecular interactions. Cassie's law is reserved for when a liquid completely covers both ''smooth'' and ''rough'' heterogeneous surfaces. More of a rule than a law, the formula found in literature for two materials is; \cos \theta_c = \sigma_1 \cos \theta_1 + \sigma_2 \cos \theta_2 where \theta_1and \theta_2 are the contact angles for components 1 with fractional surface area \sigma_1, and 2 with fractional surface area \sigma_2 in the composite material respectively. If there exist more than two materials then the equation is scaled to the general form of; \cos \theta_ =\sum_^N \sigma_k \cos \theta_k , with \sum_^N \sigma_k ...
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Planta (journal)
''Planta'' is a monthly peer-reviewed scientific journal covering all areas of botany. It was established in 1925 and is published by Springer Science+Business Media. The editors-in-chief are Anastasios Melis (UC-Berkeley) and Dorothea Bartels ( Universitat Bonn). According to the ''Journal Citation Reports'', the journal has a 2012 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as ... of 3.347. References External links * Botany journals Publications established in 1925 Springer Science+Business Media academic journals Monthly journals English-language journals {{botany-journal-stub ...
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Cutting A Water Droplet Using A Superhydrophobic Knife On Superhydrophobic Surfaces
Cutting is the separation or opening of a physical object, into two or more portions, through the application of an acutely directed force. Implements commonly used for cutting are the knife and saw, or in medicine and science the scalpel and microtome. However, any sufficiently sharp object is capable of cutting if it has a hardness sufficiently larger than the object being cut, and if it is applied with sufficient force. Even liquids can be used to cut things when applied with sufficient force (see water jet cutter). Cutting is a compressive and shearing phenomenon, and occurs only when the total stress generated by the cutting implement exceeds the ultimate strength of the material of the object being cut. The simplest applicable equation is: \text = or \tau=\frac The stress generated by a cutting implement is directly proportional to the force with which it is applied, and inversely proportional to the area of contact. Hence, the smaller the area (i.e., the sharper ...
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Nanotechnology
Nanotechnology, also shortened to nanotech, is the use of matter on an atomic, molecular, and supramolecular scale for industrial purposes. The earliest, widespread description of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabrication of macroscale products, also now referred to as molecular nanotechnology. A more generalized description of nanotechnology was subsequently established by the National Nanotechnology Initiative, which defined nanotechnology as the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). This definition reflects the fact that quantum mechanical effects are important at this quantum-realm scale, and so the definition shifted from a particular technological goal to a research category inclusive of all types of research and technologies that deal with the special properties of matter which occur below the given size threshold. It is therefore commo ...
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Electrowetting
Electrowetting is the modification of the wetting properties of a surface (which is typically hydrophobic) with an applied electric field. History The electrowetting of mercury and other liquids on variably charged surfaces was probably first explained by Gabriel Lippmann in 1875 and was certainly observed much earlier. A. N. Frumkin used surface charge to change the shape of water drops in 1936. The term electrowetting was first introduced in 1981 by G. Beni and S. Hackwood to describe an effect proposed for designing a new type of display device for which they received a patent. The use of a "fluid transistor" in microfluidic circuits for manipulating chemical and biological fluids was first investigated by J. Brown in 1980 and later funded in 1984–1988 under NSF Grants 8760730 & 8822197, employing insulating dielectric and hydrophobic layer(s) (EWOD), immiscible fluids, DC or RF power; and mass arrays of miniature interleaved (saw tooth) electrodes with large or matching Ind ...
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Langmuir (journal)
''Langmuir'' is a peer-reviewed scientific journal that was established in 1985 and is published by the American Chemical Society. It is the leading journal focusing on the science and application of systems and materials in which the interface dominates structure and function. Research areas covered include surface and colloid chemistry. The total number of citations in 2021 is 129,693 and the 2021 Impact Factor is 4.331. Langmuir publishes original research articles, invited feature articles, perspectives, and editorials. The title honors Irving Langmuir, winner of the 1932 Nobel Prize for Chemistry. The founding editor-in-chief was Arthur W. Adamson. Abstracting and indexing ''Langmuir'' is indexed in Chemical Abstracts Service, Scopus, EBSCOhost, British Library, PubMed PubMed is a free search engine accessing primarily the MEDLINE database of references and abstracts on life sciences and biomedical topics. The United States National Library of Medicine (NLM) a ...
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Dimer (chemistry)
A dimer () ('' di-'', "two" + ''-mer'', "parts") is an oligomer consisting of two monomers joined by bonds that can be either strong or weak, covalent or intermolecular. Dimers also have significant implications in polymer chemistry, inorganic chemistry, and biochemistry. The term ''homodimer'' is used when the two molecules are identical (e.g. A–A) and ''heterodimer'' when they are not (e.g. A–B). The reverse of dimerization is often called dissociation. When two oppositely charged ions associate into dimers, they are referred to as ''Bjerrum pairs'', after Niels Bjerrum. Noncovalent dimers Anhydrous carboxylic acids form dimers by hydrogen bonding of the acidic hydrogen and the carbonyl oxygen. For example, acetic acid forms a dimer in the gas phase, where the monomer units are held together by hydrogen bonds. Under special conditions, most OH-containing molecules form dimers, e.g. the water dimer. Excimers and exciplexes are excited structures with a short lif ...
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Insect
Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body ( head, thorax and abdomen), three pairs of jointed legs, compound eyes and one pair of antennae. Their blood is not totally contained in vessels; some circulates in an open cavity known as the haemocoel. Insects are the most diverse group of animals; they include more than a million described species and represent more than half of all known living organisms. The total number of extant species is estimated at between six and ten million; In: potentially over 90% of the animal life forms on Earth are insects. Insects may be found in nearly all environments, although only a small number of species reside in the oceans, which are dominated by another arthropod group, crustaceans, which recent research has indicated insects are nested within. Nearly all insects hatch from ...
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